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By R. Pakalnis, D. Tenney, B. Lang

"This paper describes three case histories whereby numerical methods were employed as a tool in the identification of potential instability. Simple two dimensional (PCBEM) and pseudo three-dimensional (BESOL, MINTAB) codes were employed to identify zones of induced stress which were subsequently related to extensometer, stress meter and observational data as the stope was excavated. The following case histories will be discussed. MacLellan Mine - sill pillar stability; Ruttan Mine-Hanging Wall Stability; and Detour Lake Mine-narrow vein mining.The MacLellan case history showed how modelling and instrumentation enabled mining to be conducted safely and under controlled conditions. MINTAB and PCBEM were employed to predict sill pillar failure. The sill pillar failure was associated, with an unloading of stress which was recorded by instrumentation (stress meter) and a decrease in the over-all rock mass strength. The yielded pillar, however, maintained its over-all configuration enabling access through the pillar.The Ruttan case history is an example of hangingwall and footwall design whereby the existence of adverse structure coupled with a zone of relaxation results in dilution. BESOL and PCBEM were employed to model a test stope and to verify the observations and measurements through instrumentation . Empirical methods of dilution estimates are employed to determine the level of walls lough with respect to the rock mass rating, stope dimensions and rate of excavation.The Detour Lake case history in an example of open stoping a narrow steeply dipping deposit. Stope dimensions are 135m in strike length, 47 m in vertical height with an average width (F/W to H/W) of3.6 m. Stress meters coupled with visual observations are related to modelled estimates of stress and dilution."

Jan 1, 1991

By Alex Luyima, Michael Moats

"In the present work, the oxidation of manganous and chloride ions on a mixed metal oxide (MMO) anode from a 40 ºC electrolyte containing 160 g/L sulfuric acid (H2SO4) with various concentrations of Mn2+ and Cl- was studied using cyclic voltammetry. These results indicated that Mn2+ concentration does not affect Cl2 evolution on a non-MnO2 coated MMO anode. However once MnO2 deposits on the MMO anode, Cl2 evolution is inhibited. The effects of manganous concentration and chloride concentration on the amount of MnO2 deposited in one hour were also evaluated. Cl- concentration did not affect the amount of MnO2 generated. Increasing Mn2+ concentration resulted in an increase in the amount of MnO2 deposited.INTRODUCTIONThe electrolytic recovery of zinc (Zn) is a well-known process and is estimated to produce approximately nine million tons of Zn per year worldwide (Recendiz, Nava, Lartundo-Rojas, Almaguer, & Gonzaleza, 2009). The Zn produced by this process is of high purity and has a wide range of applications, such as galvanizing (car body parts, pipes, metal wires, etc.), sacrificial anodes in offshore industries, casting alloys, alloying of brass, primary and secondary battery industries, etc.The electrochemical production of Zn employs aluminum cathodes and lead-silver anodes (Pb- Ag) (Recendiz et al., 2009). The Zn containing mineral (ZnS) is usually associated with other elements such as Mn, Mg, Ca, Cd, Cu, Cl, Fe, F, Co, Ni, Al, As, Sb, Si, Sn, Ge, Hg etc. (Nijjer, 2000). After processing of ZnS concentrates, the electrolyte obtained still contains residual metallic and non-metal impurities. Some of these impurities can impact the corrosion rate of Pb-Ag anodes."

Jan 1, 2016

The mechanism of thiosulfate decomposition and the products formed were investigated in the presence of pyrite or pyrrhotite in copper-ammonia solutions used for leaching gold. The presence of the sulfides significantly increased the decomposition of thiosulfate. The sulfide-surface-catalyzed oxidation of thiosulfate to tetrathionate by dissolved oxygen or the cupric tetra-ammine complex was proposed to be the dominant thiosulfate decomposition mechanism. The catalysis of the sulfides in this reaction could originate from their strong affinity for aqueous sulfur species and their semiconducting properties. Oxygen was found to be the initial driving force for thiosulfate decomposition in the absence of cupric ions and the driving force for the continuous decomposition of thiosulfate in the presence of cupric ions. Under an oxygen free atmosphere, the decomposition of thiosulfate was limited to reduce the cupric ions and the catalytic effect of the sulfides was also marginal. The dominant oxidative product of thiosulfate was trithionate in alkaline solutions especially in an oxygen rich or cupric ion rich environment. Tetrathionate was found in relatively smaller amounts in an oxygen and cupric ion deficient environment. Tetrathionate was not stable and would further decompose after extended periods. Trithionate concentrations increased almost linearly with time.

Jan 1, 2005

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By M. I. Kalashnikova, Y. M. Shneerson, M. V. Keskinova

Interaction between mattes having various compositions and solutions with a wide range of free acid and non-ferrous metals concentration have been studied in terms of chemistry, mechanism and kinetics. The solution acidity and oxidizers to reducers ratio in the matte-solution-gas phase system have been demonstrated to be the major factors determining the process behaviour. It was found that the types of copper and nickel secondary sulphides resulted from nonferrous metals precipitation from solution, depend on of the solution and initial matte composition. Based on these studies, technologies of matte leaching and nonferrous metal precipitation in the form of rich sulphide concentrates are developed.

Jan 1, 2004

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Knowing shear mechanism of discontinuities under monotonic and cyclic loading conditions is a key factor in stability analysis of rock slopes and rock foundations. In this paper, the effect of cyclic loads on the shear mechanism of joint asperities is described. For this purpose, a fresh tension-split joint from a granite block was used as a reference and thirty five mortar replicas were fabricated. Cyclic shear tests were conducted on replicas under low values of constant normal load (CNL) using a servo-controlled loading system. Tests were performed in two consecutive steps; load-controlled and then displacementcontrolled. In the load controlled part, after initial increase of shear stress to 0.25 MPa, the test was stopped for 2 minutes, then increased to 0.5 MPa, and finally decreased to 0.25 MPa. This process was repeated ten times. At the end, the test was continued up to 10 mm shear displacement under displacement-controlled loading in order to pass the peak shear strength and reach the residual strength. Characterizing joint surface and modeling of involved asperities during the tests was undertaken using a Matlab code developed with new mathematical expressions. The algorithm used in the code is based on three-dimensional coordinates of the scanned joints’ surfaces before and after the test. It was found that a high percentage of degradation happens during the first cycle of loading and during the other cycles, degradation occurs gradually. While comparing tests conducted in monotonic and cyclic loading conditions, it was observed that under low number of cycles, the pronounced mechanism is consolidation of the joint surfaces. This consolidation increases contact areas and, therefore, shear strength parameters.

Jan 1, 2015

By N. Tounsi

The use of analytical modeling of continuous chip formation in conjunction with orthogonal cutting experiments was presented in the open literature to identify the coefficients of material constitutive equation within the practical range of stress, strain, strain rate, and temperature encountered in metal cutting. Identification of reliable constitutive data was hampered by a lack of a reliable model for the prediction of the primary shear zone thickness that affects directly the effective strain rate field. An original analytical model to determine the primary shear zone thickness is proposed in this paper. It is based on the mechanics governing the material flow in the primary shear zone. Based on the distribution of the hydrostatic pressure and the forces measured from orthogonal cutting tests, the model that describes the thickness of the primary shear zone is derived. To validate the model, FE simulations of chip formation using DEFORM3D were carried out for different materials and cutting conditions. The results of the analytical model are in reasonable agreement with FEM results.

Jan 1, 2006

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By Sammy Bansah, Komla Dzigbodi-Adjimah

Abstract-Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized ("Banka") drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi- Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration programs for use in similar settings.

Jan 1, 1995

By Sammy Bansah, Komla Dzigbodi-Adjimah

Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized (“Banka”) drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi-Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration pro-grams for use in similar settings.

Jan 1, 1995

By M. Oliazadeh, A. Vazirizadeh

"The inclusion of small amounts of silicon, phosphorus and sulphur in iron ores or concentrates can have a profound effect on the steel making process and thus on the final iron and steel products. In nature however, it is inevitable that iron deposits contain unwanted elements. Each element has its own distinct effect on the final steel product. The effect of high silicon is the formation of gray iron. Phosphorus mainly increases hardness and strength, lowers solidus temperature and increases fluidity and cold shortness. Finally sulphur contamination causes cracks in the iron texture when smelting and forms white iron when casting. Overall, the acceptable level of phosphorus, sulphur and silica in the iron concentrate should be less than 0.04%, 0.15 % and 1.5 % respectively.Scarcity of high grade iron ores necessitates using lower grade ores with higher amounts of impurities. The purpose of iron concentrators is to increase iron grades to an appropriate level suitable for steel making as well as removing impurities. Although many impurities can be traced in the ore, the most predominant impurities are limited to one or two elements. In this paper the beneficiation methods for removing SiO2, P and S are presented, including flotation, and the parameters that need to be considered in the design of beneficiation plants are discussed. Finally industrial cases are discussed along with their metallurgical performance.INTRODUCTIONIn metal sector, value of iron ores and concentrates is determined by iron percentage as well ascontent of:• Useful elements (Mn, Ni, Cr, V, Ti): natural alloying elements in steel• Deleterious impurities (S, P, As, Zn, Pb, K, Na): impair metal properties or complicate operational process in blast furnace• Fluxing components (Si, Ca, Mg,, Al)Sulphur and copper result in red-short, phosphorus is the cause of cold brittleness and arsenic and copper decrease welding characteristics. Sulphur should not exceed 0.15 in commercial ore. Acceptable sulphur content in ores and concentrates for producing sinter and pellets is 0.6%max, as sintering and heat hardening of pellets remove sulphur 60-90%. Phosphorous content in ores, sinter and pellets is limited to 0.07%-0.15%. 0.00.1% As max, 0.1-0.2% Zn max and up to 0.2% Cu are allowed in iron-ore part of the blast furnace burden for the production of standard conversion pig iron. Slag-forming components are divided into basic oxides (Ca, Mg) and acidic (Si, Al). Higher ratios of basic to acidic oxides are preferred since this reduces raw fluxing material."

Jan 1, 2016

By J. Manchisi

This study has investigated the use of blast furnace slag as functional adsorbent for metal ions in acid mine drainage treatment. This opportunity has not yet been developed into a practical process partly because of limited understanding of rates and mechanisms of adsorption process and inconsistency in interpretations of adsorption data. The overall objectives were to determine the efficiency and mechanisms of sorption process of metal ions in a multiadsorbate system. We employed standard materials characterisation techniques to analyse composition, structure and surface morphology of the slag. Batch adsorption experiments were then conducted to study the mechanisms, kinetics and efficiency of metal sorption as a function of pH, phase ratio, mixing time, mass and particle sizes of slag. Both XRF and adsorption data suggested the slag to possess acid neutralising capacity. This slag is non-crystalline based on XRD pattern, has adequate porosity and pore volume comparable to similar commercial adsorbents but it has inferior pore structure, pore size distribution and BET surface area to be effective under wide applications. Metal sorption increased with decrease in slag particle diameter, decrease in initial metal concentration and increase in the mass of slag. Although slags have demonstrated to efficiently treat low concentrations of single and multiadsorbate effluents using fine particle sizes, they have limited capacity to treat multiadsorbate systems for some metal ions. This is probably due to low affinity, competitive adsorption or limitation in material?s adsorptive properties. Sorption mechanisms probably involve precipitation and ion exchange on the basis of alkaline pH and exchangeable slag surface ions. Sorption preference is proposed as Fe2+>Cu2+>>Cd2+>Co2+>Mn2+. Despite these limitations, deeper understanding of sorption behaviour of metal ions by slags for application in dilute and large volumes of effluents is necessary where precipitation and other standard techniques are either inefficient or uneconomic. Thus, this study has established that sorption capacity of slag to remove metal ions from acidic effluents is selective, limited to certain metal ions and for other ions only at low concentrations. Further adsorption studies in multiple solutes under various experimental conditions or those that can propose an economic slag activation process are needed that improves or widens adsorption window.

Aug 1, 2013

By L. Cheng, Y. W. Pan, Y. R. Liu

"Impounding deformation of slope and foundation is significant during and post dam construction. Reservoir impoundment is accompanied with various phenomena, including material degradation, effective stress decreasing and buoyancy in rock masses. These phenomena are related with some engineering concerns like reservoir-induced earthquake, landslide and dam stability. The Malpasset dam and Vajont dam are typical hydraulic projects suffering from seepage in dam foundation and slope, which finally led to failure and landslide. Pore pressure in jointed rock masses is considered in constitutive relation. The expression of effective stress for porous rock with fluids is incorporated into the Drucker-Prager criterion. Based on monitoring data of valley width and dam deformation, the effective stress law is applied to analyse the impounding influence of slope and foundation to Jinping-I high arch dam. The dam is accompanied with complicated topographical and geological conditions. The results show that calculated and monitored values agree well, and the application of effective stress law provides an approach to evaluate dam deformation, stress and stability with impounding effect considered.INTRODUCTIONImpounding deformation of slope and foundation is a common and significant problem during dam construction and operation. This phenomenon exists in a lot of reservoirs in China, like Laxiwa, Ertan, Xiluodu and Jinping-I arch dams, and some dams in Europe. It is related with some engineering concerns like reservoir-induced earthquake, landslide and dam stability. The Malpasset dam and Vajont dam are typical hydraulic projects suffering from seepage in dam foundation and slope. Monitored data indicates that the valley width tends to shrink in hydraulic engineering during the impounding process, which will change the stress and deformation of dam and abutment. Therefore, global stability of dam and foundation should be evaluated with impounding process taken into consideration."

Jan 1, 2015

By P. Sauriol

This work addresses the design challenges and demonstrates the capabilities of a novel water transfer factor measurement apparatus. Several measurement concepts were screened on the basis of their water transfer factor accuracy using Monte-Carlo generated virtual experiments. The most promising measurement concept was assembled and tested to assess its actual measurement accuracy. For these concept validation experiments, the polymer electrolyte membrane fuel cell was simulated by adjusting the water injection rate to corresponding levels. Combining the anode and cathode measurements, the water transfer factor accuracy was typically better than 0.01. Real-time measurements of the water transfer factor on both anode and cathode sides of a polymer electrolyte membrane fuel cell were achieved. The anode and cathode side measurements were in good agreement with each other; however the anode side measurements were generally more reproducible. A parametric study showed that stream humidification plays an important part in the water transfer across the membrane electrode assembly. Finally the water transfer factor along the channel of a 300cm2 co-current fuel cell was obtained by using a series of six 50cm2 sub cells. The results were in good agreement with predictions from a recently proposed model.

Jan 1, 2005

By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By William C. Browning

An economic drilling programme is one which costs the !east in chemicals, equipment, and time. The basis for such a programme with rotary drilling techniques is a drilling fluid in which bentonites do not swell. This is recognized in the growing trend toward gyp and other inhibited mud systems. Therefore, even though the mechanism of thinner action is a subject of applied colloid ,chemistry, the understanding of this mechanism is of economic importance in controlling the flow properties of inhibited muds. In phosphate, or sodium tannate, conditioned muds that are relative-!y free of contaminating-electrolytes, the thinner, or dispersing agent, is adsor.bed, ?creating an electrical double layer about the clay particles. The mutual repulsion of these charged particles effects colloidal stabilization, or deflocculation of the suspended clays, as discussed by Norton and others. In inhibited muds, however, the electrolyte concentration in the filtrate is sufficient to collapse the double layer and flocculation of the mud solids occurs, as evidenced by increased viscosity and gel values. Chemicals to control the flow properties of inhibited muds, therefore, are vital to the successful use of these systems as it is not always economical to adjust flow properties by watering back. Flocculation of suspended particles, as indicated in the work of Vervey, Overbeek, and others, is due primarily to gravity-like, long-range Van der Waals forces. Prevention of flocculation may, therefore, be secured by the interposition of any barrier between the particles, the thickness of which approximates the extension of the Van der Waals at-traction. Organic polyelectrolytes, such as Kembreak, Rayf!o, and Q-Broxin, may act to increase the double layer charge when used in small amounts in fresh-water muds. More important, however, is the fact that in inhibited muds an increase in concentration of the polyelecholyte permits the formation of a condensed film adsorption layer of the polyelectrolyte about the clay particle. When this occurs, the extremely viscous condensed adsorption layer creates a mechanical. barrier that prevents flocculation of clays, even in the presence of inhibiting concentrations of elecholytes. Rheological evaluation of the degree of deflocculation, or colloidal stability, may be made by utilizing the known effects of particle inter-action and volume concentration on the flow properties of suspensions. Rheological evaluation should be supplemented by direct microscopic or ultra-microscopic observation.

Jan 1, 1958

By Z. -G. Ren, J. -S. Qian, Y. -G. Yang

The waste slags from chemical and metallurgical plants contain approximately wt 1% water soluble Cr6+. This hexavalent chromium is very harmful to human health, and the treatment of the slags has concerned metallurgists for many years. A sintering method was developed to treat the waste slag. In this process, sinter was made from a mixture of the waste slag containing hexavalent chromium, iron concentrate and coke breezes. During sintering, hexavalent chromium was reduced to trivalent chromium. The latter is known as a non-harmful material and can be used as chromium resource for the production of ferrochromium or chromium-containing cast iron. After sintering the hexavalent chromium in the sinter could be reduced to less than 0.0008%. It was found that the waste slag with fine particles was favourable to the Cr6+ removal. An increase of carbon content in the sintering mixture could increase the rate of Cr6+ removal and the strength of the sinter produced. The rate of Cr6+ removal increased with increasing basicity of the sintering materials with basicity less than B=1.8, above which it decreased with increasing basicity. Blast furnace was found to operate smoothly when using the sinter made from the waste slag containing chromium. However the productivity of sintering machine was slightly low compared to the sintering operation using ordinary raw materials.

Jan 1, 2004

By E. S. Moore

GOLD was discovered previous to the year 1900 on the east shore of Emerald lake, Afton township, Timagami Forest Reserve. It was found in a small cavern in banded iron formation, close to the water's edge. This occurrence of gold was mentioned in several reports that referred briefly to this area, and prospectors evinced considerable interest in the region. It was not, however, until the Golden Rose Mining Company, which was incorporated in 1909, started operations that much work was done on the property. In 1915-16, this Company, under the direction of E. J. Townsend, the President, did a considerable amount of work. A small mill was built and ore was extracted from pits, trenches, and a one~ hundred-foot shaft. In 1927, Afton Mines, Limited, was incorporated to take over the property, and about thirty men were employed for a time. During 1934, the New Golden Rose Mining Company was organized to handle the property, and the Consolidated Mining and Smelting Company of Canada, Limited, undertook to develop the mine. In March of the following year, this Company began deepening the shaft from 100 feet to 500 feet. A considerable amount of drilling had previously been done on the hill of iron formation in which the mine is located. Further drilling was done from the surface, and altogether about twelve holes have been put down to test the formations. Over 2,000 feet of drilling has also been done from the underground workings. The mine is now known officially as the New Golden Rose mine, although to many it is better known as the Afton. To reach the property during the summer months, there is a boat trip of about thirty miles from Timagami, a wagon-road portage of one mile to Obabika lake, a boat trip of ten miles on this lake, and finally a wagon-road portage of one and one-quarter miles to Emerald lake. The mine lies about three-quarters of a mile down the east shore of the lake. A 75 h.p. Diesel engine and compressor were taken in over this' route last summer, and it is evident that the transportation problem is quite a serious one. Airplanes have been much in use, and a winter road runs from the mine to Chudleigh, on the .Canadian National railway near Sudbury.

Jan 1, 1936

By G. Vibert Douglas

"Gold occurs in Nova Scotia in three ways, saddle reefs, fissure veins, and fossil placers. Of these the saddle reefs are the commonest. They have been the source of most of the gold and have also been the subject of most of the literature on the gold occurrences.The Meguma or Gold-bearing series of Nova Scotia is a conformable succession of quartzite's and slates, possibly Precambrian in age, which have been folded into a number of anticlines and synclines that strike (Fig. 1) roughly east and west. This folding has been termed Acadian and is probably a westward continuation of the Caledonian revolution in Britain. It may have started in the Ordovician and continued through the Silurian and into the Lower Devonian. It was followed by the intrusion of the great Devonian granite batholiths. It is thought that the mineralization is connected with the late phases of the cooling of the granite. As the name saddle reef implies, the veins form on the crests and flanks of the anticlines, possibly in the synclinal troughs as well. The beds favoured by the solutions are the slates. The reason for this is apparent when it is realized that in order to fold over 30,000 feet of sediments (the thickness of the Meguma according to E. R. Faribault) through p radians of arc it is necessary to have a differential movement between the top and bottom beds of p times the thickness of the sediments. In the case of the Gold-bearing series, in which strong quartzite beds lie between incompetent slate beds, most of this differential movement was taken up in the slates. The evidence for this is the remarkably fine drag folding and the intense shearing and comminution of some of the beds of slate (Fig. 1). The quartzites exhibit some shearing and faulting, but there is little doubt that the greater permeability lay along the incompetent slate beds. The mineralizing solutions followed these beds and also passed from one slate bed to another through a joint or fault in the intervening bed of quartzite. These joining veins are called angulars in Nova Scotia. Within the veins the gold is in shoots and the real problem is to find out what controls the position and extent of the shoots."

Jan 1, 1954

By R. H. McMillan

A classification of important uranium deposits which utilizes both genetic and descriptive criteria is presented. The dual aspect is useful because, while the non-genetic nomenclature for the different deposit types is amenable to various interpretations, the critical characteristics of each deposit type can be analyzed to clarify various genetic points. Although the classification is intended primarily for Canadian uranium deposits, most of the important deposit types known elsewhere can be accommodated.

Jan 1, 1978