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By Jan Butra

In copper ore mines located in the Pre-Sudeten Monocline the deposit mining using room and pillar systems has been carried out for more than forty years. When implementing mining systems in deep copper ore mines it appeared to be necessary to adapt them to variable geological conditions and natural hazards. In the initial period of exploitation there were mainly caving and rockburst hazards. The adaptation of room and pillar system was connected with a state of knowledge in the scope of identifying, forecasting and controlling rock mass hazards. The new solutions allowed the safe and efficient exploitation of a blanket deposit of variable thickness from about 2 to 15m, seated on progressively increasing depth. They included exploitation in constrained conditions, such as in protective pillars. In the exploitation period, technical and organisational activities aimed at rockburst hazard control were introduced including active methods for controlling rockburst hazard and procedures for conducting mining works in the rockburst hazard conditions. When mining at a depth exceeding 1,200 m, the exploitation method and technique are additionally affected by thermal hazard and by gas and rock breakout hazard. New solutions of the room and pillar system and a longwall system with mechanical mining have been developed for exploitation in the associated hazard conditions. The require application of many innovative solutions in the scope of mining process and ore haulage mechanisation, excavation support and forecasting and control of existing hazards. The main purpose of these solutions is to conduct the safe and economically effective exploitation of the deposit.

Aug 1, 2013

By W. Hunka

PACIFIC PETROLEUMS, Ltd. first discovered commercial quantities of gas in the Peace River area in 1952. Development of gas wells in this area is quite ex-pensive due to low penetration rates. To improve the economics, the potential of the wells in many cases had to be increased. At that time, well stimulation was still in its infancy in Canada and in this area, in particular, no treatment of any consequence had been attempted. Therefore, trial-and-error was the only means available to determine the stimulating technique that would give optimum results. Various fluid treatments were available and these were used wherever the application was warrant-ed. This paper covers acid fracture and explosive treatments as carried out on various gas-bearing horizons.

Jan 1, 1958

By D. F. VanDine

The phases of a typical exploration program for sand and gravel resources include: (1) collection and assessment of existing information; (2) air photo interpretation and remote sensing; (3) ground investigation and mapping; (4) sampling and testing; and (5) data storage, retrieval, analysis and presentation. Depending on the purpose, time frame and funding available for the study, these phases, and the various techniques used within each phase, will vary. Once a sand and gravel deposit has been located, defined in size and quality, and found to be suitable for a given purpose, it can then be classified as a granular resource.

Jan 1, 1984

By A. Elsayed

Lightweight metals such as magnesium show potential in replacing aluminum alloy castings for engine cradles, cylinder heads and transmission cases. Unfortunately, magnesium alloys are susceptible to entrapping oxides and other impurities during casting that hinder strength and ductility. The current study examined various filter sizes and configurations with the aim of improving the mechanical properties of permanent mould cast AZ91E. The unfiltered casting had a yield strength, tensile strength and ductility of 93.3 MPa, 153.3 MPa and 2.2 % respectively and increased to 96.5 MPa, 167.0 MPa and 3.1 % with the use of a fine mesh filter within the well of the mould. The increased strength and ductility was likely due to the filtered castings containing fewer inclusions on their fracture surfaces as compared to the unfiltered castings.

Jan 1, 2011

By Dale Verran, Jared Orynik, Chad Sorba, David Bronkhorst

Denison Mines Corp. (“Denison”) has a 90% interest in the Wheeler River Uranium Project (“Wheeler River”) located along the eastern edge of the Athabasca Basin in northern Saskatchewan between the Key Lake mill and the McArthur River uranium mine. The project is host to the high-grade Phoenix and Gryphon uranium deposits, discovered by Denison in 2008 and 2014 respectively, which include combined Indicated Mineral Resources of 132.1 million pounds U3O8 (1,809,000 tonnes at an average grade of 3.3% U3O8). The Pre-Feasibility Study (“PFS”), completed in accordance with NI 43-101 in September 2018, is highlighted by the selection of the In-Situ Recovery (“ISR”) mining method for the development of the Phoenix deposit, with an estimated average operating cost of $4.33 (US$3.33) per pound U3O8. Phoenix is the highest-grade undeveloped uranium deposit known globally, including Indicated Mineral Resources of 166,000 tonnes at 19.1% U3O8 for 70.2 million pounds U3O8. The paper aims to provide a summary of Wheeler River and an overview of the proposed development of the Phoenix and Gryphon deposits according to the PFS completed for the Project. Further details regarding the PFS, including additional scientific and technical information are described in greater detail in the NI 43-101 Technical Report titled "Pre-Feasibility Study for the Wheeler River Uranium Project, Saskatchewan, Canada" dated October 30, 2018 with an effective date of September 24, 2018. A copy of this report is available on Denison's website and under its profile on SEDAR at www.sedar.com and on EDGAR at www.sec.gov/edgar.shtml.

Jan 1, 2020

By J. S. Stewart

THIS paper was prompted by a persistent demand for what information we have that will throw light on the oil and gas possibilities of the Maritime Provinces. The problems involved were made familiar to the writer during three seasons of field work in New Brunswick and Nova Scotia. The reasons for renewed interest are: (1) In many parts of that region, the surface is underlain by a thick series of unaltered sedimentary rocks. (2) Oil seepages occur, and oil in commercial quantity has been exploited' near Moncton, New Brunswick, for many years. (3) In recent years, a new method of attack has been developed toward the finding of stratigraphic traps. This method is based on a detailed study of the geological history of the region, as revealed in surface outcrops and samples from deep wells. The well samples show the lateral variation of strata, far from any possible surface outcrop of the same beds. Sufficient work has now been done in the Maritime Provinces to reveal the broad features of the geological history and the character and distribution of the various rock formations. Comparatively little deep drilling has been done in this region, but the holes are widely scattered and the samples from them have added much to the information obtained from the numerous outcrops of bed-rock. The following discussion gives a summary of available information that has a bearing on the subject.

Jan 1, 1943

By Walter I. Nelson

THE geology of the Copper Mountain mine has been ably described by Dr. Victor Dolmage in Memoir 171 of the Geological Survey. Reference is invited to that paper for a more extended description of the geology of the ore deposits than will be given here. The important orebodies of the mine occur in fragmencal volcanic rocks, parallel with and adjacent to the gabbro of the Copper Mountain stock. In the mine area, the contact strikes N.45°W. and dips either vertical or steeply co the southwest. For a distance of 500 feet or more from the contact, the fragmental rocks have been intensely metamorphosed both dynamically and hydrothermally. The dynamic effects are reflected in the foliation and fracturing parallel with the contact, which occurs throughout the mine, and the volcanic rocks within this foliated zone are, in places, highly schistose. Superimposed upon thi.s structure is a system of fine, straight, parallel frac-tures that strike nearly normal to the foliation (and contact) and dip between 65° and 75° to the north; it is with this last-described fracture system that the ore minerals are structurally associated. The fractures are mineralized with bornite and, to a considerably less extent, with chalcopyrite and some pyrite. A notable characteristic is the extreme fineness of the fractures; even in high-grade ore they are rarely larger than pencil lines. The tenor of the ore, therefore, varies directly with the fracture spacing. Replacemcnr of the host-rock between two or more fractures, varying in degree from finely disseminated sulphides to masses of nearly solid bornite up to 18 inches wide and 2 to 3 feet long, is not uncommon in the higher-grade portions of the orebodies. Two structural types of orebody are recognized in local nomenclature: the 'contact' orebodies, so-called because they occur along the contact; and 'outlying' orebodics, which are enclosed in the volcanics. The former arc tabular or lenticular bodies elongated along the strike and dip of the contact. The 'outlying' orebodies are coniform, chimney-like masses roughly elliptical in plan; with depth, their roots plunge at steep angles toward the contact. All of the orebodies are cut by a number of light-coloured granophyre and felsite porphyry dykes. These dykes-the so-called 'mine' dykes -enter the mine area from the north, curve gently southeasterly across the orebodies, and then cross the contact into the gabbro at the south end of the mine. All the dykes dip vertical to steeply east.

Jan 1, 1941

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By A. G. Eccles

Western Mines' milling circuit produces three concentrates (copper, lead and zinc), with the tailings being disposed of at the bottom of Buttle Lake. In view of the mine's location and the method of tailing disposal, a comprehensive pollution control program has been in effect since start-up. Changes -in the ore over the past few years have required the use of increasing quantities of sodium cyanide in order to effect a good copper-lead separation. This led to the use of alkaline chlorination for destruction of ?residual cyanide and precipitation of dissolved copper contained in the tailing effluent. The development of Western Mines' alkaline chlorination plant is discussed in detail, including initial test work and the evolution of procedures leading to the present operation. The current monitoring program is also reviewed.

Jan 1, 1977

By H. L. Snyder

This paper outlines the approach to the underground construction work involved in the Churchill Falls Power Project. It is the first in a series of papers which CIM Bulletin plans to publish as the different 11hases of this large-scale operation evolve.

Jan 1, 1968

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By S. E. Jackson, L. J. Cabri

Quantitative determination of gold at sub-ppm concentrations in sulphide minerals is an important component of deportment studies for sulphide-gold deposits. Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) analysis is preferred for this application because it rapidly and cost-effectively provides spatially resolved (<20 pm), low ppb concentration data for gold and other elements in mineral grains. Recent advances in LA-ICP-MS analysis include the development and application of elemental mapping. Raw signals from multiple line scans or lines-of-spots are deconvoluted and calibrated to generate elemental maps which provide detailed information on spatial variations of gold and other elements within and between grains.

Jan 1, 2011

By Georgy A. Cherkashov, Andrey V. Efimov, Yury S. Borodaev, Nadezhda N. Mozgova, Sergey G. Krasnov, Tamara V. Stepanova, Alexander M. Ashadze

"Abstract - A horizontal mineralogical-geochemical ore zonation with a southeast to northwest trending succession of Cu and Fe (Zn) main zones has been discovered in the Logatchev hydrothermal field (14°45??N Mid-Atlantic Ridge). The major minerals are pyrite, chalcopyrite, bornite, isocubanite, digenite and chalcocite. Zn-sulfide, marcasite and covellite are less abundant. Rare minerals are native copper, zincian copper and cobalt pentlandite (first found in oceanic massive sulfides), Cu and Cu-Co-bearing Fe-disulfides. Two groups of the main sulfide assemblages with different copper contents are recognized: Group I comprises assemblages with primary sulfides (isocubanite, chalcopyrite, pyrite and Zn-sulfide; Cu up to 35 wt% in Cu-bearing minerals); Group II contains assemblages with secondary Cu-rich sulfides (bornite, digenite, chalcocite; Cu ~60 wt%) as well as rare minerals (cobalt pentlandite, native copper and zincian copper). The assemblages of Group I formed at a temperature of about 300°C; the sulfur fugacity (log fs2 atm) at 300°C is probably 9.9. Relations between minerals of this group are contradictory, attributed to non-equilibrium environments, and no unified sequence of crystallization of minerals has been determined. Minerals of Group II replace, rim or cross the assemblages of Group I. Group II minerals crystallized in a distinct sequence (cobalt pentlandite-bornite-digenite- chalcocite-native copper), with increasing copper content from the start to the end of the depositional sequence. This may correspond to pH from 7 to 8 near Eh = -0.2 at 250°C. Minerals of this group were generally formed under hypergene alteration processes. Compositions of ore minerals were studied by means of electron microprobe analysis (EMPA) (150 analyses). Narrow composition fields were revealed in all main sulfides, which comprised known experimental data. ZnS contains 6.0 to 28.0 mol.% FeS, which is close to data known for other hydrothermal massive sulfides from the Mid-Atlantic Ridge (MAR). A common admixture in ZnS is Cu (0.16 to 1.32 wt%). Rare grains of unusual anisotropic Fe-disulfides, (Fe0.95Cu0.05)S2 and Cu(Fe,Co)9S20, were found among the ore minerals."

Jan 1, 1999

By W. Griffith

"While oxalic acid precipitation practices are commonly applied on purified rare earth elements (REEs) pregnant leaching solutions (PLS), few efforts have been reported using oxalic acid (OXA) to recover REEs directly from untreated PLS. High oxalic acid demand is the most significant issue in all these direct oxalic precipitation (DOP) practices. Preliminary research on DOP of REE from a dilute PLS originating from an acid bake followed by water leaching was conducted. At 75°C, the oxalic acid demand was between 12 and 18 times the stoichiometric requirement for complete REE precipitation. Conducting DOP at 25°C had superior REE recovery but the product purity and filterability declined. Between 75°C and 100°C, REE recovery increased with increasing temperature. When sodium hydroxide was used to adjust the pH during DOP, in the range of 0.5 to 1.5, higher pH benefited REE recovery. Using ammonium hydroxide in place of sodium hydroxide, the REE recovery was reduced by close to 5%. Sodium chloride addition to the PLS was also investigated and the results showed that at both 75°C and 25°C, the REE recovery was enhanced substantially. At 25°C, when the oxalic acid addition was controlled at 4.7 times the stoichiometric requirement, the overall REE recovery reached 95% with the addition of 240 g/L NaCl. Other reagents such as KCl, NH4Cl also showed significant enhanced REE recovery at the same oxalic acid addition. The addition of sodium sulphate appeared to largely enhance the precipitation of LREE but inhibited the formation of HREE oxalate. All results indicate the formation of rare earth double salts may play an important role in REE DOP sulphate media.INTRODUCTIONThe conventional routes for recovering rare earth elements (REEs) from a sulphuric acid pregnant leaching solution (PLS) involves an initial purification step for removal of iron, aluminium for example by precipitation through neutralization, followed by precipitation of REEs as hydroxide, oxalate or carbonate salts, or by bulk solvent extraction for REE recovery (Xia, 2013). Another route was used by Bayan Obo in their historical flowsheet, where the PLS was first subjected to double sulphate precipitation, then the remaining REEs, mostly heavy rare earth elements (HREE), were recovered by oxalate precipitation (Li, 2011)."

Jan 1, 2016

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By V. Silins, J. Tameling, R. C. Cook

"A general review of the wear problems encountered in the mining industry is presented and current practice for wear protection systems is reviewed.A new concept in wear protection is described and compared to alternative systems. Utilization of conventional stud welding technology and abrasion-resistant wear studs is shown to be a useful supplement or substitution for conventional techniques. Operating life of many consumable components can be increased by up to four fold. The technique is highly portable for on-site field application or can be used in shop environments.Details of the wear protection model and metallurgical properties of the wear component are also reviewed. Laboratory wear test data are reported to supplement field test performance or to screen potential alloy compositions for application in specific environments.A Review of Wear Problems and Wear ProtectionThe emphasis on wear protection has increased in recent years because of the increasing impact of the potential savings in time, materials and energy. A 1974 German study concluded that attention to tribology, the study of friction and wear, could save approximately $3 billion, and a study in the U.S.A. at the same time put the figure at $100 billion of which $20 billion was for materials. A more recent American study put the energy component of the potential savings at $16.2 billion per year. A recent British study estimated the total potential savings in the U.K. as $1 billion per year, with the largest savings coming from lower maintenance and replacement costs ($500 million), lower breakdown costs ($250 million) and increased machinery life ($200 million). These three major contributions are all potentially accessible in the mining industry."

Jan 1, 1982

By R. P. Charbonnier

"To understand the operation of jigs and other separating processes based on differences in gravity, it is desirable to analyse the motion of various particles in given media under specific conditions. A summary of the earlier theories shows that they lead to unsatisfactory or excessively complicated formulae in cases such as coal jigging. By adopting a simplified theory of the motion of particles in a fluid, the size and duration of the initial accelerated motion of a particle falling in hindered settling can be calculated. Based on this mathematical analysis, examples referring to actual coal jigging practice show that it is desirable to prolong and/or repeat, as frequently as possible, the optimum conditions corresponding to an effective acceleration of the particles. The separation is then obtained according to gravity rather than to particle dimensions, as would be the case if the velocity of the particles• were allowed to approach its terminal value. To achieve this gravity separation, it is suggested that the suction phase of the jigging cycle be artificially prolonged and the frequency of pulsations increased as much as possible for washing the coals of smaller sizes."

Jan 1, 1959

By Amir Asadi

Various damage modes that evolve with time in polymer composite laminates, such as transverse cracking, vertical cracking, delamination, and fiber fracture, as well as the interaction among them, influence the time-dependent degradation in modulus (creep) and strength (creep rupture) of polymer composite laminates. This study is focused on modeling the time-dependent evolution of transverse cracking in [90] plies of a multidirectional polymer composite laminate [0m/190n]. This model uses a two-dimensional variational analysis to determine the stress state at any given creep time. The elastic stored energy, determined using this stress state, is compared with a critical energy for fracture to determine the crack evolution with creep time. Model predictions are compared with experimental results to validate the model.

Jan 1, 2010

By A. D. Misener

Introduction Temperature gradients have been determined for numerous locations in the Canadian Shield in connection with mining operations (1, 2, 12, 13, 14, 15). As part of a programme of geophysical studies of this region, some of these gradients were re-determined by the writer at locations where other thermal properties, specific heat, thermal conductivity, radioactivity, etc., were also to be measured. The ultimate object was to determine the heat flow to the surface at these locations. It was felt that the practice of determining heat flow from the temperatures and conductivities obtained in a single vertical bore hole (3, 4, 5, 6, 7, 8, 9) might give results which were appreciably divergent from the average for a considerable area. Particularly, it was thought that temperature gradients, whether obtained in a single vertical hole or from a number of random locations at various depths in a mine, might be subject to local variations and anomalies serious enough to render unsure any discussions based on them. The procedure followed in this investigation was to select a location where mine workings extended to considerable depth over a reasonably wide area. At selected depths below surface, horizontal drill holes extending into regions of undisturbed rock were located and resistance thermometers were inserted into these holes far enough to record the true rock temperature. An attempt was made to obtain a sufficient number of readings at or near any one level to give a representative coverage of the area selected. This ideal could not always be attained, but the large number of readings obtained for each are a does give a reasonably representative picture of the temperature conditions. These readings required much rime and movement of men and equipment underground . They could not have been obtained without the wholehearted co-operation of the management and considerable assistance from the personnel of the mines concerned.

Jan 1, 1949

By A. Bois-Brochu, G. Morin, G. Marin, M. C. Parr, J. Carignan

The presence of an alpha case on titanium parts produced by investment casting is problematic and has to be eliminated. The traditional techniques for the evaluation of its thickness are metallographic measurements and micro-hardness profiles. To obtain a better understanding of how the alpha case is formed with the underlying objective of limiting its depth, the present study proposes to characterize the microstructure and the chemical composition of the alpha case. Electron microprobe analyzer (EMPA) linescans were used to quantify the oxygen and substitutional elements that come from the mould and promote the alpha case formation. The chemical profiles were correlated with metallographic and microhardness measurements. For microstructure, optical microscopy (etched and polarized light analysis) was used. For phase analysis, samples were mechanically polished step by step and analysed using X-ray diffraction and optical microscopy. Furthermore, surface analysis techniques such as XPS and Auger Microscopy were evaluated but results were found to be inconclusive because the formation of the oxide layer was faster than its ablation and the matrix could thus not be analysed. The alpha case was observed on a Ti-6Al-4V step block casting.

Jan 1, 2014