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By Will H. Coghill, Fred D. DeVaney

"INTRODUCTION The Mesabi iron district of Minnesota has a potential production of over 50 million tons of iron ore annually. The large shipments of ore each year are gradually depleting the reserves, and if the present rate of production is to be maintained there must be a growth in the present available ore supply.Growth is a natural course. The growth of a city may be affected by the addition of city blocks or by the improvement of utilities necessary for its betterment, these may go on in the order named or concurrently. The city-block type of growth of the Mesabi has been tremendous, and the ""betterment"" type has followed in due course. Probably the former has reached its limit, and if so, more time will be allotted to the latter. It is not the intent of this paper to present either a eulogy of the wonderful mining methods or a history of the milling, but it is pertinent to say that if the lean-ore area continues to produce, the continuance will be more the result of further improvement of milling methods now well under way than of extension of boundaries by the city block plan of growth.In an examination of the western end of the Mesabi district one finds sludge basins containing millions of tons of millable ore rejected by washing plants which were built for economy in operating cost and with little thought of conservation, and rich tailings piles of jigging plant rejects. In addition, there is an appreciable tonnage of bawl rake pro-ducts so low-grade that it requires mixing with the best ore of the district to make it merchantable.Any of these three products is a source of additional reserves, but gangue must be removed before the products will comply with blast-furnace stipulations. All investigators are agreed that to effect this separation comminution must be fine enough for liberation, but beyond this point opinions diverge; some would seek new processes, while others adhere to methods and machines developed in other mining districts.In the investigation by the Mississippi Valley Experiment Station of the United States Bureau of Mines working in conjunction with the Missouri School of Mines and Metallurgy,Rolla, Mo., the latter course has been followed. Attention was first given to the sludge basins mentioned. From their contents good grades of concentrates were made and the results published 4 later commercial-scale tests were made in a pilot plant of 10 tables, and the laboratory results were confirmed, The tailings from jigging plants are high in iron, and a study of their possible retreatment showed that if they are recrushed, high recoveries of acceptable grade may be expected. The results will be published later."

Apr 1, 1932

By N. S. Dalal, X. Shi

"SUMMARYElectron spin resonance (ESR) measurements provide direct evidence for the involvement of the glutathionyl radical, as well as an isolable Cr(V)-glutathione intermediate in the Cr(VI) glutathione redox reactions. These results indicate a new mechanism for the reduction of Cr(VI) by glutathione in relationship to cellular environment and suggest that synergistic reactions of Cr(V) and GS· might be responsible for the (unexpected) increase in the Cr(VI)-induced DNA-strand breaks at high glutathione levels.INTRODUCTIONWhile the reduction of Cr(VI) by glutathione (GSH) is thought to be a critical' step in the pathogenesis of the Cr(VI)-exposure related carcinogenesis1- 4, the exact reduction mechanism is not yet understood. The following reaction steps have been suggested :(A) Initial step:Cr04 2- + GSH - GSCrOa - (1)(B) At high GSH levels:GSCroa- + GSH - Cr( IV) + GSSG (2)(C) At low GSH levels: GSC rO a - - Cr ( V ) + GS ·(3)Thus far, however, in these reactions, the GS· radical has eluded spectroscopic detection, while the evidence for the Cr(V) formation has been reported positives as well as negative2·. Her~ we present spin-trap ESR evidence for the formation of the GS· radical, and a definitive ESR detection of an isolable cr(V)-GSH intermediate in Cr(VI)-GSH reactions.MATERIALS. AND METHODSESR spectra were obtained at X-band (-9.7 GHz) using a Bruker ER200D ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR Gaussmeter (Bruker, Model ER035M) and the microwave frequency was measured with a Hewlett-Packard (Model 5340A) frequency counter. The spin probes, a-(4-pyridyl-1-oxide) -N -tert-butylnitrone (4-POBN) and 5,5-dimethyl~1-pyrroline-1-ox1de (DMPO) were purchased from Aldrich, K2Cr201 from Fisher and used without further purification. All experiments were done at room temperature."

Jan 1, 1989

By E. J. Schneider

In view of the current interest in the constituents of low-temperature tar, the Synthesis of three known xylenols and their hydroxyacetic acid derivatives has been undertaken by the U. S. Bureau of Mines. One of these xylenols, the 1,3,2 derivative first reported by Steinkopf and Höpner,4 has been described by Brown and Branting.5 The other two derivatives, the 1,3,5 first reported by Schütz6 and the 1,2,3 reported by Steinkopf and Höpner, have now been studied in greater detail. In the present work the synthesis of 1,2,3-xylenol and 1,3,5-xylenol was repeated, with some improvements in the former. The hydroxyacetic acid derivatives were also prepared, and it was found that while the melting point of the 1,2,3 derivative agreed with that of Steinkopf and Höpner. that of the 1,3,5 derivative was found to be 111° instead of 85 to 86° as reported by Schütz, by Steinkopf, and later by Bruckner. The discrepancy between the melting-point figures is doubtless due to differences in the purity of the xylenols used in the synthesis of the acids. Schütz obtained his 1,3,5 acid by recrystallizing an impure sample obtained from a mixture of xylenols. The difficulty of obtaining a pure acid by starting with a mixture is demonstrated by Bruckner, who despite painstaking efforts was unable to obtain the pure 162.5° melting 1,2,4 isomer from a mixture that persistently melted at 138° C. Steinkopf did not repeat Schütz's work but merely used the latter's figures in compiling a table. Bruckner, on the other hand. apparently also made the acid (by an improved method), and it is difficult to explain his checking Schütz's figure, unless it is that he, too used a symmetrical xylenol obtained from a tar and not prepared synthetically, as was the one reported in this paper.

Jan 1, 1929

By John Nagy

The Bureau of Mines adapted thermal theories explaining combustion of gases to correlate parameters affecting ignition of dust dispersions. The dust dispersions were ignited in a Godbert-Greenwald furnace at atmospheric pressure. Ignition temperature and the concentrations of fuel, admixed inert powder, and atmospheric oxygen were related mathematically. Values for these parameters obtained in laboratory experiments for cornstarch agreed with theory. The developed equation permits extrapolation; the predicted upper igni-tion limits correspond with limited experimental data from laboratory and large-scale tests. Explanation of the effect of fineness of dust on ignition parameters is attempted by introducing a surface-area constant to modify the activation energy. Arguments are presented to show that the ignition process is a solid-gas phase reaction rather than an ignition of prevolatilized gases.

Jan 1, 1966

By E. G. King

Existing thermodynamic data for compounds of the rare-earth metals are few in number and often inaccurate because, in the past, it was difficult to obtain samples that were pure enough and reasonable in cost--a situation that is rapidly improving. This paper reports the results of low-temperature heat-capacity and high-temperature heat-content measurements for cerous fluoride (CeF3) and supplies the first such published data for a rare-earth fluoride. The low-temperature heat-capacity data cover the temperature range 51°-298° K. and serve to evaluate the entropy at 298.15° K. The high-temperature heat-content data cover the temperature range 298°-1,799° K., including the temperature and heat of fusion. The results are assembled for ready use in thermodynamic calculations. Cerous fluoride is one of the important intermediate compounds in the production of cerium metal.

Jan 1, 1959

By J. M. Stuve

Low temperature and high-temperature calorimetric measurements were made by the Federal Bureau of Mines on high-purity samples of Re02(s) and Re03(s) to determine heat capacities and enthalpies. The temperature range of heat capacity measurements was 5 to 310 K for Re02 and 8 to 309 K for Re03. High-temperature enthalpy measurements alone were determined for pure Re207(s,1). The derived standard entropies are S°298 = 11.43±0.01 cal/deg mole for Re02(s) and S298 = 16.55±0.02 cal/deg mole for Re03(s). High-temperature enthalpy equations expressed in calories per mole are as follows: Re02 (s) , H-H298.15 = 16.002T + 1.600 X 10-3T2 + 3.522 X 105T-1 - 6,095 (298 to 1,400 K); Re03 (s) , H-H298.15 = 20.293T + 3.238 X 10-3T2 + 3.950 X 105 T-1 - 7,664 (298 to 1,000 K); Re207 (s) , H-H298.15 = 38.437T + 10.309 X 10-3T2 + 4.315 X 105 T-1 - 13,824 (298 to 413 K); Re207 (s) , H-H298.15 = 30.181 + 17.713 X 10-3T2 - 10,612 (413 to 600 K) ; Re207 (1) , H-H298.19 = 66.101T - 10,092 (600 to 700 K). Gibbs energy of formation (?Gf°) data and related functions over the temperature ranges investigated are tabulated for the three oxides.

Jan 1, 1976

By Charles D. Litton

This U.S. Bureau of Mines report describes the results of two large-scale tests conducted to evaluate a prototype nitric oxide (NO)-compensated carbon monoxide (CO) fire sensor, developed by Carnegie Mellon Research Institute (CMRI). In the tests, small coal fires were allowed to develop in the presence of diesel exhaust at relatively low ventilation airflows. These tests compared the response of the CMRI fire sensor with that of other fire sensors, including the Bureau's diesel-discriminating smoke detector. During the tests, CO, NO, and smoke levels were continuously monitored in order to determine the sensor alarm times and gas levels as the fire developed. The data indicated that the NO-compensated CO fire sensor was capable of suppressing the CO produced by a diesel engine and that the sensor responded reliably to the CO produced from the test fires. The tests also showed that the Bureau's diesel-discriminating smoke detector alarmed earlier than the prototype NO-compensated CO fire sensor.

Jan 1, 1993

By L. G. Trudell, J. W. Smith, K. E. Stanfield

Representation of actual oil yields from sections of the Green River formation oil shales by two types of drill - cutting samples was evaluated . Average oil yields of single sets of mud cuttings from hydraulic rotary drilling in Colorado and gas cuttings from pneumatic rotary drilling in Utah were compared statistically with yields of core samples taken from adjacent holes . Oil yields from gas cuttings were identical to oil yields of core samples . Mud cuttings appeared to represent a section of the formation conservatively , the deficiencies increasing with increasing richness of sample . Because a large amount of the oil - yield data currently available for the Green River formation is based on mud- cutting samples , development of a valid correction method by additional testing is needed .

Jan 1, 1963

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. M. Suryan, V. Vallyathan

"Freshly ground and aged anthracite and bituminous coal samples were investigated by electron spin resonance (ESR) spectroscopy to detect the presence, concentration and reactivity of free radicals. Freshly ground anthracite coal produced greater concentration of free radicals than the bituminous coal, and the radical reactivity was also greater for the anthracite. The reactivity of the newly produced free radicals in the anthracite dust correlated with the dust's toxicity. Furthermore similar coal-based free radicals were detected in the lung tissue of autopsied coal miners, suggestive of persistent reactivity by the embedded coal dust leading to the progressive disease process. Results of the studies on the severity of coal workers' pneumoconiosis (CWP) and free radical concentration m lung tissue support this hypothesis.INTRODUCTIONCOAL WORKERS' PNEUMOCONIOSIS (CWP) has been an important topic of concern to miners, mining engineers, epidemiologists and medical researchers for decades. It is well known that the prevalence and severity of CWP differ markedly between different regions and mines despite comparable exposures to respirable dust (REISNER and RoBOCK, 1977; HURLEY et al., 1979). These variations in pathogenicity of coal mine dusts can only partially be explained by differences in the mineral composition and by rank of coal (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). Cytotoxity studies on mammalian cells do not correspond well with the human disease pattern (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al.,1980; VALL YA THAN et al., 1988). For example, while epidemiological studies of coal miners (REISNER and ROBECK, 1977; HURLEY et al., 1979) indicate that the prevalence of CWP correlates roughly with the rank of coal, such correlation has not yet been established in biological studies, despite considerable effort (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). In order to help resolve this apparent paradox we have undertaken a systematic study to evaluate whether any correlation exists between the concentration of free radicals present in fresh or aged coal dusts from two well-characterized U.S. coals. This study was also prompted in part by observations reported in the literature that organic free radicals can be formed on the surface of freshly fractured coals (LEBEDEV et al., 1978; DULIBA and CLARKSON, 1984). In particular, ARTEMOV and REZNIK (1980) noted that the decay lifetimes and, hence, the reactivity of the organic free radicals formed on crushing Russian coals, .depended"

Jan 1, 1989

By L. F. Heising

Ten composite samples of Mesabi Range nonmagnetic taconite from the Hibbing, Minn., area were evaluated by flotation and by reduction roasting-magnetic separation to determine their potential as a future source of iron are. Only one of the composites yielded concentrates that could be considered marketable, using as a criterion a 10-to-1 iron-to-silica ratio. Cursory petrographic examinations of all 10 composited samples and a detailed mineralogical study on 1 sample suggest that unfavorable mineralogical associations between iron and gangue minerals are responsible for their poor beneficiation characteristics.

Jan 1, 1967

By William C. Cooley

This volume contains copies of the 5 x 8 in. accession card file for all items collected which were judged to be relevant to underground hydraulic coal mining. In many cases, abstracts are included. Abstracts were taken from the source, from other reviews, or from the preliminary screening of Russian documents performed by Dr. A. L. Brichant. No attempt was made to write abstracts for every accession item.

Jan 1, 1975

By Edward F. Divers

This Bureau of Mines report describes a new type of scrubber (dust collector) and ventilation system built into the auger support frame (boom) of a Jeffrey 120L continuous mining machine. With this twin scrubber arrangement, one scrubber is mounted into each side of the boom. Each scrubber includes a 2,500-cfm fan, a flooded fibrous-bed scrubber panel, and a water droplet eliminator. The system was designed for minimum size and adds only a few inches to machine height. Exhaust duct design allows flexibility with various airflow configurations to suit both blowing and exhaust fare ventilation systems and brattice distances ranging up to 20 feet. Full-scale tests with exhaust ventilation were conducted at a Mine Safety and Health Administration surface facility at Bruceton, Pa., to determine the scrubbers' methane dilution capability. Several configurations of the twin scrubber-ventilation system produced striking improvements in face methane dilution when compared with conventional systems.

Jan 1, 1981

By David E. Siskind

A Bureau of Mines survey of noise from quarry production blasting was conducted at seven crushed-stone quarries, providing information on close-in noise generation, comparative instrumentation, and evaluation of the sound levels as related to blasting parameters and existing State and local noise standards. The results from this preliminary survey will be useful in the design of a complete investigation of the problem of noise from blasting. There exists an immediate need for technical guidelines for noise pollution control agencies presently working on the regulation of impulsive noise sources. This survey and results from previous work by other researchers are used to derive interim recommendations on weighting scales, generated sound levels, and instrumentation. These recommendations are based on the limited data presently available and may be modified with subsequent investigation of noise generation, propagation, structural damage, and human tolerance.

Jan 1, 1974

By Spangler Ricker, F. T. Johnson

"SUMMARYThe Ione-Carbondale clays area is 2 miles northwesterly of Ione, Amador County, Calif. It was explored during the war by the Bureau of Mines to obtain data on the alumina content and to recover representative samples for beneficiation tests for alumina recovery.Seventy holes, aggregating 8,837 feet, were drilled, and about 10.3 acres of land was cleared of underbrush. Maps and cross sections were compiled showing location of holes, analyses, and other pertinent data.The clay beds vary in thickness from 13 to 196 feet, and are covered by a loose overburden, averaging about 11.9 feet in thickness. The ratio of overburden to clay is 1 : 8.2. Analysis of a composite sample showed the recoverable alumina (A12O3) and Fe2O3 content to be in the order of 23.6 percent and 2.8 percent, respectively.Topography of the clay area is ideal for open-pit mining methods and plant site.INTRODUCTIONInvestigation of alumina-rich clays for the possible production of aluminum was made during the recent war period, when the shortage of bauxite was becoming critical.Results of field examinations by the Bureau of Mines and the Federal Geological Survey indicated that one of the most promising areas for the development of alumina-rich clays is in the Ione-Carbondale district."

Mar 1, 1948

By G. S. Baur, J. W. Montoya, S. R. Wilson

Beryllium occurs in the Honeycomb Hills area in volcanic tuff similar to the more extensive berylliferous tuff occurring 20 miles east at Spor Mountain , Juab County , Utah . Samples from the two areas have been mineralogically examined to ascertain whether they have similar characteristics . The Honeycomb Hills samples showed the presence of beta- Be ( OH ) 2 , as well as an amorphous berylliferous substance , whereas in the Spor Mountain tuff the beryllium- bearing minerals are hydrated bertrandite and berylliferous saponite .

Jan 1, 1964

By Edmund Shaw

This paper is one of a series being prepared by the United states Bureau of Mines describing mining and milling methods and costs at industrial mineral plants throughout the United states. These papers are designed to disseminate technical information regarding the methods and equipment used. The cost tabulations represent operating expenditures only and not total production costs. It is recognized that publication of total production costs might, in many instances, cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention' of the reader? is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. P. J. Weisel, Inc., with office at La Habra and plant at Corona, Calif., is the only local company that produces sand for the Los Angeles glass factories, although silica sand for other purposes is produced in other parts of southern California and the adjacent portions of Nevada. The deposit at Corona consists of coarse sand imbedded in a whitish clay and differs greatly from the other deposits, which are fine-grained sandstone that must be crushed before it can be screened and washed. The preparation of Corona sand has to be thorough and includes grinding in tube mills, repeated washing and rinsing, removal of dust by air separation, and magnetic separation of iron and other minerals. This requires a plant with a complicated flow sheet. The first plant built did not make a. satisfactory glass sand, and many additions and changes were necessary. It is thought that the present flow sheet will remain substantially unchanged until a new plant is built. The design of a new plant would be simpler, but the process would be the same.

Jan 1, 1937

By R. A. Guidotti

The Federal Bureau of Mines studied the thermal decomposition of the nitrides of the Group V A metals (CbN, Ta3N5, and VN) with the goal of preparing high-purity metals. Solid-state purification and arc and electron-beam melting were examined. Electron-beam melting proved to be the most efficient means of nitrogen and oxygen removal. Columbium and tantalum of 99.9-pct purity were prepared by this technique; in the case of vanadium, however, nitrogen could not be reduced below the solid-solution level.

Jan 1, 1976

By Virgil J. Stachura

The Bureau of Mines conducted a series of delayed blasting experiments at a West Virginia contour coal mine that resulted in smoother highwalls. The 17; were smoother due to reduced overbreak and inherently safer A, to reduced likelihood of rockfall. Reduced overbreak was accomplished by an increase in the highwall hole delays, which changed the effective delay pattern geometry and the direction of burden movement. The blast delays in the highwall holes were 50 to 100 ms longer than the mine's nominal design pattern (flat V, 17- by 42-ms surface delays, 200-ms in-the-hole delay). The burden movement was effectively changed from a 45* angle to 90* with respect to the highwall. The results of the blast delay changes were evaluated using terrestrial photogrammetry to generate vertical profiles at regular intervals. This evaluation showed that delay changes produced generally smoother vertical profiles.

Jan 1, 1984

By BUREAU OF MINES

In 1948 the United States became a net importer of oil. Coupled with an unpre- cedented domestic production of 5,900,000 barrels daily, imports approximating 500,000 barrels made available a total supply of 6,400,000 barrels a day. Thus, by herculean effort, the oil industry was able to meet an extraordinary demand at home and, in addition, to ship abroad almost 400,00 barrels daily of petroleum and products. The country's oil position now differs greatly from that prevailing at the be- ginning of World War II. Then, actual oil production averaged about 4 million bar- rels a day, and productive capacity probably was greater than 5 million barrels a day. As the demand of the military and industrial machine grew with the rising tempo of the drive toward victory, the United States not only met its own needs but pro- duced about two-thirds of the total oil requirements of the Allied Nations, excluding Russia. As a people, we can be deeply grateful that the Nation's petroleum resources were adequate and sufficiently developed to support such a tremendous effort. Even in those critical hours when immediate needs were the paramount issues, a prudent Congress paused to contemplate the importance of an assured long-term supply of liquid fuels. From these deliberations came the Synthetic Liquid Fuels Act of 1944, which authorized research and development work on new sources of oil coal, oil shale, and agricultural and forestry products. ce World War II, a civilian demand for 6 million barrels of petroleum prod- ucts has become the order of the day every day. By drilling as many as 39,000 new wells a year, the production rate has been increased enough to meet domestic require- ments by a bare margin. Some imports were necessary, however, to fill both domestic and foreign demands, and these doubtless will increase. Is this policy of exploration within the United States and the development of oil in foreign countries adequate insurance for the fulfillment of our future national needs? This question has two aspects one purely civilian and economic in character and the other significant from the standpoint of our national defense. There are now approximately 4,000 producing oil fields in this country. At first thought, it would appear that production could decline in a considerable number of these fields without materially affecting the over-all daily output. However, 48 percent of the oil comes from only 111 major fields which contain 50 percent of the total proved domestic reserves. It is apparent, then, that the flow from large fields - having proved reserves of 100 million barrels or more each must be sustained if daily production is to be kept at the present levels. Essentially, this means that new major fields must be discovered about as rapidly or perhaps more rapidly than the older ones lose productive capacity. From 1940 through 1947, only eight major fields with estimated reserves of more than 100 million barrels each, were discovered and proved - an average of one such field a year. The total estimated reserve of these eight fields was less than 1 year's supply at the present rate of use. As drilling continues, some existing fields ultimately will prove reserves larger than those now known. Without a pronounced increase in the num- ber of major discoveries, however, the prospects for increasing our present productive level are not encouraging. Any gap that appears between domestic productive capacity and demand could be filled with supplies from proved oil resources abroad. Assuming cheap pipe-line and tanker transportation to the United States, freedom from exorbitant taxes and charges

Jan 1, 1949

By John B. Umhau

[' is ann.tal surve:' gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta l' is ann.tal surve:' gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta ]

Jan 1, 1938