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By Harry M. Castrantas, James L. Manganaro, Craig W. Rautiola, James Carmichael

Caro's acid (peroxymonosulfuric acid) was successfully field tested as a cyanide detoxification agent at a North American gold mine. An on-site FMC generator injected Caro's acid into a mill tailings slurry sump. The WAD cN-(weakly acid dissociable plus free cN-) was reduced from 40-108 ppm to below the target level of 20 ppm using a 1/1 mole ratio of CA (Caro's acid) /CN-. At an inlet CA/CN-mole ratio of 1.8/1, WAD CN­concentrations as low as 4 ppm cN-were achieved. Raw material costs for the cyanide detoxification were cut by 60% compared to using hydrogen peroxide (H202) alone. Detoxification time with Caro's acid was much faster compared to H202. This resulted in completion of detoxification before the treated slurry reached the tailings pond thereby substantially reducing the probability of wildlife fatalities.

Jan 1, 1993

By Q. Yuan, B. Yarar

Steric stabilization is a phenomenon observed when relatively high doses of flocculants are added to fine particle suspensions. Experiments were conducted to establish conditions under which medium viscosity and the sedimentation properties of black sand components in a slurry could be controlled so as to enhance the selective sedimentation of gold grains. It was shown that black sand concentrates containing as low as 2.65 g/mt gold could be upgraded by selectively hindering the sedimentation of non-gold components in an aqueous slurry. This paper presents data describing the theory and practical implementation of this cyanide or mercury-free novel approach where gold could be concentrated by as much as 15 times with relatively high recoveries. The relationships of solids content of slurries, type and dose of polymers with the recovery process are documented. Key words: Gold, black sand, selective flocculation, steric stabilization.

Jan 1, 1993

By Zhitong Sui, Feng Zhang, Li Zhang, Tie Ou, Guangqiang Li

Researches on the recovery of iron, manganese and the removal of phosphorus from converter slag were reviewed. The carbon thermal reduction experiments were carried out by induction heating the mixture of converter slag and graphite powders at 1650°C and 1800°C in a graphite crucible. It was found that 62.7% of the phosphorus in converter slag was reduced into carbon saturated iron alloy, 32.8% of that was vaporized and only 4.5% of that remained in the final product. Totally 95.5% of the phosphorus in converter slag was removed. Almost all iron and manganese was reduced to form carbon saturated alloy. It was found that the free lime in converter slag can react with carbon to form calcium carbide at 1800°C. The main phases in the reduced converter slag are dicalcium silicate and tricalcium silicate with small amount of calcium carbide.

Jan 1, 2004

Reno, Nevada. J A Fulton, Director For publications of either the Mackay School of Mines or the State Bureau of Mines, address the School of Mines at the given address. Except where the contrary is indicated in the following list, available publications are sent free From the Mackay School of Mines. Bulletin 1, The identification of Nevada's common minerals, 50 cents; 3, Notes on the ore deposits of Cave Valley mining district, Lincoln County, 4, A preliminary survey of the Scossa mining district, Pershing County, 5, Ore deposits of the Gold Circle mining district, Elko County, 6, Bedded deposits of manganese oxides near Las Vegas, 7, Spruce Mountain district, Elko County, and Cherry Creek (Egan Canyon) district, White Pine County From the State Bureau of Mines: Bulletin 1, Mineral resources of southern Nevada One volume: Mining districts and mineral resources of Nevada, by F C. Lincoln (1923), $1.50.

Jan 1, 1933

By Ronald Thomas

The scope of this paper is to examine the growth of safety in an individual and offer new goals in that development. The paper will examine the individual's natural growth and show how it parallels the individual in a safety environment. An individual's new goals for safety include more than the standard accident-free conditions. The new goal strives for a safer working environment where unsafe acts are eliminated through independent knowledge and an individual's growth of interdependency in safety related areas of concern. It will explain how this goal cannot be reached unless driven from the top down in an organization but empowered from the bottom up. Various reference or support organizations will be covered. These organizations deal with safety in mining and explosive use of manufacturing. Other support organizations exist but since this paper is "Back to Basics" only a few major groups will be covered.

Jan 1, 2001

By Concha F, Sampaio R

In most of the literature, the hydrocyclone is viewed as a black box in which only global variables are present and where the equations are obtained by curve fitting. Recently some work has appeared where the Navier Stokes equations are solved numerically in the hydrocyclone geometry. However, in all of these works the air core surface, which has an important influence on the hydrocyclone dynamical behaviour, is modelled as being a cylindrical surface of fixed radius. In this work, we model the surface of the air core as a free-boundary which has to satisfy a jump condition, the Young-Laplace equation, relating the physics to the geometry. Based on this model, we are able to explain, qualitatively, some phenomena that have puzzled research workers in the field for many years, and can show, through the air core behaviour, the influence of material parameters on the performance of the hydrocyclone.

Jan 1, 1993

By F. L. Grammer

THE analyses given in Table I. were made several years ado at my request at a plant using Lake ores. The, are of two furnaces, one making basic, the other Bessemer pig-they gave 6 casts each in 24 hr., also two flushes of cinder between each cast. They- are offered simply for the sake of reference as, so far as I know, it is unusual to find so frequent fall analyses made and none are on record. The variations iii manganese-content in the first and second flushes on the basic furnace are interesting, if no more than a freak-the first flash being invariably higher in manganese. The iron-content of the two slugs from an. average of 12 flushes shows: Basic. Bessemer. Per Cent. Per Cent. Total iron 2.55 1.70 Combined iron 0.72 0.52 Free iron 2.13 7.15

Jan 3, 1913

By I. M. MacGregor

This paper discusses the possible use of petrological data and proximate analyses in the prediction of cutting forces for coal. It is restricted to the development of univariate predictors based on data from thirteen collieries in five major Transvaal and Orange Free State coalfields and three coal provinces. The aim of the work was the identification and development of the best predictors of mean peak cutting force and Hardgrove grindability index from among the independent variables evaluated. The data, which were obtained by use of the penetrometer developed by the Chamber of Mines Research Organization, were processed according to the SPSS computer package. The analysis revealed reasonable correlations between the Hardgrove grindability index and (1) the volatiles and vitrinite content in the Vereeniging-Sasolburg and South Rand Coalfields, (2) the contents of vitrinite, vitrinite plus exinite, and minerals plus inertinite in the Eastern Transvaal Coalfield.

Jan 1, 1985

By Jim Avraamides

Historically, much of Western Australia's gold production has come from the refractory sulphide-telluride ores located in Kalgoorlie's Golden Mile. Most of the recent gold boom has been associated with low grade, open pit free-milling oxide deposits. Primary sulphides are commonly encountered at depth and in many cases are highly refractory. Different approaches to the problem of recovering go1d from these ores have been adopted subject to local conditions both technical and environmental. The least preferred option is the preparation of a gold- rich flotation concentrate which is shipped to a smelter. Roasting of flotation concentrates can be practised in certain remote locations where sulphur emissions are tolerated. Fine grinding of flotation concentrates followed by direct cyanidation is another popular approach although this often leads to fouling of carbon by flotation reagents in the adsorption section and high soluble gold losses.

Jan 1, 1989

The old De Beers mine, which lies northwest of Dutoitspan mine at Kimberley, was the mine which launched Cecil Rhodes (In his historical career. It was the nucleus of the De Beers Mining Co. Ltd., formed in 1880, which later became De Beers Consolidated Mines Ltd. Inactive for more than a half century, the De Beers Mine is being rejuvenated for a new era of operations. Both mines were on the Vooruitzicht farm owned by the De Beers brothers, who had bought it from the Orange Free State Government ten years previously for £50. Although the brothers sold it soon after the discovery of diamonds at Dutoitspan, they are remembered for having given their name to the foremost diamond mining company in the world. Diamonds worth nearly R180,000,000 have come from this ground, and more will be recovered when the mine is re-opened.

Jan 9, 1963

By D. D. Pollock, G. P. Conard II

Equations of the form of the Mott and Jones equations for the absolute thermoelectric powers of metals are derived primarily from a thermodynamic approach. The behaviors of transition thermoelements in common use are then examined and compared with this simple theory. MOTT and ones' derived a general expression for the absolute thermoelectric behavior of metals and alloys using the approach of the solid state physicist. This expression was then applied to specific cases.1,2 The present work develops equations of the same form principally by a thermodynamic approach. These relationships are then employed to gain some insight to the behavior of the transition thermoelements in common use. I) DERIVATION OF AN EXPRESSION FOR ABSOLUTE THERMOELECTRIC POWER First consider a metallic conductor which is maintained in a temperature gradient with no current flowing. At constant pressure, there will be a gradient of the free energy (F,) given by:

Jan 1, 1963

By Guy R. B. Elliott

If chemical mining is to work, it is extremely important to watch heat balances. Some reactions with coal give off heat and others absorb heat. The reactions of coal with oxygen or air give off heat, but the reactions of coal with steam or with carbon dioxide absorb heat. By balancing the proportions of the two types of reactions, the energy of the coal can be almost completely recovered and environmental damage is minimized. The chemical reactions are listed in Table 1 in the usual form with subscripts (s) and (g) indicating solid or gaseous materials. In reaction 1, solid corbon, C(s), reacts with gaseous oxygen, O2(g), to produce gaseous carbon dioxide, CO2 (g). H means enthalpy or available heat in the material; F is free energy, and it measures whether the reaction can go at all, and if so, how much.

Jan 9, 1973

By Frédéric Pineau, Guillaume D'Amours

Semisolid metal processing of metallic alloys takes advantage of the thixotropic behavior of material with non-dendritic microstructure to produce near-net-shape components with improved mechanical properties. The much higher apparent viscosity of the semisolid billet limits the risk of oxide formed on the free surfaces to become incorporated into the easting during the process. But, the external-skin on the periphery of the billet, which is often partially solidified and contaminated with lubricants, should not be included into the casting as this can be a cause of reject for most structural parts. In this paper, a preliminary model is set-up using the LS-DYNA SPH formulation to follow the paths of the skin. Calculations carried out show that this approach appears to be very promising to predict the paths of contaminated skins into semisolid castings. It can then be utilized to design suitable molds and gating systems.

Jan 1, 2012

By E. F. Divers, R. A. Jankowski

In response to a request from the Mine Safety and Health Administration (MSHA), the US Bureau of Mines completed a respirable dust survey of 18 US coal preparation plants. Of these, three were essentially free of dust problems. Respirable dust exposure to workers in the remaining plants depended on the time spent in the dusty areas. In five of the plants surveyed, Bureau tests showed that in some areas worker exposures could exceed Federal dust limits in less than two hours. Cooperative studies were arranged with coal preparation plants using three different dust control techniques. These included a standard baghouse-type dust collector, two types of scrubbers, and an electrostatic precipitator. Results of these evaluations are presented. Various types of ventilation systems used during summer and winter conditions were also evaluated. Results showed that appropriate ventilation can provide a highly cost-effective method for controlling coal preparation plant dust.

Jan 1, 1987

The following list of corrections has been compiled from the thirty-five volumes, with some additions: VOLUME I. Page 160. The first two sentences of the second paragraph should read as follows : " For No. II we find that 2.33 percent. A1,08 take 4.07 per cent. 8109, leaving 3.48 per cent. 8102 free, which requires 3.25 per cent. CaO." Page 160, line 14, 3.79 should be 3.25; and in the 15th and 18th lines, 48.44 should be 46.98. VOLUME VI. Page 59. The discharges of the miners' inch per second, given as .2624 and .2499 cubic feet, should be .02624 and .02499, respectively. The discharges per minute, hour, etc., are correctly given. VOLUME VIII. Page 214. 16th and 25th lines, ferric carbonate should be ferrous carbonate. Page 486, 16th line, 10,000 should be 5,000. [ ]

Jan 1, 1907

By R. P. Killmeyer, W. W. Wen, B. K. Parekh

A continuous pilot-scale test of the GranuFlow Process was conducted using a screen-bowl centrifuge for the dewatering and reconstitution of column -flotation concentrate at a coal preparation plant in Virginia. In this test, a slipstream of the fine clean-coal slurry from the column flotation con¬centrate was treated with a bitumen emulsion before dewatering. The treated products from the screen-bowl centrifuge appeared to be dry and in a free flowing granularform, while the untreated products were wet, sticky and difficult to handle. Test results indicated that the average moisture contents of the dewatered coal products were 35.7%, 35.5%, 32.6%, 29.9% and 26.5% (by weight) with Orimulsion additions of 0.0%, 0.7%, 3.2%, 4.8% and 6.4% (by weight), respectively. The handleability and dust reduction of the dewatered coal products were also vastly improved.

Jan 1, 2000

By R. M. (Mike) Robb

Introduction The requirements to investigate a wide range of alternatives and analyze a variety of ‘what if’ questions make the automation of pit design a requirement in today’s rapidly changing mining industry. The wide-spread application of computers has relieved the engineer of much of the tedious and error-prone work related to mine design. He is thus free to do the creative and innovative thinking for which he is trained. It is now possible to investigate a large number of alternative pit designs in a reasonably short time period. In the past it was very easy for a team of engineers to consume 12 to 14 man-months in the detailed hand design of a large open pit. The pressure of today's mining industry, the desire to investigate a variety of alternative designs, and the shortage of qualified engineers make the slowness of hand design less preferred.

Jan 1, 1979

By Neill B. K, Fander H. W, Wong K, Dunlop G, O&apos

Commercial interest in refractory gold is increasing rapidly. This trend is supported by the work patterns of Amdel, where, apartfrom routine process- ing of free-milling and refractory ores, the majority of testing now includes biological and pressure oxidation studies to enhance gold recoveries. Central Mineralogical Services have examined, among other ores, an apparently unique type of refractory coating. A summary is given of experience at Optimet Laboratories, Pty., Limited. Research into nitric acid pre-oxidation, underway at the South Australian Institute of Technology since 1987, has shown significant improvements in gold recoveries, and in some cases, large reductions in reagent consump- tions. Three final-year student research projects were undertaken in 1990, jointly between the University of Adelaide and the S.A. Institute of Tech- nology. These projects involved biological pre-oxidation, pressure leaching, and Scanning Electron Microscope examination of refractory ores, and the resultant pre-oxidation and cyanidation products.

Jan 1, 1991

By S. Subramanian, K. A. Natarajan, D. N. Sathyanarayana

FTIR spectroscopy is used to study the ad¬sorption of an oxidized starch on hematite, corundum, and quart: substrates. The difference spectrum of the adsorbed starch on hematite indicates surface reactions involving -CH2OH and -COH groups and shows striking similarities with that of the ferric-starch system, suggesting chemical interaction between the iron of hematite and the starch adsorbate. The IR spectra of starch adsorbed on corundum and quart: show no evidence of chemical interaction, although hydrogen bonding is apparent. The extent of adsorption of starch on hematite. corundum, and quartz decreases along the series. The evidence for chemical interaction of starch with hematite is further obtained by the X-ray photoelectron spectra of starch adsorbed on hematite, showing noticeable decrease in peak positions of O(Is) and C(Is) of free starch. The Mössbauer spectrum of hematite with stanch adsorbed on it complements these findings.

Jan 1, 1990

By G. L. Hundley, R. E. Mussler, D. H. Yee, F. E. Block, R. S. Olsen

An anhydrous chlorination process for the recovery of copper from chalcopyrite was investigated. Pelletized concentrate was reacted continuously with gaseous chlorine in a vertical shaft reactor at 550° and 650°C. While the copper was withdrawn with the rest of the metals as molten chlorides from the bottom, 99-x% sulfur was distilled from the top of the reactor. The molten metal chlorides were pulverized and dropped continuously into an upward flowing stream of oxygen. Over 80% of the iron chlorides were converted to oxides in a vertical free-fall reactor at 800° and 900°C while the copper chlorides passed through unoxidized. Copper was recovered in powder form by electrowinning continuously from chloride solutions using a diaphragm cell. The product sloughed easily from a titanium cathode and showed no iron contamination. Current efficiencies and power consumptions averaged 77% and 1.24 kw-hr per lb.

Jan 1, 1974