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By F. A. Rutledge

The Bureau of Mines Investigated the Copper Bullion claims at Rua Cove on the east coast of knight Island in Prince William Sound, Alaska, during November-December 1948 and March-April 1949. This project was part of the Bureau of Mines program for developing critical and strategic minerals in Alaska, Mineralization at the copper deposit on the Copper Bullion group of claims is mainly pyrrhotate and chalcopyrite, confined to a northeast-trending shear zone in the greenstone 2,000 feet northwest of Rua Cove. The property has been partly developed by two adits, by a number of crosscuts from the upper adit, and by several diamond-drill holes.

Jan 1, 1953

By N. S. Dalal, X. Shi, P. M. Gannett

"Chromates are known to induce tumors (1, 2), mutations (3), and DNA damage (4-6). However, the underlying biochemical mechanism(s) is (are) not fully understood (6). Recent studies have indicated that hydroxyl (·OH) radical may play an important role (7-11). The mechanistic studies of Cr(Vl)-related ·OH radical generation in biochemical systems have shown the reaction of a Cr(V) species with hydrogen peroxide (H20 2 } through a Fenton-like mechanism to be one of the important steps (9-11): Cr(V) + H20 2 - Cr(VI) + ·OH + OH-. (1)In biological systems the Cr(V) species are generated via the reduction of Cr(VI) by a variety of components, such as microsomes (12), mitochondria (13), mitochondrial electron transfer complexes (14), and at least three flavoenzymes (glutathione reductase (GSSG-R),3 lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase) (9, 15, 16). In the case of flavoenzymes, Cr(V) formation is accompanied by the reduction of molecular oxygen ( 0 2 ) to H20 2 • The Cr(V) species then reduces H20 2 to generate •OH radicals and Cr(VI) (16).To understarid the mechanism by which Cr(V}-generated ·OH radicals cause cytotoxicity, Aiyar et al. (8) investigated the reaction of Cr(VI) and H20 2 to generate ·OH radical and its reaction with 2'-deoxyguanine (dG) to form 8-hydroxy-2'-deoxyguanine (8-0HdG}:"

Mar 1, 1992

By F. J. Cservenyak

The Bureau of Mines Solid Waste Program is directed toward three main areas of research: (1) Extraction of mineral, metal, and energy values from urban refuse; (2) recovery of mineral and metal values from wastes generated in the industrial extraction, processing, and utilization of raw materials and mineral-base products; and (3) upgrading and utilization of automotive scrap. The Bureau also has a contract and grant program which supplements the in-house research and aids in the training of personnel in the proper management of mineral- and metal-based solid wastes.

Jan 1, 1970

By R. V. Ramani, P. M. T. White, D. Sutton

Appendix I. Part 1: Description Of Geology & Reserves System Introduction The Ore Evaluation and Reserve programs have been developed to aid in the evaluation of coal deposits, both qualitatively and quantitatively. The "Weighted Moving Average" technique used provides considerable flexibility in dealing with diverse parameters with differing distribution characteristics. Determination of Model Constants "a" and "k" - Unit 1 The flexibility of the method in dealing with diverse value parameter distributions lies in its ability to cater to the individual characteristics of each. These characteristics are embodied in the values determined for constants "a" and "k", namely, local and regional variations in value distributions, respectively. The empirical method used attempts to optimize the "a" - "k" combination. Realistic values for "a" and "k" are entered into the program together with sample values for the required parameters and their respective coordinate location values. All the values within a specified radius from the point being evaluated are used to interpolate a value at that point. (Note, the interpolated point is the location of one of the boreholes, values of which are not used in the calcula¬tion.) 3n a similar manner, interpolated values are calculated for each borehole location and for each parameter. This is done for each possible combination of "a" and "k".

Jan 1, 1974

By Henry E. Perlee

Air compressor explosions that are caused by the ignition of combustible vapor mixtures cannot be explained by a single reaction mechanism or sequence of events. Explosions have been caused by the sudden release of large quantities of lubricating oil, by the rapid vaporization of oil that had accumulated slowly in high-pressure piping, and by the production of decomposition products from carbonaceous deposits. Ignitions can be caused by the heat produced in a catalytic reaction, in a compression process, or when a shock wave is propagated through a combustible vapor-air mixture. The frequency of these ignitions can be minimized by establishing proper maintenance and cleaning schedules. Further study is needed to satisfactorily correlate the various factors involved in compressor explosions.

Jan 1, 1963

By W. L. Crentz

Knott County is one of the smaller coal-producing areas in the Eastern Kentucky coal field. It contains numerous coal beds, many too thin to support mining over a wide area, Coal produced in the county is from a few rail-shipping operations and many small truck mines. Many smaller mines are working beds whose exact location in the coal-bearing strata is uncertain. Samples were collected from 11 different coal beds, of which the Fire Clay, Hindman, Upper Elkhorn No. 3, and Flag are the most import ant from a product ion standpoint. Known reserves in the Hindman bed. are very limited, and almost the entire production from this bed is gathered from two comparatively, large rail-shipping mines in addition to the four principal beds, samples were taken in the Francis, Haddix, Fire Clay Rider, Whitesburg, Amburgy, Upper horn No. 2, and Upper Elkhorn No. I .beds. Figure 1 is a typical section of the strata, showing the more important coal beds and. readily identifying their location with respect to each other. The bed names as shown are particularly important because of the local tendency to assign several names to the same bed. To avoid confusion, the names by which each coal bed is known also are given in the following listing. The coal. beds., in descending order, follow: [ ]

Jan 1, 1953

By H. B. Hill

The discovery of the Oklahoma City field and its .rapid development into one of the major oil-producing districts is an outstanding epoch in the history of the petroleum industry not only of .Oklahoma but also of the United States. The relatively great depth to which the wells were drilled and the large initial production of high-gravity oil are of special significance. The field has boon under proration almost from the time that its development began, and many new production problems have developed out of the changed conditions of operation. The discovery well was first tested in December 1928 at a depth of 6,402 feet, with an initial production of 4,847 barrels of 38.5° A.P.I. gravity and several months later was completed at a depth of 6,624 feet. The large initial production, the high pressure, and the large gas volume in the different horizons of the discovery well suggested the potential possibilities of gas and oil, production in formations of Pennsylvanian and pre-Pennsylvanian age.

Jan 1, 1933

By Wallace E. Anable

This investigation by the Bureau of Mines was conducted chiefly on Cuban serpentine nickeliferous ores to determine whether these materials would be amenable to direct carbothermic reduction in an electric furnace to produce a low-carbon ferro-nickel. The project was carried out as one of several under a Memorandum of Agreement between the Bureau of Mines and the General Services Administration (Contract GS-OO-B (D)-152l). Two ore samples were received for this investigation. One was a mixture of nickeliferous serpentine from the North Ocujal, South Ocujal, and San Juan claims of the Nicaro Nickel Co. The other sample was a mixture of material from the Ramona and the Lorna Mulo claims of the Cuban Nickel Co. Most of the ore from the Ocujal-San Juan deposits and about 40 percent of the sample from the Ramona-Lorna Mulo deposits were calcined before smelting. The remainder of the sample from the Ramona-Loma Mulo deposits was smelted after drying to about 8 percent moisture. An arc-resistance, selective-reduction smelting technique was employed in these tests. Either bagasse alone or a mixture of bagasse and coke was used for reductants. No flux was used in the furnace charges.

Jan 1, 1957

By James F. O?Neil

Brown iron ore deposits in Quitman County, Ga., were investigated by the Federal Bureau of Mines in cooperation with the State of Georgia, Department of Commerce, and the University of Alabama. Ninety-one holes were drilled, having an aggregate footage of 2,188 feet; seventy-one holes penetrated 248 feet of iron mineralization. Average thickness of the ore zone was 3.5 feet under an average thickness of 14.7 feet of overburden. The drilling developed inferred reserves containing nearly 30 million long tons of crude ore with an average analysis of 28 percent iron plus minor quantities of manganese. Test work done by the Bureau on the crude ore samples indicated that they would upgrade by current lug washer practice, with the use of a 1i8-inch screen, and yield 4.4 million dry long tons of concentrate with an average analysis of 52.1 percent iron plus manganese. The weight recovery obtained was 14.7 percent. Research studies made by the Bureau showed that the weight recovery would be increased by changing the screen size without any appreciable sacrifice of grade. The average weight recovery was increased to 18 percent with a 10-mesh screen and 22.8 percent with a 20-mesh screen. Screen tests studies indicated that there was no appreciable interlocking of the iron and manganese minerals and the clay and silica waste particles of the materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size.

Jan 1, 1965

This report discusses the nonfuel critical minerals position of the United States-both current and future (to the year 2000). We have assumed that there will be no major global disturbances-military, political, or economic-during the rest of this century. However, international relationships, strategies, and conditions that affect the supply of minerals are very tenuous, normal trading patterns can be easily upset, and national and ideological objectives can and do interfere with "normal" free market conditions. For example, the Department of Defense has reported that the Soviet Union is engaged in a strategy designed to reduce the availability of strategic minerals, through either physical disruption, market manipulation, or domination of producing or neighboring states. Although such a strategy poses serious concerns for the United States and the free world, the impacts of disruptions are not covered in this publication. Historical Perspective The modern industrial economy of the United States is founded on the production and use of minerals.* Two hundred years ago our forebears began taming a raw continent, developing a base for agriculture and a rudimentary minerals producing system. In the 19th century, with the aid of imported labor and capital, the development of America's vast natural resources was undertaken, and the transition from an agricultural to industrial society was underway. By the century's close, the United States had emerged as a great industrial power, partly through the development of such mineral resources as iron in Minnesota and coal in Pennsylvania.

Jan 1, 1983

By B. W. Gandrud

[The Bureau of Mines is conducting an extensive investigation of coal preparation in the Alabama coal fields in cooperation with the University of Alabama and coal-mine operators. In this investigation the drainage characteristics of typical coals from the Warrior and Cahaba n fields were studied. Tire main purposes of this study has been to evaluate no nearly as possible relative influences of certain factors on rate of drainage and to determine whether the drainage characteristics of coals from different beds or from different mines on the soma bed differ materially. A further objective was the development of a laboratory drainage test that would predict approximately the rate at which any coal will drain after having been loaded into a railroad car in a saturated condition. The study has been confined to samples of slack coals - that is, coals from which none of the fine sizes have been removed. The samples ranged in upper size limits from 7/16 inch to 3 inches. It did not seem necessary to study nut and egg sizes, that is, sizes from which the fine coal has been removed by screening, as these lose water so rapidly by natural drainage that they present no serious problem in dewatering after treatment in a washer. The significance of drainage characteristics of Alabama coals is apparent in view of the fact that not less than 70 percent of Alabama?s total coal product is subjected to wet washing before being materials.]

Jan 1, 1941

By C. M. Keenan

During the 7-1/2 years (January 1945-June 1952), immediately preceding enactment of the Federal Coal Mine Safety Act, 26 major disasters3/ in the coal mines of the United States caused the deaths of 491 persons. In the next 7-1/2 years under the act (July 1952-December 1959), only 12 major disasters occurred. The total killed was 148. This improvement is commendable. However, the continuing frequency of minor fires and gas and/or dust ignitions in the Nation's coal mines, many of which could have been of major consequence, are cause for serious concern to the coal-mining industry and those affiliated agencies engaged in promoting safety in the industry. The data presented in this report have been prepared to make available to the coal-mining industry and related groups an overall perspective of the disaster potential from mine fires and gas and/or dust ignitions in coal mines after 7-1/2 years under the Federal Coal Mine Safety Act. This act, effective July 16, 1952, which amended the original Federal coal-mine investigative act of May 1941, provides under Title II certain enforcible mine-safety provisions designed to prevent major disasters caused by explosions, fires, inundations, and man-trip and man-hoist accidents in coal mines that employ 15 or more individuals underground.

Jan 1, 1960

By A. W. Ambrose

"A need exists for men in oil-field production work who correspond to the mining engineer of a large mining property. Some oil companies prefer to call such an employee a resident geologist, resident engineer, or a petroleum technologist. He should perhaps be more correctly termed a petroleum production engineer. The duty of such a man is to apply his scientific and geologic training practically to oil-field development work.He should be, by education, a mining, civil, or mechanical engineer, with a knowledge of geology and chemistry. Upon completion of his education, such a man should spend several years in the oil-fields. There are two means of gaining proper experience. The first method is to work for an oil company in making a detailed study of each well, collecting data on the history and production, followed by a preparation of good records, from which well logs can be prepared. From the well logs, the geologic cross-sections, peg-models, and structure contour maps can be made. These allow a comparable, detailed study of each well, which is necessary to solve many of the problems. Along with this the engineer should visit drilling wells daily for collection of samples of formations and for a proper study of how they drill. He should form friendly relations with the drillers and production foremen. The second method of gaining proper experience is to start work as a roustabout, pumper, or on the pipe¬line gang, finally working up to a tool-dresser. After three or four years of such work, the engineer may be classed as a petroleum production engineer."

Jan 1, 1920

By ALBERT LONG, Wing G. Agnew, FELIX CHAYES, Alton Gabriel, Leonard Obert

Although the technique of diamond drilling was developed nearly 80 years ago, the use of this process as an aid to mining and other fields of engineering has increased greatly during the last decade , primarily as a result of the development of the cast -set bit , which now largely replaces the hand - set types , and of the use of bort instead of carbons . Since this transition to cast - set bits and bort diamond , many papers ( 1-14 ) have been written on the application of diamond drilling to various engineering problems . These papers contain , besides specification of the problems , some information on the labor and bit costs and a few data on drilling technique . These data , however , are subject to restricted interpretation owing to the large number of variables , which are not controlled in field drilling . Only one paper has come to the attention of the authors , namely , that by Sundberg and Lindqvist ( 16) , which reported a study of diamond drilling under controlled conditions . This paper was written early in the transition period, and the data and conclusions presented therein have had , without a doubt, considerable influence on the development of presentday diamond bits and In view of the fact that during the last 10 years thrilling procedure . have been new developments in diamond bits. and new applications of diamond drilling , a general program of research has been inaugurated to study the problems resulting from these changes .

Mar 1, 1947

By E. E. Maust

The literature on the activation of sphalerite for flotation by short¬chain xanthates leaves unanswered the question of whether a compact surface film of activator sulfide is necessary or merely sufficient for high flotation recoveries. Studies by Guarnaschelli and Plaksin indicate that xanthate adsorption and flotation of sphalerite are increased with increasing hole/ electron ratio. These results, and the known acceptorlike behavior of many heavy-metal impurities in zinc sulfide, suggest that activation may result from a traditional semiconductor doping effect at the surface. Using the theory of chemisorption states on ionic crystals as developed by Levine and Mark, the Bureau of Mines has carried out A calculation to estimate the surface-state energies of various metals when they are substituted at zinc sites on (110) sphalerite surfaces. Based on a simple Madelung-Born treatment of ionic solids, the calculation indicates that many of the metals known to activate sphalerite for subsequent flotation have lower surface-state energies than nonactivators. The results of these calculations are discussed from the standpoint of consistency with the proposed activation mechanism and observed flotation results. The satisfactory agreement obtained is taken to be support for the proposed mechanism, and further elaboration of a surface-doping model is attempted.

Jan 1, 1976

By D. R. Tesarik

The factor of safety, the traditional measure of stability for earth embankments, is graphically presented in factor of safety charts in this Bureau of Mines report. Factor of safety contours are drawn for homogeneous earth embankments for two contrasting situations: (1) no phreatic surface and (2) a phreatic surface that assumes 10-pct freeboard. The factor of safety can be read directly from the charts if the physical properties of the soil and the geometry of the embankment are known. The curves provide a quick first approximation of the "most stable" and "least stable" condition of the embankment. The Simplified Bishop Method was used for the safety factor calculations, and a sequence of least squares curve fitting steps was used to present the factor of safety in final chart form.

Jan 1, 1981

By Ivor Hawkes

This report describes how longitudinal and bending stress waves in' percussive drill rods generate noise. It is shown that in practical drills the largest noise source is the bending waves, which are mainly generated because of imperfections in the piston, chuck, and drill rod alignment. Equations are presented which enable the noise spectra generated by the bending and longitudinal waves to be precisely predicted. Means for reducing the amplitude of the bending waves are discussed.

Jan 1, 1977

By Seth C. Schaefer

The Bureau of mines investigated thermodynamic properties of MnSO4 and 2CdO CdSO4 to obtain basic thermodynamic data applicable to the treatment of mineral concentrates during roasting and sintering processes. Standard Gibbs energies of formation were determined with high-temperature galvanic cells using stabilized Zr02 as the electrolyte. Potential measurements were obtained from the cells?

Jan 1, 1983

By M. J. Ankeny

Coal-mine haulage ranks second as a cause of coal-mine fatalities, and the prevention of such accidents will materially improve progress in safety in the coal-mining industry. Beginning March 1950, Federal coal-mine inspectors were made responsible for completely investigating all fatal accidents in and around coal mines. During these 10 months, Federal coal-mine inspectors investigated 447 fatal accidents. This is a study of 121 of the fatal haulage accidents investigated, which constituted 27 percent of fatalities from all causes. Haulage employees represent only 12 to 15 percent of mine personnel, but, on the basis of accident frequency, their work is the most hazardous in coal mines. Fatal haulage accidents occurred in 53 bituminous coal-producing counties representing 14 States and Alaska. The physical conditions represent a cross section of' producing coal beds. Mining and transportation methods vary, from those of small hand-loading mines to those of modern mechanized mines.

Jan 1, 1951

By Farrel W. Lytle

An X-ray emission spectrographic method of analysis is presented for determining rare-earth elements in fractions obtained from bastnaesite ore. The method includes determination of yttrium, thorium, lanthanum, and the rare-earth elements in various complex mixtures. The analysis technique is based upon comparing the samples with synthetic standards approximating the composition of the samples. Working curves are plotted on an absolute-intensity basis, with no correction for back-ground. Examples of working curves and the analyses of typical rare-earth concentrates are included. The selection of spectral lines for the various sample matrices is discussed. A special technique is used for samples in which rapid hydration and carbonation occurred. By analyzing synthetic samples of known composition, the accuracy of the method was determined. The average error of analysis was about 3 percent of the amount present in the range from 5 to 100 percent and about 7 percent in the 0.2-to 5-percent range. A maximum of about 40 samples per day may be analyzed for 7 elements each.

Jan 1, 1957