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By W. McCombe, G. Remple, L. Nightingale-Mercer

The McClean Lake Mill is located approximately 850 kilometres north of Saskatoon, Saskatchewan, Canada, and is operated by Orano Canada Inc. (Orano). The mill was designed to process high grade uranium ores, and a multi-year expansion was completed in 2014 to increase its production capacity to 24 Mlbs U3O8 per annum. The mill also underwent various upgrades to allow it to safely transition from processing low grade ores to high grade ores from the nearby Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones of the deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk posed by hydrogen gas. During 2013 Orano and its consultant Hatch designed and engineered several novel upgrades to the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit could be safely operated with ores that evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project, and also provides an update on the operational reality of hydrogen in the circuit gained through five years of operational experience with hydrogen evolving ores.

Jan 1, 2020

By Harold S. King

TWO summers ago I had the privilege of visiting No. 18 colliery at Glace Bay. Underground, we travelled along the haulage-way behind a powerful electric locomotive. The motor in this locomotive began to smoke badly and a carbon tetrachloride type of extinguisher was used several times during the trip. At the time, I noted a strong odour of phosgene. On my return to Sydney, I spoke to Mr. Harold Gordon, Assistant to the General Manager of the Dominion Steel and Coal Corporation, and warned him of the danger of using this type of fire extinguisher in confined spaces, since it is a well known chemical fact that phosgene, a dangerously toxic gas, is formed by the decomposition of carbon tetrachloride. This danger does not seem to be widely recognized, so it seems advisable that a more general warning be published. Attention was first drawn to the danger by the death of two men in the United States Navy Department subsequent to breathing fumes from carbon tetrachloride used in a fire, and when an employee of the Bureau of Mines also was overcome while fighting a fire with carbon tetrachloride liquid. These accidents led to an investigation of the decomposition products of carbon tetrachloride by a group of workers in the Research Laboratory of the Pittsburgh Experimental Station, U.S. Bureau of Mines, the results of which were published in the October, 1920, number of the Journal of the .Franklin Institute (1). Their experiments were conducted by two methods. The first consisted in applying the liquids to actual fires and -to hot metal in a closed room of 1,000 feet capacity, where the gaseous products, mixed with air, could be retained and analyzed. The second method was to pass the vapour:s in air through heated tubes of iron or quartz, where the humidity of the air and the temperature could be controlled.

Jan 1, 1939

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016

By N. Gharib, F. Hassani, P. Nekoovaght

"Novel rock breakage techniques are becoming more viable and attractive to industry. Microwave energy, as a thermal energy capable of inducing micro cracks through differential heating (therefore expansion) is a technology gaining considerable attention in mineral processing and ore comminution applications. Recently, the use of microwave radiation has been evaluated as a possible avenue for terrestrial and extra-terrestrial drilling applications as well as full face tunneling or rock breaking machines. As part of an overall research on use of microwave in rock breaking systems, the influence of microwave energy on the mechanical properties of common hard rock types as basalt has been investigated. The results revealed that microwave energy irradiation imposes micro and macro cracks to the surface of the rock being irradiated. In explosive free tunneling applications using TBM, jointed and cracked surface of rock eases the cutting process and increases penetration rate. The experimental setups have been simulated with the help of a multi-physics numerical modeling and the results have been compared with practical experiment. The wave propagation of microwave has been simulated and the distances where the power intensity is higher are identified. Experimental and simulation results underlined the potential impact of the use of microwave energy in underground or surface excavation applications such as mining and tunneling. This will also contribute economically when mine-to-mill operation is fully considered to improve the efficiency of rock crusher stages. INTRODUCTIONDuring hard rock breakage (i.e., separation of a piece of a rock from its parent deposit) in mining and civil applications, the performance of mechanical equipment such as tunnel boring machines (TBMs) is limited by high levels of bit wear and maintenance. Preweakening natural rock prior to breaking it by machine is one approach to lower bit wear and maintenance costs. Some preweakening methods apply heat directly or indirectly. For example, flame torch-assisted TBMs (Lauriello et al., 1974; Resource Technology, 1984) have been deemed economical in terms of equipment, but their feasibility is limited by high fuel consumption. Microwave energy could offer several advantages over the flame torch method: it does not produce emissions or increase fuel consumption (electricity source is available on the machine), and is easy to control (quick power on and off)."

Jan 1, 2015

By Wang Wenqian, George W. Poling

"Devices and flowsheets for recovering fine placer gold are reviewed. Inefficiencies of gravity processing techniques are documented and discussed. Prospects of combining gravity and froth flotation techniques are presented. Possibilities of using other separation techniques, such as magnetic and electrostatic devices are also discussed.IntroductionSeveral new methods for beneficiating different types of placer ores have been developed in the last two decades. Improved efficiencies in the recovery of fine particles have been achieved by improving gravity flowsheets and machines as well as by developing multiple treatment techniques involving flotation, magnetic and electrostatic separations. Placer gold processing, however, has been an exception to some extent. Gravity concentration using riffled sluices accompanied by mercury amalgamation is still the main method in use today. Because of this, the recoveries of fine gold and the other associated values are often similar to those achieved several decades ago. For example, very few sluice systems recover significant placer gold finer than 100µm in size.Only a few proposals for using alternatives to simple gravity methods for recovering fine placer gold can be found in the published literature. The fixed, low gold price discouraged research in this field for many years. Development of more efficient processes has not kept pace with the recent rapid escalation in the price of gold. Froth flotation for saving fine placer gold might now prove economic, for example. This paper reviews literature published on the recovery of fine placer gold over the period 1907 to 1980. Suggestions for improving the performance in this field, based on the authors' current testwork, are also presented."

Jan 1, 1983

By Lloyd F. Dunham

"Crucial to the implementation of new computer-based information systems at Sudbury Operations of Falconbridge Limited was a data communications network that would take computing power to the various mine and plant sites. Falconbridge required a capability to provide on-line data entry, inquiry, and reporting capabilities in three geographical areas, six mines, two mills, a smelter, approximately fifty shops, seven warehouses and numerous administrative offices throughout the Sudbury basin.Conventional cabling methods were rejected based on the projected cost of installation of necessary cables; lack of flexibility to meet the changing requirements of the mine environment; and the risk of losing service to an entire area depending on solitary communication lines.Instead, Falconbridge selected and installed a Data Carrier System (DCS) and Packet Switching Communication System from Teltone Limited, Markham, Ontario. This combined system ""piggy-backs"" computer data over voice-grade twisted pair wire, bringing data to the associated PBX equipment. From there data packets are assembled and routed to the central computer site where they are disassembled for entry into the host machine.Falconbridge has been successful in using existing technology to solve communications problems in a difficult environment. Plans for the future of this network will increase its utilization for technical and real time data communications in addition to the business systems workload it now handles. The Computer Services group in Sudbury is confident that the data highway will handle communications traffic well into the future.IntroductionIn late 1984, the Sudbury Operations of Falconbridge Limited undertook a review of their existing business computer systems. The results of this review indicated that there was an opportunity to improve the timeliness and quality of information coming from the existing computer-based systems while achieving an investment payback by undertaking the project. The greatest benefits from this project would be achieved if the computing tools could be delivered to the employees that were the day-to-day users of the data. Falconbridge's existing business systems were oriented to the batch mode of processing. An alternative solution to using the existing programs had to be found."

Jan 1, 1988

By A. Lawson

"Continued and expanded use of underground diesel-powered equipment is considered desirable in order to achieve necessary production capability, particularly when coal becomes increasingly in demand as an energy source. Although diesel engines are derated for underground use, concern has been expressed in many quarters regarding the health effects of worker exposure to diesel-generated particulate and NOx emissions. This concern will increase as Canadian diesel fuel quality becomes heavier and with higher sulphur content. This could result in a requirement to increase ventilation rates by 50%.This paper describes the results of studies of various approaches designed to reduce diesel emissions. Two major approaches have been followed: fuel modification, and emission control hardware development. The results of progress in the development of these approaches will be described.Fuel modification includes the application of water/diesel and methanol/diesel fuel emulsions to the engine. Details of the techniques employed in this approach will be described, together with the effects on diesel emissions. (The paper is concerned with the emission aspects only, not the possible major engine modifications and/ or substitute materials of construction for 100070 methanol.) Use of methanol has the added advantage of acting as a diesel fuel substitute and extender, and there are expectations that underground diesel engines could eventually operate on close to 100% methanol fuel, thereby eliminating particulate emissions. The results of emission control hardware development will also be presented and will include the effects of catalysts, water scrubbers, exhaust filters and exhaust gas recirculation techniques on emissions. A combined systems approach employing a number of these components appears to be the most viable method of controlling the complete array of diesel emissions.This work should culminate in a better understanding of the costs involved in employing fuel modification or emission control hardware relative to the costs of increased ventilation which mpy be necessary to maintain a safe working environment for the underground worker."

Jan 1, 1981

By Paul Guliov

Industrial clays, including a variety of bentonites and kaolinbased clays in southern Saskatchewan are hosted by Late Cretaceous and Early Tertiary sediments. Ofparticular significance are the deposits of swelling bentonite in the Cretaceous Bearpaw Formation and the kaolinitic clays of the Cretaceous Whitemud and Paleocene Ravenscrag Formations. Swelling bentonite is currently produced in the Wilcox-Truax area by Canadian Clay Products Inc. and yields at least seven different commercial products for a variety of applications. Kaolinitic plastic clays, including ball clay, stoneware and earthenware clay, as well as kaolin in southern Saskatchewan, have a long history of development and use. Products include common and face brick, refractory bricks and other shapes, chinaware, pottery, sewer pipe, chimney flue linings and tiles. Currently clay production is for out-of-province brick manufacturing and for pottery. Recent research and improved technology combined with expansion in certain areas of the global clay industry generally hold promise for a resurgence of a clay-based industry in Saskatchewan. Products of particular promise include: clay tiles; kaolin fillers and extenders; and aluminum as well as related by-products from kaolinitic clays based on the carbochlorination process.

Jan 1, 2001

By E. Uzun

"In this study, H2SO4 and HCl leaching behaviour of an ore sample containing 1.87% of Ni, obtained from the Karaçam (Eskisehir-Turkey) lateritic deposit that started operation recently was investigated. Acid concentration, temperature and reaction time were investigated as variables by comparative leaching tests and the optimum leaching conditions were selected on teh basis of Ni, Fe, Co and Mg behaviour. For H2SO4 leaching, optimum leach parameters were 95°C, a 12 normal H2SO4 concentration and 90 minutes of reaction time, and under these conditions Ni and Fe dissolutions were 97.6% and 95.4% respectively. On the other hand, 70°C, an 8 normal HCl concentration and a reaction time of 90 minutes were found to be the optimum parameters for HCl leaching, and Ni and Fe dissolutions found were 97.1% and 97.8%, respectively.INTRODUCTION Today, nickel and various nickel compounds are obtained from sulphide and lateritic nickel ores (Moskalyk & Alfantazi, 2002). Even though about 72% of the world's nickel reserves constitute lateritic ores, only about 42% of nickel is produced from these ores. The decrease in production from sulphide deposits, on the other hand, and increases in the use of nickel in the iron and steel, and battery production sectors, and especially the production of nickel cast irons in recent years, have accelerated the importance of making use of lateritic deposits (Luo et. al., 2010; Chang et. al., 2010). In the beneficiation of sulphide nickel ores, mostly pyrometallurgical methods are used. On the other hand, about 39% of lateritic ores are beneficiated by pyrometallurgical, and 61% are beneficiated by hydrometallurgical methods (USGS, 2009). In laterite beneficiation, the ore properties are of significance; that is to say, limonitic ores are eneficiated by high pressure acid leaching or via the Caron process, nontronitic ores are beneficiated by high pressure acid leaching or heat treatment (smelting), and ores containing serpentine by pyrometallurgical methods (Berezowsky, 2004; McDonald & Whittington, 2008a; Dreisinger et. al., 2015)."

Jan 1, 2017

By John B. Hodgeson

AMMONIA is an essential constituent in the production of the ammonium-sulphate and ammonium-phosohate soil fertilizers manufactured by the Consolidated Mining and Smelting Company of Canada, Limited. The fertilizer plant, built in 1930 at Warfield, near Trail, provides a means of utilizing the large amount of sulphuric acid produced from the sulphur dioxide which is removed from the smelter smoke. The plant has an avail-able source of cheap power which makes the production of fertilizer economically possible. The fundamental operations involved in the production of ammonia at the Warfield plant are, first, the manufacture of hydrogen by the electrolytic dissociation of water; next, the recovery of nitrogen by the fractional distillation of liquid air; and finally, the combination of hydrogen and nitrogen in proper proportions and under suitable conditions to form ammonia.

Jan 1, 1938

By J. W. Craig

CHROME ore, which is used in Canada in the production of ferro-alloys, in a variety of refractories, and indirectly in many chemical industries, is both commercially important and scientifically interesting. The sight of chromium metal is familiar to all of us in the home, the office, the automobile. Chromium is synonymous with armaments: it is understood to be one of several essential metals in tanks, which played an important role in the defeat of France in the spring of 1940. Chromium, in other forms, comes into our daily lives by way of paint and leather, of the familiar green ginger-ale and beer bottles, and more indirectly in every pound of steel produced in the .Dominion. Necessary to our civilization in peace and war, the ores of chromium occur in many corners of the earth. This paper attempts to describe the chemical constitution of chrome ores, their world distribution, and the various chrome products and their industrial applications in Canada.

Jan 1, 1940

By G. C. Nowlan, A. Illis, H. J. Koehler

At its iron ore recovery plant at Copper Cliff, INCO produces about 17 million pounds per year of a pure, acid-soluble, dense nickel oxide from nickeliferous pyrrhotite. The process used is also applicable to a broad range of ammoniacal nickel-bearing streams. The product has been widely accepted by the chemical, ceramic and electronic industries.

Jan 1, 1970

By J. F. Henderson

THIS paper relates to an area of more than 5,000 square miles in the Northwest Territories extending north from Great Slave lake and including-the Yellowknife, Beaulieu River and Gordon lake areas. Within the last three years much interest in the area has been created by the discovery of remarkably rich gold-bearing veins and the realization that thousands of square miles of unprospected ground are underlain by rocks like those in which the veins have been found. Probably there were more prospectors in this area in 1938 than in any other part of Canada. The area lies 650 miles north of Edmonton, and 425 miles north of the terminus of the Northern Alberta railway at Waterways, Alberta. The Athabaska and Slave rivers provide an excellent water route from Waterways to Great Slave lake for large oil and wood burning boats and barges which operate from the latter part of May to October. The only portage is around a 16-mile stretch of rapids on the Slave river between Fort Fitzgerald and Fort Smith. The town of Yellowknife, on the north side of Great Slave lake, has sprung into existence during the past year and is the centre for distribution of supplies for the Yellowknife-Beaulieu region. The Con-Rycon and Negus gold mines, which came into production in September, 1938, and February, 1939, respectively, lie about two miles south of the townsite. Excellent airplane service is available from Edmonton to Yellowknife and from Yellowknife to all parts of the area. The prospector and mining operator have come to rely almost entirely on the airplane for supplies and for the transportation of personnel, camp equipment, and canoes from Yellowknife to localities selected for intensive prospecting.

Jan 1, 1939

By L. K. Smith, C. R. May, K. R. Schrag, H. Buchwald

"New contracts for 65 million long tons of coking coal valued at over $900 million, over the next 15 years, herald the rebirth of Alberta's coal industry. The industry is optimistic that export orders may reach 20 million tons per annum by the mid-1970's. Coal will be extracted from underground and surface mines and it is expected that the total labour force will double from the present 1,200 men within the next two years. Ali the health hazards associated with coal mining are likely to be encountered and it will be incombent on the Provincial Department of Health to specify the standards which relate to health and environment where no such standards have previously existed. This paper examines some of the problems which are being encountered in setting up an environmental health program and reviews the practicability of environmental monitoring methods, with special reference to respirable dust."

Jan 1, 1969

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017

By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By Mike Johnson, Greg Andrews, Niels Verbaan, David Dreisinger

"The Search Minerals Foxtrot project in Labrador represents a significant Canadian resource of rare earth elements rich in the sought after heavy rare earth elements (19.8% HREE/TREE). A preliminary economic assessment of the project indicated that the project is technically feasible and economically attractive. A variety of metallurgical test programs have been undertaken which have led to significant streamlining and simplification of the process flowsheet. The improved flowsheet should allow Search to reach production earlier and will use conventional processing equipment. The results of these test programs are presented and discussed in this paper INTRODUCTIONSearch Minerals Inc. (Search) is exploring and developing a number of deposits for rare earth element (REE) recovery in Labrador, Canada. The Port Hope Simpson District is in the southeast of Labrador and is highly prospective for heavy and light rare earth elements. The Foxtrot deposit sits within the Port Hope Simpson REE District (Figure 1), which is 70 km long by up to 10 km wide. The infrastructure available at Foxtrot is excellent; a deep-water port, air strip, and road and power infrastructure are pre-existing at St. Lewis. The three communities of Port Hope Simpson, St. Lewis and Mary’s Harbour are in close proximity to the site."

Jan 1, 2016

By W. L. Brown

"The Normetal mine is about 7 miles east of the Ontario-Quebec boundary, and 13 miles north of the town of Dupuy on the Canadian National railway. The mine workings are largely on lots 44 and 45 in the south half of range 10, Desmeloizes township.The surface outcrop is reported to have been discovered by a trapper previous to 1925, but the details are obscure. The property was originally owned by the Canadian Exploration Company of Amos, Quebec, and was later transferred to Abana Mines, Limited. The latter Company carried out underground work from two shafts down to the 550-foot level. The property was acquired by Normetal Mining Corporation in 1931 and was reopened in 1933, when development work was carried down to the 800-foot level. The mine was closed down in 1935 because metal prices did not justify production at that time. It was reopened early in 1937 and milling commenced in September of that year. To the end of 1945, a total of 1,497,- 169 tons of ore was milled from which was produced 184,533 tons of copper concentrates containing 84,738,368 lb. copper, 2,744,100 oz. silver, 26,230 oz. gold, and 153,524 tons of zinc concentrates containing 163,752,433 lb . zinc."

Jan 1, 1954

By E. LaRocque

Denison Mines Limited has been processing uranium ore in the Elliot Lake area for the past 20 years. As the original concept of uranium processing has been modified somewhat over this period, the present paper will describe the current recovery practices at the Denison mill from crushing through concentrate drying and packing . Special emphasis will be placed on the leaching, ion exchange and precipitation sections of the process, with consideration being given to the entire circuit. Descriptions will be given of equipment now being used and control strategies will be discussed.

Jan 1, 1979

By A. J. Naldrett

"Sulphurization of peridotite, that is 'to say reaction between sulphur from an external source and iron and nickel in the silicate minerals of the peridotite or in partially consolidated magma, is believed to be the me-chanism by which the small iron-nickel sulphide deposits associated with the ultrabasic rocks of the Porcupine district have formed.The pyrrhotite-pentlandite ore at the Alexo mine, Dundonald township, is localized by a shear that closely follows the lower contact of a peridotite lens. In the past, to account for this orebody, the magmatic segregation hypothesis has been advanced on the basis of textural evidence and the presence of the sulphides at the base of the lens. The nickel sulphide de-posits of the Porcupine, however, are not characteristically found along the basal contacts of bodies of peridotite. Furthermore, this study has shown that textures formerly thought indicative of magmatic segregation have been formed in certain deposits by the selective replacement of silicates by sulphides.At the Alexo mine, very minor amounts of pentlandite and heazle-woodite (Ni3S2) occur in the peridot-ite hanging wall adjacent to the ore. These sulphides are interpreted as having formed by sulphurization, the sulphur involved coming from the pyrrhotite-pentla.ndite ore emplaced along the shear. This reaction aureole raises the question of the role of sulphurization in the formation of the main mass of the sulphide ore. The very localized equilibrium that has been found to exist between sulphides and silicates in deposits throughout the area, the results of nineteen sulphur isotope determinations, and the abundance of pyrite and pyrrhotite in the volcanic country rocks of the Porcupine indicate that these deposits were formed by sulphurization rather than magmatic segregation."

Jan 1, 1966