Search Documents

By Arash Nikvar-Hassani, Lianyang Zhang

To address the drawbacks of the conventional portland cement/fly ash (PC/FA)–based cementitious material currently used in practice to construct pumpable roof supports (PRSs), a novel cementitious material has been developed based on geopolymerization technology. The novel cementitious material is comprised of two pumpable grout streams: Stream 1 is a slurry composed of pozzolanic material and high-calcium additive and stream 2 is an alkaline solution comprised of a gelling agent. Biopolymer has been added to the second stream to provide ductility to the geopolymer cementitious material. In the laboratory scale, systematic experiments have been carried out to investigate the viscosity, setting time, and uniaxial compressive strength (UCS) of the new cementitious material and develop the right recipe for field applications. By collaborating with industry and the National Institute for Occupational Safety and Health (NIOSH), full-scale PRSs have been constructed and tested. The results show that (1) the novel cementitious material based PRSs has much higher peak UCS and similar or higher residual strength than the conventional PC/FA-based PRSs; and (2) unlike the PC/FAbased cementitious material, the novel cementitious material shows good long-term durability with nocracking/disintegration when exposed to air.

Jul 1, 2023

By R Fox, R Watt

On behalf of ICI's group of explosives companies around the world, a research programme is being undertaken to develop a new electrical shotfiring system which will have markedly improved safety features and operational advantages over existing initiating systems. The paper describes the development of the 'Magnadet' Electric Detonator and 'Magna' Primer and the field experience to date. It also indicates those areas where further work is being carried out on modification of the basic designs to meet specific application requirements.

Jan 1, 1981

By J R. Ruiseco, D La Rosa, L Julian, W Hunt

The DeGrussa copper-gold deposit is located 900 km North of Perth. Copper-gold bearing massive sulfide lenses occur in lower greenschist facies meta-sedimentary and mafic volcanics of the Bryah Basin. Regional folding, faulting, and tilting of the stratigraphy primarily occurred during the Capricorn Orogen (Johnson, 2013). The Shiraz Fault and Merlot Fault are regional oblique-sinistral faults that offset the DeGrussa massive sulfides lenses into three fault blocks by ~350 m and ~120 m, respectively. A network of deposit-scale brittle-ductile faults splay from, and in one example are cut by, the Shiraz and Merlot faults. This results in localised ore displacement, selvage alteration and degradation of the rock mass integrity. Historically, only the Shiraz and Merlot Faults were modelled and validated during mining and grade control. The requirement for a comprehensive structural model became more relevant as mining became advanced and confining stresses on local rock mass became more complicated. The DeGrussa Structural Model has been developed to delineate areas of structural complexity and is an important tool in mitigating rockfall risk through well informed technical design. During this process, every accessible excavation was walked and structurally mapped. New workflows in Leapfrog Geo and new technology, including an app that runs on mobile phones streamlined the validation process. Drill hole orientation was a limiting factor during validation. At the time of writing this submission, the DeGrussa Structural Model consists of 34 faults, and is now an important tool for the Technical Service team when developing mine plans and schedules. Applied structural geology is often seen as exclusive to those with a PhD in the field. Faults at DeGrussa have been modelled and reconciled by a Mine Geologist and Geotechnical Engineer, using first principles geological characterisation. This is a simple process that demonstrates any geologist can contribute to a structural model, provided they understand the fundamentals of unbiased structural measurements and consistent record of observation

Mar 22, 2022

By R A. Pax, B Cornish

Increasing the throughput of the MMG Century operation by over 25% from past practice to preserve cash flow close to the end of life of mine has revealed new throughput and load dynamic instabilities in the SAG mill causing significant time averaged loss of production. A twelve microphone array around the SAG mill (Pax, 2014) using the non-contact acoustic measurement methodology (Pax, 2011, 2012) has been used to diagnose the new dynamics. Dynamic acoustic noise signal information allows discrimination of the behaviour of the steel balls and the rock. Determination of mill load, toe and shoulder angles, water holdup, and proxies for mill load are possible.The instability was diagnosed with the help of an abnormality in the liners/lifters of the SAG mill with one row of lifters having a slightly increased in-mill life compared to the rest. The steel shoulder angle is observed to be disturbed cyclically at a rate of precisely one revolution at low throughputs of 750 t/h. However, at throughputs closer to 1100 t/h, the cyclic signal disappears indicating additional dynamics to randomise the repetitive behaviour of the mill charge. The cyclic signal has been used to operate the SAG mill with improved stability at 1100 t/h by adjusting the feed water addition rate.This paper presents and discusses these results and proposes the suggested origin of the extra dynamics. A small consistent aberration of the lifters circumferentially provides a useful detector of stable mill operation and a novel sensor for the dynamics of the internal operation of a SAG mill.CITATION:Pax, R A and Cornish, B, 2015. A novel measurement for the internal operation of a semi-autogenous mill using acoustic sensors – a case study, in Proceedings MetPlant 2015, pp 120–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By Huimin Lu, Shi Zhou, Lisha Yang

"The Zeolitic imidazolate frameworks (ZIFs) were successfully synthesized by applying a combination of ionothermal synthesis and microwave energies for rapid synthesis. The synthesis was proceeded under various conditions including different raw materials, reaction temperature as well as microwave irradiation time. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are new type of porous materials formed by inerratic polyhedral in three-dimensional. They are the ideal crystalline substances for gas separation and storage. The assynthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and C02 adsorption test. Results illustrated that the synthesized samples had stable structure, high thermal stability (up to 530 °C) and C02 adsorption capacity (10.2 cm3/g at 0°C under ambient pressure). This novel method also showed great advantage with high energy efficiency, safe synthesis conditions, and rapid crystallization time (60 minutes).IntroductionNowadays, carbon dioxide capture has become imperative due to the global warming caused by the increase of C02 in the atmosphere, especially produced by the concentrated sources such as power plants [1]. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are ideal crystalline substances for gas separation and storage due to their structure diversity, high thermal and chemical stability [2-5]. They are formed by inerratic polyhedra in threedimensional with large cages and small apertures. Traditionally, ZIFs are synthesized by solvothermal method in a sealed autoclave under autogenous pressure [6-9]. However, in order to generate the products, the solvothermal temperature should not be lower than 100°C according to the sovlothermal mechanism. Moreover, at such a temperature, molecules with a low boiling point (such as water) may generate high pressure in reactor which might cause danger [9]. Thus the synthesis requires the equipment to possess resistance to autogenous pressure and corrosion. Further, conventional solvothermal methods need a long time to prepare products, usually a few days, which is a large energy consumption and inefficiency. So it is interesting to synthesis ZIFs through other ways under mild reaction condition with high energy efficiency."

Jan 1, 2012

By Stuart Hardy, Xiangbo Qiu

The South Bank Place project comprised the redevelopment of the iconic Shell Corporation headquarters in Waterloo, located on the Southbank of the River Thames in central London. The site was originally developed in the 1950’s and due to the monitoring of the underlying Bakerloo Line tunnels by the Building Research Station it has become a seminal case history for the long term swelling behaviour of London Clay. The redevelopment, undertaken by a joint venture of Canary Wharf Group and Qatari Diar, included demolition of the existing building (with the exception of the main towers) retention of the existing basement structure and the construction of eight new mixed use buildings, up to 31 storeys in height. The foundations for the new buildings varied according to the building height and the below ground constraints. Two of the buildings are partially founded in reused under reamed piles that were installed as part of the original 1950’s development. The paper describes the novel methodology developed to assess the re-use of the under reamed piles which builds on the guidance published by CIRIA and the BRE for straight shafted piles. The paper also describes the physical investigations and numerical analyses undertaken as part of the assurance process and the procurement of latent defect insurance by the client.

May 1, 2022

By M. Saghaeian, R. Hejazi, Fakoor Sanat Tehran Company, H. Abedini, M. Zare

"Dewatering of final tailings is one the biggest issues in iron ore processing plants. Because of the fine and hydrophilic particles in the iron ore tailings, dewatering of such material is difficult and, in most of the cases, needs to be processed using expensive and complicated equipment. In this study, a novel method based on classification of small and large particles has been proposed to improve the dewatering performance of iron ore tailings. In the proposed method, a hydrocyclone has first been used to separate the fine and coarse fraction of iron ore tailings. Then, the coarse fraction (hydrocyclone underflow) is easily dewatered by using vacuum belt filter. Then, the fine fraction (hydrocyclone overflow) is primarily dewatered by using a high rate thickener. Finally, the thickener underflow is added to the bed of solids on the same belt filter, which is used for dewatering of hydrocyclone underflow. The efficiency of this method has been compared with other solutions for tailings dewatering including changing vacuum filtration parameters, using fabric with larger pore size, and using pressure filtration, all through laboratory scale experiments on the tailings of an iron ore processing plant in Iran. The results indicated the superiority of this method compared to the other ones, which increased the specific filtration capacity of the tailings by around 46%.INTRODUCTIONWet beneficiation of minerals requires a substantial amount of water to enhance the efficiency of the process. Used water should be recovered at the end of process to minimize shipping costs, meet contract specifications, and reuse process water (Wills and Napier-Munn, 2006). Dewatering equipment is usually divided into sedimentation (thickening) and filtration (pressure and vacuum) equipment, the choice of which depends on particle size, solid content of slurry, and material nature (Mular et al., 2002)."

Jan 1, 2016

By Kathryn Hindmarsh

The most common method for the concentration of cyanide in gold leach circuits is based on the titration of cyanide ions with silver ions. This can either be done manually as a titration with a visual end-point or by using one of several commercial cyanide analysers which are 'based on the same titration but use a potentiometric end point This method has 'its limitations in the case of some ores such as those containing high amounts of soluble copper and those that are treated at low (less than pH 9) pH values in that the titration results do not accurately reflect the concentration of cyanide which is available for the dissolution of gold. This paper will present the results of the development of a novel "active" cyanide analyser which is based on the rate, of the reaction between gold colloids and cyanide. Gold colloids have a deep red colour and can be very simply prepared and stored for extended periods of time when stabilized. t has been shown that colloidal gold behaves similarly to metallic gold, dissolving in aerated sodium cyanide solutions to give the colourless Au(CNh-ion, This allows the reaction between the colloids and cyanide to be monitored spectrophotometrically at 520 nm. An automated instrument has been developed around this concept which can analyse a filtered pulp stream every few minutes with periodic calibration using standard cyanide solutions, Results of test work on synthetic solutions and solutions derived from several Australian gold plants will be presented as will the results of a comparative evaluation with a commercial titration analyser on a local gold plant

Jan 1, 1998

By D. D. Marsden, L. E. Kun

Although a regulation is in force that all water used underground shall be free of bacterial contamination, in practice it is often very difficult to accomplish this. The standard method of disinfection m South African mines IS treatment with calcium hypochlorite, although liquid sodium hypochlorite is used at a few sites. Primarily because the process depends on human control for the addition of the hypochlorite and the regulation of its now, it is frequently found difficult to disinfect mine water adequately and continuously. In many marine environments, chlorine generated by the electrolysis of seawater in its passage through an electric cell is used for disinfection. The generation procedure is continuous and needs no human control except for occasional checking of the equipment. This paper describes the successful implementation of the process, suitably .modified, .at four underground sites. After severe scaling problems had been overcome, a procedure resulted that chlorinates considerably more effectively than the previous system (dosing with calcium hypochlorite), and that has a lower amortized operating cost.

Jan 1, 1981

By S. Abe

Various copper anodes to be electrorefined were subjected to a heat treatment comprising annealing at a temperature in the range of 700 °c to 1,000 °c followed by a slow cooling preferably on the order of about 150 °c, and using these heat treated anodes , a series of dissolution experiments were conducted under conventional electrorefining conditions. The results obtained have indicated that the above annealing/slow cooling process dramatically improves the dissolution activity regardless of the type of anodes. As an example, passivation times of l to 3 minutes in a standard test have been increased to more than 80 minutes by this innovated heat treatment. Other advantages sterning from the improved anodic activity include reduced electrical short circuiting which results in substantial labor effort in the tankhouse, reduced energy requirement, and reduced cost of processing anode slimes because the amount of anode slimes is reduced. In addition, this process gives rise to a dramatic change in the nature of anode slime layer formed in such a way that a comparable final cathode copper product can be achieved even from high-impurity copper starting material.

Jan 1, 1987

By L. Zhou, D. Bahrami

Mine ventilation is one of the most important aspects of mining operations in underground mines. It is critical to maintain and deliver required fresh air to the active areas to reduce the risk of overexposure to hazardous contaminants or explosive atmospheres. An unexpected or unknown event such as roof collapse, unexpected mine door closure/opening, a fire/explosion, or fan malfunction could adversely alter the airflow distribution within the mine ventilation network that could lead to a hazardous underground environment. Knowing the occurrence and location of such an incident is of critical importance. In this study, the authors developed a novel methodology to assist mine operators in quickly identifying the location of any abnormal airflow change within the network using the airflow changes at monitored airways. The concept is based on a direct derivative method developed by the authors. This paper provides the details of the developed method as well as numerical verification examples. The application of this method can benefit mine operators and safety personnel in making better decisions during a mine emergency response operation to mitigate hazardous conditions arising from an unexpected airflow disturbance

Mar 2, 2022

By Limao Zhang

This paper presents a novel model to assess the risk of adjacent buildings in tunnelling environments based on Extended Cloud Model (ECM). ECM is an organic integration of Extension Theory (ET) and Cloud Model (CM), where ET is appropriately employed to flexibly expand the variable range from [0, 1] to (-8, +8), and CM is used to overcome the randomness and fuzziness during the gradation of evaluation factors. The risk level of a specific adjacent building is assessed by the correlation with the cloud models. A confidence indicator ? is proposed to illustrate the rationality and reliability of evaluating results. Ten buildings adjacent to Wuhan Metro Line Two (WMLT) are randomly chosen among hundreds of adjacent buildings for a case study. Results have proved to be consistent with the actual situation. Compared with other traditional evaluation methods, ECM has been verified to be a more competitive solution with high calculation accuracy, wide adaptability, as well as simplified computer programming. There are no stringent requirements on the quantity of training data during the modelling process, and the original data can be directly entered into ECM without a normalization procedure, avoiding the potential information loss. ECM can be offered as a decision support tool for the risk assessment in urban tunnelling construction and worth popularizing in other similar complicated projects.

Aug 1, 2013

By E. A. Devuyst, M. A. Mosoiu, V. A. Ettel

Nickelic hydroxide is an important metallurgical reagent used for precipitating cobalt from nickel sulfate solutions. Existing methods of preparation of nickelic hydroxide involve electrolytic oxidation of Ni(OH)2 or the use of strong oxidizing agents such as chlorine, ozone and persulfate. Although the oxidizing properties of the SO2 + O2 system have been known for some time, e.g., detection of SO2 and oxidation on iron in acidic solution, the application of this system for the preparation of nickelic hydroxide as a process was not considered in the past. The present paper describes a new method for chemical preparation of nickelic hydroxide which has been developed in INCO laboratories. The technique consists of reacting nickelous hydroxide suspensions with a slurry of calcium sulfite in the presence of air or oxygen. The main advantage of the process is the cost of reagents and an absence of soluble by-products (e.g., C1-). The chemistry of this process is unusual since the redox potential obtained during the reaction exceeds that of the oxygen electrode. Therefore, the effect of CaS03 is not just a catalytic acceleration of the reaction NI(OH)~ + 02. The so3= must be involved in the stoichiometry of the overall reaction producing in the initla1 phase some strongly oxidizing intermediate species.

Jan 1, 1981

By D. W. Wu, M. T. Haque

A novel impedance probe has been commissioned specifically for capturing fast dynamic information about filtration processes. It provides an attractive alternative to more complex measurement techniques in situations where the slurry system is primarily one-dimensional. The probe can monitor mud-line, slurry densification and drainage. Dynamic variations in cake permeability are obtained by combining dynamic mud-line information obtained with the probe and filtrate rate data derived from a leaf test apparatus. The measurements are re-viewed in relation to micro structural measurements obtained on iron ore filter cakes. The practical significance of these measurements for optimization of the filtration process is discussed.

Jan 1, 2000

By Fu-Shen Zhang, Mengjun Chen, Jianxin Zhu

"A novel approach for foam glass preparation, namely vacuum-aided powder sintering technique, was preliminarily investigated in the present communication. The key point of which was to prepare foam glass at a negative pressure. Compared to normal powder sintering process, the new approach could benefit the foaming process by shorting the holding time, reducing the amount of foaming agent and especially decreasing relative density of the product. Optimum conditions were 750 °C, 1000 Pa, 5 min and 1 wt.% foaming agent, respectively.IntroductionFoam glass represents a highly valuable solution for thermal and acoustic insulation, since it possesses a generally higher mechanical, chemical and thermal stability than other foams'1'. The first industrial processing for foam glass production, the direct introduction of gases (""blowing"") into the special molten glass, can be dated back to the end of 1930s'2'. At present, almost all foam glasses is prepared by powder sintering technique instead of blowing,3 since it reduces the temperature by several hundred degrees. Moreover, as fine glass powders or similar powders can be used to substitute corresponding glasses by this technique, considerable attention has been focused on the production of foam glass by considering fully recycled glasses, coal fly ash, or other solid wastes as raw materials,4 especially CRT glasses'3' 5', on the point of environmental protection.In a previous report'6', when discussing the lead removal and recovery from CRT funnel glass by a pyrovacuum process, we found that foam glass could be prepared at a negative pressure. Therefore, in this communication, the similarities and differences between the powder sintering process for foam glass at normal and negative pressure was preliminarily discussed."

Jan 1, 2011

By A. Robles-Vega

Personnel of Mexicana de Cobre, a subsidiary of Southern Copper located in Nacozari, Sonora Mexico have been working in the past few years on the development of a process to treat and manage, in an environmentally accepted practice, the residues and effluents generated during the process. To date, this team has been reviewing existing technologies and also has explored new alternatives. At the end of this phase, a novel, efficient and complete process has been configured which will be able to treat some solid and liquid streams such as Teniente converter dust, Peirce Smith converter dust, a Sb-rich precious metals slag, copper refinery electrolyte bleed, acid plant blowdown and an acid bleed of the precious metals plant. The process will consist of a leaching stage, followed by a very selective copper precipitation using novel technology which has been named as back reactions. After copper precipitation, impurities (As, Sb and Bi) will be precipitated mainly as arsenic trisulfide (As2S3) using H2S(g) which will be generated by means of a new process developed in our company. At the end of the process, small volumes of arsenic trisulfide will be vitrified and then disposed as a stable residue.

Jan 1, 2007

By Xuliang Yang, Yuemin Zhao, Bo Zhang, Liang Dong, Cheng Sheng, Gongmin Li, Zhenfu Luo, Yaqun He, Chenlong Duan

Coal plays an important role in the primary energy consumption of all over the world. In 2012, coal reached the highest share (29.9%) of global primary energy consumption since 1970. Coal burning mainly contributes to the emission of SO2, NOX, Hg and other impurities that jeopardize the future of environment. . Beneficiation before coal utilization is the most economical and effective technology for removing the hazardous material and gangue. In this paper, a novel process of dry beneficiation based on gas-solid two-phase flow composed of the compound dry cleaning separator (FGX), the air dense medium fluidized bed separator (ADMFB) and the vibrated fluidized bed with autogenous medium (VFB) is proposed. The main equipment and the flowsheet of the united system are described in detail. Separating principle of the FGX, ADMFB and VFB devices are all based on gas-solid two-phase flow. In FGX, gassolid suspension is composed of continuous gas flow and coal powder in feed coal. Large size coal (+6- 80mm) can be pre-separated effectively, and large size gangue can be removed effectively. Moreover, - 6mm particles fed serve as autogenous medium in FGX. The probable E value is 0.13 for -80 mm raw coal. In ADMFB, magnetic powder with -0.3 + 0.045 mm size fraction and coal powder in feed coal are compound medium solids. The separation density can be adjusted and controlled according to properties of raw coal. -50 + 6 mm raw coal can be cleaned efficiently, the probable E value is 0.05. In VFB, -6 + 1 mm coal can be separated. Generally, -80 mm raw coal can be cleaned efficiently in the united system based on gas-solid two-phase flow.

Jan 1, 2014

By Atsushi Shibayama, Toyohisa Fujita, Luo Lin, Toshio Miyazaki

A novel process is developed in this study for separation of tungsten and vanadium from a leach solution of tungsten alloy scraps. Specifically, a magnesium salt combined ammonium solution is employed to precipitate vanadium and impurities in the purification of the leach solution. This separates vanadium from tungsten by rejecting tungsten in aqueous solution. Finally, tungsten is recovered as the form of ammonium para-tungstate (APT). Vanadium is recovered as the form of ammonium meta-vanadate(AMV).

Jan 1, 2003

By I. Paredes, R. Díaz, H. Henao

Smelting of copper concentrate generates a significant amount of dusts which are collected in electrostatic precipitators. This material, which is a complex oxide of Cu, Fe, S, As, Sb, Bi and others, is difficult to recirculate into the smelting process due to the reported high concentration of arsenic. However, the dust also has concentration of copper above 10wt %, aside from reported contents of silver corresponding as much as 25wt% of the total inventories of this element in the smelters. Thus, it is of economic and environmental interest the development of a process able to reduce the concentration of arsenic in the dust and produce a material suitable to be recirculated into the smelting process. The present experimental work shows the results of a process of dust sulfidization-oxidition able to remove more than 65wt% of the arsenic present. INTRODUCTION Copper sulfide deposits worldwide exhibit increasing concentrations of arsenic. One case of interest would be the copper ores from the northern zone of Chile, which report high concentrations of enargite (Cu3AsS4) (Revista química, 2015) (Latinominería, 2014). The obtained concentrate from this ore is treated in a Fluidized Bed Roaster, producing calcines with low concentration of arsenic (<0.5 wt% As). This material is suitable to be treated in a Flash Furnace. At the roasting process, the arsenic is volatilized and then precipitated as fine particles of complex oxides. Most of this particulate material is removed from the gas stream through a device called Electrostatic Precipitator (Minería chilena, 2014). The experimental results reported in the literature indicate that arsenic present in these particulate materials (or dusts) cannot be eliminated in oxidizing atmospheres (air) or with inert gases (N2) in a Fluidized Bed Roaster even at temperatures as high as 700°C. There is also information that even the recovery of valuable metals from the dust is difficult through hydrometallurgical processes (private communication). This is how in some foundries these dusts are considered environmental liabilities. Regarding the decomposition of enargite (Cu3AsS4) in neutral atmosphere, it is reported in the literature (Padilla, 2001) that the main chemical reactions are:

Jan 1, 2019

By D. R. Spears

The U.S. Bureau of Mines has developed a Fast Air-injected hydrocyclone-Shallow Tank (FAST) flotation system. Conventional flotation cell kinetics are a compromise between two conflicting requirements, the need for an agitated zone for rapid bubble-particle collision, and a quiescent zone for bubble-pulp separation. The Bureau of Mines has designed a flotation system in which bubble-particle collision and bubble separation are carried out in two discreet unit operations. A bubble slurry was mixed with an ore slurry at a high rate in a modified air-injected hydrocyclone for rapid bubble-particle collision. The mixture was then fed into a unit specially designed for rapid separation of the bubbles from the pulp. A conventional flotation cell required 2.8 min to obtain 90 pet recovery at a 7-pct Cu rougher concentrate grade, whereas the FAST flotation system can obtain 85 pet recovery with a 13-pct Cu rougher concentrate grade in 0.28 min, and 92 pet recovery with a 7-pet Cu grade in 0.56 min. The Bureau&apos;s FAST flotation system is adaptable to a wider variety of flow sheets and could potentially allow for replacement of conventional flotation cells with smaller and faster units.

Jan 1, 1991