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By S. G. Tsimas, A. K. Moutsatsou, G. K. Parissakis, M. A. Komiotou

For Greek kaolin producers, a considerable proportion of whose output is from deposits containing more than 4 wt% Fe2O3, the colouring resulting from iron oxide impurity represents a serious problem that necessitates upgrading of the ore to meet commercial specifications. Autoclave leaching with oxalic acid for 1 h at 120 degrees C and 5-6 bar was shown to reduce Fe2O3 by up to 90% without affecting the structure of the kaolin, which maintained its physicochemical properties. The iron oxalate product can either be removed from solution or precipitated as iron hydroxide with recycling of the oxalic acid

Aug 1, 1995

By G. G. Barbante

The oxidation behaviour of selenide matte with a substantial Cu content and low Ag differs significantly from that of high-Ag matte. Low-Ag selenide mattes display a large oxygen solubility and the upper boundary of the miscibility gap in the Ag-Cu-Se-O system is depressed to quite low Se contents. As a result, the formation of Ag metal is considerably delayed. The oxidised selenide matte, low in Se and with a relatively high oxygen content, has previously been termed oxymelt. With further oxidation, its composition enters the misciblity gap and crude Ag is formed. The sodium silicate slag captures very little of the SeO2 and the dissolved Ag2O(s) content of the slag is relatively small, with a Raoultian activity coefficient of 0.57. This value was found to be independent of the slag's Cu2O content

Jun 19, 1905

By M. W. Robotham, H Wang

removal efficiency is analysed from a stochastic

Apr 1, 1995

By P. A. Rossouw, G. A. Fourie

Several attempts have been made over the latter half of the twentieth century to devise a system for the classification of underground mining methods. None of these are found to be totally successful. A revised classification is suggested with three main categories being identified by reference to fill requirements, steep stopes and stratified geological environments. Methods always needing lasting mass or structure fill include methods with timber-structured stopes and those with mass-filled (or cut-and-fill) stopes. Methods associated with steep stopes are subdivided into steep-stope-specific caving and steep-stope-specific non-caving (or self-supporting) methods. Methods not in the first two categories, often used in stratified geological situations, are not necessarily restricted to stratified environments and include caving as well as non-caving varieties. This category is further divided into room-and-pillar mining, longwall and shortwall coal mining and the type of open stoping found in gold or platinum reefs comprising overhand, underhand and breast-stoping variations

Dec 1, 1996

By J. A. Finch, Zhenghe Xu, Z. A. Zhou

Whether the microscopic bubbles generated by the high energy dissipation and high feed-slurry velocities in new flotation cells are stable in solution and what roles they play in particle collection are of great interest for the flotation of fines. Experimental work has shown that, with fast flow of liquid through an orifice, stable microscopic bubbles can form in flotation systems by hydrodynamic cavitation in the absence of gas supersaturation. The minimum flow rate at which bubble formation is initiated varies from 8 to 15 m/s, depending on the design of the cavitation tube, which is within the range of feed slurry velocities of some newly developed cells. Feed aeration enhances the formation of micro-bubbles by hydrodynamic cavitation. The study suggests that the fast flotation kinetics of some new cells may be attributed in some degree to the formation of microscopic bubbles

Jun 21, 1905

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By A Cox

It has been demonstrated that all the cadmium from spent batteries, typically 4 g per battery, can be recovered by burning polyvinyl chloride waste to yield hydrogen chloride; this reacts to produce volatile calcium chloride, which can then be condensed and collected in a separate reactor. Alternatively, chlorine may be used to chlorinate the cadmium with equal efficiency. There is also a prospect of using very low concentrations of these gases, less than 1%, to effect the separation. The Cd was recovered more quickly when exposed to sustained, controlled flow rates of chlorinating gases, whereas when PVC was burnt most of the gas was produced in a very short time, not allowing complete reaction. This problem can be overcome by recirculation of the gas into the reactor. The technology is efficient and clean and the equipment used is simple, enhancing the prospects for a pilot-scale version of the process

Jun 21, 1905

By A. J. Davidson

A Cu-conducting solid electrolyte was used to develop the sensor. Instead of measuring the potential across the electrolyte from the reference material to the Cu-containing phase, a potential was applied and the stable current measured. This gave reasonable readings for copper-tin alloys, which agreed with the theoretical calculations, but was less satisfactory in the case of mattes because the surface area of electrolyte presented to the matte phase varied from sensor to sensor. To overcome this problem the potential was applied, the current was measured and then reversed and remeasured and the ratio of the currents was calculated. The current ratio is shown to be independent of the resistance of the electrolyte and the surface area of the electrolyte offered to the melt, but strongly dependent on the activity of the copper

Jun 21, 1905

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By R. Poulin, C. F. Gleeson

The Birimian rocks of the region are gold-bearing and show many similarities to those of Burkina Faso. All three greenstone belts (Goroual, Tera and Sirba) host gold-bearing quartz veins. It appears that, contrary to previous misconceptions, lateritic terrain is not an unfavourable environment for exploration geochemistry. This is demonstrated by the results for the Koma Bangou area, where soil and termite-mound geochemistry have been successfully used in the search for gold. Soil provides an effective sampling medium where it is shallower than about 2 m; there is evidence that some soil anomalies are enhanced by the presence of secondary (botryoidal) gold. In areas of thicker, allochthonous soil cover, termite-mound sampling is more effective. At Koma Bangou an identified resource of some 11 100 000 tonnes with an average gold grade of 2.44 g/t has been reported. The gold mineralisation occurs in quartz veins and stockworks aand in the wallrocks of shear and fault zones that trend N, NW and NE. The host rocks are a granodiorite-syenite porphyry and intermediate metavolcanic rocks and tuffs

Apr 1, 1996

Errors in ore reserve estimation can occur during drilling and sampling, sample preparation and analysis, geological logging and modelling, database construction, statistical or geostatistical evaluation, selection of economic parameters, selection of ore reserve method and assessment of mining constraints. Core sample recovery can be a major source of error, and it is proposed that the modelling of grade, metal accumulation and thickness should be accompanied by the modelling of core recovery (or core loss) so that for each ore block a weighted block recovery factor is obtained. This gives a good indicator of the reliability of a reserve estimate. It is suggested that a resource reliability rating (RRR) system be established to quantify what is meant by geological assurance and to combine this with an estimate of the precision of estimation as gained by geostatistical analysis. Proven and probable minable reserves would be those with an RRR better than 50% and a precision of estimation better than 20%

Dec 1, 1996

By G. W. Harris, J. J. K. Daemen

Slightly shorter, modified version also published in CIM Bull., vol.94, no.1047, Feb. 2001, p.52-55. To minimise ore dilution induced by blast movement in surface mines it is necessary to quantify such movement. This will allow more accurate location of the grade boundaries on the surface of a blasted rock pile before excavation. A method has been developed and tested for measuring accurately the direction and magnitude of subsurface blast movement, using a caesium vapour gradiometer and a real-time, differentially corrected global positioning system to locate the pre- and post-blast positions of magnetically enhanced target objects placed in blastholes inside a bench. The procedure does not necessitate disturbance of the blasted rock and the movement information is available sufficiently quickly to allow for modification of the selective mining boundaries for each surveyed blast. It was found that the maximum depth of target detection was 18 m and the overall accuracy was plus or minus 1 m horizontally and 1.2 m vertically

Jun 21, 1905

By Gruenewaldt von

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The principles of shear-driven aggregation of particulate matter suspended in fluids, a common industrial method of concentration and separation, were applied to a convecting magma to estimate the time required to sparge or strip the PGE and Cr content and concentrate it into the boundary layers. It was calculated that an ore-grade (e.g. 6 ppm PGE) boundary layer about 1 m thick would require 100 000 years at most to form from a body of magma 500 m deep with a PGE content of 20 ppb. Since concentration would be most vigorous when the magma was warmest, at least half of this concentration would take place in the first 10 000 years. The effect of dispersive pressure in the boundary layer would generate a concentration high of refractories just below the top of each boundary layer and another just above the bottom. If the magma was a double-diffusive system, it might evolve by the downward cascade of enriched boundary-layer material into the hotter, lower magma layers, where depending on saturation levels chromites would equilibrate and sulphides undergo partial or total resorption, enriching PGE levels in any remaining sulphides. This cascade process would in time greatly enrich the lower regions in PGE-bearing sulphides and chromites

Apr 1, 1994

By R. D. Dukimo, M. V. Sevian

The nature of fracture and factors that control the extent of fracture in the tumble-drum and drop-tower tests have been identified. The product-size distribution, on which the standard strength indices for these tests are based, and the breakage rate constants depend on a number of factors other than the strength of the lumps. The standard indices and rate constants are meaningful only in a comparative context and for events whose loading mechanism is similar. The results of experiments on three Australian ores, from Yandi, Koolan and Mount Whaleback, are used in combination with fracture mechanics theory to explain why different tumble-drum standards have been found to be fully consistent. A more meaningful measure of strength could be the parameters of the Weibull function, scatter and average strength

Jun 19, 1905

By W. D. Maier, H. V. Eales

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. A lithological and geochemical study revealed significant lateral variation of the interval over 170 km of strike, from about 30 m at the Union Section to 220 m near Brits. The cumulates also become more evolved and leucocratic with distance from the Union Section both towards the NE (Amandelbult) and SE (Impala, Rustenburg and Brits). It is inferred that the persistent heat flux from a putative major feeder zone near the Union Section impaired deposition of felsic cumulates in the vicinity, delaying crystallisation of successive phases in parts of the chamber near the feeder. New influxes were therefore deposited on a footwall of varying thickness and lithology in response to different degrees of crystallisation and accumulation along strike. The development of cyclic units of chromitite, harzburgite, pyroxenite, norite and anorthosite was interrupted at different stages in different parts of the chamber

Apr 1, 1994

By T. C. Alex, S Srikanth, Premchand

It has been suggested that reduction of the iron and manganese phases as far as FeO and MnO is preferred for the complete liberation and selective reduction of the copper, nickel and cobalt oxides in manganese nodules. The oxygen partial pressure/temperature regime suitable for this purpose has been delineated. Free-energy minimisation and thermogravimetric results indicate that the requisite conditions can be achieved if more than 10% of neutral oil is used at temperatures greater than 923 degrees C. Neutral oil content, temperature and roasting time have been optimised to maximise leaching recoveries of Cu, Ni and Co: up to 96% of Cu and Ni and up to 85% of Co can be recovered if 15% of neutral oil is used as a reductant at 973 K for 90 min

Jun 21, 1905

By B. M. England, M. V. Swain, N. Bristow, R. D. Dukino

The toughness and fracture mechanisms of ores with significantly different microstructures from Yandi, Koolan and Mount Whaleback were studied with a view to understanding their degradation behaviour. Bulk fracture toughness was determined by the 3-point single-edge notch beam test and the results interpreted using Weibull statistical analysis; indentation fracture mechanics was also used to measure fracture toughness of the different mineral forms and to understand their response to contact fracture

Apr 1, 1995

By D. M. A. Flight, G. E. M Hall, P. R. Simpson

theoretical viewpoints.

Apr 1, 1994

By D. M. Evans, D. L. Buchanan

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. The Zinca area was chosen as a suitable location for an investigation of the weathering and secondary dispersion of platinum group metals from the Zone. It was concluded that platinum is immobile while within weathered rock, its mineral phases tending to alter from primary sulphides and tellurides to secondary Pt-Fe alloys. Palladium is variably mobile in weathered rock. In stream sediments Pt occurs mainly as small, dense, discrete particles, giving rise to a nugget effect, whereas Pd probably occurs as much finer particles or chemically adsorbed on to a suitable substrate. Pt shows a rapid decrease in sediments downstream from mineralisation, whereas Pd has a much slower downstream decay

Apr 1, 1994

By P. H. Morris

To achieve the full potential of sub-aerial co-disposal the properties of the co-disposed wastes must be known and understood. A description is given of the morphology and properties of waste deposits that were formed during 19 field trials of sub-aerial co-disposal at the dual Goonyella-Riverside mine in Queensland and at Hunter Valley No.1 and Warkworth mines in New South Wales

Jun 19, 1905