Search Documents

By H. Manurung, I. M. Bendiayasa, W. Astuti, and H. T. B. M. Petrus, F Anggara, K. C. Wanta

The leaching kinetics of cerium (Ce) and yttrium (Y) in sodium-hydroxide-digested non-magnetic coal fly ash using acetic acid were investigated. The variables analysed were pH, solid-to-liquid ratio (S/L), and temperature. The results show that cerium and yttrium's maximum recovery was 57.33% and 58.36%, respectively, under leaching temperature of 90°C for Ce and 60°C for Y at pH of 1,74 and 10 g/mL solid-liquid ratio in 240 minutes. Increasing the leaching time to more than 120 minutes did not significantly improve the results. After the magnetic separation process, the ICP-OES analysis shows a slight increase in the concentration of cerium and yttrium on nonmagnetic components. The XRD and ICP-OES analysis for the sample before and after silicate digestion shows that 40% silicate was dissolved. The calculation of apparent activation energies of leaching using the Arrhenius law for the leaching of cerium and yttrium gives 22.72 kJ/mol and 35.84 kJ/mol, respectively. The kinetic leaching model of cerium and yttrium all fit Dickinson's new shrinking core model. The calculation results show that the leaching reaction is controlled by combining interface transfer and diffusion across the product layer.

Nov 6, 2024

By B. S. Agbenuvor, R. Morrison, V. Jokovic, C. Antonio

Body breakage usually involves breakage of particles by compression between two surfaces or impacted against a rigid surface, with the latter of interest in this current study. This mode of breakage has been identified to be the most elementary size reduction process and the most effective breakage process in comminution devices. It has been found in the literature that the progenies produced from this form of breakage possess a residual velocity at which they move, after the breakage event. In the pursuit of efficiently utilising applied comminution energy, a laboratory-scale breakage device has been developed to deliver precise specific impact breakage using the concept of a fast-moving hammer and a slow-moving particle to effect breakage. The residual velocities of the progenies from the breakage event may be used to generate secondary breakage without further addition of energy if the particle encounters a stiff obstacle such as a steel plate at right angles to its path. To measure the extent of secondary breakage, the steel wall of the device was lined with a rubber material to suppress the second set of breakage events. The performance of the new device is analysed, based on calculated t10 values and measured residual velocities of the moving daughter particles. Testing involving anvils showed a much finer PSD and higher t10 compared to the test involving rubber lining. This finding is corroborated by the measured residual velocities of the progenies. The resulting energies calculated from the measured residual velocities of the progeny were found to be approximately 42-88% of the primary specific impact energy. This retained energy was found to be sufficient for secondary breakage. Keywords: Impact breakage, residual velocity, secondary breakage, energy utilisation

Jan 1, 2020

By D. Brazier, W. Laing, D. Nixon

Keywords: Pyrometallurgy, furnace, smelter, copper, Palabora The Palabora copper smelter has operated for the past 38 years, treating concentrates produced at the mine site. Palabora has reduced captive material by almost 40 per cent with the transition from a large open-cast to a smaller underground mine. The smelter and refinery complex was designed to treat 120 kt contained copper units per annum, with the underground only supplying 70 per cent of the feed. The agreed strategy was to import enough concentrates to maximise production and reduce operational unit costs. This transition has presented the Palabora management with new challenges both in technical and financial aspects.

Jan 1, 2006

By N. J. Alderman, R. Haldenwang

Flumes are ubiquitous throughout the mining and minerals processing industries as well as being used in the polymer processing and pulp and paper industries. With the increased demand for the transport of highly concentrated slurries in rectangular open channels, there is an impetus for a better understanding of the role of rheology in flow hydraulics. Until recently, design of such channels has been based on either the Chézy or Manning equations used for modelling open channel flow of Newtonian fluids. This has been done for modelling turbulent flow of low concentrated slurries with some success. However, this is not the case for highly concentrated slurries where the flow in the channel is no longer turbulent. Unlike Newtonian fluids, work carried out on flow of pseudo-homogeneous, non-Newtonian fluids in open channels is somewhat limited. Moreover, these results have been published in a variety of sources. This paper attempts to give a critical review of the work carried out on Newtonian and non-Newtonian flow of pseudo-homogeneous non-settling slurries in rectangular open channels. A comparison is also made of the models based on power law, Bingham plastic and Herschel-Bulkley fluids for laminar and turbulent flow in rectangular open channels.

Jan 1, 2007

By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

By C. Hartford, T. Holmes

Bulk-solids handling systems are often the most over-looked component and thereby weakest links in a processing plant’s value chain. Since their performance can dictate that of the entire operation, they actually deserve special attention. When designing a liquid handling plant, density and viscosity are well known and commonly used as design parameters. Bulk solids however, differ. While the design process is similar, the relevant parameters in handling bulk solids are instead friction, cohesive strength, compressibility, and permeability. These then vary depending on the mineralogy, particle size distribution and shape, moisture content, storage time-at-rest, temperature, and consolidation pressure. With so many variables, it becomes important to characterize each individual bulk solid across the full range of representative process conditions within the handling system, plant wide – or if you are not very lucky, suffer the consequences of poor material flow. Measuring flow properties and applying them correctly in bulk solid handling system design reduces project risk, saves significant capital, and drastically increases throughput, especially when done in the early stages of a project. Keywords: Flow Properties, Bulk Solids, Process Conditions, System Design

Jan 1, 2020

By J. H. van Laar, L. J. van der Walt, P. L. Crouse, H. Bissett, G. J. Puts

"SynopsisSilicon carbide nanopowders were produced using a microwave-induced plasma process operating at 15 kPa absolute and at atmospheric pressure. Methyltrichlorosilane (MTS) served as precursor, due to its advantageous stoichiometric silicon-to-carbon ratio of unity, allowing it to act as both carbon and silicon source. Argon served as carrier gas, and an additional hydrogen feed helped ensure a fully reducing reaction environment. The parameters under investigation were the H2:MTS molar ratio and the total enthalpy. The particle size distribution ranged from 20 nm upwards, as determined by SEM and TEM micrographs. It was found that an increase in enthalpy and a higher H2:MTS ratio resulted in smaller SiC particle sizes. The adhesion of particles was a common occurrence during the process, resulting in larger agglomerate sizes. SiC layers were deposited at 15 kPa with thicknesses ranging from 5.8 to 15 µm.IntroductionIt is well known that methyltrichlorosilane (CH3SiCl3 or MTS) decomposes to form silicon carbide (SiC) and hydrogen chloride (HCl) as shown in Equation [1]. The reaction kinetics and mechanisms for this reaction are thoroughly reported in the literature (Sone et al., 2000; Papasouliotis and Sotirchos, 1999; Kaneko et al., 2002; Wang et al., 2011)."

Jan 1, 2015

By Ernst-Ulrich Reuther, Alexander Donmen

Mine ventilation in the German coal mining industry is concerned mainly with problems of thermal environment arising from greater depths and with increasing emission of methane gas. The development of computer techniques over the past ten years for solving these and ancillary problems is reviewed. The emphasis from a planning and control point of view falls mainly on ventilation network calculations, temperature predictions and advance estimates of methane emission.

Jan 1, 2014

By D. F. Malan

This study Investigates transient closure piles of tabular excavations. Measured closure profiles in stopes indicate that time-dependent acts f the rockmass can be very prominent but such effects have been largely neglected in past analyses and modelling. This was due to a poor understanding of the time-dependent mechanisms controlling closure rates This paper investigates the feas-ibility of representing the rockmass as a visco-elastic medium. Currently, no analytical solution for the viscoelastic convergence of a tabular stope is available in the literature. Therefore, the author derived a solution using the correspondence principle and a known elastic solution. It is assumed that the rockmass behaves elastically in hydrostatic compression and as a Kelvin substance in distortion A parametric study is Included to aid in the calibration of the model parameters, together with a discussion on the correct calibration of these parameters from experimental data.

Jan 1, 1995

The following contributions were received to the paper entitled 'Safety in South African mines: An analysis of accident statistics', by H.S. Eisner and J.P. Leger, which appeared in the J. S. Afr. Inst. Min. Metal., vol. 88, no. 1, Jan. 1988, pp. 1-7. Contribution by H. WAGNER* The paper by Dr H.S. Eisner and Mr J.P. Leger is critical of the safety situation on South African mines and portrays the industry as having little concern for the health and safety of its workers. Moreover, the casual reader gains the impression of deliberate misinformation by the industry to the public concerning safety maters. Furthermore, certain socio-economic reasons are advanced for the apparent differences between the fatality and injury rates reported for coal mines in South Africa and those for the United Kingdom. Contribution by S.A. WATTS. Authors Eisner and Leger are to be commended on their paper, which highlights, according to their interpretation, various shortcomings of both the Chamber of Mines accident statistics and those published by the Department of Mineral and Energy Affairs. Authors' Reply We gratefully acknowledge Dr Wagner's contribution to the discussion on our paper. For convenience, we shal use his sequence of comments in our reply. Before doing so, however, it may be useful to explain how our paper came to be written. After the explosion at Hlobane Colliery in 1983, one of us (HSE), in February 1984, was retained by the lawyers acting for some of the dependants of the victims to advise on technical maters relating to the explosion. Contribution by Ms S.A. Wats Some of the points made by Ms Wats have already been answered in our comments on Dr Wagner's contribution. We are fully aware that the number of accidents leading to absences of less than 4 days would be much greater than shown in our bar chart, and are grateful to Ms Wats for drawing attention to the specific exceptions that can make a 1-3 day accident compensable and that are clearly responsible for the relatively low count in that category of the chart.

Jan 1, 1988

By C. G. Schmidt, N. W. Hanf

Many of the pyrite concentrates produced at South African gold and uranium mines contain economically significant amounts of nickel, copper, and cobalt, apart from gold and uranium. In some cases these concentrates are leached for uranium, followed by roasting and cyanidation of the calcine for the extraction of the gold. Even if their intrinsic value is excluded, the presence of appreciable amounts of base metals can lead to excessive consumption of cyanide and zinc in the conventional process for the recovery of gold from calcines. The extent to which base metals, particularly cyanocides in the calcine, can be made soluble in water or in dilute acid by variation of the pyrite roasting conditions was investigated. An important finding of the investigation was that the conditions producing favourable base-metal sulphation (and hence solubility in water) also produced good sulphation of the uranium values that had not been extracted in a conventional leach of the original pyrite. Thus, if the pyrite is subjected to a sulphating roast followed by quenching in water (or dilute acid), it should be possible for the uranium to be extracted in improved yield. The need for leaching of the pyrite would therefore fall away. It was noted that sulphation roasting also resulted in improved gold extractions when the calcine was subsequently subjected to conventional cyanide-extraction procedures. From well-sulphated calcine, the dissolution of base metals and uranium appeared to be fairly independent of leaching pH, time, and temperature. On an inadequately sulphated calcine, Iow pH values during leaching gave increased extraction of copper and uranium but did not have a significant effect on the dissolution of nickel and cobalt. The extraction of uranium increased with increasing leaching time and temperature, while only longer times at a Iow pH value markedly improved the extraction of copper. The extraction of cobalt was fairly independent of leaching time and temperature, but the results were insufficient for a conclusive evaluation to be made of their effects on the dissolution of nickel. A cursory economic assessment 'indicated that sulphation roasting applied to the pyrites investigated is likely to be very profitable.

Jan 1, 1979

By M. Asghari, R. Amiri, A. Haratian, M. Noue Parast, S. Haji

Today the roller screen has a wide range of applications in the steel-making industry. It is used for screening of green pellets before using the kiln. Since the appropriate size of a green pellet is -16+9 mm, there are different gaps between rollers that make green pellets classified in three categories: -9 mm (undersize), -16+9 mm (onsize) and +16mm (oversize). The efficiency of a roller screen is specified according to the weight percent of undersize in onsize as a fine material, and weight percent of onsize in oversize (loss). This efficiency is influenced by different operational parameters such as roller diameter, roller speed, and roller gap, material type of rollers and inclination of roller screen. This study investigates the effect of different material types of rollers in efficiency of Ardakan roller screens, located in the Yazd province of Iran. The rollers of the existing roller screens in this pelletising plant are made of polyurethane which according to this investigation, has a maximum lifetime of about six months. Operating the polyurethane rollers beyond its lifetime generates serious problems such as high wear of rollers, and consequently, material buildup on the roller surface which then significantly decreases the roller screen efficiency. So, after examining different roller materials, stainless steel 304 with higher surface roughness to help pellets move properly on the roller screen surface was selected as a solution to this problem. The new roller screen was constructed by Fakoor Meghnatis Spadana (FMS) and replaced the previous one. In this way, the maximum capacity of the roller screen was increased about 17% and the roller screen efficiency was increased about 15%. Keywords: Roller screen, green pellets, efficiency, onsize, operational parameters

Jan 1, 2020

By G. Peinaar

Superhardening is a new development by which a substantial increase in hardenability above the normal can be achieved in Iow-alloy steels. This paper concerns the reversible temper-embrittlement behaviour of steels with a superhardenability characteristic. Steels of type BS 530A40 with manganese modifications varying from 0,72 to 1,27 per cent in the superhardenable and conventional condition were compared. It was concluded that superhardenability in itself does not affect the susceptibility of a particular steel to temper embrittlement. However, an increase in manganese content, which was intended to increase the base hardenability of the steel, caused serious deterioration of the temper-embrittlement properties. As the use of manganese, chromium, and nickel to increase base hardenability results in an increase in susceptibility to temper embrittlement, it is suggested that this effect should be countered by the addition of 0,2 to 0,3 per cent molybdenum.

Jan 1, 1984

By N. C. Joughlin, D. K. Hallbauer

The size distribution and morphology of gold particles in Witwatersrand reefs and their crushed products by D. K. HALLBAUER, Dr. rer. nat., Dipl. Min. (Visitor) and N. C. JOUGHIN, B.Se. (Eng.), Ph.D. (Rand) (Member) Undistorted gold particles were obtained from samples of a variety of Witwatersrand reefs by dissolution of the quartz in hydrofluoric acid. The size distribution of the gold particles and their shapes and association with thucholite and pyrite are discussed. Gold particles with a natural flat, plate-like appearance occur in varying proportion in all reefs. The effect of a number of different comminution processes on the gold particles was investigated, and the shape of gold particles in mill pulp from a number of mines was examined.

By K. R. Vost

"In situ" measurements of the surface heat transfer coefficient in underground airways by K. R. VeST,* B.Se. (Glas.), M.Se. (N.S.W.) (Visitor) Few "in situ" measurements have been made of the surface heat transfer coefficient in mine airways despite the importance of this coefficient in determining the heat flow into the ventilating air. In this paper, the values obtained at various air velocities and the comparisons of these values with theoretical values are given. Examples are also given ofthe errors which would result if rock surface temperatures were obtained by extrapolation from temperatures further into the rock without taking into account the time delay which occurs before a given change in air temperature reaches the points from which extrapolation is carried out.

Minerals and Manpower - PRESIDENTIAL ADDRESS given by R. P. Plewman, Pr. Eng., B.Sc. (Eng) (Wits), M.A. (Oxon.) INTRODUCTION What I want to discuss is the future pattern of manpower in the mining industry, and I should like to begin by examining some relevant statistics. There are four areas that must be examined. Firstly, the future rate of production of different minerals must be estimated. Secondly, an assessment must be made of the balance of different mining technologies likely to be used for each mineral. Thirdly, the manpower requirements for each technology must be determined. And, fourthly, the future manpower resources of the country must be explored. NIM report Report No. 1646 Examination of the methods of analysis for calcium fluoride in fluorspar.

Jan 10, 1974

By N. du Preez, J. Christie, F. Crundwell

Precipitation is a key process in the recovery of copper and cobalt. While there is a wealth of experience in operating precipitation steps, improving their performance remains challenging. Chemically, the reaction might be controlled by reaction kinetics, be limited by oxygen mass transfer, or be at equilibrium. In this paper, we examine these different operating regimes and demonstrate how they can be identified from plant operating data, process modelling, and pilot plant test work

Jan 1, 2023

By T. B. Beeton

In view of the limited reserves of good-quality coking coals in South Africa, Iscor has been involved in direct reduction since the middle sixties. Since the early seventies, its interest in direct reduction was stimulated further by a swing towards' continuous casting, which, in turn, contributed to a shortage of the scrap supply for electric-arc-furnace (EAP) steelmaking. Rock engineering The First International Conference-Rock Enginet:ring and Excavation in an Urban Environmentorganized by The Institution of Mining and Metallurgy and the Hong Kong Section of the Institution, in association with the Hong Kong Institution of Engineers, will be held in Hong Kong from 23rd to 28th February, 1986. SPOTLIGHT on Gold Fields National Engineering Awards For the Gold Fields Foundation National Engineering Awards, each university affiliated to the South African Federation of University Engineering Students (S.A.F.U.E.S.) selected a candidate who, in their opinion, presented the most outstanding design project in their final year during 1984.

Jan 1, 1985

By Karl-Heinz Obst, Juergen Stradtman

The importance of the chemical and physical properties of lime has been overlooked for years although the quality of lime plays an important role in the production of steel. With the introduction of the oxygen injection process these properties have been re-evaluated. The CaO, MgO, S, and P2O5 contents of lime are important, but so are the physical properties such as granulation, reactivity with respect to slag formation, and the degree of burning. Soft burnt lime enhances de-phosphorisation and de-sulphurisation, and facilitates the smelting process in general, mainly due to its large specific surface. Special lime, prepared as briquettes from quicklime and fluxes or as pellets from limestone and various fluxes with or without binding agents, clearly accelerates lime dissolution during the slag formation process, lowers the melting point, and enhances de-phosphorisation, de-sulphurisatlon, and de-carburisation even more than soft burnt lime. The introduction of special limes in the oxygen injection process for steel production has opened up new fields for commercial exploitation of slags as well as improved operational techniques.

By M. A. de Ruijter

Bracken Gold Mine ceased mining operations during February 1993. The clean-up of the gold plant, which had already commenced in September 1992, was completed in January 1994. The mine had been in production since early in 1962 but, because of a decreasing ore reserve, increasing working costs, and a relatively low gold price, closure had become inevitable. The closure had been under consideration since August 1983, when the first estimate was made regarding the amount of gold that could be recovered from the clean-up operations. Until that stage, it had been accepted that Bracken would conform to the commonly accepted idea that 0.25% of the total gold produced by the plant would be recovered during the clean-up operation. This idea was dispelled when the initial estimates indicated that the gold recovery would vary between 0.049 and 0.095%. The actual figure realized was 0.036%, showing that there is no generalforl1ula for the calculation of the amount of gold to be recovered from such clean-up operations. During the clean-up operation, Bracken became an unexpected contributor to the State's Reconstruction and Development Programme by having al the mine and plant buildings purchased and converted into a community development centre. This shortene4 the time available for the clean-up, and several of the buildings remained intact. However, the foundations and sub-soils had been sampled extensively, and it is considered that no recoverable gold was left behind.

Jan 1, 1996