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The Direct and Indirect Effects of the Reagent Suite on Froth Stability in Laboratory Scale Batch Flotation Tests

Sep 13, 2010

By S. Ramachandran, N. J. Grant, T. B. King

MANY investigations of the rate of the sulfur transfer reaction between carbon-saturated iron and blast furnace type slags have been made." It is evident that the reaction is complex, the rate being affected by the presence of elements dissolved in the metal that are readily oxidized and therefore capable of existing in the slag phase. Thus Goldman, Derge, and Philbrook- have shown that carbon, silicon, manganese, and aluminum, in order of increasing effectiveness, accelerate sulfur transfer from iron containing these elements to blast furnace type slags. Quantitative information is still, however, not available on the relation between what have been termed side reactions, such as silicon transfer and CO evolution, and the sulfur transfer reaction itself. In other words, the stoichiometry of the reaction has not been investigated. In the present investigation, the transfer of all reacting elements and the evolution of CO have been measured simultaneously in order to establish the mechanism of the reaction which occurs in practice. Information of this nature cannot be deduced from equilibrium studies. It should be pointed out that in kinetic studies of this type quantitative conclusions are applicable only to the system studied. This restriction should be borne in mind when attempts are made to compare results from different investigations. Apparatus The apparatus used enables slag and metal samples to be taken at frequent intervals and also provides a continuous record of the amount of gas evolved. A sketch of the apparatus is given in Fig. 1. It may be considered in three sections: 1) furnace section, 2) blank volume section, and 3) pressure measuring section. The furnace section is shown in detail in Fig. 2. It consists of two graphite crucibles, C and D, super-

Jan 1, 1957

By P D. Katsabanis

According to Persson(1) steady state detonation along a cylindrical charge can be regarded as a self propagating process in which the axial compressive effect of the shock front discontinuity changes the state of the explosive so that exothermic reaction sets in with the requisite velocity.

Jan 1, 1990

By A. Berry, N. R. Banerjee, C. S. Finnigan, M. Fayek, N. J. Bridge

Lac Cinquante is a mineralogically simple, vein-hosted uranium deposit in Archean basement rocks (Angikuni greenstone belt) that originally were unconformably overlain by Proterozoic sedimentary and volcanic rocks of the Baker Lake Group (BLG). Basement rocks are mainly pillowed and massive tholeiitic lavas (N-MORB) with interbedded tuff; overlying sedimentary rocks comprise a basal talus/fault breccia that grades upward into fluvial sedimentary rocks and subaerial, trachytic volcanic rocks; granite and porphyry dikes (Hudson and/or Nueltin granitoids) intrude the basement rocks. A typical section through the Main Zone comprises 1) laminated ‘tuff’, 2) altered (carbonate-hematite-chlorite) schistose ‘tuff’, 3) a pitchblende-bearing, breccia-vein, 4) altered ‘tuff’, and 5) laminated ‘tuff’. The vein comprises brecciated chlorite, hematite, and pitchblende with carbonate cementing the breccia. Graphitic ‘tuff’ with sulfide-stringer veinlets locally overlies or underlies the vein. Pitchblende also occurs in the altered rocks and in gash veins that cut basement rocks. U-Pb ages on pitchblende fall into two groups: one at 1828 } 29 Ma reflects primary uranium mineralization, and a second at 1437 } 31 Ma represents resetting. Pb-Pb chemical ages show other resetting events at 1260-1321Ma, 895 Ma, 741-813 Ma, and 660-706 Ma. One possible genetic model for the Lac Cinquante deposit involves leaching of uranium from granitoids and the BLG by basinal brines that migrated to depositional sites where graphitic rocks acted as a reductant. A second model requires that uranium was sole-sourced from the BLG and that granitoid rocks provided heat to drive the hydrothermal system, which leached and ultimately precipitated uranium. The deposit has characteristics similar to vein-type uranium deposits in the Beaverlodge District of Saskatchewan

Jan 1, 2013

By K. Morin

"Silver and gold leaching by cyanidation is a well-known process used around the world. This reaction is often accompanied by the leaching of other species throughtout the cyanidation circuit that causes the diversion of cyanide towards non valuable by-products (SCN-, Cu(CN)x, Fe(CN)x, etc.). One of the detrimental impacts of the formation of these by-products is the precipitation of silver-cyanide complexes that occurs when cyanide concentration is too low. Without any extra-addition of free cyanide, the precipitated silver is lost and cannot be recovered causing an important economic loss. To overcome silver precipitation, cyanidation circuits are often operated at higher cyanide concentrations. Recently, COREM’s research team has been working on a technology to measure and control silver precipitation during the cyanidation process. Moreover, a methodology has been elaborated in order to evaluate threshold cyanide level which corresponds to the cyanide concentration at which silver starts to precipitate. This technology has been tested on site on a real cyanidation circuit at Agnico Eagle’s LaRonde mine."

Jan 1, 2014

By J. L. Wiley

THIS REVIEW contains abstracts of the technical literature and patents dealing with the history, development, and commercial application of the Bergius and related processes for the hydrogenation, under greater than atmospheric pressures, of liquid and solid carbonaceous materials such as coal, lignite, their distillation and extraction products, pitches and tars, and petroleum and its distillation residues. An attempt has been made to include abstracts of all the published information on this process and of as much of the captured foreign documents and reports compiled therefrom as could consistently be reviewed during the time allotted for the work. Contact with the current literature and patents and review of the foreign documents will be continued and the information will appear in Synthetic Liquid Fuels Abstracts, which is being issued bimonthly as a Bureau of Mines publication. The material in this review is divided in two sections-literature (part I) and patents (part II)-and each of these is arranged alphabetically by author or patentee with further chronological arrangement under each author or group of authors. Secondary authors and patentees as well as assignees are cross-indexed to the main entry. In serial articles or reports the complete series appears in the alphabetical arrangement according to the author of the first member of the series. Succeeding members as well as secondary authors are entered as cross references; Titles of the journals are used as the authors in anonymous references. By following such a procedure, an author index is not required. However, a detailed subject index and a numerical patent list by countries are given as part III.

Jan 1, 1950

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and therate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By Jon R. Maki

"EVTAC, an iron ore mine in Minnesota, had trouble meeting the customer’s pellet silica requirements. In addition, the mine plan was moving towards a lower grade ore and funding was not available for plant improvements to compensate for the change in ore or improving quality. Small changes to optimize various processing equipment resulted in significant improvements in both quality and productivity; for example, productivity on one mill line increased by 10% while producing lower silica concentrate. This paper will provide the methodology that allowed EVTAC to improve quality and productivity through process optimization with little capital investment.INTRODUCTION EVTAC, an iron ore mine in Minnesota, had trouble meeting the customer pellet silica requirements. In addition, the short-term mine plan was changing to a lower ore grade. Because of limited funds, EVTAC did not have the capital for investing in the plant to compensate for the ore change or to make improvements to lower product silica levels. Small changes to optimize process equipment resulted in significant improvements in quality and productivity; for example, one mill line feed rates increased by 10% while also producing a higher quality concentrate. These changes were sufficient enough to allow the mine to lower the target ore grade beyond their initial goal. At one time, a $3M flotation facility was considered as a way to meet quality with the new ore grade. However, the process changes were able to accomplish the same silica reduction with roughly a $50,000 investment in VFDs for sump controls. This paper will discuss some of the modifications that allowed EVTAC to meet the quality and production objectives with little capital investment. It also discusses the methodology used to make these process improvements."

Jan 1, 2014

By Botelho Junior, Amilton Barbosa, Denise C. R. Espinosa, David B. Dreisinger

Copper and cobalt can be found on nickel laterite ores, and cobalt can be found also on copper ores, and many contaminants such as iron, aluminum, and magnesium are associated with these ores. In hydrometallurgical process, a purification step is necessary after leaching due to the presence of these impurities. Chelating resins are more selective for some metals than others, making them more efficient than cationic resins. This overview discusses chelating resin applications to recover copper, nickel, and cobalt from mining process and mining tailings and the effect of contaminants in leach solution. Chelating resins with iminodiacetate functional group can be used for selective copper recovery, and both iminodiacetate and bis-picolylamine resins are highly selective for nickel and cobalt. Chelating resins with the same functional group can have different performances on the kinetics of loading, because of variations of structure, the density of functional group, and degree of cross-linking. This article reviews commercial chelating resins that can be applied in leach solutions with different compositions, and also possible innovations for uses of chelating resins to recover metals from mining process and mining tailings.

By Philip C. Tully

This bibliography contains 2,072 citations to technical and scientific literature about helium and alpha-particles abstracted by 12 abstract service publications during 1962. Citations are listed by 16 major subject classifications with several subclassifications to minimize areas of literature search. Automatic data processing was used to reduce the time and labor required to compile the bibliography.

Jan 1, 1969

By Y. M. Jiang

A users friendly PC Computer Program has been developed to implement a systematic design of the powered support. The required input data are: (1) thickness, RQD, and compressive strength of the immediate roof; (2) mining height; and (3) type, thickness, and tensile strength of the main roof. Several important parameters for support selection under a given geological condition are generated through the implementation of the program, including type of support most favorable for the geologic condition, minimum inclination angle of the legs with respect to the horizontal axis, suitable setting load ratio of the front to rear leg for the 4-leg supports, optimum setting load, and support capacity.

Jan 1, 1989

By Daniel Harrington

On the night of June 8, 1917, the flame of a carbide lamp accidentally set fire to the uncovered and frayed insulation of an armored power cable near the 2,400-foot level of the North Butte Mining Co.'s Granite Mountain shaft. How this insulation accidentally became exposed is explained on page 15. The highly flammable oiled fabric set fire to the shaft timbers, and as this is a downcast shaft the fire spread with great rapidity, soon filling the mine workings with smoke and gas. At the time 410 men were working underground, 247 of whom escaped by various means, but most of the 163 remaining were probably overcome soon after the lire started, and perished. Only two men were actually burned. The cause of the disaster was purely accidental. The immediate effect was the unexpected reversal of normal conditions; the ultimate effect was great loss of life and the destruction of the main hoisting shaft, putting it temporarily out of service. The work of rescue and fire fighting continued eight days. The following pages present an attempt to draw some practical conclusions and suggestions from this disaster. The property of the North Butte Mining Co. consists of about 220 acres in the northeastern part of the Butte district, Montana. Next to the Anaconda Copper Mining Co. it is the largest pro¬ducer of the district. In 1916, the year before the disaster, there were 1,160 men employed. The output was 560,947 tons of ore, which yielded 24,498,181 pounds of copper, 1,047,063 ounces of silver, 1,712 ounces of gold, and 412,953 pounds of zinc. The profit was $2,479,595. The total development work for that year was 21,694 feet. During the first half of 1917, the year of the accident, the daily tonnage of ore averaged 2,000, an increase of 400 tons over that of the year 1916.

Jan 1, 1922

By William N. Hale

This Bureau of Mines report gives a detailed study of water usage in the Montana mineral industries, along with projections for the future. The mineral industry of Montana in 1963 used 36.5 billion gallons of new water, and reused or recirculated an additional 53.5 billion gallons for a total water requirement or usage of 90 billion gallons. The petroleum industry was the major water user, followed by the copper and zinc industries. Many mineral industry operators provide their own water, and new water is withdrawn largely from surface sources. At present, sufficient water is available in rivers, streams, and reservoirs in Montana; however, shortages do exist locally near mineral industry operations using large quantities of water. Some is supplied from sources up to 44 miles distant. New water withdrawn by the State of Montana mineral industry is expected to increase from 36.5 billion gallons in 1963 to 51.1 billion gallons by the year 2000. The total-water requirement is expected to more than double, or reach 182 billion gallons by the year 2000.

Jan 1, 1966

By William N. Hale

This Bureau of Mines report gives a detailed study of water usage in the Montana mineral industries, along with projections for the future. The mineral industry of Montana in 1963 used 36.5 billion gallons of new water, and reused or recirculated an additional 53.5 billion gallons for a total water requirement or usage of 90 billion gallons. The petroleum industry was the major water user, followed by the copper and zinc industries. Many mineral industry operators provide their own water, and new water is withdrawn largely from surface sources. At present, sufficient water is available in rivers, streams, and reservoirs in Montana; however, shortages do exist locally near mineral industry operations using large quantities of water. Some is supplied from sources up to 44 miles distant. New water withdrawn by the State of Montana mineral industry is expected to increase from 36.5 billion gallons in 1963 to 51.1 billion gallons by the year 2000. The total-water requirement is expected to more than double, or reach 182 billion gallons by the year 2000.

Jan 1, 1966

By Ted Klemetti

Roof deterioration in weak moisture-sensitive rock leads to roof falls in coal mines. An observation site was set up in intake air at an underground coal mine in central Ohio to evaluate the time-dependent deterioration of moisture-sensitive roof rock. By periodically collecting and weighing the rock falling from the roof, the National Institute for Occupational Safety and Health (NIOSH) was able to quantify the deterioration of the moisture-sensitive shale roof. The measurements showed that more roof rock is falling in the dry winter months. Movements in an intersection were monitored in order to determine if deformation correlated with seasonal changes in temperature and humidity. The rate of intersection roof-to-floor convergence was found to be cyclical and related to seasonal changes, with more convergence during the months of April through September. At the study site intersection, the roof beam did not show deflection indicating movement most likely due to mine floor deformation. The bolt load also increased in the warmer months before shedding load, possibly due to rock failure. Temperature and relative humidity sensors, placed in holes in the roof show that mine air does not mix with the air in the holes. Consistent saturation levels of relative humidity were measured in the holes and it appears that high levels of moisture may have migrated into the bolt holes from roof shales. A roof sealant applied to a portion of the test roof appears to be preserving the roof and reducing the amount of rock fall into the entry, while the screened area virtually eliminated rock falling from the roof.

Jan 1, 2009

By D. Rahal, I. Shah, B. Hines, S. Reddick

"The development of stirred milling technology has proven to be an enabling technology in fine grained metallic deposits. The increased grinding efficiency allows for the economic size reduction required to produce saleable concentrates. This improvement has opened the door to retreatment projects such as reprocessing of historic gold mine tailings. Recently a VXP2500 stirred mill was installed at Casmyn Mining Zimbabwe Turk mine to allow the reprocessing of historic mine tailings. After commissioning, an extensive joint research project between Casmyn and FLSmidth Minerals was conducted to optimize the performance of the mill. This paper outlines the challenges encountered in the optimization program and the outcomes from the joint research project.INTRODUCTION The development of stirred mills has opened up many new opportunities to recover valuable minerals from refractory ores. Stirred mills have already been reported as an enabling technology for the processing of fine grained ores in lead/zinc applications (Pease, Young and Curry, 2005). Historically, conventional ball mills were unable to economically grind material fine enough to produce the required recovery or concentrate grade. This often resulted in the loss of valuable materials to the final plant tailings. The advent of stirred milling has now provided an opportunity which has both economic and environmental benefits, the reprocessing of historic mine tailings. Many tailings stockpiles now contain economic concentrations of gold because of the ability of stirred mills to efficiently and economically grind the tailings to liberation sizes. The primary advantage of reprocessing historic tailings is very low cost processing. Recovering the tailings is usually as simple as pumping the material into the reprocessing circuit. The disadvantage of reprocessing tailings is the low feed grade and greater difficulty in recovery valuable minerals at the same size distribution. The material has already been previously processed so fresh surface area or an increase in metal exposure is required. These are both provided by regrinding the tailings material."

Jan 1, 2014

By Heiner J. Sander

Stanford University operates the National Research Facility which is located at the Stanford Linear Accelerator Center (SLAC) in Menlo Park, California. In order to improve and allow for enhanced experiments, the current facilities required expansion. A1500 foot long tunnel (20 ft wide by 21 ft high) and a 220 foot long underground cavern (49 ft wide by 32 ft high) were excavated through the Ladera Sandstone formation which is an intermediate geo-material with week rock properties. The overburden between surface and crown of the structures varies from 10 to 80 feet. The underground structures were excavated according to the principles of the NATM (New Austrian Tunnel Method). This paper addresses the challenges that were encountered during the construction phase of the project and how construction issues were resolved mutually by the owner, engineer and contractor. The implementation of geotechnical instrumentation, recorded data and interpretations, soil conditions and behavior encountered during construction are also presented.

Jan 1, 2008

By Panagiota Tsolis-Katagas, Basilios Tsikouras, Tassos A. Grammatikopoulos, C. Katagas

"Mineralogical techniques including microscopic methods, reflected and transmitted light microscopy, Cathodoluminescence (CL) and Scanning Electron Microscopy equipped with an Energy Dispersive Spectrometer (SEM-EDS), are useful in determining the quality of industrial minerals. They are essential for studying ores and metallurgical products including the evaluation of physical characteristics of the mineral, paragenetic relationships, associations with possible deleterious contaminants (e.g., sulphides), spatial distribution within the ore zones and liberation characteristics. The methods are inexpensive, and provide quick identification and distinction among the industrial minerals and the gangue minerals in a section. Additionally, SEM is necessary to reveal complex textural sequences and 3-D measurements of minerals and quick semi-quantitative analysis.Common analytical methods include Electron Microprobe Analyses (EMPA) and Whole Rock Analysis (WRA) (commonly with XRF and ICP) for major and trace elements. The EMPA analyses of industrial minerals provide information on the purity of the analyzed grains as opposed to the bulk chemical analyses that may be misleading due to contamination by other associated common “gangue” minerals. These techniques have been implemented for the case studies of wollastonite, V-magnetite and muscovite. Therefore, these methods can provide extremely useful information and lead to the implementation of a successful pilot-testing programme.MINERALOGICAL EVALUATION OF DEPOSITSDespite their considerable and increasing economic importance, industrial mineral deposits have traditionally been neglected by economic geologists, and are only rarely the subject of the detailed analysis widely lavished on metallic mineralization. Moreover, in that they generally represent concentrations of “normal” rock-forming minerals, albeit commonly with particular textural and/or geochemical features, they have tended to fall between the mainstream of petrogenetic studies and mineral deposit research (Grammatikopoulos 1999). For many industrial minerals, little attention has been paid to the factors responsible for their local concentration as large and high-grade bodies. This comparative neglect has particularly been the case for minerals such as talc and wollastonite, widespread in metamorphic rocks, in which they are reasonably interpreted as components of assemblages derived, respectively, from pelitic sediments, ultramafic igneous rocks and siliceous limestones."

Jan 1, 2003

An understanding of the origin of mineral deposits and their relationship to local and global geotectonics is essential if regional targets for mineral exploration are to be chosen. Volcanism, metamorphism and tectonism are especially significant for the origin and emplacement of mineral deposits, which, far from being fortuitous oddities of nature, occupy well defined positions within distinctive lithofacies. Thus, suggestions for mineral exploration targets can be made taking into consideration the position of 'fossil' convergent and divergent plate tectonic boundaries to indicate areas of specific types of mineralisation. To be borne in mind, though, that level of exposure, time and location of magma generation are all additional and important controlling factors. To further understand the importance of the above parameters, one must refer to the concept of paired metamorphic belts (Miyashiro 1973) which develop during an orognic cycle. These belts are generally constructed in such a way that an ophiolite type complex with metamorphic grades related to high pressure and moderate temperature regimes is flanked by an area of calc-alkaline volcanism and granitic activity with metamorphic grades within a region of high temperature and low pressure. The former situation is usually the seat of primary magmatic mineralisation, whereas the latter contains base metal. Deposits of acid plutonic and volcanic association. As will be seen later, this particular metamorphic-volcano-orogenic situation is well developed in some parts of New Zealand. For the present purpose a distribution of potential ores as related to plate tectonic processes is given below:a) Divergent plate boundaries: primary magmatic Ni-Cu, Pt,Cr, PeS2 and Cu, Pb,Zn in hot brines-hydrothermal environments Mn deposits.b) Convergent plate boundaries: stratabound Cu-Fb-Zn-Ag of felsic volcanogenic association. Porphyry eu-Au of island arc type, porphyry Cu-Mo of continental type. Cu, Au, Y, Sn, Hg, Sb of vein type and replacement lode related to granitic activity.c) Au of hydrothermal vein association, related to late dynamo-metamorphic events. By virtue of ocean floor spreading, regions of divergent plate boundaries are eventually juxtaposed or welded n to areas where plate collisions occur. This is then followed by partial melting due to various causes, just above the descending plate; thus creating a zone of acid to intermediate magmatism. The final picture is that of an orogenic zone with the paired metamorphic belts outlined above.

Jan 1, 1976

By Ronald M. Hays

The Duluth Gabbro Complex in Northeastern Minnesota possibly contains a significant domestic copper resource and the nation's largest nickel resource. Exploration has discovered large low-grade copper-nickel (Cu-Ni) deposits between Hoyt Lakes and the Boundary Waters Canoe Area (BWCA). The mining and processing of Cu-Ni will have environmental, economic, and social impacts. The purpose of this study is to relate major environmental, economic, and social considerations to various aspects of Cu-Ni extraction. An open pit and two underground (block caving and open stoping with backfilling) models were developed to generate information on the impact of Cu-Ni extraction. Important considerations having environmental, economic, and social impacts (luring various aspects of Cu-Ni extraction are identified and defined. These aspects are exploration, development, mining, beneficiating, smelting, transportation, and termination of operations. Considerations are grouped into the general categories of site, industrial, energy, climatic, resource, water, air emission, waste disposal, employee, tax and royalty, transportation, and community considerations. Cu-Ni extraction in Northeastern Minnesota presents major environmental, economic, and social risks. Decisions are required on trade-offs between adverse and beneficial impacts. The approach used in this study assists in assessing environmental, economic, and social impacts. It will aid in the examination of potential and projected short-term and long-term advantages and disadvantages and will aid in the development of Minnesota's Cu-Ni resource for the maximum benefit to society.

Jan 1, 1974