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By Heyes GW, Orrock GI

The fine grained complex orebody at Elura contains galena, silver and sphalerite in a matrix which is mostly pyrite; sulphides account for about 90% of the orebody. A differential flotation circuit is operated to con- centrate lead and silver in the first section and zinc in the second. The metallurgical performance to date indicates the need for improvement. The lead section has been sampled in detail to comprehensively assess its overall performance and to define problems associated with lead and silver flotation. The substantial amount of pyrite in the feed dominated the perfor- mance of each stage of the separation. It was responsible for extensive dilution of all concentrates and, as a consequence, for very large circulating loads. The rougher concentrate contained 68% pyrite some of which was rejected through the three stages of cleaning to 39% in the final concen- trate. However, this was still sufficient to hold the assay of this product below 45% Pb. Size by size behaviour shows that flotation rates of the valuable minerals, as characterised by their rate coefficients, were low through- out the circuit. There was a significant deterioration in these rates between rougher and cleaner I stages which resulted in large circulating loads between these stages. There was practically no recovery of coarse valu- able minerals to the final concentrate. The dilution of the final concen- trate by non-sulphide gangue was not a major problem. If the recovery of the galena and silver in the +38¦m size range could be raised to that of the - 381Lm size range, galena recovery would rise from 78% to 86% and silver recovery would improve from 46% to 59%. The Pb grade of the final concentrate would remain the same.

Jan 1, 1988

By T Mizuta, T Nakano, D Ishiyama

The Tamagawa Hot Spring, from which Ra-Pb-Sr-bearing barite precipitates, is a representative hot spring in a volcanic gas-bearing hydrothermal system associated with Quaternary andesitic to dacitic magmatic activity beneath the Yakeyama Volcano. Thermal water in the Tamagawa Hot Spring is divided into three types: Cl-SO4-type (Ohbuki hot spring: pH 1.2); SO4-type (pH 1.8 to 2.9); and neutral-type (pH 6.1). The concentrations of dissolved components in the Ohbuki Cl-SO4-type thermal water are about ten times higher than in the SO4-type thermal water. The 87Sr/86Sr isotopic signatures of the Ohbuki Cl-SO4-type thermal waters (0.703992 ¦ 0.000004 to 0.704032 ¦ 0.000006) are different from those of SO4-type thermal waters (0.704245 ¦ 0.000003) formed by the interaction of andesitic volcanic rocks (0.704065 ¦ 0.000007 to 0.704093 ¦ 0.000009) and groundwater derived from river water (0.704314 ¦ 0.000012 to 0.704519 ¦ 0.000013) in a shallower part of the hot spring area. The possible origins of Sr in the Ohbuki Cl-SO4-type thermal water and in the SO4-type thermal water are different. The Sr isotopic ratios (0.704130 ¦ 0.000012 to 0.707556 ¦ 0.000014) of Aniai Formation andPreYakeyama Lake deposits occurring below the hot spring area are distinctly higher than those of the Cl-SO4-type thermal water. However, it is expected that a solidifying andesitic or dacitic magma which has similar Sr isotopic ratios of the Ohbuki Cl-SO4-type thermal water, occur in the deep portion of the Tamagawa Hot Spring. The Cl-SO4-type thermal waters having low Sr isotopic ratios do not acquire their Sr isotopic signatures by interaction with strata below the hot spring area, but they are likely to reflect water interaction with a solidifying magma with low Sr isotopic ratios. Components including rare metals in Cl-SO4 type thermal water could be transported from a deeper part. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By D Craw

Interactions between structure and lithology in the Hyde-Macraes Shear Zone controlled the style of gold mineralisation at the Macraes mine. Large volumes of rock in some mine pits have most gold disseminated in hydrothermally altered schist, rather than in quartz veins. Mineralisation was initiated in the latter stages of metamorphism. Pods of massive schist rich in quartz and feldspar are surrounded by more fissile schist consisting of interlayered micaceous and quartzofeldspathic schist. Later shears have been partly controlled by the micaceous schist, and anastomose around pods of more massive schist. Micaceous schist was replaced by pyrite and arsenopyrite, accompanied by recrystallisation of phengitic muscovite under lower greenschist facies conditions. Gold occurs in sulfides and with microcrystalline quartz formed during minor silicification. Massive schist is locally mineralised along sulfidic microshears which have phengitic muscovite largely illitised under sub-greenschist facies conditions. Mineralised massive and micaceous schists were overprinted by cataclastic shears, with addition of graphite and more sulfides. Mineralisation occurred during a transition from ductile to brittle deformation regimes as the schist was uplifted in the late Jurassic.

Jan 1, 2004

By Rajan S, Mainwaring P, Gould WD, Beaulne M

Polished discs of a complex sulphide ore were leached with three lixiviants; a mixed culture of Thiobacillus ferrooxidans and Thiobacillus thiooxidans, Thiobacillus ferrooxidanalone, and ferric sulphate. At either one or two week intervals the discs were examined by scanning electron microscopy, and the amount of soluble metals released from the discs were determined. The mixed culture solubilized more Cu, Zn and Pb than did either ferric sulphate or T. ferrooxidans alone. However, no differ-ences were observed between the three treat-ments by scanning electron microscopy during the first 44 weeks. The minerals were attacked in the following order: pyrrhotite, cubanite, sphalerite, pyrite and chalcopyrite.

Jan 1, 1990

By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997

By Hinton A. T

Three, and possibly four, distinct types of quartz-vein associated gold mineralisation are recognised in New Zealand. They are: epithermal, schist-hosted, metagreywacke-hosted and metamorphic core complex associated types. Each has a unique geological environment and structural regime which has provided the gold source, scavenging mechanism, emplacing mechanism and geometry. Each has a characteristic suite of associated metals and trace elements. The first three types form economically important gold deposits while the fourth type have been historically worked for gold and base metals. Intense exploration is currently being focussed on all four types.The epithermal type is typified by the extensive vein systems of Martha Hill, Karangahake and Golden Cross and numerous smaller examples. The veins were deposited in a near surface active volcanic environment from deeply circulating hot water. Their structure is tensional, veins are vertical-to sub-vertical and have limited depth. Their geochemistry is identical to that in active felsic hydrothermal centres in the central North Island. Major minerals are gold, pyrite, arsenopyrite, galena, chalcopyrite, sphalerite and argentite.

Jan 1, 1990

By Bhattacharyya AK

With increasing demand for more efficient production from the underground coal mines in the Southern Coalfields- of New South Wales, their design and operational aspects are constantly being reviewed and improved. One key area in such pursuits is the reliable design of stable and yielding pillars. The current designs of pillars based mostly on experience leads to unnecessary sterilisation of coal or strata control problems. To explore such mine design problems, computer based modelling is increasingly being applied. In the study described in this paper, the object was to determine the particular width of pillars separating three roadways in a panel at which the pillars yielded completely and their loads largely transferred to the unmined coal at the flanks of the panel. This was approached through a computer simulation of the behaviour of the strata around a panel, in which the three roadways were separated by pillars of progressively decreasing width. A computer program called FLAC based on the finite difference method was used to simulate the relevant strata behaviour in vertical sections. The appropriate in situ values of the deformability parameters relating to the coal seam, roof and floor were determined from the back analysis of some displacement measurements in such a panel. The process involved successive modelling of a vertical section through such a panel,starting with realistic values of the parameters and varying them until the measured and the modelled displacements agreed closely. Based on the results of the numerical modelling, the width of a yielding pillar for the given conditions is Suggested.

Jan 1, 1992

INCREASE OF CATASTROPHE FREQUENCY AND SEVERITYIn the last couple of decades the frequency of natural catastrophes has increased dramatically. This realization results from the statistical analysis of the comprehensive loss data that we have been collecting constantly over the last 30 years and have evaluated in connec-tion with the preparation of our "World Map of Natural Hazards", which is now in its second edition (Munich Re, 1988). Each month brings data on between 30 and 50 new loss events. Fortunately, however, only a few of these have to be added to the list of major natural catastrophes, that is only those involv-ing damage that considerably exceeds what the country or region concerned can handle itself so that substantial na-tional or international aid is required. That is generally the case if the number of dead runs into the hundreds or thousands, if tens or hundreds of thousands of people are rendered home-less and if the total economic loss is in the region of US$ 100 million. These major catastrophes, about which we have fairly comprehensive data even in the case of those that occurred farther back in the past, numbered only 14 in the 1960s but 70 in the 1980s; they there-fore increased over a period of 30 years by a factor of 5. The trend is also very clear when we consider the total economic loss, which - adjusted for in-flation - increased during the same period from an average of US$ 3.7 bil-lion per year to US$ 11.4 billion, i.e. by a factor of 3.1. The insured losses, finally, increased by as much as a fac-tor of 4.8.

Jan 1, 1990

In 1556, Agricola noted that "a prudent owner, before he buys shares, ought to go to the mine and carefully examine the nature of the vein, for it is very important that he should be on his guard lest fraudulent sellers of shares should deceive him"(1). In today's world, the owner rarely has the opportunity to visit the mine and, instead of reading about the `nature of the vein' in annual reports, prospectuses, government publications, et cetera he sees the words `reserves' and `resources'. Unfortunately, the subject of reserves and resources has become increasingly complex and Canadians, along with their counterparts in Australia and elsewhere, are still struggling with definitions which will attempt to cover all conceivable circumstances from national or regional resource endowment to the material to be extracted next week from a given stope or open pit bench. The providers and recipients of reserve and resource data are: - Government agencies who are concerned with questions of national endowment, strategic use of raw materials and other questions of public policy. - Stockholders who have a vested interest in the basic assets of their companies. - Financiers who are concerned about the security of their loans. - Regulatory bodies whose function is to protect a frequently naive investor from unscrupulous practices. - Management, at head office and on-site, who need basic information for decision-making, whether it be to open up a new mine, expand or close an existing operation, acquire or merge with other entities, or, more mundanely, for routine mine planning. To satisfy their demands with unanimously accepted definitions is a formidable task but, it is my impression that, little by little, a concensus appears to be growing within the industry.

Jan 1, 1987

By Ofori-Ansah K

The zeta potential on the surface of activated orit carbon were estimated in lhe presence of selected cations and anions that are normally associated with gold bearing ores in Kalgoorlie area of Western Australia. Additions of such ions to solution of varying pH shifted the isoelectric point of carbon from pH 4.45 to pH 7-8.3, while the anions moved Lhc isoelectric point 10 less than pH 3.2. In the presence of gold cyanide SoluLion additions of spectator ions indicated the isoelecLric poilll to be aL pH less than 3.2; the only exception was for Fe" ion where the isoelecLric point was at pH 5.9. The decrease in zeta potential appeared to be related to the counter-ions present. The decrease may also be related to the adsorption of hydroxyl ion complexes that are likely to be formed when cations are present in the solutions.Gold adsorpLion by activated orit carbon from gold cyanide solution seem to be indicated by the magnitude of zeta potential on the carbon surface. An attempt is made to relate gold adsorption and zeta potential on carbon surface with the pH of the medium.

Jan 1, 1984

With the continued drop in export coal prices (as measured in US$) delivered to the Pacific Rim market, and a fixed annual 12 per cent increase in overburden, Usibelli Coal Mine Inc was faced with the need to reduce mining costs substantially or else forfeit its foreign coal contractual commitment which amounted to about half of annual mine output. Management made a difficult and fortuitous decision to proceed with an engineered plan to switch from a two seam, extended bench dragline operation to a two seam, cast blast and spoil side operation. While down-sizing and cut-backs became the rule in all departments of the mine, the drilling and blasting budget was more than doubled. Most will agree that this is contrary to what usually happens when a mine is faced with down sizing. The more common scenario would have management target the drilling and blasting budget for decrease as a first priority to cutting cost, and then later witness a decrease in equipment performance leading to an increase in the production cost per tonne. Although Usibelli Coal Mine more than doubled its annual drilling an blasting budget three years ago, the overall stripping cost has be, reduced by more then 37 per cent.

Jan 1, 1995

The intention of this work was to con struct a machine on a pilot scale which could hoist a mixture of ore and water through a height of 300 metres and to operate the mach- ine to determine the parameters which affect the success of upscaling the machine to a pro- duction unit size. The investigation into this form of hoist- ing was stimulated by the interest shown by Roan Selection Trust (RST) into the Mills Pulse vessel system. Agreement was reached between these two parties that RST would in- vestigate the Mills System and determine if this system, shown to be successful on a Lab- oratory scale, would be successful as a pro- duction unit. The investigation has shown, however, that for practical reasons, the Mills System is not satisfactory. As a consequence, the RST system was invented and developed which on a pilot plant scale would be capable of lifting 7,000 tonnes of ore per month. The inventions included amongst other things, a valve to control the flow of the abrasive mixture of ore and water, a new pumping system employing a filter mechanism, and a method of changing the downward direction of flow of the pipe mixture through the plant to an upward flow in the hoisting pipe. The valve has operated to pressures equivalent to 300 metres

Jan 1, 1973

Peko Mines, a Division of Peko-Wallsend Operations Limited (PWOL) has operated several small underground mines in the Tennant Creek district of the Northern Territory supplying ore to a central treatment plant. The Argo Mine is the most recently developed by Peko Mines. A magnetic anomaly was identified from low level airborne magnetics in 1960 and drilling, which commenced on the site in 1969, was halted in 1974 and resumed in 1980 following the rise in the price of gold. By mid 1983 a resource of + 200 000 tonnes of 12 g/tonne Au had been outlined and a decision to develop the resource was taken following the drilling of three further diamond drill holes which did not significantly alter the value of the resource. The small size of the orebody could not support the full capital cost of two shafts and a single entry mine plan was developed to extract the ore at a rate of 15 000 tonnes per month and to provide all the safety features, ventilation systems and services of a two shaft mine. In December 1983 a contract was let to Allied Constructions Pty. Limited (Allied) to sink and equip a 4.8m shaft to a depth of 410m and to convert the headframe and winder, which are leased for the life of the mine by PWOL from Allied, from a sinking to a production configuration. Shaft equipment designed by Hardcastle & Richards Pty. Ltd. (H & R) in conjunction with PWOL includes a skip/cage, counter- weight, and an auxiliary cage on rope guides, a sealed ladderway and exhaust air ducts.

Jan 1, 1986

The methods used by the Anglo American Corporation for analysis of long-term metal markets and prices are described. The principal factors affecting the relationships between production costs and metal prices are analysed. These are firstly the type of market, - speculative or consumer commodity, free market or subject to price control; and secondly the rate of growth of demand for the metal. It is shown that virtually all metals will have relatively low rates of demand growth for the foreseeable future, due to market saturation, increased economisation, substitution and product obsolescence. Metal prices have a clear dependance on production costs, however forecasting future costs is by no means simple; amongst other things, account must be taken of changing exchange rates, inflation rates, and the potential for operating more efficiently. The paper concludes by giving brief assessments of the long-term future for aluminium, copper, zinc, nickel and tin.

Jan 1, 1986

By Hodges D. A

The manufacture of steel from raw materials which have to be mined, transported and processed must affect the environment. Steelmaking, like almost every other stage of manufacture involves the unwanted production of dust and fume; thus a major part of the steel industry's effort to minimize changes to the environment is the collection, treatment and recycling of dust and fume to avoid pollution of the atmosphere and waterways. The paper describes how this achieved in the various steelmaking processes and shows the diversity of problems-and their solutions in this context. Particular emphasis is, given to basic oxygen steelmaking.

Jan 1, 1976

In reviewing recent developments in the process mineralogy of gold it is convenient to distinguish between visible (>0.1 pm) and invisible gold (1 - 2 pm in size in polished section; these can scan the surface of a polished section, identifying the gold minerals, recording co-ordinates of the grains for subsequent examination, and making measurements of areas and sizes of the grains. However, problems of sample reliresentivity in polished section mean that such data may not give good quantification of gold mineral proportions and liberation/locking characteristics and other methods are required for this (amalgamation, cyanidation, ultra-fine milling and cyanidation). Characterisation of invisible gold in bulk material (eg a sulphide concentrate) can be done by mineral separation, ultra-fine milling and cyanidation or by quantitative point analyses of a large number of mineral grains. Analytical methods include electron microprobe analysis (detection limit normally -200 ppm but -10 ppm by using special techniques), ion microprobe analysis (secondary ion mass spectrometry - SIMS; detection limit -0.2 ppm) or proton microprobe analysis (PIXE; detection limit

Jan 1, 1992

The mining and resources industry in general has relied on macro separation technologies (greater than 1 micron) through processes which include: ò sedimentation ò flocculation and coagulation screening and filtration ò absorption ò magnetic separation ò chemical leaching and precipitation Essentially, these processes and technologies provide the industry with an effective arsenal to handle most separation requirements to date. Dewatering of solutions is one of the most significant requirements of the resources industry, as practically all mining endeavours use water in their process for leaching, extraction, cooling, dilution or for potable drinking water.

Jan 1, 1989

By Salley J, Gould WD

The stack-gas scubber effluent from base metal smelters often contain 20-100 ppm of oxidized selenium salts. Due to their toxicity, these must be removed from solution prior to release of the effluent to the environment. Many species of microorganisms including Corynebacterium diotheriae, Neurospora crassa, Candida albicans, Escherichia coli and various species of Salmonella are capable of assimilating oxidized selenium and reducing it intracellularly to red amorphous selenium. CANMET in cooperation with several companies has developed a biological process to recover selenium from dilute solutions. The laboratory, mini-pilot plant and the large industrial pilot- plant studies leading to the development of this process will be described.

Jan 1, 1990

By E Werner, J J. Donovan, A J. Morris

Coal mining in the Pittsburgh coal seam, in the eastern United States, began in the late-1700s. Since that time numerous mining technologies have been used throughout the basin. Environmental concerns, particularly mine discharge quality, have only been considered since the early-1970s. During the last 20 years, many of the larger underground mines have closed and are now either flooding or already flooded. In order to understand the consequences and potential future effects of this flooding, mine mapping of the basin has been compiled utilising a geographic information system (GIS) with an emphasis on locating barrier pillars between mines. Mine flooding has been monitored at numerous sites utilising pressure transducers and data loggers. These data have been combined with historical data from mining companies and structure contour maps to yield chronological flooding maps of the basin from 1980 to present. Utilising these maps and the indicated flooding rates, future discharge locations have been identified along with estimates of when these discharges are likely to occur. Related work has identified barrier pillar hydraulic conductivities and vertical infiltration rates as a function of overburden thickness. All of this information has been integrated into a groundwater flow model that simulates mine flooding. This model is useful in defining mine to mine interactions as the various mines fill with water, and the testing of various flooding scenarios. The model will be used in evaluating mine discharge rates and evaluating the options for regional mine drainage treatment.

Jan 1, 2003

By Propster M, Choudhry M

THIS note gives comments on the paper by Kitaev et al on p. 68 of this book and compares results with those obtained by ourselves. We wish to say that the authors are to be congratulated on their sophisticated approach to an important problem and that it complements our efforts on flow maldistribution.1-5 It is our view that Eqs. (1)-(5) on p. 69 are impressive, but unfortunately with present day computers and computational facilities, it would be quite impractical to contemplate the numerical solution of these. Eq. (8) in the authors' paper, on p. 70, does provide the logical starting point for tackling flow maldistribution problems and strictly speaking this equation is more accurate than Eq. (1) in our paper in this book. We note in passing that there is direct experimental evidence to support the contention that our Eq. (1) is at least a reasonable approximation and one may question in a practical sense whether the refinement afforded by Eq. (8) in the paper by Kitaev et a/ is justified. While one must readily accept the appropriateness of Eq. (8) of Kitaev et al as a starting point, the subsequent mathematical manipulation by the authors is open to serious criticism. In order to solve this complex, non-linear equation Kitaev et al postulated irrotational flow, which afforded considerable simplification. One can argue simply on physical grounds that the assumption of irrotational flow is inappropriate, a fact which should be readily apparent on inspection of the flow fields shown in Figs. 2 and 3 of Kitaev's paper. It follows that while the starting point through the use of Eq. (8) is correct the results derived from this starting point may be suspect because of the erroneous nature of the irrotational flow assumption.

Jan 1, 1975