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By A. R. Miller, G. Desrivières, M. C. Bétournay, D. L. Barnes, P. Laliberté

"Over the last four years, an international initiative, championed by Vehicle Projects LLC, the Fuelcell Propulsion Institute and Natural Resources Canada, has been active in carrying out research projects to prove out the concept of applying fuel cell technology to underground mining vehicles. These have been carried out by a consortium consisting of mining companies, equipment manufacturers, technology developers, national laboratories and consultants, with the participation of Canadian and U.S. mine regulatory agencies.This clean technology, which produces only water and electricity, would allow several advantages to be obtained, in the health area (by eliminating diesel emissions and reducing noise generation), in lowering production costs (such as reducing ventilation required) and lowering greenhouse gas emissions.This paper outlines the results obtained in several key areas, such as, the operation of fuel cells in underground conditions, risk issues related to underground and surface operation of hydrogen vehicles and hydrogen production and delivery systems, and the design and mining performance of the world’s first hydrogen mining vehicle, a mine production locomotive. The work to date on the fuel cell loader, designing the power plant and power transmission systems, operational requirements, and operating cost reductions is also presented."

Jan 1, 2003

By C. R. Whittemore

IT can be truly stated that no branch of the engineering industry has progressed more rapidly in the last few years than that of welding. In spite of depressed economic conditions, this industry has continued to advance along scientific lines, replacing the old hit-and-miss method of welding. The development work is intensive, and increased activity is recorded in every sphere of the industry, new applications of existing methods, together with new processes, being added to those already proved in practice. The general acceptance of the welding processes can be measured by their utilization as a manufacturing tool in the metal-working industries. Many manufacturers have partially or wholly adopted welding. These concerns have on their staffs welding specialists, design engineers, and metallurgists, who are qualified to design and supervise the manufacture of welded parts, at a considerable saving to the purchaser. The steady, consistent, and sound growth of welding is based upon investigation of the fundamentals of the various processes, together with their proper application. The classification of welding processes varies in different countries. In Europe, they are divided into two main classes, namely, heterogenous and autogenous. In the former, the parts are joined, as a ruler without melting the edges, and by using as filler a metal different from that of the object welded. Such welding differs from soldering and brazing in that higher temperatures are required to effect the union of the parts. In autogenous welding, the parts are joined by melting of the edges, with or without the addition of a material similar to the parts being joined.

Jan 1, 1936

By H. M. Lewis

The current status of the international zinc market is summarized, and a supply /demand outlook is presented for the next five years. A number of technical problems facing the industry are outlined. Introduction ZINC has sometimes been called the unknown metal. Considering that on a world basis it ranks third among non-ferrous metals in production and consumption, zinc retains a certain modesty. It has no distinctive colour like copper, lacks the low density of aluminum or magnesium and is not always easy to identify as a product. The 'spangle' of galvanized steel is probably zinc's most distinguishing feature. The purpose of this article is to develop an over-all review of zinc. Starting with the current position of the metal, the major factors that will shape its future will be described so that an assessment of the outlook for zinc can be made.

Jan 1, 1978

By B. S. A. Tatone

The surface roughness of unfilled rock discontinuities has a major influence on the deformational and hydraulic behaviour of discontinuous rock masses. Although it is widely recognized that surface roughness is comprised of a large-scale (waviness) and small-scale (unevenness) components, most investigations of surface roughness have been restricted to small fracture surfaces (< 1m2). Hence, the influences of the large-scale components of roughness are often neglected. Furthermore, these investigations typically focus on analyzing roughness in terms of two-dimensional profiles rather than the complete three-dimensional geometry, which can lead to potentially biased estimates of roughness. This contribution demonstrates the use of a new optical digital measurement system, based on the principle of triangulation, to digitize a large-scale natural rock discontinuity surface at both outcrop-scale (~6m x 2m) and lab-scale (~100mm x 100mm). Subsequently, the digitized surfaces are systematically analyzed using the three-dimensional roughness methodology proposed by Grasselli to investigate the dependency of roughness on sample window size and measurement resolution.

May 1, 2009

By A. P. Bois, K. Saleh, A. Ghorbal, V. Hajiabdolmajid, G. Ballivy

"The knowledge of the initial stress field is not always sufficient to ensure the stability of mining stopes due to the high-stress variations generated by mining. Monitoring of these openings is then necessary and can provide quantitative information (deformations and stress variations) as well as qualitative information (state of stability).An applied technique for following the variations of stress and deformation in static and dynamic conditions, in relation to the evaluation of the stability of underground openings known as “Cylindre Instrumenté de l’Université de Sherbrooke” (CIUS) is discussed in this paper. In addition, a data acquisition system combined with a rock failure warning system has been developed to be connected to the CIUS for detecting the instabilities, which can endanger the stability of underground openings. Also, the installation of six CIUS and a data acquisition system as well as the selected procedure of programming in a warning system are briefly described."

Jan 1, 2003

By Guy Archambault, Réal Daigneault

"Un trait marquant du cadre tectorwstratigraphique de la Sous-province de l'Abitibi est la présence de nombreux couloirs de déformation d’extension régionale et sub-concordants au grain stratigraphique. La présence de grandes masses granitoïdes qui perturbent l'allure du grain tectonique est typique de la partie nord de la Sous-province de l'Abitibi. Des rides E-W constituées de complexes plutoniques précoces forment des reliefs structuraux agissant comme des moles résistants qui interfèrent avec la déformation régionale.Deux types de couloirs de déformation sont distingués, les couloirs de bordure et les discontinuités structurales. Les couloirs de bordure représentent des auréoles de déformation élevée qui s’accompagnent généralement d’un métamorphisme au faciès amphibolite. lls suivent /'interface entre les roches granitoïdes et les assemblages supracrustaux. Ces couloirs sont de puissance kilométrique et sont confines, surtout au sein des roches vertes, a l’interface des complexes granitoïdes d’importance. La limite entre la Sous-province de l'Opatica et les roches supra crustales de l'Abitibi est caractérisée par un important couloir de bordure issu possiblement d'un chargement tectonique irrégulier et concentre lors du raccourcissement horizontal.Les discontinuités structurales sont des failles ductiles qui se propagent surtout en direction E-W mais avec des variantes de directions SE et NE. Les discontinuités E-W se caractérisent par la présence d'une linéation d'étirement à fort angle de chute. Les discontinuités SE sont caractérisées par des linéations d'étirement horizontales et directionnelles et les mouvements observes sont system attiquement dextres. Les discontinuités NE sont des failles à comportement beaucoup plus fragile et se distinguent par des composantes de mouvement senestre. Elles sont tar dives par rapport aux discontinuités E-W et SE et ne représentent pas la symétrique du système SE.La combinaison des systèmes E-W et SE décrit un motif anastomose a l' échelle régionale. Les failles ductiles se rejoignent defaçon asymptotique, isolant des blocs peu ou pas affectes par la déformation. L'anastomose est un phénomène qui se produit a toute échelle et est reliée principalement aux Mt érogénéités et aux anisotropies 1) des forces agissantes (champs de contraintes régionale et locale) et 2) de la réponse del' empilement supra crustal (compositions différentes, fabrique initiate, propriétés mécaniques variées, niveaux d'altération).Dans le but de respecter un raccourcissement horizontal N-S, différents modelés sont proposés; ils mettent en cause soit une transpression dextre, soit des failles inverses réactivées en failles décrochèrent dextres soit des failles de chevauchement redressées."

Jan 1, 1990

By L. Price, R. Hortie

Movement of ore and waste from the Hilton Mines pit is accomplished by truck haulage. With the aim of reducing costs, a study of truck fleet replacement was initiated. The study included on-site short-term tests and longer-term rental purchase agreements for haulage trucks. The operation and maintenance characteristics of different trucks, along with projected haulage conditions, were used to prepare cash flows, from which the most advantageous trucks were selected. The results of the study and implementation of the recommendations gave a cost saving greater than had been estimated. The study also indicated areas where improvements could be made, and resulted in much more attention being paid to road conditions, the training of operators and mechanics, and the development of a practical preventative maintenance scheme.

Jan 1, 1971

By Karl J. C. Harries

"3.1. INTRODUCTIONThis chapter discusses briefly the common law concepts of fiduciary relationship, constructive trust, and breach of confidence. Following a discussion of confidentiality agreements, the last section of the chapter compares and comments on two common law cases, the LAC Case and the Metalore Case. Civil law readers should not ignore this chapter or § 3.5. the comparison as, to a large extent, the concepts and comments are universal, even though the procedures for applying them may vary.1It should be appreciated that, regardless of the legal system, if the Court sees that a wrong has been done, it will attempt to right that wrong, either by awarding monetary damages against the wrong-doer to compensate the injured party or by attempting to make the injured party whole again by such means as negating an agreement (as in the Metalore Case) or returning property to a wronged party (as in the LAC Case). The methodology for accomplishing either of these results will vary with the jurisdiction, and the two are not mutually exclusive.These two Ontario cases have been chosen, not because they are the only ones available – they certainly are not – but because both are relatively well known within the minerals industry and they deal with problems that may face any explorationist (although it is to be hoped that the facts of the Metalore Case do not represent “normal” behaviour). Each judgment offers useful guidelines, as well as insight into a judge’s approach to problems, the type of information he expects to receive, how his mind works, and, particularly in the Court of Appeal judgment in the Metalore Case, how he might reason through and “justify” his decisions.3.2. SOME LEGAL CONCEPTS In order to appreciate some of the matters discussed in this chapter, it is necessary to have some idea of the common law considerations of fiduciary relationships, constructive trust, and breach of confidence."

Jan 1, 2003

By T. R. Roy

"This paper presents an objective model for the estimation of fire risk potential of an underground coal mine panel by the bord-and-pillar method of mining where extraction is carried out by depillaring with caving. The fire risk rating procedure for the estimation of fire risk potential involved in the panel is described in detail. The model developed thereof is tested with the field data collected from different collieries across the country along with the laboratory data for critical assessment of fitness of the model. Some results showing the validity of the model are also cited here. Introduction The occurrence of fire in underground coal mine panels is quite common in India and elsewhere. These fires cause extensive loss of resources.Although substantial work has already been done by different research organizations, the problem has not been fully eliminated.The causes of panel fires depend not only on the spontaneous heating susceptibility of coal, but also on the extraneous conditions created in the panel due to the mining operations. From the studies done so far by various organizations, it is apparent that two types of parameters associated with spontaneous heating of a coal mine panel exist: intrinsic and extrinsic. Parameters related to the nature of coal, i.e., its physicochemical characteristics, petrographic distribution and mineral make-up are intrinsic, while the extrinsic parameters are related to the atmospheric, geological and mining conditions such as scope of leakage of air into the panel, wetness of mines, heat dissipation capacity of the panel, gassiness of seam, geological disturbances, method of extraction, size of panel, etc.Banerjee (1982) identified twenty-two mine parameters such as spontaneous heating susceptibility of coal, method of mining, geological disturbances, quality of overburden, degree of consolidation of coal mass, scope of accumulation of coal fines, etc. that can influence spontaneous heating in underground mines. He used the terms “high” and “low” for fire risk rating of each of these parameters. Since this approach is oversimplified, it can not determine the exact fire risk potential of an underground working."

Jan 1, 2003

By Robert B. Parsons

"Once all the hullabaloo about Finance Minister Wilson&apos;s April 27 budget died down (or was it an April 26 budget?), the pain of the budget papers began to sink in. Individuals and corporations will have to dig deeper and pay more taxes - and government will continue to dig deeper and spend more. The irony of the situation is that higher tax rates actually make flow-through shares more attractive as a tax-deferral investment - a bittersweet ""bravo"" for the mining industry.INTRODUCTIONFor the first time in Canadian history, a major budget address has taken two days to deliver. Of course, it&apos;s not a case of long-windedness, but rather a case of a hastily called press announcement on April 26 in response to a budget leak, followed by a formal budget speech on April 27.The general reaction of the business community to the budget was to the effect that the tax hikes are acceptable, but the government&apos;s failure to curb spending is less than acceptable. Mr. Wilson&apos;s reported response indicated that the government had never promised to cut spending, and that increased government spending would actually benefit the country. That age-old debate will doubtlessly continue for generations.In any event, three noteworthy components of the budget papers are:• Personal income tax rates increase effective July I, 1989;• A ""large corporations tax"" (in effect &apos;a corporate ""minimum tax"") is effective July I, 1989; and• Federal sales tax increases are effective from June 30, 1989, to be replaced by a national sales tax in 1991.A brief overview of these and other budget proposals follows."

Jan 1, 1989

By D. O. Downing

"The 1990s saw enormous changes in the Canadian coal industry and the future promises to be no less turbulent. While the markets served by Canadian coal producers have changed and buying practices continue to evolve, the coal mining, or supply side, has also changed remarkably in response and now provides the basis for an interesting industry story.The dynamic situation in coal mining has led to some surprising outcomes and seemingly contradictory developments. This paper outlines the changes that have occurred, and which are still unfolding in Canadian coal mining, firstly, in terms of mining technology and productivity, secondly, in terms of corporate divestments, acquisitions and bankruptcies, and finally, in terms of resource development. The paper also outlines some plausible futures for the industry looking ahead."

Jan 1, 2002

By Cedric E. Gregory

"A study of model rectangular mine shafts has been made in the wind tunnel, with the aim of reducing air-flow resistance elements to a practicable minimum. An analysis of Table 7 shows an indicated average decrease in resistance of 28 per cent by adopting the over-all modifications involved in the configurations actually tested. Much greater reductions (up to 68 per cent) are indicated by extrapolating beyond the test results directly achieved. Intermediate partial reductions in aerodynamic resistance are shown for individual modifications, such as: (1) about 3 per cent for locating the lagging in the No. 4 (inside flush) position as against the No. 1 position - 8 per cent as against the No. 2 position - and 23 per cent as compared with position No. 3; (2) about 12 per cent for using lagging instead of steel meshwork along the divider separating the skipway from the service compartment; (3) about 14 per cent for using steel gridwork ladder stagings at 3-set intervals instead of similarly spaced wooden stagings; (4) about 12 per cent for using steel gridwork ladder stagings at 3-set instead of at 1-set intervals; (5) about 13 per cent for fitting a streamlined fairing (see Fig. 5) to the upstream face of the skipway divider. Contrary to expectations, an advantage of only 3 per cent is indicated for lagging in the inside flush (No. 4) position over the outside position (No. 1). This slight gain does not appear to warrant the cost of moving the lagging. However, if the lagging is already in the No. 2 or No. 3 position, there is an 8 and 23 per cent advantage respectively."

Jan 1, 1973

By Steven R. McCutcheon

ABSTRACT - The Bathurst-Newcastle district, a subcircular area approximately 50 km in diameter, contains 37 massive-sulfide Zn-Pb-Cu deposits that have defined tonnages, and has 58 additional significant occurrences. The largest deposit is Brunswick No . 12, with total reserves (including past production) of 148 million tonnes grading about 12.50% combined Pb-Zn. The deposits/ occurrences are spatially associated with a felsic volcanic pile that contains a significant sedimentary component. In the vicinity of the Brunswick deposits the pile is divisible into lower and upper sequences. The lower is characterized by megacrystic rhyolite (QFAS) and coarse- to fine-grained quartz ( ± feldspar) wackes and/or tuffites (QAS); the upper sequence is characterized by aphyric to sparsely porphyritic rhyolites (HWR), micro-breccias, and acid hyaloclastites with interbedded dark gray sedimentary rocks. A greenish gray to dark gray siltstone (GGS) separates the two sequences and hosts the sulfide deposits. Lithogeochemistry of !east altered samples shows that the QFAS and HWR have an igneous character, whereas the QAS and GGS have a sedimentary sig­ nature. The two types can be distinguished on the basis of total alkalies (Na2O + K2O) versus SiO2/Al2O3, and Ti02 versus Fe/(Fe+ Mg). Some trace elements, such as Sr and Y, also help differentiate the two types. The QFAS differs from HWR by having higher La/Yb ratios but lower Zr and Th. The Bathurst deposits do not show a close spatial association with rhyolites but rather are stratiform bodies (lacking clastic textures) within fine-grained sedimentary rocks. The scarcity of barite and other sulfates indicates that there was little mixing between the metal­ bearing fluids and cold seawater. High Fe/(Fe+ Mg) ratios in chlorites also indicate the fluids did not contain a significant seawater component. These features and the large size of many deposits suggest that the deposits formed from metal-rich pore waters that were released catastrophically from an acquifer in the footwall stratigraphy.

Jan 1, 1992

By Meimei Zhang

In the overall open pit mine planning process, mining phase design is a strategic driver in guiding and constructing the block extraction sequence and determining the annual net cash flow distribution. Mining phase design should obey some practical constraints, such as ?minimum mining width? and ?flat mining phase bottom?, to allow space for haul road development and truck and shovel access on each bench. However, these practical mining phase design requirements are not taken into account in all first-cut mining phase design methods and post-processing is always required to convert an impractical design to a practical one, resulting in a potentially significant loss of Net Present Value (NPV) relative to the first-cut impractical designs. In this paper, we present a method using a meta-heuristic algorithm ? Simulated Annealing ? to enforce those practical constraints in determining a mineable phase design whilst ensuring minimum NPV loss.

Oct 1, 2009

By F. Hassani, D. O’Donnell, M. Momayez, P. Guevremont

Shotcrete is a practical and economical support system in many Canadian underground mines. Although shotcrete technology has gained acceptance in the mining industry, there are some problems that have emerged with respect to quality assessment and thickness measurement of the liner. This paper presents recent tests performed with miniature seismic reflection technology (MSR) developed and patented at McGill University primarily for thickness measurement of this heterogeneous liner. MSR is also capable of providing information regarding the quality of shotcrete in terms of its mechanical properties such as modulus of elasticity and Poisson’s ratio. Work was performed on site in an underground mine in Ontario, Canada. This paper also presents the results from laboratory tests performed on fiber-reinforced and non-reinforced shotcrete panels that were used to assess the P-wave velocity in both materials. The results of these tests were used in a second site investigation. The NDT thickness measurements showed good agreement with direct thickness measurement such as coring. In addition, the MSR technology has the advantage of being more accurate and more affordable compared to other non-destructive testing (NDT) systems in the market.

Jan 1, 2002

By John N. Ludden, Maurice Rive, Hillar Pintson

"Quelques soixante-dix-sept plutons présents dans la Sous-Province de Pontiac et dans la partie centrale de la Sous-Province de I’Abitibi ont fait I ’objet d’une reconnaissance systématique. Ils ont été regroupes en huit suites plutoniques majeures et trois suites mineures à partir de critères géologiques et petro logiques. Parmi les suites majeures, quatre représentent I' activité intrusive la plus ancienne dans la région. L’une d' entre e/les est représentée par deux complexes anorthosito-gabbroi' ques lites et les trois autres comprennent les orthogneiss dioritiques a leucotonalitiques et les intrusions dons la composition varie de diurétique et granodioritique à leucotonalitique. Leur mise en place peut être pretectonique a syn ou tarditectonique; certains plutons sont synvolcaniques. Quelques data/ions U! Pb effectuées à propos de ces roches donnent des âges s' étalant entre 2 718 et 2 694 MA. Les données géochimiques indiquent la présence des deux lignées magmatiques, tholemique et calcoalcaline bien qu’il n'y ait aucune évidence de relations entre elles dans I' espace et dans le temps. Ces suites magmatiques différentes peuvent provenir soit d’une croute tholemique impliquée dans un processus de subduction soit directement du manteau.Les trois autres suites majeures comprenant des monzodiorites, des granodiorites et des monzonites ainsi que les deux suites mineures comprenant des syenites correspondent à un évènement intrusif plus jeunesse déroulant entre2 694 et2 680 MA. Ces roches sont syn, tarti a post tectoniques et sont enrichies en alcalins, Ba, Sr et terres rares legeres par rapport aux quatre suites précédentes. Leurs caractères chimiques prop res suggèrent qu' e/les proviennent d' une source différente par rapport à celle precedemment citee.La derniere suite plutonique majeure correspond a un monzogranite leucocrate, riche en pegmatite, également syn a tard tectonique, dont I' age n' est pas connu avec précision. ll représente le seul granite ""vrai"" de la région et dérive d’une anatexie soit des meta sédiments soit des granodiorites-tonalites plus anciennes. La troisième suite plutonique mineure correspond a quatre stocks de granodiorite porphyrique qui n’ont pas été étudiés en détail.ABSTRACTSevenly-sevenplutons have been identified in the east-centra/part of the Abitibi Subprovince and adjacent Pontiac Subprovince. These have been subdivided, on the basis of geological and petrological criteria, into eight major and three minor plutonic suite. Four of the major suite, which represent the oldest intrusive activity in the area, range in composition from dioritic-leucotonalitic orthogneisses to diorite-granodiorite/leucotonalite and include two layered anorthosite- gabbro complexes. Their time of emplacement ranges from pretectonic to syn-late-tectonic and some plutons are synvolcanic. U-Pb zircon ages for these rocks range from 2 718 to 2 694 Ma. Geochemical data indicate the presence of both calc-alkaline and tholeiitic magma series for these rocks although there is no evidence time and space relationships between the two. The different magma series also suggest the derivation of these rocks from two sources, either from subduced tholeiitic crust or directly from the mantle. Three major monzodiorite-granodiorite, monzonite, and two minor syenite suites comprise a younger inlrusive event ranging from 2 694 to 2 680 Ma in age. These rocks are syn-, late- to post-tectonica and, compared to the above four plutonic suites, are enriched in alkalis, Ba, Sr and light Rare Earth Elements.Their distinctive geochemistry suggests that these rocks were derived from a different source region than for the older plutonic suites. The remaining major plutonic suite consists of leucocratic, pegmatite-rich, monzogranite-granodiorite. These rocks are also syn- to late-tectonic but their ages are not known with precision. They are the only ""true"" granites in the area and were derived by the partial melting of either older"

Jan 1, 1990

By Eugene (Gene) Bounds

The Mining industry faces many challenges, one of which is the demand to communicate over a variety of media, be it visual, sound, voice, data or any combination. Over the years multiple infrastructures have been put in place to overcome environmental obstacles and address these communication needs. A mine is an aggressive environment for electronic equipment and as such only the best quality equipment can perform under those special conditions of e.g. temperature, dust and humidity. Siemens Canada and its partner LComm will discuss a mining solution using a unique combination of technologies based on fibre optics, standard communication interfaces, passive antenna infrastructure and wireless services. The presentation looks at maximizing the use of infrastructure, reducing costs, addressing difficulty of communications coverage above and below the surface and the capability to future proof the capital investment as new requirements and applications are identified. Discussion will address: Wireless voice, high speed data Data acquisition for process control from sensors Video for remote control and security Miner safety and location Timely receipt of large volumes of information

Apr 1, 2005

By Ludwig M. Strah

"Wear is a universal problem and is present in all cases wherein one weighted surface moves with or relative to another surface. A practical description of wear as applied to mineral processing plants is outlined.With the advent of higher material and maintenance costs, more attention is being focused on the field of wear resistant linings. The aforementioned is magnified today as the production facilities continue to be designed to handle larger daily capacities. These changes, higher costs and larger plant handling facilities have necessitated the introduction of different materials and designs to combat the never ending battle against wear.In order that wear be understood, it can be relegated to two specific types:1 - Mechanical Wear - due to movement of one loaded surface relative to another.2 - Chemical Wear - more easily defined as corrosionMechanical wearMechanical wear can be subdivided into two basic forms:A.,Material movementB.,Material impactMaterial movement Abrasion is the result of, as earlier stated, the straight move¬ment of one loaded material relative to another.Material impact Is the striking effect when a mass strikes another from various angles and at various speeds. Impact can be severe enough to permanently damage and distort the basic component installed to overcome impact."

Jan 1, 1983

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003

By N. Thompson

The Right Hon. Viscount Long, late Secretary of State for the Colonies, in his inaugural address to the Empire Mining and Metallurgical Congress in London last June said: "I am more and more? convinced by every day experience that the development and strengthening of the Empire must depend upon individual effort and action, and that it is useless to look to Governments for assistance." I am inclined to agree with Viscount Long, to this extent, that the initiative must come from individual effort, but Government assistance is necessary to put the results of that effort and action into effect. It is perhaps fitting at a gathering of this kind to remind ourselves of the part the mining industry has played, not only in the development of the British Empire but in the world at large, in the promotion of modern civilization. We do know that all human progress has been coincident with the early discoveries in the recovery and treatment of metals and, as the centuries have passed, the human race has become more and more dependent on these sciences as factors of all progress, and no nation has ever become powerful and prosperous that has lacked adequate mineral supplies, or having these, has allowed them to be exploited by other nations.

Jan 1, 1925