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By Peter A. Hacquebard

"Two continuous coal zones occurring in a 2500f t (762 m) thick section of the Upper Carboniferous Pictou Group (Westphalian C and D) have been encountered in five offshore wells drilled f or oil and gas in the Gulf of St. Lawrence. They correlate, by means of fossil spores, with thick coals of the Mabou and Inverness coalfields situated at the eastern margin of the Basin. Therefore, the presence of a large submarine coalfield of at least 18000 sq mi. (46 620 km'] is indicated. This compares with an estimated size of 14 000 sq mi. (36260 km' ) for the Sydney Coal Basin.Accessibility is provided only by the small onshore parts of the Mabou and Inverness fields, because farther offshore the coals lie too deep to be mined (below 4 OOO f t ([ 219 m)).Two near-shore coal exploration wells indicate that at Mabou Mines the younger Inverness coals occur at a mineable depth to at least 5 km from land. A structure contour map of this area shows a reserve of 125 million tons in two Inverness equivalent seams that are 8.5 ft (2.6 m) and 4.5 ft (f.4 m) thick. The Mabou coals, however, reach too great a depth close to shore to possess mineable resources.A structure contour map of the Inverness submarine area, based on mine data and one off shore seismic profile, indicates inferred mineable resources of 160 million tons, in two seams that are 7ft (2.1 m) and 4.5 ft (f.4 m) thick . A detailed deep seismic survey will be necessary to substantiate the structure and resource estimates"",Maceral and coal quality percentage diagrams of five column samples of these seams (the 7 Foot and 13 Foot Seams of Inverness Equivalents) show a bright banded coal, high in reactive macerals, which will produce a weak coke unsuitable f or metallurgical purposes. A thermal coal with a rank of H. V. ""B"" Bituminous (0.64% Ro) is present, averaging 12000 btu llb (6 660 kcai/kg), 10% ash and 6% sulphur, of which 60 to 80% is derived from pyrite.Microlithotype profiles of the major Mabou and Inverness coals show characteristic successions that can be used f or seam identification and proved valuable f or structural interpretations.The time of faulting in the major fracture zone on the eastern margin of the Gulf of St. Lawrence Basin has been deduced from coal rank variations. It occurred in pos tPermian, probably Early Triassic time."

Jan 1, 1986

By D. R. Spink

An historical background is presented to provide a basis for the lack of normally expected developmental effort over the first 20-25 years of viable zirconium production operations. This is followed by a description of developing technology, which is the result of years of research and piloting effort directed to the development of a more economical method to produce high-grade metallic zirconium. It is predicted that many of the process improvements described will have a significant impact on future zirconium production methods and consequently on future prices and markets.

Jan 1, 1977

By J. W. Bawden, J. Nantel

"The mine operator has two prime objectives when he operates a mine: (l) the mine must be safe, and (2) the mine must operate with the lowest possible costs. The operator constantly faces a dilemma; if he is over cautious with regard to safety, his costs may be very high, and if he is over-zealous in trying to reduce costs, the safety of his operation may be jeopardized.Modern bulk mining methods rely heavily on high productivity non-entry stoping techniques (e.g. open stoping, VCR, etc.). Such techniques have the advantage of removing the operator from the active and sometimes dangerous mining face and ofminimizing costly development. On the other hand, this generally results in a certain loss of flexibility in following irregular ore-waste contacts. If stopes are opened too large and/or are inadequately supported, severe dilution with resulting escalating costs usually results. If initial access drift support is inadequate for latter mine induced stresses high rehabilitation costs may also be incurred.Optimization of stope dimensions should logically occur as part of a general mine rock engineering program, within the over-all mine planning context. The same program should help highlight those areas where drift rehabilitation may be a problem.Whenever successful mining is performed, rock engineering is being applied, either by design or by chance. The cost implications of planned practical rock engineering as an integral part of mine planning and design can be very significant to the ultimate mining ""bottom line"". At Noranda Minerals Inc. allowable stope dimensions are derived using a combination of numerical stress analysis and empirical design techniques. This paper discusses the use of the above techniques and their limitations as tools for rock mechanics based stope dimension optimization. The potential cost implications of such design efforts within the general mine planning context are also addressed."

Jan 1, 1989

By Fathi Habashi, Michel Pagé, Farouk T. Awadalla

"Chrysotile asbestos can be dyed with certain dyestuffs to form stable coloured products whose hemolytic and cytotoxicity are greatly reduced. Examples of these dyes are Thiazol Yellow G (a monazo dye) and Trypan Blue (a diazo dye). Other dye stuffs, for example, basic dyes with triphenyl methane structure, Brilliant Yellow (a diazo dye), and Methylene Blue (a thiazine dye) colour asbestos but do not reduce its toxicity. Similarly alizarin, 8-hydroxyquinoline, and representative members of the phthalein group Bromocresol Purple and Phenolphthalein.IntroductionThere is, at present, a controversy regarding the dangers of asbestos fibres, and attempts are being made to render it less toxic. One of these attempts consisted of treating chrysotile asbestos with gaseous phosphorus oxychloride, POCI], at ambient temperature and in absence of moisture. The product had to be heated at 300°C to 500°C to expel exess entrained reagent to get a material containing 0.5070 to 5% phosphate groups and known as Chrysophosphate (Lalancette and Dunnigan, 1982). This product showed decreased toxicity as measured by its hemolytic effect on red blood cells (fable 1). In another approach, Flowers (1983) showed that when chrysotile asbestos was thoroughly mixed with a solution of ferric ammonium sulphate and the slurry was then filtered and dried, the product showed a marked decrease in cytotoxicity.In the present investigation the problem of toxicity was considered from a different point-of-view. Chrysotile asbestos is a hydrated magnesium silicate that can be represented by the structural model shown in Figure 1 from which it can be seen that magnesium hydroxide groups, Mg(OH)2, form a part of the silicate structure. Certain organic reagents that are known to react with magnesium ion in solution to form chelates were reacted with asbestos to find out whether a chelate was also formed on the fibres, and if so , what will be the hemolytic action and cytotoxicity of the product."

Jan 1, 1991

By D. W. McDonald, N. A. Duke, R. L. Hauser

"Abstract- The NERCO Con Mine is situated in the amphibolite facies aureole of the Western Plutonic Complex overprinting the Yellowknife Greenstone Belt. Metamorphic grade of the upright monoclinal basaltic succession decreases from hornblende-amphibolite facies along the border of the batholith to greenschist facies. Metamorphic isograds, subparalleling the faulted margin of the batholith, transect volcanic stratigraphy and coincide with major gold­ bearing shears.Gold mineralization is confined to north-striking, west-dipping shear zones where hanging­ wall amphibolite facies mineral assemblages retrogress to chlorite-carbonate-sericite-sulfide bearing schists hosting multiple generations of quartz-ankerite veins. The gold-producing portions of the Con and Campbell Shears occur where these structures transect an east trending thermal corridor. The corridor is defined by granitic plugs and a number of related breccia bodies, that can be traced outwards from the batholith across the greenstone belt.Prograde reactions of greenstone during amphibolitization effectively liberate fluids that partition metals. With retrograde reactions at shear zones, gold is precipitated with quartz due to the destabilization of sulfide and arsenic complexes. The coupling of regional prograde metamorphic and restricted retrograde metasomatic overprints suggest mineralization is temporally related to emplacement of the Western Plutonic Complex. Economic gold concentrations within the intrusive corridor indicates enhanced metamorphic overprint of hornfelsed greenstones enveloping satellite intru sives peripheral to the main batholith."

Jan 1, 1993

By G. E. Agar, W. B. Kipkie, R. A. Tenbergen

"This paper describes the successful pilot plant testing of a flowsheet, developed at INCO Ltd.'s J.Roy Gordon Research Laboratory (JRGRL), for improved separation of the constituent minerals in a bulk copper nickel concentrate.The flowsheet utilized the fact that xanthate concentration on the mineral surfaces is the most important variable affecting the high lime separation and that reduction of the xanthate concentration could be effected by an oxidative conditioning stage.When the adsorbed xanthate was reduced to a suitably low level, chalcopyrite and pyrrhotite could be floated to leave a high grade nickel concentrate as the residue. Sodium cyanide was added to the froth product to depress pyrrhotite and any remaining pentlandite. The temporary depression of chalcopyrite by the sodium cyanide was overcome by introducing a conditioning step following cyanide addition. The advantages of the flowsheet; improved copper-nickel separation, operation without heating of the pulp, production of both high grade nickel concentrate ( 29. 5% Ni, . 26% Cu) and copper concentrate ( <O. 5% Ni, 30% Cu) were all realized."

Jan 1, 1984

On the recent trip from Vancouver to Calgary with the President, Mr. C. C. Huston, and yourself, I had the opportunity of outlining a plan based on the following: Among the aims of the Institute are, obviously, the fostering of the confraternity of those engaged in the technical and management fields of the mining and petroleum industries. This may be achieved in a number of ways, of which, to me, the interchange of ideas and experience between different parts of Canada and different sections and divisions of the Institute appears to be one of the most important. I think you and the membership as a whole are, and have been, well aware of this. The annual tour of the President .and Secretary, particularly their visits to Branches, shows this to be true. The interchange of ideas through the medium of the BULLETIN also illustrates the point; indeed, most Institute activities are directed along these lines. I am convinced that much more could be accomplished if it became financially possible to do so. Many able and fine men are, I think, willing and anxious to give their time and energy to furthering these phases of Institute activity, but it is unfair to expect them to assume as well the financial obligations involved. Specifically, I would suggest that the following could be done if sufficient funds were available:

Jan 1, 1952

By Jean-Marc Lulin

"Depuis 1906, pres de 130 gisements ont ere decouverts dans la inture archeenne polymetallique (Cu, Zn, Au, Ag) du nord-ouest becois. Une etude regionale du developpement du potentiel inier est presentee puis detaillee pour quatre secteurs: RouynDranda, Val d'Or-Malartic, Bousquet-Cadillac et Matagami.L' analyse est conduite a l' aide des parametres suivants: temps, ethodes de decouverte, profondeur des gisements et poids metal. ~~ courbes cumulatives illustrant le nombre de gisements decouverts fonction du temps montrent une forme generale en ""S"" dont les i'iations de pentes correspondent aux variations dans les taux de ~ouverte. Initiation, realisation et stabilisation des cycles de decourte sont ainsi mis en evidence. Deux ""bourns miniers"", de 1922 a ~5 et de 1955 a 1965, rassemblent 72 % des mines identijiees squ' a present.La plupart des mines sont trouvees en subsurface: 90% ont leur fmet entre 0 et 100 metres de profondeur dont 70 % entre 0 et 10 etres. Dans le temps, il y ad' abord recolte par prospection puis par fphysique et enjin, developpement progressif du potentiel en proeur avec des methodes composites. Environ 80% du poids metal extrait de 4 camps miniers, couvrant 8% de Ia surface regionale quelques gros gisements dominent /a production.Ces donnees permettent de proposer une nouvelle approche pour lysed' une region miniere:La distribution de Ia profondeur des gisements en fonction du temps est indicatricede /amaturite d' uncampminieret peut servir a evaluer son potentiel residue/.L' analyse des courbes en ""S"" permet d' extrapoler les taux de succes relies aux differentes methodes et met en relief le role crucial de I' innovation dans I' exploration.ABSTRACTSince 1906, some 130 deposits have been discovered in the Archean polymetallic belt of northwestern Quebec. In this paper, the development of the mining potential is analyzed at the regional scale and for the following mining camps: Rouyn-Noranda, Val d'OrMalartic, Bousquet-Cadillac and Matagami.The analysis is based on the following parameters: time, discovery method, depth and weight of metal extracted. Curves showing the cumulative number of deposits discovered as a function of time are ""S"" shaped with slope variations corresponding to changing discovery rates. Initiation, realization and stabilization of discovery cycles are thus well represented. Two ""mining booms"", 1922 to 1945 and 1955 to 1965, account for 72% of the mines identified to date.Most exploitable orebodies have been found near the surface: 90 %have their top between 0 and 100 meters, including 70% between 0 and 10 meters. Early discoveries were made by prospecting, followed by geophysics while the progressive development of the depth potential is being realized by a combination of methods. Approximately 80 %of the metal extracted comes from four mining camps which cover 8% of the area, but most of the production can be allributed to only a few large deposits. Based on these data, a new approach to the analysis of a mining region is proposed:1) The distribution showing deposit depth versus time is indicative of the maturity of a mining camp and can serve to evaluate its remaining potential.2) The ""S"" curve analysis can be used to extrapolate the success rate of a specific exploration method and also stresses the crucial role of innovation in exploration."

Jan 1, 1990

By Jean-Marc Lulin

"Depuis 1906, près de 130 gisements ont été découverts dans la inture archéenne polymétallique (Cu, Zn, Au, Ag) du nord-ouest québécois. Une étude régionale du développement du potentiel inier est présentée puis détaillée pour quatre secteurs: Rouyn-Dranda, Val d'Or-Malartic, Bousquet-Cadillac et Matagami.L' analyse est conduite a l' aide des paramètres suivants: temps, méthodes de découverte, profondeur des gisements et poids métal. Les courbes cumulatives illustrant le nombre de gisements découverts fonction du temps montrent une forme générale en ""S"" dont les i'iations de pentes correspondent aux variations dans les taux de couverte. Initiation, réalisation et stabilisation des cycles de décourté sont ainsi mis en évidence. Deux ""bourns miniers"", de 1922 à 1945 et de 1955 à 1965, rassemblent 72 % des mines identifiées sqú à présent.La plupart des mines sont trouvées en subsurface: 90% ont leur mmet entre 0 et 100 mètres de profondeur dont 70 % entre 0 et 10 êtres. Dans le temps, il y a d' abord récolte par prospection puis par ophysique et enfin, développement progressif du potentiel en proeur avec des méthodes composites. Environ 80% du poids métal extrait de 4 camps miniers, couvrant 8% de Ia surface régionale quelques gros gisements dominent /a production.Ces données permettent de proposer une nouvelle approche pour analyse d' une région minière:La distribution de Ia profondeur des gisements en fonction du temps est indicatrice de la maturité d' un camp minier et peut servir a évaluer son potentiel résiduel.L’analyse des courbes en ""S"" permet d’extrapoler les taux de succès relies aux différentes méthodes et met en relief le rôle crucial de I' innovation dans I' exploration.ABSTRACTSince 1906, some 130 deposits have been discovered in the Archean polymetallic belt of northwestern Quebec. In this paper, the development of the mining potential is analyzed at the regional scale and for the following mining camps: Rouyn-Noranda, Val d'OrMalartic, Bousquet-Cadillac and Matagami.The analysis is based on the following parameters: time, discovery method, depth and weight of metal extracted. Curves showing the cumulative number of deposits discovered as a function of time are ""S"" shaped with slope variations corresponding to changing discovery rates. Initiation, realization and stabilization of discovery cycles are thus well represented. Two ""mining booms"", 1922 to 1945 and 1955 to 1965, account for 72% of the mines identified to date.Most exploitable orebodies have been found near the surface: 90 %have their top between 0 and 100 meters, including 70% between 0 and 10 meters. Early discoveries were made by prospecting, followed by geophysics while the progressive development of the depth potential is being realized by a combination of methods. Approximately 80 %of the metal extracted comes from four mining camps which cover 8% of the area, but most of the production can be allributed to only a few large deposits. Based on these data, a new approach to the analysis of a mining region is proposed:1) The distribution showing deposit depth versus time is indicative of the maturity of a mining camp and can serve to evaluate its remaining potential.2) The ""S"" curve analysis can be used to extrapolate the success rate of a specific exploration method and also stresses the crucial role of innovation in exploration."

Jan 1, 1989

By D. E. G. Maschmeyer

The operation of the pilot plant for the S-C Copper Process during 1976 has provided the basic data for the design of a commercial-scale plant. This paper introduces the commercial aspects of the S-C Copper Process through the presentation of a process flow diagram, a schematic flow diagram and basic design parameters for 75,000 tonnes per year (tpy) copper rod production from chalcopyrite concentrate. Basic operating requirements are outlined and a preliminary estimate of operating and capital costs for a Western Canadian location are summarized. The results have been compared with a modern smelter/electrorefinery to highlight the advantages and disadvantages of these two alternatives and to show why the new S-C Copper Process technology should be of interest to the copper industry.

Jan 1, 1978

By Y. Gordon

ABSTRACT A methodology based on a two-stage approach was developed for process technology selection. The first stage includes evaluation of available technologies, followed by shortlisting the best technologies based on mass and energy balance modelling, financial analysis, and risk analysis. The second stage involves detailed analysis using refined input data, mass and energy balance modelling, and capital and operating cost estimation, as well as a more detailed financial analysis. A case study covering the selection of ironmaking technologies for a company in the Russian Federation is presented to illustrate the critical elements of the methodology and the analysis process.

Jan 1, 2014

By H. J. McQueen

Large-scale industrial production of pipe began with longitudinal hot pressure welding of wrought iron by passage of skelp (narrow strip with beveled edges) through a die or bell that curled it about a longitudinal axis until the edges were forced together. Such small to medium tubes could be reduced by rolling or drawing; with threaded connections, they were excellent for distribution of clean water and of illuminating gas for street, home and industrial lighting. Although steel lacks the fluxing slag for pressure welding it has hot strength similar to iron; hot-pressure bell welding was advantageously transferred to steel in long coiled strip with 50% higher cold strength. For pipe without weld-line defects, hot cupping followed by Pilger mill rolling produced tubing that revolutionized bicycle quality and high-pressure service for boilers and chemical processing. Mannesman hot rotary piercing produced long thick walled tube that permitted reduction or expansion by rolling to provide pipe sections up to 60 cm diameter and 12 m long. During 1910 - 1940, oil and gas pipeline technologies, notably welding evolved markedly as they proliferated in the United States, in response to far-flung petroleum fields, expanding industry consumption and the automobile revolution. In the Second World War combat pipelines were laid rapidly, such as: the Canol line through the Yukon to Alaska, and fuel supply lines across the channel and through liberated France. Perfection of welding techniques for both longitudinal and spiral weld large diameter pipe in combination with controlled-rolling of micro-alloyed steels made possible reliable Arctic pipelines. The development of pipe production and utilization in Canada is recounted. The fabrication techniques and metallurgical controls are explained.

Jan 1, 2005

By A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia?s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By C. H. G. Bushell, G. Brown, C. J. Krauss

1N FLOTATION, copper sulphate is used universally for the activation of sphalerite and marmatite and, to some extent, for the activation of other minerals. The copper activated surface readily adsorbs standard collectors such as the xanthates and dialkyl dithiophosphates whereas untreated zir~ sulphide does not. With the host of reagents available, making a mineral float is seldom difficult. The problem is to achieve selective flotation. In zinc flotation, the great value of copper sulphate results from its ability to activate zinc sulphide preferentially to gangue minerals. At the Sullivan Concentrator of The Consolidated Mining and Smelting Company of Canada Limited, the most abundant gangue mineral in the lead-zinc ore is pyrrhotite, and the zinc mineral is marmatite of somewhat variable zinc to iron ratio. For this Cominco study, selectivity between marmatite and pyrrhotite was therefore the most interesting aspect of copper sulphate activation.

Jan 1, 1961

By S. F. Featherby

"This paper traces briefly the historical development of coal handling systems to meet the needs of a rapidly developing thermal power generation technology. The wide range of operating requirements is demonstrated by comparing and contrasting the Wabamun GS of Calgary Power Ltd. and a typical modern Ontario-Hydro thermal plant. The problems of safe storage of large tonnages of coal in stockpiles are discussed, together with recommendations for stockpile management. The development of coal bunkers and their management is discussed in detail, together with future trends in the industry."

Jan 1, 1966

By C. Stamberg, W. McGuire, R. C. Carlson, L. W. Vollmer

"The selection of materials and pre-cautionary measures for handling natural gas and condensate containing aqueous hydrogen sulphide are presented. Based on the results of a pilot production test and laboratory studies, together with several years . of operating experience, it was found that the behaviour of materials in sour gas environments can be predicted sufficiently accurately for engineering purposes.The selection of proper materials is essential for preventing sulphide-stress cracking. Where high strength materials are not required, low car-bon steel is used. Components requiring high tensile strength and hardness characteristics should be made from K-monel or properly heat-treated carbon-manganese-molybden-um and AISI 4140 steels. Welded connections are a potential source of sulphide-stress cracking. Consequently high quality welding and strict inspection are suggested as the most economical precautionary measures available.A maintenance program based,. where possible, on visual inspection of equipment and/or test spools located at strategic points should be used to follow weight loss and putting corrosion in sour gas environments. If severe weight loss or pitting corrosion is encountered, inhibitors have been found to be an effective deter-rent."

Jan 1, 1960

By Jean-Paul Drolet

"This paper charts, briefly, the :salient facts of international trade in minerals and their products and Canada's place in it. It also reviews inter-national agreements, economic groupings and national measures to channel and regulate production and trade in minerals. Canada's mineral industry now produces raw materials worth $3.7 billion per year, making this country a giant among mineral producers. Two-thirds of this production is exported, chiefly to the United States, accounting for about 30 per cent of Canada's merchandise exports and topping all other classes.However, several other nations are also pressing the development of their mineral resources and markets. The Soviet Bloc, China and principally Australia and Africa are becoming important suppliers of basic raw materials to some traditional markets of Canada in Europe and Japan.The outlook for Canadian mineral exports to the countries of the Common Market, Great Britain and Japan is good, although some tariff barriers remain troublesome.Concerning the United States, our most important market, Canada is seeking to have that country lift import quotas on lead and zinc, and re-cent statements by U.S. authorities give hope that this may be achieved soon. Moreover, Canada wishes to obtain easier access to the American market for several of its metals and minerals.Canada is now participating in the Kennedy Round of tariff talks under the auspices of the General Agreement on Tariffs and Trade (GATT), and is seeking to open wider doors for its exports of products.In summary, Canada has done reasonably well in some mineral commodities on world markets, but has lost ground in others. Any slackening of Canada's efforts in the development and marketing of mineral resources would soon lead to the decline of its role in the world miueral economy."

Jan 1, 1966

By N. R. Thote, J. L. Porathur, C. P. Verma

Highwall mining is a highly mechanized coal mining method associated with several advantages, such as a very high production rate (approximately 3,000 t/d) and low production costs. There is no requirement for underground support, ventilation, or blasting. Production leads to added recovery, which is otherwise lost in the ultimate pit. The use of highwall mining can bridge the gap that exists between supply and demand in the energy sector. This paper presents a brief review of highwall mining technology, including current status, analysis tools, and design techniques. In addition, it identifies important parameters from the analysis of failure case studies.

Jan 1, 2014

By W. A. Lang

"I.-IntroductionAn attempt bas been made in this paper to provide a basis for appraisal of the future of the coal briquetting industry in Alberta by outlining the processes used for briquetting various ranks of coal, by specifying the requirements of a briquetted fuel, by indicating .the status of the industry in the United States, by giving developments in Western Canada, by assessing costs of processing, and by discussing briquetting researches in progress. Much of .the detail bas been omitted since this might mask, rather than reveal, the more important phases of the problem. Reference will be made when possible to published articles where many of the details can be obtained.It should be stated at the outset that, in the writer’s opinion, there are three possible developments in Alberta as regards briquetting: (a) an expansion of the briquetting of the fines of • non-coking and coking coals of semi-anthracite, and of low and medium volatile bituminous rank; (b) the processing of the fines of high-volatile C bituminous coals; and (c) the upgrading of the lower rank high-moisture sub-bituminous coals. Details of the chemical and physical properties of these coals can be obtained in publications of the Research Council of Alberta (1, 2), and of the Fuel Research Station, Bureau of Mines, Ottawa (3).Semi-anthracite and low and medium volatile bituminons coals occur in the mountain areas of Alberta, where, during the upthrust of the Rocky mountains, the coal beds served as the sliding surface. This resulted in the coals being; crushed and consequently they contain a h1gh percentage of fines. In some cases they are high in mineral matter and require to be cleaned before being processed. However, the cleaning of fine coal is both difficult and costly. Both the amount of fines present in the mine-run coal and the amount of mineral matter associated with the coal have increased through the introduction of mechanized mining and through the recovery of coal by stripping operations."

Jan 1, 1950

By G. B. Harris, C. W. White

A study to investigate the recovery of base metals, notably copper, nickel, cobalt, zinc and manganese from iron-free concentrated chloride solutions using ion exchange was undertaken. In such solutions, apart from nickel and, to a lesser extent manganese, these metals are present predominantly as complex anions, and therefore conventional separation techniques based on cationic resins are not applicable. The results demonstrated that zinc, copper and cobalt can all be separately recovered leaving nickel and manganese behind. Specifically, zinc is a major nuisance element in nickel and cobalt processing, and the testwork showed that it can be preferentially removed prior to copper and cobalt. Selective resins for both copper and cobalt were identified, and it was demonstrated that the strength of the chloride background matrix has a significant effect on the efficiency of separation. An additional major advantage in such systems is that stripping can mostly be effected with water. Finally, some observations are made on the hurdles that must be overcome when attempting to introduce and commercialise new technologies.

Jan 1, 2015