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By Lowell Stroud

Ten natural gases containing from 0.023 to 8.4 percent helium were investigated. In seven high-helium samples, the isotopic abundance of Ne21 was greater than in the atmosphere, being supplemented by 33 to 85 percent of "excess" or "radiogenic" Ne21. The ratio of He4/Ne21(rad) in these gases was evaluated and found to vary between 2.9 x 107 and 5.9 x 107 , a factor of approximately 2. Argon concentrations were determined by the isotope dilution method. The isotopic ratios of Ar40/Ar36 in the high-helium gases were from 5 to 75 times the atmospheric value, with the Ar40 being about 80 to 99 percent radiogenic in nature. The ratios of He4/Ar40(rad) in all 10 gases were evaluated and found to range from 4 to 18. The isotopic ratio of N14/N15 in four of the high-helium gases was essentially the same as in the atmosphere; in three cases it was approximately 5 percent higher than the atmospheric value of 272.0. The genesis of nitrogen and the relationship of nitrogen to helium in natural gases were reviewed and are discussed in terms of a theory for the concurrent generation of nitrogen, helium, radiogenic neon 21, and petroleum (hydrocarbon gases and liquids).

Jan 1, 1967

In 2005, a total of 263 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Metal mines were the smallest mining commodity sector, comprising 1.8% of all mining operations. ? Gold mines comprised 46.0% (n=121) of all metal mining operations. Other common types of metal mines were iron ore (n=32; 12.2%), copper ore (n=31; 11.8%), and lead and/or zinc ore (n=16; 6.1%). ? Nevada had the largest number of metal mines (n=52; 19.8%), followed by Alaska (n=27; 10.3%).

Sep 1, 2008

By S. H. Ash

THE MAGNITUDE of the anthracite industry's drainage problem in the Northern field of Pennsylvania is realized when it is known that, for the 8-year period 1944-51, all pumping plants in this region pumped an average volume of 112.5 billion gallons of water from the mines to the surface each year. This is over 214,000 gallons per minute pumped against an average hydrostatic head of 400 feet each year for that period (12).4 By comparison, Lake Wallenpaupack, the largest artificial body of water lying wholly in Pennsylvania, contains 71 billion gallons of water in its 24-square-mile area; the average volume of water pumped from the mines in the Northern field each year during the 8-year period was 58 percent more than the volume impounded in Lake Wallenpaupack. The natural configuration of the drainage area overlying the Northern field subdivides the total area into two major drainage areas-the Lackawanna River drainage area and the Susquehanna River drainage area overlying the Wyoming Basin. Although the 169-square-mile drainage area overlying the Wyoming Basin is slightly less than half that of the Lackawanna River drainage area (10), the total volume of water pumped to the surface from mines in the Wyoming Basin is 21 percent more than the total volume pumped to the surface from mines in the Lackawanna Basin. From this, it is apparent that the Susquehanna River and the pervious deposits in the buried valley over which it flows in its course across the coal measures of Wyoming Valley is the greatest single source of mine water affecting mines in this area. Because of its relatively flat terrain, the wide flood plain of Wyoming Valley does not facilitate rapid runoff; consequently, much of the surface water seeps directly into the buried-valley deposits and eventually into the mine workings.

Jan 1, 1953

By Larry G. Stolarczyk

An underground medium frequency radio communications system has been developed and demonstrated in both coal and metal/non metal mines. The principal advantage of the system are its low cost, ease of installation and the ability to provide radio communications to any vehicle or roving miner in the underground mine. The system provides high quality radio coverage in work areas and along manways with existing "wireplant" conductors. The conductors include AC power cable, telephone cable, metal water and high pressure air pipes, etc. The measured communications range from the base station to mobile transceiver exceeded 12,500 ft without the use of repeaters. A cost/benefit analysis shows that the initial cost of the equipment can be returned 2-6 times in the first year. The mine productivity increases by approx. 13 percent.

By Harold L. Riley

This Bureau of Mines paper describes the methods and practices used at the Peck quarry of the Crab Orchard Stone Co., Inc., one of the leading producers of dimension stone in the Crossville, Tenn., area. The product is marketed under the registered trademark "Crab Orchard Stone". Another large producer of stone from the Crossville district sells its product under the registered trademark of "Tenn-Quartz". Both companies, and a number of other companies and individuals who quarry and process dimension stone from the same general geological formation, are members of the Quartzite Producers Association of Tennessee. The salable product is shipped throughout the country for use as architectural building stone. In 1959, 653,008 cubic feet of stone was produced in the Crossville area and was sold for $1,414,405. Terms and descriptions used in this report are those of the quarry and building trades. The offices, pitching sheds, wire saws, railroad siding, and storage areas of the Crab Orchard Stone Co., Inc., are on a side road 0.3 mile north from a point 2.2 miles east of Crossville, Tenn., on U.S. Highway 70. The quarry is on this same side road 2.0 miles south of Highway 70. Crossville is 62 miles west of Knoxville and 65 miles northeast of Chattanooga, Tenn.

Jan 1, 1962

By V. L. Burdick

A literature review of current uses of Mn02 in ceramic applications with suggestions for future research. Historical background, oceanographic distribution, geology, exploitation, law and politics. Uses of Mn02 in ferrites, semiconductors, catalytic processes, thermo-luminescence and photochromic materials. Select bibliography of 33 items, plus 129 references.

Jan 1, 1980

By Victor R. Spironello

Applications of three experimental design techniques to smelting operations are explained. The report describes a factorial design using three variables at two levels, a fractional factorial design which investigates seven variables, and response-surface methodology for optimization of electric- furnace smelting processes. These methods may be applied with a minimum of trials and at little expense. Further, the writer knows of no reasons why the same methods could not be applied to other operations as well, such as steelmaking.

Jan 1, 1970

By R. M. Gooding

This paper presents a short history of the production of mineral-energy fuels and energy from waterpower in the United States, with brief discussions of the utilization of each of the fuels and hydropower, and a look at fuels competition and interchangeability. Basic data, in figures and tables, are brought together in this publication for the production of coal in the United States from 1800 to 1960, for crude petroleum, natural gas liquids, and natural gas from 1859 to 1960, and for hydropower since 1900. Production for each segment of the fuels complex in the principal producing States from 1946 to 1960 is shown. Data are not included for consumption as such or for imports and exports.

Jan 1, 1963

By R. M. Gooding

This paper presents a short history of the production of mineral-energy fuels and energy from waterpower in the United States, with brief discussions of the utilization of each of the fuels and hydropower, and a look at fuels competition and interchangeability. Basic data, in figures and tables, are brought together in this publication for the production of coal in the United States from 1800 to 1960, for crude petroleum, natural gas liquids, and natural gas from 1859 to 1960, and for hydropower since 1900. Production for each segment of the fuels complex in the principal producing States from 1946 to 1960 is shown. Data are not included for consumption as such or for imports and exports.

Jan 1, 1963

By G. A. Apell, E. G. Howe, S. W. Hazen

"INTRODUCTION As a small amount of manganese was produced from the Lake Valley mining district of Sierra County, N. Mex., during the First World War, the district was reexamined in March 1941 by John H. East, Jr., an engineer of the Bureau of Mines, as a possible source of manganese for use during the Second World War. Preliminary examination indicated a substantial reserve of 25 percent ore, so it was recommended that an exploratory program of mapping and sampling be undertaken by the Bureau.The program was started in the fall of 1941 and was completed the middle of 1942. The project 3/ was divided into two parts: The first, an underground sampling program, formed the basis for the second, or churn-drilling program. Mapping and sampling of old underground workings were begun in October and finished in November 1941, whereas churn drilling was begun in February and completed in June 1942."

Jun 1, 1947

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1983 was $361.3 million, an increase of $61.9 million over that of 1982. The increase reversed a downward trend that started in 1980 and established a new record high for value of nonfuel minerals in the State. Output of most nonfuel minerals increased to some degree with unit value increases creating the record-high value year. Cement, clays, lime, sand and gravel, and crushed stone were the major commodities produced in Alabama. Alabama led the Nation in the production of crushed marble; was second in bauxite; fourth in ferroalloys, dimension marble, common clay, and fire clay; fifth in bentonite and kaolin; and sixth in masonry cement and lime.

Jan 1, 1985

By Charles S. Allbright, Frank G. Schwartz, Marvin L. Whisman

Radioactive tracer techniques were used to gain a better knowledge of the types of compounds that cause gum formation in gasoline during storage . A selected organic compound was labeled with tritium and purified . An unstable gasoline was tagged by adding a small amount of the labeled compound . After storage of the gasoline at 110 ° F for 16 weeks , the gum that had formed was recovered . The amount of the test compound converted to gum was determined by liquid scintillation counting . About 70 compounds , including several classes and types , were studied . The compounds , listed in order of descending reactivity in the test fuel , were sulfur compounds , nitrogen compounds , polycyclic hydrocarbons , olefins , alkylbenzenes , and saturates . In the order of decreasing percentage of each in the gum , the compounds were monoolefins , alkylbenzenes , sulfur compounds , polycyclic hydrocarbons , nitrogen compounds , and diolefins . This type of information should be helpful in developing a method for predicting the storage stability of gasoline .

Jan 1, 1964

By Terry J. Close

In 1985, at the request of the U.S. Bureau of Land Management, the U. S. Bureau of Mines studied part of the 56,623-acre South McCullough Mountains Wilderness Study Area (NV-050-435) in order to evaluate its identified mineral resources. The area studied is located in Clark County, NV, about 30 miles southwest of Boulder City. No mineral resources were identified. The study area contains the eastern part of the unorganized McCullough Mountain (McClanahan) mining district which has had no recorded production. Between 1911 and 1982, 23 lode claims were located in the part of the mining district that is in the study area; four of these claims are currently held by assessment (1986). A total of 11 mineral sites were found and examined during the U.S. Bureau of Mines investigations; 26 mine workings were examined. Of the 11 sites, four are within the study area, and seven are nearby. Of the seven nearby sites, six are adjacent to the west boundary and consist of precious-and base-metals bearing vein occurrences in metamorphic rocks. The seventh site is near the east study area boundary, and consists of a tungsten-bearing vein occurrence that is also in metamorphic rocks. The four sites within the study area consist of vein occurrences in metamorphic rocks that contain silver, gold, arsenic, lead, zinc, and copper. The veins at these four sites are too small and low grade to be classified resources; however, there are indications that three of the sites may have silver and gold resources at depth. Detailed delineation of the veins, and determinations of tonnages and grades are needed. This would entail additional mapping and sampling, trenching and drilling, and opening inaccessible workings.

Jan 1, 1987

By James C. Barker

Yttrium and rare-earth element. pegmatite dikes are associated with a peralkaline granitic and nephelene syenite complex near Dora Bay on southern Prince of Wales Island. Mineralized dikes were mapped and sampled during USBM investigations in 1987 and 1988. Coarse-grained pegmatite dikes, which emanated as late-stage magmatic fluids from the intrusion, further evolved into vein-dikes and ultimately silica-rich veins. The dikes can be traced up to two miles along a north-south zone. Lithophile elements exhibit a pronounced zonation in vein-dikes and veins that are distal to the Dora Bay complex with increasing values correlating with increasing distance from the complex. The pattern of mineralization suggests very late stage magmatic fluids containing the incompatable lithophile elements were injected into a preexisting north-south fracture zone. REE mineralogy exhibit fine-grained intergrowths of principally thalenite and bastnaesite with lessor monazite and eudialyte. Euxenite contains most of the columbium values and zircon is commonly associated with the dikes. Estimates of inferred and hypothetical resource tonnage range from 1.7 X 1C6 to 8.5 X 106 st for two deposits. Contained RED (including yttrium) averages 0.5 pct and ranges up to 2.0 pct. Deposits are of polymineralic composition and about half of this resource comprises the heavy yttrium subgroup.

Jan 1, 2011

By V. A. Marple, K. L. Rubow, S. M. Behm

"An eight-stage cascade impactor, with cut-sizes ranging from 0.056 to 18 um at a flow rate of 30 L/min, has been developed, calibrated, and tested in field programs. This impactor, called a microorifice uniform deposit impactor, has several features not normally found in cascade impactors. Ultrafine particles as small as 0.056 um are collected while keeping the pressure drop moderate by utilizing multiple nozzles (up to 2000) as small as 52 um in diameter. At each stage the collected particles are deposited uniformly over the entire impaction plate by rotating the impaction plate relative to the nozzles and by the correct radial placement of the nozzles. The particle cutoff characteristics (collection efficiency curves) of each stage and inter-stage losses were determined by means of monodisperse aerosols. The cutoff characteristics were found to be sharp and similar for all stages.Inertial impactors are widely used for the size-selective collection of aerosol particles. One reason for their wide usage is that the principle of operation is simple: a jet of particle-laden air is directed at a flat impaction plate. Large particles are collected on the plate while smaller particles follow the airflow out of the impaction region and are not collected. The division between the size of particles collected and those that are not is quite sharp. Secondly, the particles in an impactor are classified by their aerodynamic diameter (an important size parameter in many fields of study, including those related to respirable particle health effects). Thirdly, it is easy to collect particles in discrete size ranges by passing the aerosol through a number of stages (one stage consisting of a nozzle and impaction plae) in series, with each subsequent stage collecting particles smaller than the one before it. This is known as a cascade impactor. Finally, impactors can classify particles over a wide range of particle sizes: as low as 0.005 um (Fernandez de la Mora et al., 1990) and as large as approximately 50 um (Vanderpool et al., 1987).This paper describes a general purpose cascade impactor that has been developed in our laboratory and used in a variety of studies including visibility studies (McMurry et al., 1986; McMurry and Zhang, 1989), underground mine studies (Marple et al., 1986; Rubow and Marple, 1988; Rubow et al., 1988), and general atmospheric pollution studies (Macias et al., 1981; Dzubay et al., 1984). The impactor, called a microorifice uniform deposit impactor (MOUDI model 100, MSP Corp., Minneapolis, Minn.), is the integration of two earlier impactor de¬velopments: the microorifice impactor (M01) (Kuhlmey et al., 1981) and the uniform deposit impactor (UDI) (Marple et al., 1981).The MOUDI has several features normally not found in other cascade impactors. These include collection of particles as small as 0.056 um in aerodynamic diameter with a moderate pressure drop, uniform particle collection on the impaction plates, inter-changeable impaction plates to allow for the plates to be easily and quickly changed in the field, and covers for these substrates to provide a means for safe storage and/or transport of the collected particles to the laboratory for analysis."

Mar 1, 1992

By Jr. Sayre

Results of studies of reservoir and wax-precipitation temperatures relating to wax deposition in the reservoir of the Bradford oil field are presented in this report. During 1949 and 1950 Bureau of Mines engineers made temperature measurements in 42 wells, which indicate that the Bradford Third-sand temperatures range from 59.7° F., at 1,150 feet, to 71.9° F., at 2,040 feet. Reservoir temperatures measured at the same depths in newly drilled wells and oil-producing wells differed as much as 4.5u F. Injection-well temperatures measured during water injection showed that the temperature of the water entering the sand was 11.5° F. lower than reservoir temperatures before injection. The cooling in the formation resulting froth the injection of low-temperature water was 11.5° F. in the vicinity of the injection-well bore, and a maximum of 2.1° F. 200 feet from the injection well. Sand temperature, after 5 months of water injection, was reduced 1.5° F. 90 feet from water-injection wells. The temperature at which wax begins to precipitate from solution in crude oil was determined at atmospheric pressure for 26 samples and ranged from 51° to 67° F. Oil samples from wells producing no water had wax-precipitation temperatures ranging from 51° to 58° F. and wax contents from 2.20 to 2.97 weight percent, whereas the samples from wells producing water and oil had wax precipitation temperatures ranging from 580 to 67° F. and wax contents from 2.57 to 3.42 weight percent .

Jan 1, 1952

By Nancy Potts, M. G. Barker, W. C. Holliman

"SUMMARYThis report on the characteristics of commercial aviation gasolines presents compilations of inspection test data furnished on their products by manufacturers of commercial grades of aviation gasoline, and special data obtained in Bureau of Mines laboratories on samples of these gasolines. Data and physical samples for the survey were submitted by 15 manufacturers on 18 grade 80, 21 grade 91/98, 22 grade 100/130, end 10 grade 115/145 aviation fuels.The inspection test data supplied by the participating manufacturers consist of octane and performance numbers, tetraethyllead content, dye color, and other characteristics usually listed in aviation gasoline specifications, such as AN-F-48a or ASTM Designation D910-47T. These data are tabulated and averaged by grades in tables 1 through 4 and, as reported, meet the AN-F-48a and similar specifications with a few exceptions. Two grade 80 gasolines show a lean-mixture octane rating slightly below 80.0, and 91/98 grade fuel shows a lean-mixture rating of 90.9 and a rich-mixture rating of 97.5, two 100/130 grade gasolines have a rich-mixture performance number slightly below 130.0, and one 115/145 grade gasoline shows a rich-mixture performance number of 144.5. However, octane and performance number averages are above the mini¬mum requirements for each grade. Tetraethyllead content in the 91/98 and 100/ 130 grades generally is above the maximum outlined in these specifications, whereas dye color for each of the four grades, with the exception of two gasolines in grades 80 and 100/130, is that designated for the particular grade. Distillation requirements, with a few exceptions at individual points, are met by gasolines of all grades. Reid-vapor-pressure, copper-dish-residue, heat-of-combustion or aniline-gravity-constant, freezing-point, and copper-strip-corrosion requirements are met by all gasolines so far as reported. No data for some of these tests wore submitted on a few of the gasolines. One gasoline, grade 115/145, shows a sulfur content greater than the specified maximum."

May 1, 1948

By A. J. Kraemer, O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Coordinating Fuel Research (C. F. R. ) Committee of the Coordinating Research Council (C. R. C.) and the Bureau of Mines of the United States Department of the Interior . The first of these reports contained data on motor gasolines sold during the winter of 1935-36 and further reports on motor gasolines sold during the succeeding summers and winters to the summer of 1941

Dec 1, 1943

By Earl T. Hayes, W. M. Sternberg, F. P. Williams

"INTRODUCTION The limited domestic demands for lithium salts and metal before the war were met readily by the use of minerals particularly lepidolite (lithium mica) and amblygonite (a lithium phosphate), from which lithium can be recovered relatively easily. New wartime uses, however, created such a demand that it became necessary to turn to spodumene (a lithium feldspar) as the principal source of supply. Although very large deposits of spodumene occur in South Dakota and in North Carolina, it much more difficult to extract lithium from spodumene than from lepidolite or amblygonite.During the spring and summer of 1942 a study was made in Salt Lake City laboratory of the Bureau of Mines on the recovery of lithium from spodumede. Preliminary tests were made on two processes - roasting with potassium sulfate 4/ 5/ and roasting with calcium chloride and calcium carbonate 6/ -,which appeared to be the most promising of the various processes that had been proposed. By roasting spodumene with approximately its own weight of potassium sulfate at 1,050º C. and leaching the product with water, about 70 percent of the lithium could be extracted. Consumption of the relatively expensive potassium sulfate, however, was high; much of the potassium was found in the insoluble leach residue, end large amounts were lost by volatilization and dusting. By roasting the spodumene with calcium chloride and calcium carbonate, nearly 90 percent of the lithium was chloridized temperatures of 850° to 1,050° C. Much of the lithium could be extracted from the calcine by leaching with water after roasting at the lower temperatures, but volatilization of lithium chloride was appreciable, amounting to 20 to 25 percent in a direct gas-fired furnace at temperatures of 800° to 850° C. At 1,000° to 1,050° C., volatilization was far from complete. Thus, it would be necessary to use both fume collection and leaching of the calcine, unless the roasting temperatures were sufficiently high to volatilize all the lithium chloride. Because of the well-known difficulties of collecting chloride fumes, it was decided to search for a better process."

Mar 1, 1946

By R. A. Busch

Sludge ponds of fine coal, fine soil, and water created behind large piles of coarse coal waste can present hazardous conditions; this is a Bureau of Mines report of the subsurface physical property data developed on the fine coal waste materials that make up the core areas of two typical coal waste impoundments. These data will help define more completely the engineering properties of this problem area of the structures. Additional calorific, chemical, and mineralogical data were obtained on the coal waste materials to determine possible uses or development of byproducts. The possibility of extracting alumina from coal ash was also investigated.

Jan 1, 1975