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By Zhen Hu, Chenghang Wang, Jianjian Zou, Xiujuan Li, Hanwen Li, Tai Wang, Baoxu Song

A rare earth deposit in Sichuan, China is rich in wulfenite in addition to bastnaesite and barite, and the deposit has already adopted high intensity magnetic separation technique to pre-enrich the rare earth minerals, during which the wulfenite and barite have been left in the non-magnetic product. Because the chemical composition of wulfenite is only 24.17% Mo and 42.15% Pb, it is very hard to obtain qualified lead or molybdenum concentrates by physical separation process. To pre-concentrate the wulfenite, flotation has been first introduced, and by using 100g/t GY-7 as dispersant, 1500g/t CP-1 as depressant and 160g/t GY-4 as collector, a floatation concentrate assaying 15.52% Mo with a recovery of 86.12% was obtained. Then a leaching process was conducted by using 1.2mol/L Na2S as leaching agent, and molybdenum can be translated into sodium molybdate in the solution with a leaching recovery of 99%. To recover rare earth oxides (REO) and lead from the leaching residue, a magnetic separation process has been conducted. Above all, by the whole process, the molybdenum recovery reaches 86.16% in the sodium molybdate solution, and a lead concentrate assaying 54.59% Pb with recovery of 27.99% could be obtained.

Jan 1, 2014

By C. H. Zhou

Cryogenic grinding of Printed Circuit Board will bring less pollution, reduce energy costs, smaller particles, regular particle size, efficient process, separation various materials due to different fracture toughness. Systemic studies of recycling discarded Printed Circuit Board (PCB) by low-temperature modification and cryogenic grinding have been made in this paper. Firstly test mechanical property of PCB at different low-temperature, including impact strength, flexural strength, and shear strength. Do experiment on the power consumption of different cooling temperature, The results show that the average power consumption is lower between -30? to -60? and the average power is decrease in evidence at -30?. Use ZKB type double roll shear crusher to crush PCB to 20mm×20mm particle size, in a temperature range of -10 ~ -30? Used R type mill to grind sample to minus 3mm under different working condition, the average power consumption is decrease in evidence from -10 ? to -30 ?, power consumption is the lest at rotational speed is 1180rpm.

Jan 1, 2014

By Andrzej Luszczkiewicz, Aleksandra Potulska

"Flotation is a basic process of beneficiation of mineral raw materials which requires very fine grinding for liberation of valuable minerals. Probably flotation will also play this role in the future. In the case of flotation of difficult-to-upgrade non-ferrous ores, currently one of the most important trends in technology development is solution to fine grinding even down to a few micrometers in size and elaboration of effective flotation technology for such fine particles. Both industrial flotation data and many investigators suggest that the best results of flotation of ore minerals are observed for particle size range from 20 to 100 µm. Many base metal ores require grinding below 20, or even 10 µm, to liberate valuable ore components. However, industrial flotation of particles below 20 µm in size creates numerous challenges. Further complications may be caused by a complex nature of the ore, especially when the valuable metals are present in several different sulfide minerals. This problem occurs in the case of the Polish sedimentary copper ores. In the present study, flotation of the ore of different size distributions and degrees of grinding, having the size of particles below 25 µm, was investigated. The behavior of different sulfide minerals naturally present in the ore was analyzed. The best results of flotation tests were obtained for the ore ground down to 95% below 25 µm. Narrow size fractions -10; 10-15; 15-25; 25-40, and +40 µm were separated using special micro-sieves and mineralogical as well as chemical analyses of each size fraction were carried out for monitoring the behavior of the fine sulfide particles. Differences between flotation of chalcocite-digenite, bornite, chalcopyrite, covellite, galena and pyrite-marcasite naturally occurring in the ore were described. The role of different particle sizes in flotation performance of each mineral was also presented."

Jan 1, 2014

By Chanki Jeong, Heechan Cho

In this study, batch flotation experiments were conducted to recover rare earth elements (REE) from an REE ore deposit in the Mushgai Khudag area, Mongolia. Apatite was found to be the major REE mineral while monazite and xenomite were observed as minor minerals. The main purpose was to float apatite to increase the REE content. Oleic acid was used as collector and MIBC was used as frother. Sodium silicate was used as a depressant for iron compounds. NaOH was used to adjust the pH of the flotation to about 9.5~10.0. The particle size was 90% less than 152 ?m (- 100 mesh). The content of REE elements was analysed by ICP - OES to determine the contents of REE such as Ce, La, Nd, Pr and Y. When sodium silicate was used, the best result was obtained using 0.2 mL of sodium silicate, 2 mL of oleic acid and 2 mL of MIBC. Under these conditions, the recovery of REE was about 78% and the grade of the first froth product was 42,995 ppm Ce, 24,088 ppm La, 14,236 ppm Nd, 4,388 ppm Pr and 1,570 ppm Y. When conducting flotation after iron minerals were removed by magnetic separation, a better result was obtained; with 2 mL of oleic acid, 2 mL of MIBC and no sodium silicate, the recovery was increased to 90% and the grade was also increased to 58,600 ppm Ce, 28,624 ppm La, 17,160 ppm Nd, 5,348 ppm Pr and 1,971 ppm Y.

Jan 1, 2014

By B. Rath

An effective process plan is an important part of maintaining consistent recoveries in mineral processing operations. Traditionally, Mineralogical studies are completed using chemical and metallurgical methods to monitor recovery and elemental distribution. The development of mineralogy and more efficient processes in mineral analysis techniques means that mineralogy is now more accessible as an efficient and comprehensive study tool. As operating costs increase and feed grades decrease it is important to maintain tight control of process and ensured maximum recovery is maintained at all times. Just a few days of losses in recovery caused by changes in ore type or processing conditions can have a large effect on total metal recovery and profit. Mineralogical audits can be used to minimize these losses by monitoring the fundamental behavior of feed ore on a regular basis. Smart use of mineralogical studies can develop mineralogical and ore type benchmarks in a detailed, which can be used in process control and monitoring. Geological ore types can be used to identify key mineralogical parameters that may be used in routine and cost effective analysis. Mineralogical systems ideally suited to this because of the depth of information on everything from modal mineralogy to locking/liberation characteristics and mineral associations. Mineralogical studies can equally be applied to specific unit operations within the process, which can allow more detailed information to be gathered on areas of the process that have been identified as critical. This will be especially effective for flotation or oxidation processes where process parameters can be very sensitive to small changes in mineralogy. This paper deals with the Ore Morphology, Ore Mineralogy, Gangue mineralogy, Photo micrographs under reflected, transmitted light and XRD studies Ore, Mineral studies of Sub grade Iron ore of Bacheli Complex, Bailadila Sector, India. Keywords: mineralogy, liberation, liberation studies, ore mineral, gangue mineral, morphology, jasper, ferruginous clay

Sep 1, 2012

By C. Y. Wang

Anodic reaction mechanism of complicated antimony-lead concentrate in Slurry Electrolysis has been investigated by the anodic polarization curves determined under various conditions. The main reactions on the anode are the oxidation of FeCln (2-n), though the oxidation of jamesonite particle on the anode can occur during the whole process, it is less. With the help of mineralogy study and relevant tests, the leaching reaction mechanism of jamesonite and gudmundite during Slurry Electroly-sis has been ascertained also. Because of the oxidation reaction of FeCl3 produced by antimony-lead concentrate itself, the non-oxidation complex acid dissolution of jamesonite, the oxidation complex acid dissolution of gudmundite, and the oxidation of air carried by stirring, the leaching ratio of antimony reaches to about 35% when using HCl-NH4Cl solution to leach antimony-lead concentrate directly. So given the theoretical electric quantity, which to oxide antimony in Slurry Electrolysis, all of antimony, lead and iron, which contained in antimony-lead concentrate, are leached.

Jan 1, 2014

By Rod Hocking, Nenad Djordjevic, Randolph Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures of operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill.Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulated the assemblage of a physical mill."

Jan 1, 2003

By V. Sovmen

The gold-ore Olympiada deposit is located within the Yenissei range (Krasnoyarsk Region, Russia). Primary sulphides ores are metasomatic changed rocks, mica-calcite-quartz structure with impurity amphiboles, chlorites, carbon, the rare thin grains of sulfides (up to 3%~5%) and native gold. The structures of ores are fine-grained, prevailing texture of ores - interspersed, vein-interspersed, band-interspersed, veinlet. The most important minerals in the deposit are: gold, arsenopyrite, pyrrhotite, antimonite, Sb-sulphosalt, quartz, muscovite, calcite, siderite, titanium minerals, chlorite and minor sulfides like chalcopyrite, galena, sphalerite, etc. A common problem in mineralogical studies applied to mineral processing (concentration, cyanidation, etc.) is the characterization of gold in ores and technological products. This paper discusses the behavior of minerals during technological process at operating factory in Olympiada Mine and gold distribution in the ores and products. For the mineralogical characterization of minerals ? combination of analytical techniques was used. Gold is encountered in the primary ores as free grains among rocks, growth with sulfides and nonmetallic minerals, inclusions in sulfides, sulphosalt, and nonmetallic minerals. The gold-sulphide ores of Olympiada deposit can be quite complicated for enrichment. With the purpose to increase the extraction of metal from concentrates by liberating the dispersed gold, forming inclusions in sul-fides, there is used technology of biooxidation of flotation concentrates in Olympiada Mine. Gold and the basic ore-forming minerals in the ores feed, sulphidic concentrates, biocakes, tailings of concentrates of flotation and products of hydrometallurgical leaching have been studied in the mineralogical research. During researches it is established that pyrrhotite was completely oxidized while arsenopyrite was oxidized almost completely in the bacterial oxidation process. Pyrite and antimony minerals behave similarly and were oxidized only partially. The main oxyhydroxides in the bacterial oxida-tion process are goethite, limonite and jarosite. The results of mineralogical researches showed reasons of losses of gold during hydrometallurgical enrichment.

Jan 1, 2014

By V. F. Petrov

Today, sodium cyanide is extensively used for extracting gold, however it is highly toxic to the environment if not managed properly. This paper discusses the key challenges presented to gold operations in efforts to come into alignment with the Russian environmental regulations and suggests solutions to overcome these challenges. It is a fact that the major environmental threat cyanide poses to water sources. Therefore, natural water sources should be well protected from the adverse effect of cyanides used in hydrometallurgical processes. For this, the following site procedures and facilities are practiced: in-site and external water recycling systems, reclaim water treatment if required and tailings ponds with water impermeable screens (tailings ponds with controlled leakage). Cost comparison analysis of cyanide destruction methods was carried out. It was revealed that the aldehyde treatment method developed by Irgiredmet JSC demonstrated the best economics. Cyanide emissions are treated by mass-manufactured packed and membrane devices which allow to keep cyanides at the acceptable limiting values established by environmental regulatory agencies.

Jan 1, 2014

By Xuliang Yang, Yuemin Zhao, Bo Zhang, Liang Dong, Cheng Sheng, Gongmin Li, Zhenfu Luo, Yaqun He, Chenlong Duan

Coal plays an important role in the primary energy consumption of all over the world. In 2012, coal reached the highest share (29.9%) of global primary energy consumption since 1970. Coal burning mainly contributes to the emission of SO2, NOX, Hg and other impurities that jeopardize the future of environment. . Beneficiation before coal utilization is the most economical and effective technology for removing the hazardous material and gangue. In this paper, a novel process of dry beneficiation based on gas-solid two-phase flow composed of the compound dry cleaning separator (FGX), the air dense medium fluidized bed separator (ADMFB) and the vibrated fluidized bed with autogenous medium (VFB) is proposed. The main equipment and the flowsheet of the united system are described in detail. Separating principle of the FGX, ADMFB and VFB devices are all based on gas-solid two-phase flow. In FGX, gassolid suspension is composed of continuous gas flow and coal powder in feed coal. Large size coal (+6- 80mm) can be pre-separated effectively, and large size gangue can be removed effectively. Moreover, - 6mm particles fed serve as autogenous medium in FGX. The probable E value is 0.13 for -80 mm raw coal. In ADMFB, magnetic powder with -0.3 + 0.045 mm size fraction and coal powder in feed coal are compound medium solids. The separation density can be adjusted and controlled according to properties of raw coal. -50 + 6 mm raw coal can be cleaned efficiently, the probable E value is 0.05. In VFB, -6 + 1 mm coal can be separated. Generally, -80 mm raw coal can be cleaned efficiently in the united system based on gas-solid two-phase flow.

Jan 1, 2014

By Wang Xu, Tao Dongping, Zhang Jie, Tao Youjun

Based on the principle of fly ash triboelectrification, the mineral electrical index and testing method are introduced. The electric differences of various mineral components of fly ash are discussed in view of the results of chemical and mineral composition analysis of the fly ash sample acquired from the Xin-wen power plant. The dielectric constant and charge-mass ratio of carbon and ash in the fly ash are determined. The data were then used along with the rotary triboelectrostatic separator (RTS) testing results to investigate the charging characteristic of fly ash particles in different sizes. The results show that the dielectric constant of fly ash with different particle size decreased with the decrease in particle size, which led to a poor electrical conductivity. Thus particle size has an important effect on conductivity. The charges of carbon and ash particles increased with decreasing particle size. The charge-mass ratio of carbon and ash particles of the same size increased with decreasing particle size. This indicates that finer particle size is more favorable for triboelectrification separation from the charging efficiency point of view. The rotary triboelectrostatic fly ash separation tests show that the best decarbonization performance was achieved with particles in the size range of 0.038-0.074mm with which the decarbonization rate and efficiency index reached 38.93% and 120.83% spectively.

Jan 1, 2014

By Kaustubh Joshi, Pradip, Beena Rai, Venugopal Tammishetti

"Rapid depletion of high grade iron ores coupled with the increasing demand for the blast furnace grade iron ore in recent times has shifted the research focus on the development of appropriate technologies for the utilization of low - grade alumina rich iron ore slimes. These slimes are currently being dumped into tailing ponds owing to their high alumina content. Typical constituent minerals present in the Indian iron ore slimes are hematite, goethite, gibbsite and kaolinite. Considering the fine particle size distribution (<37 microns) in the slimes, selective dispersion-flocculation seems to be one of the most appropriate process which has been explored by us. We present our successful results on a natural iron ore slime sample obtained from one of the mines in India. We have been able to achieve a concentrate assaying >67% Fe, and <3% Al2O3 and 2.8% loss on ignition (LOI) from the slime sample assaying 60.4% Fe, 7.7% Al2O3 and 5.45% LOI with an Fe recovery of 62-69% simply by adjusting the pulp pH. We have scaled up the process to a semi batch scale as a prelude to commercialize it for the beneficiation of low grade iron ore slimes."

Jan 1, 2014

By Gabriel Barrios, Juan Pérez-Prim, Marcelo Tavares

"The application of High Pressure grinding Rolls (HPGR) has been growing in the mining industry for the last 10 to 15 years. The major benefits generally supporting this trend are better energy efficiency, improved grinding capacity, less sensitivity to ore grindability variations and higher metal recovery in downstream processes such as heap leaching and flotation. The HPGR machine comprises a pair of counter-rotating rolls mounted in a sturdy frame. One roll is fixed in the frame, while the other is allowed to float on rails and is positioned using pneumohydraulic springs. The feed material is introduced in the gap between the rolls and is crushed by the mechanism of interparticle breakage. Comminution performance is largely determined by the pressure exerted on the bed of particles by the floating roll hydraulic system. The operating bed pressure depends on the hydraulic system start-up parameters and the loading response of the feed material. The work describes how the coupling of the multi-body dynamic simulation with Discrete Element Method in which particle breakage is described using the particle replacement method, can be effectively used to predict the performance of the HPGR. The model considers important variables as the HPGR rolls geometry and design, the hydraulic spring system start-up parameters and the material loading response, to describe operational key outputs as material throughput, operating gap and roller pressure distribution. The preliminary version of the model has been used to predict the effect of material properties on the operating gap and the load distribution on the surface of the rolls, demonstrating that it can describe qualitatively the HPGR operation, indicating that the model will be a power full tool for the simulation and selection of industrial HPGR units."

Jan 1, 2014

By J. Roth

The increasing demand of the filler industry regarding fineness and better delaminated products led to the development of a series of different grinding machines, which differentiate basically by the grinding mechanism as well as the kind of classification. Spiral jetmills grind, as it is well known preferably by delamination, therefore a spiral jetmill with integrated dynamic classifier has been developed. Especially the enhancement of the functional properties of the used industrial mineral fillers is a factor of highly increasing importance. These properties are very often bound to the platy shape of the minerals expressed by the aspect ratio. The developed Spiral Jetmill shows sufficient ability for such delamination and therefore increases in aspect ratio. In a series of comparative tests the suitability and advantages of this system regarding achievable fineness down to the submicron range as well as the conservation or even improvement of the aspect ratio of different minerals has been studied. As an emphasis on the results application tests with certain materials in the plastics field have been conducted. Due to the fact that in this range the required specific energy for achieving the necessary fineness increases exponentially another target is to optimize the grinding efficiency. A special feed control system provides on one hand a sufficient load inside the mill to obtain maximum utilization of the applied energy and on the other hand to prevent the mill from overfilling and coming with this a poor classification. The integrated classifier is a combination of a high speed motor with directly attached classifier wheels. This unit on one hand grants the necessary high circumferential speed of up to 190 m/s for providing an exact top cut of the ultrafine products and on the other hand gives the required operational reliability for continuous operation. Hard grindable impurities, which enrich inside the mill chamber, can be rejected from the process leading to an even cleaner product. Comparative tests on a talc product with certain free quartz impurities showed a significant improvement of the final product with respectively low loss on rejected material. This effect again had a beneficiary impact on the suitability of the final product when used in plastics application.

Jan 1, 2014

By Wantae Kim, Hoon Lee, Kwanho Kim, Sangbae Kim

Mechanochemical activation of starting minerals and their effect on the solid-phase synthesis and properties of ceramics with lower thermal expansion coefficient was examined. The mineral mixture, pyrophyllite-gibbsite-lithium carbonate, was prepared for the synthesis of ?-eucryptite (Li2O•Al2O3•2SiO2). Dry grinding using a planetary ball mill promoted the amorphization of the starting mixtures. XRD and FT-IR results showed that the crystallization of the target materials occurred from the ground mixtures by calcination. The crystallization of them increased with increment of grinding time and calcination temperature. In the synthesis, the trace of undesired phases such as quartz and cristobalite once formed during calcination at the temperature range from 750 to 850 °C almost disappeared and monophase ?-eucryptite was formed in the ground mixture at 950 °C. The lowest liner thermal expansion coefficient (TEC) of ?-eucryptite prepared was -2.5x10-6•°C-1. The thermal expansion behavior characteristics of the calcined

Jan 1, 2014

By M. Ghiani, R. Peretti, S. di Giovanni, G. Zonnedda, A. Serci

"An interesting occurrence of gold bearing ores of economic interest has recently been discovered in the Serrenti- Furtei district, central-southern Sardinia (Italy). The upper part of the orebodies are leaner and fairly porous, and are undergoing intense oxidation processes. In the lower parts sulphide ores predominate, chiefly enargite-luzonite and pyrite and these have a more compact structure. The passage from the oxidized to the sulphide zones, is rather irregular and difficult to delineate. The gold, generally occurring in its native form, is found in small grains. Mineral reserves in the area concerned were originally estimated to total 2.77 Mt: 0.63 Mt of oxide minerals with average gold content of 2.75 g/t and 2.14 Mt of sulphide ores with average gold grade of 3.18 g/t.Recovery of the valuable metals is a complex problem.The effectiveness of a variety of gold extraction techniques has been evaluated conducting tests on batches of ore representative of the different orebody depths obtained from core samples.The techniques investigated were: heap and vat leaching; flotation and flotation followed by leaching of the flotation tailings. The findings indicate that:• the gold contained in the ores in the upper oxidized zones of the deposit can be efficiently recovered by direct cyanidation via heap or vat leaching;• the sulphide ores in the deeper portions, that are not amenable to direct cyanidation but contain enargite concentrations of potential economic interest can be processed by means of flotation to produce a gold/copper bulk concentrate;• beneficiation of the difficult-to-treat minerals contained in the transition zone requires some knowledge of their intrinsic properties. A distinction should be made between the ores containing minor amounts of enargite which appear to be amenable to vat leaching and those with relatively higher enargite content which are processed using bulk flotation of the gold and copper minerals followed by vat leaching of the resultant tailings."

Jan 1, 2003

By Philippe De Donato, Odile Barres, Mukendi Kongolo, Stoyan Gaydardzhiev, David Bastin, Jean-Marie Kanda

The adsorption patterns of potassium amylxanthate on the surface of high purity malachite subjected to prior sulfidization with NaSH have been followed and elucidated. DRIFTS spectroscopy has been used to trace the associated physicochemical alterations as well as the chemical species present on the mineral surface. Varying the collector concentration from 5.10-4 to 1.10-2 mol/L has led to different degree of surface coverage of the alkyl groups and to formation of organometallic hydrophobic complexes of CuX or CuX - X2 type. The results reveal that the CuX complex formed on the malachite surface without sulfidizing agent is more unstable and prone to dissolution-precipitation phenomena. Based upon the constructed adsorption isotherms and upon the degree of statistical coverage, different zones of mineral-reagent interactions could be distinguished. They correspond respectively to the monolayer, bi-layer and tridimensional condensation domains. In each of the identified zones mono or double layer adsorption patterns of the collector are proposed leading respectively to formation of surface compounds with different degree of hydrophobicity. The results suggest that sulfidisation remains an important prerequisite in view achieving efficient flotation of the malachite from the studied copper ore.

Jan 1, 2014

By Jiang Wenli, Zhang Yimin

In order to enhance the quality of iron concentrate from magnetic separation, reverse-flotation technology is often applied in an iron ore dressing plant.However, this technology has disadvantages in terms of operating cost,energy consumptionand environmental protection(Zhao, Wu& Wang,2005).Developing innovative equipment to process magnetite ore more-effectively is a way to get rid of these disadvantages of reverse flotation and improve the quality of iron concentrate.This paper describes the development of Complex Flashing-Field Magnetic Cleaner,a new kind of equipment based on the principle of combination of separation in magnetic field and separation in gravity field(Hao & Jiang, 2002).This innovative equipment possesses a tailor-made magnetic system and has the characteristics of a magneticfieldwhich can strengthen the formation of magnetic agglomerations and the dispersion of gangue mineralsto improvethe quality of separation.The automatic control system developed specifically for this equipment can further increase the accuracy of separation and stabilize the process.

Jan 1, 2014

By L. J. Li, Q. Zhang, Z. H. Liu, Q. L. Chen

Phosphogypsum (PG) is an industrial waste from the production of phosphate fertilizer. The utilization of PG is restricted by its containing impurities, and the pretreatment is crucial to eliminating these impurities. The purpose of the research is to recycle pretreatment PG as raw material for preparation of a-calcium sulfate hemihydrate (a-HH) by salt solution method. The effect of pretreatment technologies of lime neutralization and washing on dehydration rate, phase composition and morphology evolution of a-HH were investigated by crystal water content analysis, XRD and SEM. Furthermore, the change of pH in the reaction process was also discussed in detail. The results show that the dehydration rate of conversion PG to a-HH increases and the corresponding induction period, crystal growth period and total time decrease with an increase in CaO dosage from 0.2% to 0.6%. In the presence of 0.4% CaO or 0.6% CaO, the a-HH presents a long hexagon-prism-shaped crystal with a purity of 94%, and the end face of a-HH presents polyhedron. The system pH sharply decreases with the reaction time under different CaO dosage, and the pH variation from the initial alkalinity to acidity. The main reason is that as the co-crystallized phosphorus dissolved and released HPO42-, and with the pH decreasing to 4-5, HPO42- transformed into H2PO4-. The dehydration rate of washing PG is lower than that of original PG. Compared with the original PG, a-HH with the larger width and smaller aspect ratio can be achieved from the pretreatment PG subjected to lime neutralization and washing, meanwhile the crystal surface is more smooth.

Jan 1, 2018

By G. Dodbiba, T. Fujita, M. Kawata, S. Yamasaki, K. Mitsuhashi, J. Ponou, Y. Iwazaki, T. Atarashi

"The grade of copper ore and concentrate is recently decreasing and it will continues decrease further in the future. The effective liberation treatment for low grade copper ore and the removal of arsenic from copper concentrate is becoming even more important. In this work, the magnetic separation of copper concentrate by heat treatment and the flotation of low grade copper ore by microwave irradiation was studied. The heat treatment of copper minerals in the air atmosphere, the magnetization of most copper minerals increases and especially the magnetization of chalcopyrite shows the largest magnetization, after being heated at 500 oC. The wet HGMS of copper concentrate has been studied and the results have then been compared with the ones when calcined concentrate was used instead. The microwave treatment before ball milling increased the degree of liberation up to 100%, especially when compared with the case when only ball mill was applied to the as-received ore. The flotation of ground copper ore after microwave irradiation showed that the grade copper minerals such as chalcosite and bornite in froth part is much larger than that of tailing part.INTRODUCTION The copper has been used many kind of technological fields and will be more important for the future technology. The global copper production from mine is predicted as shown in Figure 1 (Northey, S. 2014). The copper production peak will be appeared in 2030 and the demand peaks in 2040. In the future the recycling of stocked copper and copper alloy will be necessary to satisfy the demand (Yoshimura, A. 2018). Changes in the grade of copper in copper concentrate, exported from several countries are shown in Figure 2. The copper grade in copper concentrate after mineral processing is gradually decreases every year and it is less than 30% nowadays. On the other hand, the copper ore grade change and prediction are shown in Figure 3. The grade of copper ore is also decreasing to less than 1% in 2010 (Northey, S. 2014). In the future the copper grade gradually decreases, reaching to less than 0.5% in 2080 and the energy to produce the copper metal will increase. The effective liberation treatment for low grade copper ore and the removal of arsenic from copper minerals become more important, nowadays. The microwave irradiation of copper ore for the liberation, energy etc. has been reported by several researchers (for example, Batchelor, A.R. 2017). The magnetization change of copper ore by heating has been reported to remove the arsenic (Sawada, M 2015). In this report, the magnetic separation of copper concentrate by heat treatment and the flotation of copper concentrate by microwave irradiation are discussed after the characteristics of secondary copper minerals are investigated by these treatments."

Jan 1, 2018