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By Güven Önal, Zeki Dogan, Neset Acarkan

"In general, the processing of glass sand may involve comminution, washing, wet classification and attrition scrubbing. Additional processes may include magnetic separation, flotation and leaching in various combinations.Yaliköy sand dune deposit is located near to Istanbul on the European side by the Black Sea coast. The reserve of deposit is around 70 million tons. Iron content of Yaliköy sand dunes is 0.48 % Fe2O3 and not suitable for glass manufacture. The iron content of glass sand should be less than 0.15 % Fe2O3 for window glass manufacture and 0.05 % Fe2O3 for glassware. In this study, it was aimed to produce glass sand with less than 0.15 % Fe2O3 for window glass and with less than 0.05% Fe2O3 for glassware manufacture from Yaliköy sand dunes. A representative sample with a weight of 200 kg was taken from Yaliköy sand dunes deposit through opening small pits.• Mineralogical studies have shown that iron is present in three forms:• Hematite, limonite, clay and iron silicate minerals such as epidote and garnet occur in free form.• Quartz grains are coated by hematite and limonite.• Iron is also present in the cracks of quartz grains.Free iron minerals such as hematite and limonite and silicate minerals were subjected to magnetic separation and flotation for removal. Iron coatings were tried to be removed by scrubbing and leaching. Iron removal in the cracks of quartz grains was attempted by grinding and leaching.Under optimal conditions, sand concentrate with 0.38 % Fe2O3 was obtained by means of high intensity disc type magnetic separation. Grinding and scrubbing were applied to see the effect of size reduction and attrition at room temperature and 90 ºC, by using non-magnetic fraction. Sand concentrate with 0.13% Fe2O3 was obtained at 90 ºC in this test.Sand sample which was previously ground to minus 0.5 mm and scrubbed, was floated by using sulphonates as collector. After flotation tests, sand Concentrate was obtained with 0.11 % Fe2O3.The optimum iron removal was achieved by H2SO4 leaching at 90 ºC depending on acid concentration and leach duration in static, percolation and agitation leaching. Agitation leaching was done by the use of mixer at 600 rpm, 50% solids and leach duration was 15 minutes."

Jan 1, 2003

By Manisha Singh, Manikanchan Sarkar

"Presently the global steel production is mainly based on iron ore sourced from high grade hematite deposits. India has large deposits of good quality hematite ore but with the prevailing practice, such deposits are depleting fast and getting exhausted. However, apart from such high grade iron ores, India is also endowed with large reserves of low grade iron ore, such as BHQ (Banded Hematite Quartzite), BHJ (Banded Hematite Jasper), BMQ (Banded Magnetite Quartzite) and Magnetite. In the present situation, it has become necessary to focus attention on upgradation of these low grade ores to produce useable concentrate. It augurs well that already substantial investigation work has been carried out in this respect and a few plants have been set up in India and abroad. One important aspect in this regard is the process route options with optimum yield and grade. Some of these low grade ores, particularly magnetite, are found to contain high phosphorous level, removal of which poses a major challenge. Since the grade is low, substantial upgradation necessitates fine grinding for appropriate liberation. Fine grinding is energy intensive and needs attention to achieve economy in this regard. Large quantity of tailings is generated in the process, wet disposal of which gives rise to a lot of hassles and hence, possibility of dry disposal of the same needs to be explored. The experience of the authors, with regard to aforesaid aspects which has been gained in course of carrying out relevant assignments is presented in this paper."

Jan 1, 2014

By Markus A. Reuter, Joep Verwoerd, Marc J. A. Pijnenborg, Yongxiang Yang

"Incineration is a proven disposal technology for all waste materials with heat release potentials, and provides high degree of toxic destruction and control for a broad range of hazardous materials. In the Netherlands, all the hazardous wastes are processed at AVR-Chemie located at the Rotterdam harbour, through rotary kiln incinerators. The newly enforced regulations from the European Union with stricter emission levels require a better understanding of the incineration process and improved process control. However, the transport phenomena and combustion processes within the kiln system are very complex and not well understood. In order to get better understanding of the incineration process, research has been carried out to study the fluid flow and combustion behaviour of the incineration system. Computational Fluid-dynamics (CFD) was used to simulate the gas flow and waste combustion process, and temperature measurements of the operating rotary kiln incinerator were conducted to validate the CFD model. This paper will present the latest results from the current research project for simulating gas flow and combustion heat transfer for a wide range of hazardous waste streams.The simulation of the waste incineration process was carried out using a general-purpose CFD code Phoenics. The rotary kiln and the secondary combustion chamber (SCC), with a waste processing capacity of 50,000 ton/y and an energy input of 30 – 40 MW, is translated into a CFD model. The model includes a k-e turbulence model and a global gas-phase combustion model (3-gas or 7-gas combustion model). The 3- gas model (Simple Chemically-Reacting System, SCRS) predicts only the thermal effect of the fuel combustion, and only one global fuel is used, therefore, real chemical species are not taken into account. In the 7-gas combustion model, (an Extended SCRS, ESCRS), different forms of waste fed into the incinerator have been modelled into a mixture of a general hydrocarbon fuel C3H4 and other components such as CO, CO2 and H2O. Thus, all the incoming fuel streams with different compositions and calorific values can be properly converted into separate inlets. The combustion of the waste is assumed to take place only in gas phase in two steps: (1) primary combustion of the main fuel component C3H4 to form CO and H2, (2) secondary combustion of CO and H2O to form CO2 and H2O. The rate of each combustion reaction is assumed to be controlled by turbulent mixing of fuel and oxidant (air or oxygen), i.e. the Eddy-Break-up (EBU) model. The resulted temperature field was validated with temperature measurement data, and the simulated temperature distribution from both 3-gas and 7-gas model have reasonable agreement with the measured data."

Jan 1, 2003

By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.Sluices are the simplest forms of the flowing film concentrators and have been used in the mineral industry since at least the 15th century (Agricola, 1556). Flowing film concentrators, in general, still have widespread applications in the mineral industry and their designs vary according to the specific need.Particle separation in a sluice appears deceptively simple, but the separation mechanism has proven complex and difficult to quantify. Separation in the sluice takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in socalled hindered settling mode. The difficulty arises because the presence of the particles influences the flow pattern and when the particles are fully transported by the flow, the flowing slurry may not have the same viscosity as water and does not have the same density. For this reason a universal theory which can explain the behaviour of a suspension in a sluice or any other gravity equipment has still not been developed. Few attempts have been made to analyse the mechanisms involved in the concentrating processes of pinched sluices and Reichert cones.Fluid flow behaviour and slurry transportation characteristics in open channels have, however, been active research topics in the disciplines of fluid mechanics, chemical engineering and civil engineering for many years. As a result, an extensive literature is available, which has led to the development of the model described in this paper.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates, and the actual particle separation taking place compared to predictions from modelling.The modelling strategy was divided into two parts; the first was to predict the horizontal slurry flow velocity profile and the second to predict the solid particle concentration over the depth of the flow at different flow conditions. The predictions were then validated with measured data sets. This can easily be done if the slurry flow is split at different fractional flow depths so that the mass flow of solids over different flow heights is measured accurately over a fixed period. Mass flow splits can then be calculated by integrating the product of the predicted slurry velocity profile and the predicted solids concentration profiles from the base of the sluice bed to the slurry free surface."

Jan 1, 2003

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is main parameter for precipitate flotation in pilot or industrial scales. The knowledge of aggregate structure can lead to better understanding and control of many solid-liquid separation processes (sedimentation, filtration, thickening and flotation). Many authors highlight the importance of structural properties (i.e. floc density) for different industrial applications.This approach was applied to achieve the flotation of molybdenum precipitate obtained with organic collector a- benzoin oxime for molar ratio 1:2. Flotation tests were carried out at lab and pilot scale with rigorous control of the size distribution of bubbles and the values of dissipation energy in the systems.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions, which were deduced from experimental data of laser sizer devices and optic microscopy pictures of precipitate. The boundary fractal dimensions Df of large aggregates allows the detection of a structural scaled organisation of the precipitate flocs (elementary germs-microflocs-flocs). The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with structuration or breakage phases.The destruction process characterised by a fractal dimension Dg controls the final size distribution. The floc destruction occurs for the lowest values of the dissipation energy (0.02 – 0.05 W/kg). The relation between Dg and the system dissipation energy Et (for various energy E dissipated in the agitation cell) involves the different breakage mechanisms of aggregates in function of the aggregation bonds (Fig. 1).Besides, the destruction of floc produces very fine particles (elementary germs or/and microfloc according to E), and thus induces the difficulties of bubble-particle attachment during the precipitate flotation in column. Yet, very small bubbles, which increase the collision probability, would make the flotation feed rate decrease. The optima ratio between superficial gas and feed velocities are determined for bubble size and flotation results control at pilot scale. Thus, it is possible to providing the catastrophically changes of precipitate column flotation by using the following established experimental relation: the mean diameter d of the flocs under the action of dissipated energy Et follows a power like law (d~Et -0.5). This allows estimating the size distribution of flocs for the E values which can appear in column."

Jan 1, 2003

By Wayne van Drunnick, Mervyn Ruthnasamy, Olvier Guyot, Christophe Bouché

"Anglogold’s Mponeng Mine is situated in South Africa’s North West Province approximately 80km from Johannesburg. The reefs being mined in this area are among the deepest deep level mining operations in the world. These shafts often exceed several thousand meters making these operations complex and expensive.The gold plant is fed with run-of-mine ore which is stored in mill silos. Feedrate to the mills is controlled by a variable speed belt. Three parallel SAG mills (4.85 x 9m) treat 80-100tph, operating in closed circuit. Hydrocyclones classify the mill discharge, returning the oversize to the mill feed. Cyclone feed density and pressure are measured and are used with typical control loops to determine water addition rates to the mill. Control loops at PLC/SCADA level were historically used with limited success in the control of the milling circuits. Mill control for an installation of this type used mill mass (measured by load cells) and feedrate to control throughput. An online particle size analyser (PSI) was installed to assist grind control in tandem with pressure/density control on the cyclones. Although the accuracy of the measured grind was reliable, long term consistency of the PSI could not be guaranteed. Economic pressure from the business sector requires consistent mill throughput at optimum grind conditions. Fluctuations in production targets can manifest due to inconsistent control and the lack of real-time information from the process.This sensitivity to process movements may vary between shifts and also with changes in ore competency.Whilst tools are available to improve control, few have the sensitivity to process movements to provide real-time information for optimal grind control. For this reason an Advanced Control solution was sought. Advanced Control is often described as the supervision of basic PLC/SCADA control. Advanced control systems have to seamlessly compliment the existing control strategy and bridge the gap that exists between basic control and optimised control. A solution was found in the Metso Minerals CISA’s OCS (Optimising Control System). This French designed system makes changes to process setpoints to achieve peak performance and is distinguished from others by its soft sensor capabilities. The soft sensor is an embedded module in the OCS package that can be configured to estimate values normally obtained from field instruments. Advanced control using a Fuzzy Expert System assisted by Statistical tools (such as moving averages and a Soft Sensor using Phenomenological Models) would serve to bridge that gap. Metso Minerals CISA’s OCS is a modular system with various capabilities.It was successfully used to provide on-time process information via Soft Sensors. Circuit stability was achieved using Rule Based Expert Control in complete synergy with Fuzzy Logic. Two rule-based strategies were developed for this circuit. The first uses the online product size analyser as a primary control variable. The second uses a calculated kWh/t value and a modelled mill discharge density as primary control variables. The latter had more availability than the particle analyser and is currently in use."

Jan 1, 2003

By Fu Ping-Hao, J-P Franzidis, Sergio Mauricio Vianna, Ewen Silvester, Emmy V. Manlapig

"Over the last 5 years, an ambitious project has been undertaken at the Julius Kruttschnitt Mineral Research Centre (JKMRC) aiming to isolate, study and, if possible, model the effect of particle size, liberation and collector adsorption density on the floatability of mineral particles. As part of this project, we have conducted highly controlled flotation test-work, combined with state-of-the-art solution and surface analytical techniques such as High Performance Liquid Chromatography (HPLC), Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) and detailed mineralogical analysis to fully characterize the flotation behavior of a natural ore.The flotation tests were undertaken using a high-grade lead-zinc ore from BHP-Billiton's Cannington mine (Australia) in a specially designed continuously operated laboratory scale flotation rig. Solution and adsorbed collector concentrations were measured independently during the course of the flotation tests using HPLC based ex-situ techniques. Liberation studies were performed using the JKMRC Mineral Liberation Analyser (MLA) on selected size intervals of different streams to estimate the specific surface area of galena. These results were used to calculate the collector adsorption density (collector coverage) on galena particles, with the eventual aim of developing a mathematical model describing the relationship between pulp chemistry, feed mineralogy, and floatability of galena particles."

Jan 1, 2003

By Janusz S. Laskowski

"Frothers offered by different manufacturers are marketed with some information on their chemical and physical properties (e.g. density, viscosity, color, water-solubility, safety/toxicity, etc.). But frothers are used in flotation to generate fine bubbles and to stabilize the forth, and this information is only provided in a very qualitative description of the visual appearance of bubbles and froths. The terms “powerful” and “selective”, which have been commonly used to characterize frothers, have intuitive rather than scientific meaning.This paper introduces the DFI (Dynamic Foamability Index) plotted vs. CCC (Critical Coalescence Concentration) diagrams to classify flotation frothers (Fig. 1). The frothers characterized by low CCC and high DFI values have properties of strong flotation frothers, while those with high CCC and low DFI values are more selective. The proposed frother classification system, based on simple CCC and DFI measurements, provides, for the first time, a solid ground-work for characterization of the flotation frothers."

Jan 1, 2003

By Jia Muxin

The adsorption behaviors of metal ions on a silicate mineral and the flotability of a metalized silicate mineral with sodium oleate as collector are closely related to the structure of the silicate mineral. The adsorption isothermals of the metal ions on different silicate minerals are studied, the parameters of the isothermal give the information how many surface oxygen anions a metal ions is attached to, from this information and the structure of the mineral the site where a metal ion is attached can be guessed (The adsorption isothermals and adsorption behaviors with pH are fitted with Temkin, Frenudlich and Kurbatov equations respectively). Metal ions as Cu2+, Ni2+, Zn2+ are attached to the oxygen anions of surface species –Si-O– on the quartz surface, most of them coordinate to only one surface oxygen, their adsorption ability on quartz is low, but this metal ions on quartz surface protrude out of the surface perfectly, so their ability to combine with oleate acid radical is excellent. Quartz can be activated well by such metal ions. The isothermal of Fe3+ on quartz indicates these cations coordinates with more than two surface oxygen anions. This means the Fe3+ nucleates on quartz surface in the form of Fe(OH)3 colloid particles. The isothermals of Cu2+, Ni2+, Zn2+ Fe3+ on spodumene shows such ions coordinate with more than two surface oxygen anions, it indicate these ions may attach to the position where Li+ is formerly exists, such metal ions stay in a cave on the mineral surface, their adsorption abilities on spodumene are quite well, but they are affect by the oxygen anions of the two Si tetrahedron chains, the can almost not activate this mineral. These cations may attach on the site where Al3+ exists on the muscovite surface, just like spodumene, muscovite can not be activated well by such cations. Pt2+ has a large ion radius, as Pauling’s rules depicts polyhedron can not attach to Si tetrahedron well, the adsorption ability of Pt2+ on quartz is low and quartz is activated badly by Pt2+. On the other Pt2+ can adsorb well on spodumene and muscovite well and activated them well because it is not affected so bad by the tetrahedron oxygen anions of the minerals for their its large radius. The isothermal of Ca2+ on quartz indicates a Ca2+ coordinates with less than one surface oxygen anion, this means Ca2+ attaches on quartz mainly by physical adsorption. The adsorption abilities on mineral surface and the interaction abilities with oleate acid radical of the transition metal ions with the same valence are guessed to be determined by their d electron number, the rules should be d1<d2<d3<d4>d5<d6<d7<d8<d9>d10. Hydrogen bond may play an important rule in the activation of the mineral by HF and the interaction of the HF activated silicate mineral with collectors. The general rule is high bond valence and small metal ion radius surface species –Me-O can be activated well by HF with sodium oleate as collector. For example – SiIV-OH is neutral while –SiIV-FH+ and –SiVI-FH+0.33 are positively charged, the positively charged surface species are more likely to connect oleate acid radical via hydrogen bonds.

Jan 1, 2003

By Nani Pajunen, Kari Heiskanen

"Products filling our societal needs, like communication and transportation needs, are becoming more sophisticated and efficient. The cost has been an increased complexity of material combinations. The same trend is also seen in investment goods. As an example, different crusher types have almost doubled the power to weight ratio in a relatively short time while producing even higher crushing rations. This has been possible by high performance materials and advanced designs. Another example is new hybrid materials in prefabricated high-strength steel structures in construction with the aim to lighten the products and obtain energy savings in the use phase e.g. in transportation. This development in general has made the end of life phase obscure. Recycling is often understood as the first phase of the material cycle. This has been supported by the material centric point of view. When, say indium, has been collected and mechanically treated to a concentrated fraction, it is assumed as recycled. This is not the case. The same applies to special steel alloys where one tends to lose some of the alloying elements to slag or even into the gas phase in the melting and refining stage, not in the earlier steps of recycling. At present there is no clear understanding of recycling of hybrid materials and no clear willingness to create new functional recycling systems. As the EU directives and most of legislation worldwide are based on the material centric thinking and implemented even on total mass recovery basis there is neither legislative incentive nor very strong economic incentives to work out the problem. In our research, we focus on industrial design towards sustainability from a product centric point of view from product collection to final metallurgical steps. It is vital, in the design phase of product, to understand the effects of decisions on recyclability to a saleable raw material. Main goal of our work is to create the fortunate circumstances in supply chain - to pass the barriers and find the effective and fruitful drivers - for reasonable use of raw materials and recycling co-operation with industry. The boundary conditions in the work are extractive metallurgical performance and the economic viability of all the steps. It can be shown from our work that small design alterations may have a large impact on the recyclability. The earlier the decisions are made in the product life chain the more positive impact they will have. It can also be shown, that a strong processing and metallurgical industry is vital to any meaningful recycling of the modern EoL products. Finally, it is also question of the individuals and values: supply and demand. Are you ready to take up the gauntlet: demand recyclable products."

Jan 1, 2014

By Hugo Barrientos

"The growing need to optimize the mining processes produces a need for users to have a simple, reliable, secure and cost-effective method to monitor the values of the variables measured in field. The solutions described in this paper, we will demonstrate how the implementation of Emerson Smart Wireless technology helps to optimize the leaching and electro winning processes. An effective monitoring of the variables involved in the operation of a heap leach, such as pressure, flow rate, pH, water level control and regulator valves can improve production and optimize the use of sulfuric acid, which results in a more effective management of resources and helps reducing input costs. Moreover, the constant monitoring of variables prevents the risk of landslides, reducing maintenance costs. In electro winning cells, the wireless solution measures variables such as pressure, flow rate, temperature and voltage provides a performance indicator for the entire operation, capable of detecting and predicting shorts, and monitoring the overall functioning of a cell or group of cells. As a result of the applications studied, users can monitor variables in real time, optimizing the use of resources, quickly detecting possible flaws in the process and reducing the risks in the operation. All these factors have a direct impact on company results."

Jan 1, 2014

By Gjergj Dodbiba, Toyohisa Fujita, Li Pang Wang, Masashi Yamane

"The platinum-group metals (PGMs), are currently receiving worldwide attention as they have major industrial uses. PGMs, i.e. ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and platinum (Pt), are widely used as catalysts in petroleum and chemical processes. In addition, they find wide applications in automotive exhaust-gas control converters and are of immense importance to the electronic industry. Broadly speaking, PGMs are extracted in minute quantities from a limited number of ores, found mainly in South Africa and Russia. As the PGMs are both costly and almost indestructible, they are usually recycled from various forms of scrap. In other words, the recycling of the PGMs is an essential factor in the overall management of the PGM economy. In addition, the ever-increasing user areas have created renewed interest in the search for new sources or deposits of PGM, which in turn requires an in-depth knowledge of its characteristics. In this work, the emphasis is placed on the need to analyze the composition and microstructure of blast-furnace slag for recovering PGM metals. In other words, chemical composition, surface analysis and microstructure analysis of the DC arc furnace slag have been carries out. The aim is to provide a detailed analysis of this material for anyone with an interest in gaining further knowledge of its specific content for recovering PGMs."

Jan 1, 2014

By W. P. Roux

With depletion of higher grade iron ore reserves, and the need to process finer, lower grade material; there is a need to better understand the recovery efficiency of jigging process. The use of Positron Emission Particle Tracking (PEPT) was examined as a technique, to study the motion of particles inside a laboratory batch jig. PEPT is a noninvasive method that can provide three dimensional kinetic data of a particle during jigging. Particles with different densities and sizes were traced under the same jigging parameters, to obtain a data set that can be used for the development and verification of jigging models. From the results, detailed information on the stratification rate of a particle was obtained, with adequate resolution to see particle movement through an individual pulse. Detailed data of this nature is critical for the validation of CFD and DEM models. Keywords: positron emission particle tracking, jigging, jig models

Sep 1, 2012

By T. Fujita

A high-grade fluorite ore is converted into hydrogen fluoride to produce many kinds of materials containing fluorine. Recently, it is becoming necessary to use low-grade fluorite ore due to the depletion of high grade ore. The low-grade fluorites usually have impurities such as SiO2, P, CaCO3 and arsenic. The most impurities such as SiO2, CaCO3 and P can be removed by using flotation method. However, the removal of arsenic is difficult, and the arsenic contamination decreases the hydrogen fluoride production percentage. The novel technologies for processing low-grade fluorite ore are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, the removal of arsenic from low-grade fluorite ore has been investigated by means of an autogenous grinding using tower mill in sulfuric acid aqueous solution and 0.3 mm zirconia balls in water. The nano grinding in water can prevent the dissolution of 0.3 mm size zirconia balls as grinding media by sulfuric acid solution. Experimental results showed that the arsenic concentration was reduced from 260 mg/kg to 90 mg/kg and CaF2 recovery reached 90% by this process.

Sep 1, 2012

By Sunil Tripathy, Y. Rama, Srinivasulu. A., Amit Ranjan

Process improvements in an operating plant are always challenging. Mineral beneficiation plants based on gravity concentration techniques need continuous evaluation and monitoring of its processes for getting maximum recovery and better grades. But, in an operating plant it is very difficult to control all the parameters due to numerous reasons such as unsteady operation, fluctuation in the quality of run-off-mine ore, overall flow rate etc. For better understanding of the beneficiation circuit, it is necessary to evaluate the critical operating parameters which affect the performance in terms of grade, recovery and throughput including losses of valuable materials into tailing. Accurate data collection and proper data interpretation followed by making necessary change which is implementable in an operating plant play very critical role in performance of the circuit. In case of gravity operated beneficiation circuits of chrome ores where the quality of the feed and physical parameters varies continuously, the operators are required to modify the critical operating process parameters on continuous basis which is very difficult and tiresome. There are many causes of the data variability, including both error (sampling and assay), and real variation in performance due to changes in ore mineralogy, operating conditions and other factors. In this article, attempts made to evaluate the performance of ultra-fine beneficiation circuit in terms of silica reduction in the concentrate of chrome ore beneficiation plant (COB), India are discussed. The approach adopted and practical problems encountered during the study were also discussed. Results obtained from plant audit based on the above methodology has shown that SiO2 content in the concentrate can be reduced to <4%.

Jan 1, 2014

By Saveliy F. Kaplan, Valeriy N. Tsyplakov, Vasily N. Kovalev, Igor A. Agapov, Nikolai V. Vorob’ev-Desyatovskii

"Based on the experiments, a possibility of successful processing of double-refractory gold sulphide concentrates with a high content of natural organic carbon, which has a high sorption capacity toward gold chloride complexes, has been demonstrated. The proposed approach involves deep burnout of sorption-active organic carbon in an autoclave at a higher temperature and a longer retention time. INTRODUCTION It is known that one of the reasons why gold-bearing ores and concentrates are refractory is the occurrence of fine gold in sulphides (usually in pyrite and arsenopyrite) in ores and concentrates. In addition, refractory gold-bearing ores and concentrates also contain an organic carbonaceous material, which has a sorption capacity towards gold chloride complex, making the ore or concentrate even more refractory. In pressure oxidation, metallic gold is oxidized by Fe (III) aqua-ions and complex Au(Cl)4- ions are formed at temperatures over 180°C, in the presence of chlorides contained in ores. Complex gold anion is adsorbed on the organic carbon surface and then reduced to Au0; the chloride ion is regenerated and gold, adsorbed on organic carbon microparticles, is ultimately transferred to tailings (preg-robbing). Currently, there are several suggestions how to suppress preg-robbing (Simmons, 1998, Pyke, 1999, Rees, van Deventer, 2000, Zhao Jun-wei, 2008). It can be done by reducing the organic carbon content by processing (flotation, etc.),reducing chloride ion concentration by preliminary washing of concentrates in thickeners, reducing the adsorption capacity of organic carbonaceous material by introducing some organic substances that are strongly adsorbed on its surface (blanking agents), and reducing the redox potential of the slurry liquids by introducing neutralizing agents (limestone)."

Jan 1, 2018

By I. N. Babich

"Complex technological problems associated with the processing of mineral raw materials require the search and development of new means and ways of thinking. At present, computer cognitive graphics (CCG) are one of the most actively developing areas of new information technologies. The aim of the study was to optimize the cycle of technological evaluation of ores at all stages of geological exploration of deposits on the basis of analysis of geological sampling data using CCG. A new approach has been developed that facilitates optimization of the whole cycle of subsoil exploration. At the gold ore deposit, the results of the geological sampling data were processed by the method of constructing the CCG in the form of a histogram showing the frequency of gold extraction and the average amount of its content. Significant peaks of the metal content in the ore, exceeding the level of the average content in the ore by tens of times, have been revealed. Graphical interpretation of the parameters of mineralization reflects the uneven nature of its variability, which indicates the presence of large, rarely occurs of gold in the ore and the need to conduct studies on a sample of ore of greater mass than for ores with tiny gold. On a sample of 50 kg gold-quartz ore studies were carried out on gravity enrichment. The maximum size found in the gold concentrate was 0.07 mm. In the course of integrated tests in a gravity concentrate, gold particles up to 3 mm in size were found, which predetermined the need to include the operation of gravity before flotation. A new approach to subsoil research is protected by a patent (RU 2620823).The technological problems that arise before the researcher associated with the processing of resistant ores require the exploration and development of new means and ways of thinking. New problematic situations on complex mineral and raw materials objects are practically not amenable to resolution by existing methods. Integration of industrial and information technologies is necessary. At present, computer graphics (CG) is one of the most rapidly developing areas of new information technologies. For example, in scientific research, including in fundamental research, the accent from the illustrative function of CG (the visualization of what is already known) is increasingly shifting towards the use of computer cognitive graphics (CCG) tools (Bashlykov, 2016). The function of the CCG is to obtain a new knowledge with the help of a graphic representation - a cognitive image or at least to promote the intellectual process of the logical acquisition of this knowledge. In this study, cognitive images are used to graphically represent the distribution of valuable components in the bowels of the deposit, characterizing the state of mineral-raw materials."

Jan 1, 2018

By M. Mezzetti, E. Anders, O. Popov, P. Hoske, H. Lieberwirth, M. Voigt

"The material breakage induced by high energy electric discharges is known in general as electric impulse technology. This technology can be used for processing solid materials, such as rocks and ores. The electric impulse technology has been around for about 60 years, originally developed and intensively investigated by Russian researchers. However, the application fields have been limited to research and laboratory scale projects. Currently, there are new attempts to transfer this technology into practical industrial applications. Practical examples include drilling of deep geothermal wells with an electric impulse driven drill-head. Traditional comminution implies high energy consumption, hence, high costs. The Electric Impulse Technology is interesting for comminution of mineral and complex ores since it could allow improved recovery and energy reduction, thus resulting in significant savings. Another advantage is the dust free processing, which contributes to make minerals processing environmentally friendly. The use of electrical comminution for processing complex ores is investigated within the ELIZE research project funded by the BMBF (project No. 033R161 A) and industrial partners. The main objective is the development of an industrial scale electrical comminution machine. The first development stages include the investigation and characterization of the electric impulse induced weakening on rocks and ores. The characterization results of the preliminary trials at the microstructural scale on granite, skarn and greisen will be presented and discussed in this article. INTRODUCTION The pioneer work in the area of electric impulse technology was conducted by Russian researchers about 60 years ago [1]. While there have been some successful attempts to transfer this technology into practical applications, such as rock processing [2], laboratory processing of mineral ores [3–5], recycling [5] and geothermal drilling [6–9], the jump into practical industrial large scale application has not been accomplished yet. The Institute of Mineral Processing Machines of the TU Bergakademie Freiberg currently leads a project which can be seen as the next logical step for the technology transfer to industrial applications, namely, the development of continuously operating complex ore processing machines based on the electric impulse technology."

Jan 1, 2018

By V. F. Petrov

Cyanide is widely used gold lixiviant for hydrometallurgical processes. The resulting tails contain complex toxic compounds. With reference to this, the protection of the environment should be the major issue. A complete detoxification of cyanides before disposal, a partial detoxification to the allowable concentrations and a disposal of tails at a polygon followed by the detoxification of excess water into the environment are offered as an environmentally friendly way of disposal. However, a complete detoxification of the cyanidation tails does not give the required results due to the presence of toxic compounds, cyanides and thiocyanates in tailings ponds. This is due to adsorption-desorption process occurring between solid and liquid phases. A partial detoxification is used to down cyanide to the allowable concentrations, which are safe to the environment. The storage of tails without detoxification is mainly used at low concentrations of toxic compounds in the disposed tails. With reference to this, water recycling is practiced by Russian plants in order to reduce as much as possible or almost eliminate toxic effluents into the environment. Fresh water is applied if necessary and to make up for water losses, with 8-12% of total water supply. This allows for the stability of water balance and the decrease of consumption of the reagents applied. The conditioning technologies of water recycling followed by regeneration of free cyanide and metals recovery as saleable concentrates are specially developed due to adverse impact of water recycling on gold recovery processes due to high concentration of base metals (copper). These technologies are also profitable. In order to detoxify cyanide in the tails for tailings dam, effective and inexpensive technologies involving a seasonal use of detoxified reagents were developed. For example, a technology with aldehydes use which is applied by a series of operations. Effluents disposed to the environment are detoxified using chlorination followed by almost a complete destruction of toxic cyanides and thiocyanates. Before disposal, chlorinated water is settled to precipitate the resulting hydroxides of metals and complete chemical reactions such as a full decomposition of hypochlorite ions. In order to protect ground water, watertight screens from local water-resistant materials are used. The samples of these materials were previously tested and chosen according to their maximum ability to adsorb toxic compounds in the tailings pond. If local water-resistant materials are not available, whole welded impermeable polymer screens are used. The options mentioned allow the storage of cyanidation tails in accordance with national ecological standards. Keywords: cyaninides, thiocyanates, wastes, environmental safety, recycled water-supply, detoxification, storage

Sep 1, 2012

By Zhou Yucai, Zhou Jing, Zhu Yimim

"In this article, research on the beneficiation process for a carbon containing copper-molybdenum deposit in Henan province has been carried out. The elemental composition, mineral composition and relative content, characteristics of embedded and symbiotic relationship, the forms of the copper-molybdenum particlesand their disseminated features, and particle size distribution have been worked out. Flotation behavior of copper-molybdenum mixed flotation and separate flotation in the systems of different collectors and depressants, and the influence of different flowsheets on the copper-molybdenum separation have been investigated by actual ore flotation tests, The separation problem of copper-molybdenum for a carbon-containing copper molybdenum ore has been solved.INTRODUCTION In this paper, technological mineralogy, small experiment of flotation recovery of copper Molybdenum ore, and expansion experiment of mineral recovery of copper Molybdenum ore are introduced. (1) The results of process mineralogyshow that the content of copper is 0.42%, molybdenum is 0.021% in the raw ore, they mainly exist in the form of sulfide, with low oxidation rate. (2) The results of flotation tests show that the combination of butyl xanthate and isopropyl ethylthionocarbamate reagents is effective collector of copper-molybdenum mixed flotation for carbon copper molybdenum, (3) When the grinding fineness is -0.074 mm taking 71%, and regrinding fineness is -0.038 mm taking 85%, the flowsheet of first copper-molybdenum mixed flotation and then regrinding rough concentrate and last separation flotation of copper and molybdenum was adopted, which realized the effective separation of copper and molybdenum for carbon-containing copper molybdenum ore. Good flotation indexes were gained with copper concentrate containing 20.96% copper and copper recovery 90.06%, and molybdenum concentrate containing 46.78% molybdenum with molybdenum recovery 72.68%. (4) The seven days average concentration index of scale-up the continuous dressing experiment is as follows, the copper content in copper concentrate is 20.16% and the recovery is 89.61%; the molybdenum content in molybdenum concentrate is 24.58% and the recovery rate is 74.09%."

Jan 1, 2018