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The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008

By Muir D. M

Highly saline process water has a number of implications for the CIP process during the leaching, adsorption and recovery of gold. The reduced oxygen solubility in saline water can seriously reduce the rate of gold leaching, while dissolved oxygen meters do not necessarily reveal actual oxygen concentrations in saline water. High levels of magnesium in the ground water necessitate operation at lower pH (-9), with the potential for greater cyanide loss via HCN stripping. In addition increasing salinity renders viscosity modifiers largely ineffective.The adsorption capacity of aurocyanide onto activated carbon is improved with increasing salinity, but misleading results can be obtained in assessment of gold loading kinetics of plant carbon samples already loaded, or partially loaded, in saline water if subsequently tested in fresh water. Elevated chloride levels in the Zadra elution process can cause severe anode corrosion in the elecuowinning cell. The Anglo elution process is tolerant to only slight increases in water salinity, but elution times can be reduced by ethanol addition. Care is required in carbon regeneration, as salts can catalyse carbon decomposition as well as increase kiln corrosion.

Jan 1, 1994

Hilton Mine is located 20 km north of the city of Mount Isa and Isa Mine in far north west Queensland. The sealed road used by the 500 employees to commute from the city is part of the Barkly Highway linking Mt Isa to the Northern Territory.Although discovered in 1947, major underground development did not start until late-1982 and first cut-and-fill production in mid-1987. The J53 exploration shaft was sunk in 1970-73 and the main P49 shaft in 1973-75. Since January 1990, most of Hilton ore production has been treated in the Hilton Concentrator, and concentrates trucked in slurry tankers to Isa for smelting or shipping.

Jan 1, 1993

By J Khosa, J Manuel

Iron ore sintering is very complex with many interdependent variables. For the same ores, the sinter quality and sintering performance may vary significantly with the scale at which the sintering tests are conducted. Therefore it is important to understand the effect of test scale on sintering performance and sinter quality while interpreting the test results. In this paper, different scales of iron ore sintering research at CSIRO are described and compared. This is followed by the results of two sinter blends tested at different scales. The results are compared and correlated to demonstrate the benefits of iron ore sintering research at the laboratory (4 g), small (5 - 8 kg) and pilot (55 - 140 kg) scales.

Jan 1, 2007

South Crofty's ventilation network is large and complex. Of the total exhaust air quantity 40% enters the mine by leakage routes through old workings, this air carries high concentrations of radon gas and results in the mine becoming a classified work place under the Ionising Radiation Regulations 1985. Improvements in the control of the ventilating air and dilution by increased air quantity have reduced the average contamination to aelow-0.2 WL. The major part of the radon originates from ground water inflows and from concentrations of radium within the mine with direct emanation from rock surfaces being negligible. Of 600 kBgs-1 total radon leaving the mine 93% cannot be accounted for from known and accessible sources.

Jan 1, 1988

Kalgoorlie Consolidated Gold Mines Pty Ltd (KCGM) is a management company, formed in 1989, to manage the assets and operate the Kalgoorlie joint venture for the owner companies Gold Mines of Kalgoorlie Limited (GMK) and Homestake Gold of Australia Limited (HGAL). Mining is still in progress on the 'Golden Mile' and surrounding areas more than 100 years after Paddy Hannan's discovery adjacent to the active Mt Charlotte mine. From 1893 until 30 June 1995 the Kalgoorlie Goldfields has produced approximately 45 million ounces (-1400 tonnes) of gold from mining and treating about 179 million tonnes of ore. This production equates to about 20 per cent of the total Australian gold production and about one per cent of the world's

Jan 1, 1996

Technical control in an industrY invariably leads to a basic contribution from the science of chemistry. It is interesting to note. that the change from the "Assay Office" to the "Chemical Laboratory" has already taken place on the majority of progressive mining fields.Although the serlvices of an efficient chemical staff are freely availed of by operating departments, it is not generally realized that practical chemistry is definitely expensive. A great deal of misplaced energy and expense can be involved in an enthusiastic research campaign where a full appreciation of laboratory economics and a balanced sense of analytical values are lacking.In order to supply data to the various departments concerning individual costs, it was decided at the North mine to issue a supplementary sheet concerning laboratory activities.The costs are compiled under the Unit System, which is based on a relative comparison between the total cost of the various determinations. carried out and the number of such determinatiQns converted to an equivalent aggregate of units.The introduction of the system necessitates the initial compiling of a table of relative units for the various estimations carried out on the works. Each laboratory will find it necessary to draw up such a table governed by local conditions, and, as will be anticipated, a relative comparison of the cost for any particular estimation will show a variation on a lead field, a copper field, or a steelworks, etc.This is due, of course, to the predominating type of routine work, cost of landing reagents, frequency of assays, etc. The satisfactory preparation of the Unit Table requires a good knowledge of laboratory procedure.

Jan 1, 1940

A survey of derelict and active alluvial tin and sapphire mines in the Emmaville area of northern N.S.W. as the first step in a pro- gramme of similar surveys to be undertaken throughout the State by the State Pollution Control Commission is presented. Thirty nine individual mine sites in the study area were included in the survey and an assessment made of the current level of impact on the environment at each site by assigning values of "magnitude" and "importance" to a number of impacting factors. Results are pre- sented in matrix form and mine sites ranked in order of impact "importance". Examples of alluvial tin, underground tin/arsenic and alluvial sapphire operations are discussed in detail and rehabilitation programmes proposed for implementation.

Jan 1, 1976

By Troman L, Groutsch J. V

The Kwinana Nickel Refinery began operations in 1970 processing sulphide concentrates from Kambalda using the Sherritt Gordon pressure leach and hydrogen reduction process to produce nickel metal as powder and briquette. Over the years a number of changes have seen the refinery capacity increased from the original design capacity of 15 000 tpa nickel on an all concentrate feed to its current design capacity of 42 000 tpa nickel on an all matte feed. This paper outlines the changes in plant equipment and process for the most recent refinery expansion from 35 000 tpa to 42 000 tpa which have been implemented since 1992.

Jan 1, 1996

There are two main areas of application of geology in quarrying: (i) In regional planning for industrial mineral requirements.(ii) In direct quarry management. The regional planning requirement has recently become more evident because of greatly increased land demand conflicts around cities. The direct quarry involvement is a reflection of both the economy and the greatly increased sophistication of the quarry industry. Here, professional planning and development expertise by a geologist is required, to ensure continued supply of raw materials at the best price to the consumer with sufficient profit to the producer. Today, geological insurance safeguards capital investment in plant and assures economical development plans.

Jan 1, 1978

By Wilson GR

Pellets were produced from carefully sized iron ore and silica sand fractions, under controlled moisture conditions, using a sealed balling drum. The strength of these pellets was measured as a function of moisture content and particle size. The results showed that the strength of the pellets could be adequately described by a model which equates the strength of the pellets with the negative pressure developed within the porous mass, provided that the particle size distribution was narrow and the mean particle size relatively large. However this model failed to account for the observed strengths of pellets produced from systems containing even small quantities of ultrafine particles (

Jan 1, 1972

By Mckenzie CK, Scott A

The injection of coal as an auxiliary fuel in ironmaking blast furnaces has been introduced on many furnaces worldwide. This paper examines the present practice of coal injection and discusses future directions for the technology. This has been undertaken through the use of a heat and mass balance model which predicts the replacement rates of coke by coal and the effect of coal injection on blast furnace productivity. The results indicate that future pulverised coal injection could replace substantial quantities of metallurgical coke, but that the energy balance economics of individual steel plants will have a dominating influence on the future of the technology.

Jan 1, 1987

Alcoa of Australia's Western Australian bauxite mining operations in the Darling Ranges, south east of Perth, present major challenges in the control of air blast. The close proximity of rural communities and the face profile make the traditional methods of air blast control difficult. An extensive blast noise monitoring programme has been established. The develop- ment of a computerised blast noise prediction model and the establishment of a radiosonde weather balloon facility have reduced blast induced complaints by a factor of ten. The meteorological factors affecting blast noise transmission are discussed and examples are given of adverse weather condit- ions for the south west region of Western Australia.

Jan 1, 1982

By Haigh C. J

A process has been developed to recover at least 75% of the 2-naphthol contained in cobalt precipitate produced during the removal of cobalt from electrolytic zinc plant solution. The recovered material is in a form suitable for recycling to precipitate further cobalt from solution. The process consists essentially of two steps. The first involves leaching of cobalt precipitate in 400 g/l sodium hydroxide solution at 95¦C in the presence of an additive. The second step involves treating the filtrate from the leaching stage with sodium sulphide to precipitate cobalt as the sulphide thereby re- generating the sodium hydroxide for recycling. The process is only marginally profitable at present 2-naphthol prices, giving a net return of 20% on a capital investment of $1 200 000. A reaction mechanism is proposed which accounts for the 25% loss of the 2-naphthol in the recovery process.

Jan 1, 1977

By S Brochot

In cases where coarse gold is present in a deposit, it is usual to use the screen fire assay (SFA) method to analyse the samples. There is no doubt that this method is more accurate than the standard fire assay (FA) and reduces the risk to have a systematic bias. Nevertheless, the difference between the analytical errors of both methods can be glossed over when the overall sampling error is added to obtain the measurement error. In that case, the advantage of the SFA cannot justify its higher cost.The current paper attempts to address this question in the case of a gold ore deposit with visible coarse gold in various sampling situations (drill core sampling in exploration, blasthole or chip sampling in mining exploitation). The overall measurement error is estimated taking into account the analytical error and all the sampling error components following the Pierre GyÆs theory of sampling.Firstly, only the last sampling stage is considered when the pulverised sample is processed either to obtain one analysis sample for a FA or to be screened and subsampled for a SFA. The calculated measurement error clearly shows the advantage of the SFA specifically in presence of coarse gold. Secondly, the half core sampling is studied to explain the observed discrepancies when controlling the second half core. Finally, the blasthole sampling is treated using in situ heterogeneity models to show that the relative advantage of the SFA is hidden by the large overall sampling error.In conclusion, the choice of the assaying method is discussed at the light of the overall measurement error and in accordance to the analysis objective.CITATION:Brochot, S, 2012. Standard fire assay or screen fire assay? Application of the overall measurement error approach to choose the most appropriate method, in Proceedings Sampling 2012 , pp 135-142 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

Coal losses and dilution are among a coal mine operators everyday problems. These losses and unwelcome additions are generated primar- ily by the stripping operation and secondly by the coal mining opera- tion. Losses in yield due to preparation plant efficiency are a separate issue although they may be related to the coal mining operation. The losses and dilution can be traced to the following operations: (A) Overburden or Interburden Removal (1) Removal of coal edge by blasting operations. (2) Removal of top of seam by drilling/blasting. (3) Removal of top of seam by stripping equipment. (4) Removal of coal edges by stripping equipment. (5) Dilution due to stripping equipment. (B) Coal Mining (for the case where seams are ripped rather than shot) (1) Coal rib losses. (2) Coal rib dilution. (3) Coal left in floor. (4) Coal left in fault areas. (5) Floor material picked up whilst loading. (6) Spoil material picked up. (7) Spoil material from poor surface clean up. (8) Top of coal losses from final clean up. (9) Dilution from ripping too deep, i.e. into floor below seam. (10) Dilution from interseam parting. The losses apply to both the single seam and multi seam oper- ations although they are more pronounced in the multi seam mines than in a single seam mine due to the position of the coal which is lost. For example in the multi seam case the top seam coal edge loss is final. There is little chance of recovery with the subsequent pass even if the extra rehandle is done. However conversely the lower seam is relatively easy to locate as it has nowhere to go being contained by the lowwall bench.

Jan 1, 1988

By M Csar

The Nicolsons Find gold project is located 35 km southwest of Halls Creek in the east Kimberley. It was discovered in the late 1980s by John Nicolson and Stuart Skoglund, when high grade gold mineralisation within outcropping gossanous quartz reefs was found. The area has produced a modest 28 150 ounces of gold over two brief mining periods in 1996 and 2002 - 2003. Indicated and inferred resources as of September 2011 stand at 1 384 000 t at 5.58 g/t Au for 248 500 ounces of gold.The project is situated within the Halls Creek Orogen. Principal host units are metasediments and volcaniclastic sediments of the Koongie Park Formation. Minor mafic units are also recognised. Immediately east of these units, emplacement of the loadstone granite is believed to have provided the structural setting for the later gold mineralising event.Mineralisation is hosted within a broad, brittle-ductile arcuate shear zone about the western contact of the Loadstone granite. In the Nicolsons Find area, the shear zone strikes north-northeast and within the shear zone, gold is hosted in a series of narrow, quartz rich veins up to 200 m in strike length, plunging moderately to the north-northeast. To date, mineralisation has been drilled to a depth of 360 m below the surface. The veins are stepped or en-echelon in nature with low gold values towards the quartz vein limits where compression is inferred and higher grades present in the dilational body of the quartz veins. Gold is fine grained and can be present with or without associated sulfides. Sulfides are generally minor and consist mainly of arsenopyrite with traces of chalcopyrite, pyrite and sphalerite. Where present, sulfides are generally indicative of higher gold values.CITATION:Csar, M, 2012. NicolsonÆs Find gold project, East Kimberley, Western Australia, in Proceedings Narrow Vein Mining 2012 , pp 31-36 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

Shear-flocculation is one of a munber of potential processes for upgrading deposits of finely-grained minerals and, more generally, for separating different types of particles suspended in a fluid.The smaller the particle the more likely it is to follow the fluid streamlines, or be entrained within turbulent eddies, and the less likely it is to deviate from the streamline and attach to bubbles (froth flotation), other particles (selective flocculation) or magnetic poles (wet magnetic separation). As shown in Figure I, a number of ingenious ideas have been proposed to overcome this effect. The suspended particles are assumed to be 1 - 10 µm.Thus, the efficiency of attaching ultrafme particles of the valuable component (solid circles) to air bubbles, as in process A, is poor. The efficiency may be improved by attaching the particles to oil droplets (Ralston, Kart and Newcombe, 1984) to form agglomerates that rise or sink (B), to magnetic particles (C) (Parsonage, 1988) to allow recovery in a magnetic separator (D), to other particles to form aggregates (E) that are then either attached to bubbles (F) or recovered by sedimentation (G) (Warren, 1992), and to pieces of polyethylene (Rubio and Baltar, 1991) that rise or sink (H).In A, C, E, F and H, the forces that are generally used to ensure collisions result in adhesion are hydrophobic forces, hydrodynamic forces and inertial forces (Warren, 1992). These drag particles from the streamlines to allow particle-particle adhesion. In B and E, soluble polymeric molecules have been added to bridge between particles as they approach closely during a collision.The second major consideration is selectivity. Selective adsorption of the hydrophobe or polymer onto the valuable particles is the key. Many subtle effects of surface chemistry are involved in obtaining adequate selectivity. A complication in real systems is that the initial suspension is often naturally coagulated and needs to be dispersed before being selectively flocculated.

Jan 1, 1993

By Paine G

Kidston Gold Mines commenced mining in 1984 and currently mine approximately 10 million tonnes per annum of ore and waste using a conventional truck and shovel open pit method. The overall mine grade is a low 1.82 grams per tonne.The mineralisation is generally uniform within the ore zones and mining boundaries are staked out from blasthole assays according to pre-determined cut-off grades. Buffer blasting is necessary to minimise post-blast lateral movement of in-situ grade for digging control.The characteristics of the rock currently mined vary widely from soft oxidised to hard unweathered rocks. Blasting problems have been experienced during the initial mining phase in these harder rocks.

Jan 1, 1986

Mineral exploration conducted over a wide area of the State during the period 1960 to 1973 has resulted in the discovery of a number of significant deposits. Base metals, particularly copper, have been of prime interest while, more recently, the search for uranium and coal have assumed import- ance. Expenditure of $27.6 million by companies during the period under re- view has located 580,000 tonnes of cop- per, 370,000 tonnes of zinc, 350,000 tonnes of lead, 24 million Kg of uran- ium oxide and 2,500 million tonnes of coal. A variety of other metals and non metallic and industrial minerals have been investigated in a diversity of geological environments.

Jan 1, 1975