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By Markus Thewes, Mario Galli

"INTRODUCTIONProject-related studies showed that lab tests are a helpful tool for the planning of EPB tunneling and soil conditioning in cohesionless soils. This type of ground commonly represents the extended application range for EPB shields, which demands for a treatment with additives. Considering soil conditioning with foam, so far, approaches exist for the investigation of the foam quality and of the conditioning behavior of soils (e.g. (EFNARC GUIDELINES 2001 2003)), but not any standards for testing procedures related to soil conditioning. State-of-the-art research on the topic is and was conducted for example in Bochum (Germany) cf. (Budach 2012; Maidl 1995), in Lyon (France) cf. (Quebaud et al. 1998), in Oxford and Cambridge (Great Britain) cf. (Borghi 2006; Peña Duarte 2007), in Delft (Netherlands) cf. (Bezuijen and Schaminée 2001), in Turin (Italy) cf. (Borio 2010; Peila et al. 2013; Vinai 2006), and in Aachen (Germany) cf. (Vennekötter 2012). Additionally, applied science is reported by the tunneling practice and suppliers of conditioning agents. Although the research focus in all these and further studies varied, similar test methods and test series were applied. A standardization of essential properties and testing methods (setup and procedures) however did not take place. The results from laboratory testing can only function as index values for practice because in the studies, production and application of the conditioning agents mainly takes place under atmospheric conditions. Nevertheless, the tests enable basic understanding of feasibility as well as processes and interactions going on during soil conditioning. For recommendations for standardized and reproducible testing see (Budach 2012; Budach and Thewes 2015).The most extensive investigations on the flow behavior of soil-foam mixtures have been performed by using the slump test from concrete engineering, cf. (DIN EN 12350-2 2009-08), which originally is applied on evaluating the workability of fresh concrete. Although this test does not describe the actual flow behavior, it rather represents an index on the workability, very much experience exists with this test method. Besides others, the workability – or flow behavior – of the EPB support medium certainly is a major factor of influence on the properties of the material in the excavation chamber and thus, for effective tunneling with EPB shields, cf. (Galli and Thewes 2014). For a summary of various investigations on the workability of conditioned soils using the slump test and resulting recommended slump ranges see (Budach 2012; Vinai 2006). Thereof, slumps between 10 and 20 cm have been reported as suitable workability for EPB applications. However, there is actually not much known about the real flow behavior of soil-foam mixtures related to rheological properties such as the viscosity (?) or potential yield stresses (t0). These physical values are necessary for a realistic determination of face pressure, for the design of required torques, and for an evaluation of the material flow at different locations in the excavation chamber, in the screw conveyor or on the conveyor belt. To generate a linear pressure distribution at the tunnel face, as it is assumed a priori, a low-viscosity fluid is favorable, whereas in the screw conveyor, a high-viscous fluid is needed for a controlled pressure decrease. On the conveyor belt, yield stress plays an important role preventing deliquescence and spilling from the belt. Attempts in characterizing the actual flowing of soil-foam mixtures have so far only been made by few researchers, the application of rheometry is rare."

Jan 1, 2016

By Karen J. Dawson, Francisco Johnson

"Pressure-grouted high strength helical displacement piles are a recently developed pile type that can be useful in conditions where noise or vibrations must be low or where access or clearance is limited. However, there is no information in the literature that can be used to estimate the soil resistance of these piles or production rates. To fill this information need, this paper presents a New Jersey installation case history and the results of static axial and lateral load tests on both pressure-grouted and ungrouted high strength helical piles at the case history site and trial installation locations in New Jersey and Washington State. Piles between 25 and 50 feet long comprised of steel shaft diameters of 4.5, 5.5, and 7 inches with equivalent grout column diameters ranging from 12 to 22 inches were tested. Lateral loads of up to 100 kips and axial compression loads of up to 700 kips were applied. The results of the load tests are compared to predictions of lateral deformation and axial resistance.INTRODUCTIONHelical piles have long been recognized as a useful foundation type in situations where noise and vibrations must be limited, or where there are access or clearance restrictions. Relatively well-documented design methods and torque to capacity correlations have been developed for the most commonly used helical piles, which are relatively small (typically shafts of 6 inches or less) with corresponding low load carrying resistance.With the increased need to construct in congested urban environments, there is incentive to develop helical piles with higher axial resistance. Seismic and other loading conditions also require lateral resistance, which is low for the typically small helical pile shafts. One method of increasing the soil resistance, both axially and laterally and at relatively low cost, is to place grout around the shaft. Injecting the grout under pressure through the hollow helical pipe section and out a grout port or ports located near the toe of the pile has the potential to increase the pile resistance significantly above that which can be achieve by gravity grouting. Not only does the pressurized grout push out against the surrounding soil, but the rotating helix helps to distribute the grout laterally. Unfortunately, little information is available in the literature to help designers estimate the resistance of grouted helical piles in general and none is available regarding pressuregrouted helical piles."

Jan 1, 2016

By Fang-Qui Zu

Understanding the nature of liquid structures and properties remains an open problem for many fundamental and applied fields such as materials sciences and processing. And as well known, there is no other defined phase line above liquidus (TL ) in phase diagrams of ordinary binary systems. However, via different experimental resorts, our research results on over 30 metallic melts including alloys and elements show a novel physical image: temperature induced liquid-liquid structure transition (TI-LLST) can occur hundreds of degrees over TL. On the other hand, the solidification behaviors and structures out of the melts experienced TI-LLST are distinct from those out of the melts before TI-LLST. In this presentation, some characteristic aspects of the TI-LLST and the effects on solidification behaviors and structures are briefly summarized, and the pertinent rules and mechanism are also analyzed.

Jan 1, 2009

By A. Daugiala, D. Coleman

In 2014 the New York State Department of Transportation (NYSDOT) awarded a Design-Build contract to the joint venture team consisting of Skanska which is the managing partner; Kiewit Corporation and Ecco III (SKE) and HNTB as the lead design firm. The design build team employed methods to provide schedule savings and commercial benefits to the owner NYSDOT. This paper presents the design approach and construction methods used to accelerate drilled shaft installation supporting the main span foundation for the cable stayed bridge. The drilled foundation contractor Underpinning and Foundation Skanska, a division of Skanska was responsible for assisting with design, budgeting and construction of the drilled shaft foundation construction. As part of the Request for Proposal (RFP) bid process, Alternate Technical Concepts (ATC) was encouraged by the NYSDOT. The JV team proposed an ATC which involved a scaled production shaft testing method to simulate the ultimate load level, commonly referred to as the “Chicago Method” was used in the rock socket employing the Osterberg Cell (O-Cell) testing procedures. To the authors knowledge this was the first NYSDOT project where this approach was utilized on a Demonstration/Production installation to validate construction procedures and load bearing capacities. Construction procedures, challenges and solutions are discussed in detail. Upon completion of successful drilled shaft construction, concrete integrity is verified using two methods – Cross Hole Sonic Logging (CSL) and Thermal Integrity Profiling (TIP). A comparison from the contractor’s perspective is provided. Finally the drilled shaft rock socket is tested to ultimate end bearing values while rock socket side shear stresses are not exceeding the service level loading. Lateral load test was also a RFP requirement; the test arrangement and performance are discussed in detail as well. The Kosciuszko Bridge location poised unique geotechnical challenges on many levels shifting towards an extreme boundary of parameters encountered in New York City Area for drilled shaft construction. The JV team and specialty drilled shaft contractor actively participating in the shaft design and construction practice coordination and working with NYSDOT yielded a successful foundation solution which provided cost and schedule savings to the project.

Jan 1, 2016

By Eli T. Conner

(Wilkes-Barre Meeting, June, 1911.) My connection, under a commission from the Councils and Board of School Control of the city of Scranton, Pa., with a recent investigation of mine-caves and the resultant damages to surface-improvements, has led to the preparation, at the invitation of our Secretary, of the present paper. It is notorious that there are, in the anthracite-fields, frequent subsidences of the surface, due to the removal of the coal beneath. No particular attention is paid to such occurrences, unless they happen to injure surface-improvements. Many caves have happened in Scranton and its vicinity, which have excited but little remark, since they have generally caused no serious damage. In August, 1909, a cave occurred in the Hyde Park section of the city, generally known as the West Side, which nearly destroyed school-house No. 16 and considerable adjacent property. 'Fortunately, there were no pupils in the building at the time; but the thought of the possible result, bad the usual number of pupils and teachers been present, aroused the public to the gravity of the situation; and the School Board employed engineers to investigate the case. Two reports were made by separate sets of engineers, which differed in some particulars. These differences were pointed out in the public press and magnified, and the consequent agitation of the subject was taken tip and greatly exaggerated by some of the metropolitan newspapers, giving to uninformed people the very erroneous impression that the whole city of Scranton was in danger of sinking into the bowels of the earth. All this tended to affect the credit of the city and to depress real-estate values. The matter was considered at a joint meeting of the Board of Trade, the Councils, and the School Board. The Hon. J. Ben. Dimmick, a former Mayor, suggested that it

Sep 1, 1911

By Ali Azizian, Brian Hall

"Driven piles were selected to support the Fraser Heights Bridge bents. Piles were a key component of the top-down construction approach, which was adopted for minimizing potential impacts on an environmentally sensitive wetland. Project requirements mandated verification of pile capacities using dynamic methods. More than 40 Pile Driving Analyzer (PDA) tests were performed. The subsurface conditions were highly variable. On the east side, piles extended through loose sands, soft silts/clays, and two peat layers and were founded in glacial till-like soils at about 45 m depth. However, on the west side, till-like materials were so shallow that it was difficult to drive the piles sufficiently deep to obtain the necessary lateral support. This paper provides an overview of the geotechnical considerations of the bridge design and top-down construction approach, and expands on the presentation of PDA results and how they compared to pile capacity estimation methods and parameters recommended in the applicable design codes.INTRODUCTIONThe Fraser Heights Bridge (FHB) was a component of the Fraser Heights Connector (FHC), a 2 km section of the South Fraser Perimeter Road (SFPR), constructed as part of the Port Mann/Highway 1 (PMH1) Improvement Project. The FHC is located in northeast Surrey BC (Fig. 1).Two major design and construction determinants were: 1) a mandated tight schedule to provide a non-tolled alternative to a new toll bridge; and, 2) an obligation that construction had to occur with minimal impact on the environmentally sensitive wetland the FHB crossed, including limiting the footprint of the permanent and temporary works to less than 45 m2, and prohibiting construction access onto the wetland. Construction equipment was only allowed on the wetland on temporary trestles or on the finished structure. This latter requirement resulted in the bridge being constructed span by span, using a top-down approach."

Jan 1, 2016

By Satyajit Vaidya, Rudolph Frizzi, Sandy Larimer

"This paper presents a case history in design and construction of a deep foundation system that included high-capacity open-ended driven piles constructed to support a high-rise building in Manhattan, New York. The project site is bordered by existing buildings, active streets, and critical public transportation infrastructure, which were considered in the new building’s deep foundation and seismic design. This paper focuses on driven pile foundation design and installation through relatively loose soil deposits. Unique design aspects included seismic design considerations, and pile splice design for open-ended steel pipe piles subject to significant uplift and lateral loading. Unique construction aspects included quality assurance of open-ended steel pipe pile splices, and uplift and lateral load testing of driven piles installed in close proximity to other foundation elements installed for the project.SITE CONDITIONS AND SUBSURFACE CONDITIONSThe project site is located in Manhattan, New York, and is bordered by existing buildings, active streets, and critical public transportation infrastructure that is located about 60 feet from the site. The existing sidewalk grades around the site are between about el 4 and about el 13; elevations are referenced to the North American Vertical Datum 1988 (NAVD88).Subsurface conditions at the site generally consist of successive strata of historic fill, former river bottom deposits consisting of compressible clayey soils, and medium dense to dense sand, overlying mica schist bedrock. A generalized subsurface profile is shown in Fig. 1. The historic fill stratum is about 10 to 45 feet thick, and generally consists of loose to medium dense sandy soils with varying proportions of silt, gravel, and miscellaneous debris such as brick, concrete, and glass fragments. The underlying former river bottom deposit stratum is up to about 15 to 20 feet thick, and generally consists of very soft to very stiff clay and lenses of very loose to loose sand. Medium dense to dense sand was generally observed below the historic fill and former river bottom deposit strata and overlying bedrock. Top of bedrock was generally observed at about 80 to 105 feet (i.e. at about el -75 to el -100), except in the southeastern portion of the site where the top of rock was observed as deep as about 140 feet (i.e., at about el -135). Groundwater levels typically ranged between about el 1.5 and el -0.5."

Jan 1, 2016

By John P. Turner, Steven S. Dapp, Dan A. Brown

"The Goethals Bridge Replacement (GBR) spanning the Arthur Kill Waterway between Elizabeth, NJ and Staten Island, NY is supported on over 200 drilled shaft foundations ranging in diameter from 4.5 ft to 10 ft and socketed into Passaic Formation siltstone. Four drilled shafts, two on each side of the bridge (NJ and NY), were load tested using the bi-directional axial load method. Axial test results demonstrate that RQD, taken by itself, is not necessarily a reliable indicator of side or base resistance. High recovery with low RQD can be a function of horizontally bedded siltstone and shale where the individual pieces of core do not exceed four inches, but may still provide very high side and base resistance. Axial testing was followed by a lateral rapid-load test (Statnamic) on each of the same four shafts. In addition, one of the shafts was subjected to a static lateral load test to validate the rapid-load method as being representative of static loading conditions. Results of the axial load tests provide the basis of unit side and unit base resistances used in the LRFD design of the rock sockets for axial loading, while results of the static and Statnamic lateral load tests were used to calibrate p-y curve parameters used for design under lateral and moment loading. This paper describes implementation of the load testing program and its role in the design process.INTRODUCTIONDesign of drilled shaft foundations for the Goethals Bridge Replacement (GBR) required load testing in order to validate the parameters used for calculating geotechnical axial and lateral resistances. The bridge, including foundations, was designed in accordance with the AASHTO LRFD design specifications, 6th Edition (2012). The bridge owner is the Port Authority of New York and New Jersey (PANYNJ). One of the PANYNJ project requirements was stated as follows:“Perform a minimum of two (2) separate axial compression load tests (one [1] in New York and one [1] in New Jersey) for each demonstration shaft of different size and construction methodology to verify the design assumptions and construction procedures. At a minimum, one (1) demonstration shaft is required to be representative of production shafts with a diameter within one (1) foot above or below the demonstration shaft diameter.Conduct a minimum of two (2) lateral load tests (one [1] in New York and one [1] in New Jersey) for each demonstration shaft of different size and construction methodology. At a minimum, one (1) demonstration shaft is required to be representative of production shafts with a diameter within one (1) foot above or below the demonstration shaft diameter.”"

Jan 1, 2016

By R. Boom, C. F. Balentina, J. H. L. Voncken

During vitrification of bottom ash generated from the combustion of municipal solid waste (MSW), a Fe-Cu based alloy phase with great value was formed. In order to find proper commercial use in metallurgical industry, it is necessary to separate Cu and Fe. The present study focuses on the sulfide treatment at temperatures of 1400 – 1500oC, in particular with FeS containing minerals. Various sulfide compounds such as Na2S, Al2S3 and Ni3S2 were added to promote the copper removal. Pyrite and zinc sludge (containing ZnS) as waste streams were studied with specific interests. The results showed that both zinc sludge and pyrite are effective for copper removal with the highest removal efficiency of 95% by using pyrite. The copper content drops from 12 wt% to about 2 wt%. However, it is still difficult to remove copper completely from the alloy in one step, and a multi-step operation is needed.

Jan 1, 2008

By Giulia M. B., Ferruccio Cribari, Alessandro Bertero, Eliano Romani, Roberto Sorge, Francesca Casini

"The use of Artificial Ground Freezing (AGF) to form earth support and seepage control barrier systems has had applications worldwide. These cover a variety of construction problems, including the formation of frozen earth walls to support deep excavations, structural underpinning for foundation improvement, and temporary control of ground water in construction processes. An application of AGF during construction of Line C of Rome underground is described in detail.The new line “C” of San Giovanni metro station was constructed adjacent to the existing line “A” of San Giovanni station; the new metro line “C” is deeper than line “A” and runs below the existing station. The underpass project envisages an Artificial Ground Freezing in order to create a structural and waterproof temporary cut-off suitable to the two new tunnels excavation, while keeping trains running in the safest possible condition. The excavation of tunnels under the water table, with a hydraulic head of over 10 m in not homogeneous soils having different mechanical properties and permeability and below existing sensitive structures, involves special ground freezing sequences and methods, as well as peculiar drilling systems and operations, such as TDDT (Trevi Directional Drilling Technology).Artifical Ground Freezing IntroductionNatural freezing occurs seasonally in many areas of the globe and can affect negatively the engineering performance of geotechnical structures; on the other hand, man-made freezing is a controllable process that can be used by civil engineers to stabilise temporarily the ground in order to support and/or exclude groundwater from an excavation until the final retaining and lining structures are constructed. Freezing and thawing of the pore fluid within soils involve complex thermal, hydraulic and mechanical processes that have significant mutual interactions. For example, phase changes of the pore fluid caused by temperature variations can modify the pore water pressure in the soil, which, in turn, can induce mechanical deformation. At the same time, any changes in the hydraulic and mechanical conditions affect the thermal processes by advection and changes of ice and water contents.An application of AGF which will be presented in the paper, refers to the construction works of Line C of Rome underground. In this case AGF was carried out to provide temporary support during excavation of the two Line C running tunnels directly underneath the existing S. Giovanni station of Line A, in the safest possible condition. In order to keep the trains of Line A operational during excavation, a temporary structure was installed and a real-time monitoring system was conceived in order to control the temperatures of the soil during freezing and the response of the structures of the existing station."

Jan 1, 2016

By M. Z. Emad, A. Khan, N. Abbas, K. G. Li

Probability-based empirical methods were employed as an alternative approach to predicting uncertainties associated with rock mass properties. The focus was on developing probabilistic spreadsheets to forecast rock mass classification indexes. Histograms were constructed to describe the best distribution in predicting rock mass properties. The developed models also offer utility in predicting the impact of discontinuities within the rock mass on rock strength and rock mass classification systems. Statistical analyses identified volumetric joint count, joint spacing, joint frequency, and rock strength as the most influential parameters. Moreover, the statistical analysis revealed varying degrees of correlation among different rock mass properties. While some properties demonstrated significant correlations suitable for modelling, others did not align well with any correlation model. The results highlight the need for a comprehensive approach to rock mass characterization, considering multiple factors beyond volumetric joint count. Geological complexities, including tectonic activity and weathering processes, may obscure direct correlations. These results emphasize the importance of empirical modelling and detailed site investigations for accurate assessment of rock mass quality and stability in the Himalaya.

Jun 10, 2024

By Matheus Felipe dos Santos, Eric Yoshimitsu Sako, Murilo Henrique Moreira, Douglas Fernando Galesi, Ricardo Afonso Angelico, Vladnilson Peter de Souza Ramos, Maria Gabriela Garcia Campos, Victor Carlos Pandolfelli

O consumo de energia em panelas de aço está relacionado às etapas do processamento que ocorrem durante o refino secundário. O aço líquido perde energia térmica quando são adicionadas ligas, pelo sopro de gases, agitação e por convecção natural. Cerca de 70% dessas perdas ocorrem pelos revestimentos refratários, que dissipam energia para o ambiente quando suas superfícies são resfriadas. A microestrutura dos refratários Carbonfree resulta na redução da transferência de calor no material, devido a presença de fases de baixa condutividade térmica (por exemplo, agregados porosos) e sem o carbono que é uma fase usualmente presente e aumenta a condutividade térmica nos materiais. O processo nas panelas de aço é transiente e necessita de ferramentas numéricas avançadas para investigar o desempenho desses materiais nas condições específicas de cada aciaria. Tais ferramentas foram aplicadas para estimar o potencial de conservação de energia dos revestimentos Carbonfree em um caso real (linha de metal e sola) e os resultados mostram um potencial de redução de 21%. Os testes realizados in-situ compararam as diferentes taxas de queda de temperatura para cada configuração com as previstas pela ferramenta. Os benefícios estimados foram comprovados e a eficiência dos materiais investigados foi validada.

Oct 1, 2019

By J. B. Zadra, J. M. Gomes, Don H. Baker

Electrolytic deposition at 1,000 ° C in an electrolyte essentially consisting of 7 parts sodium pyrophosphate , 2 parts sodium chloride , and 1 part sodium tetraborate yielded tungsten of 99.9 percent purity . Scheelite concentrates containing 25 to 73 percent WO, and varying quantities of iron , lime , and silica were used as feed materials for the electrolysis . The metal contained less than 0.01 weight - percent each of iron , calcium , silicon , aluminum , carbon , and oxygen . Modification of the electrolyte permitted deposition of equal - quality metal from scheelite concentrates containing higher quantities of iron , calcium , and silica . The electrolytic separation of molybdenum and tungsten was accomplished by minor variations in the operating procedures .

Jan 1, 1964

By R. L. Crosby, L. W. Higley

Magnesium- rich magnesium- aluminum- zirconium alloys in the cast and in the extruded and heat- treated condition were studied to identify the phases present and to determine phase distribution . In cast alloys , two intermetallic compounds were identified : ZrAla by X- ray diffraction ; and Mg₁ Al₁₂ by microscopical observation . Based on microscopical comparisons between the known phases in the cast structures and the phases in the structures of extruded and heat - treated rods , ZrAl₂ and Mg1 , Al12 were identified in the structure of the latter . The presence of these intermetallic compounds in rod specimens could not be confirmed by X- ray diffraction . ZrAl₂ was observed in the structure of extruded and heat - treated rod specimens containing as little as 0.01 weight - percent zirconium . The presence of aluminum restricts the solubility of zirconium in magnesium because of the strong tendency to form ZrAla . This intermetallic compound segregated in clusters of small particles in the matrix of cast alloys , and only slight improvement in distribution was noted when the alloying techniques were varied .

Jan 1, 1964

By R. T. Johansen, R. J. Heemstra

In water flooding the gradual accumulation of insoluble materials on the sand face causes the injection pressures to increase while decreasing the amount of water injected . This plugging material often is composed primarily of insoluble precipitates of calcium , iron , and magnesium . Treatment with sodium tripolyphosphate ( STP ) either eliminates or reduces the formation of precipitates . Field tests are discussed showing the almost immediate effects of using STP in the injection water . Methods of treatment , solubility of STP in fresh water and brines , and precautions to observe when starting to treat a waterflood with this chemical are given . Laboratory data show that the preferential wettability of a crude oil for reservoir rock can be reversed by adding a small amount of STP to the flooding water . This reversal in wetting tendency should not only decrease the injection pressures but also increase oil recovery by improving the sweep efficiency of a water flood .

Jan 1, 1964

By K. E. Tame

An alkaline leaching procedure for recovering uranium from a submarginal 0.1 percent Ug Og calcareous carnotite ore from the Shiprock , N. Mex . , area was investigated . A recovery of 72 percent of the uranium was attained in a preliminary test embodying the commonly accepted practice of ( 1 ) alkaline leaching at 90° C , ( 2 ) multiple stage filtration and washing for recovery of a clear pregnant solution , and ( 3 ) caustic precipitation of uranium as sodium diuranate , with recycle of the barren solution to the leaching and washing circuits . Ion exchange resins were used in a second , less orthodox test that comprised ( 1 ) sodium carbonate leaching of minus 10- mesh ore at 90 ° C to dissolve the uranium , ( 2 ) filtration to recover the leaching reagent for reuse , (3 ) recovery of the uranium- bearing solution in the filter cake as a pregnant slime slurry by repulping of the filter cake followed by a sand- slime separation and countercurrent decantation (CCD ) washing for rejection of the sand fraction , (4 ) recovery of the dissolved uranium from the pregnant slime slurry by resin- in- pulp (RIP ) , ( 5 ) elution of the uranium from the resin with a solution of ammonium chloride acidified with hydrochloric acid , and (6 ) precipitation of the uranium with ammonia gas . About 83 percent of the uranium was extracted from the ore and 95.5 percent of the dissolved uranium recovered by ion exchange . Improved laboratory results were obtained using the RIP process , but larger scale tests would be necessary for economic evaluation of the two processes .

Jan 1, 1964

By J. A. Ruppert, P. M. Sullivan

A study was made of filtration techniques for recovering the major part of the tin contained in iron - tin alloys known as hardhead . Special smallscale filtering apparatus and a three - stage cyclic process were developed . Eighty- seven percent of the tin contained in an alloy of 82 percent tin and 17 percent iron was recovered as pure metal by pressing at 975° C followed by a second pressing at 800 ° C and a final filtering at 250 ° C. Small amounts of Sb , Cu , and Fe impurities were removed by adding Al to the molten product and performing another filtration at 250 ° C.

Jan 1, 1964

By H. R. Shell, John L. Miller, M. V. Denny

In the mica research program conducted by the Bureau of Mines at Norris , Tenn . , many micas other than silicon fluorphlogopite have been synthesized . It has been well established since the initiation of the program that synthetic micas are important materials useful for their superior or unique properties as well as substitutes for natural micas . The possibility of controlling the physical properties of synthetic mica by isomorphic substitution of other ions in the fluorphlogopite lattice further emphasizes the importance of these materials . Accurate measurement and reporting of their properties constitute an essential part of the research program . The study of germanium fluorphlogopite is in keeping with the requirements of a comprehensive study on isomorphic substitution , specifically to identify precisely the material -- chemically , structurally , and optically . The X- ray measurements , including indexed powder and single crystal data , with a description of the methods used to obtain these data , are provided . 5 Earlier work on germanium mica by R. A. Hatch et al . (5) gave an estimate of the cell parameters from X - ray powder data , but no attempt was made to index the diffraction pattern or to determine the space group symmetry . Later work by E. A. Schatz and J. C. Withers (9) listed X- ray and optical measurements , but no attempt was made to index the mica or determine its symmetry . Roth (7) found that germanium dioxide having the a - quartz structure , when heated with equimolar percentages of MgO , CaO , Sr0 , or Ba0 at 1,235 ° C , formed ABO3 -type compounds , e.g. MgGe03 isostructural with enstatite (MgSiO3 ) . Geo₂ also has a rutile - type polymorph with Ge ++ ions in octahedral coordination . Germanium was substituted for silicon in the serpentine structure by Roy and Roy (8 ) using hydrothermal techniques . These authors wrote as follows : "The substitution of Ge + for Si + yielded a magnesia - germania serpentine , formed easily in euhedral hexagonal plates which in some instances were visible in the light microscope . Electron micrographs and the sharp X - ray diffraction patterns confirm a plate - like rather than tubular habit . " It has been shown in this investigation that substitution of germanium for silicon in the mica structure is readily accomplished without radically changing the characteristics of the mica . Substitutions in the mica structure take place in three locations : Tetrahedral , octahedral , and interlayer positions . The tetrahedral positions are normally occupied by Sit or by a combination of Sit with Al +3 the most common combination being 2A1 +3 and 6Si +4 · , The octahedral position , which has six - fold coordination in phlogopite , contains a larger cation such as magnesium . In muscovite it contains only 2A1 ions ; therefore , this mica is considered a dioctahedral mica , whereas phlogopite is considered trioctahedral . +3 The interlayer position has twelve - fold coordination with six oxygen ions from each of two adjacent tetrahedral silica layers . This is the cleavage plane of the mica and commonly contains the largest cation in the mica structure (e.g. potassium) .

Jan 1, 1964

By Charles C. Myers, Robert M. Doerr

The apparatus described was developed for determining the kinetics of gas - solid reactions at high temperatures by measuring the volume of gas consumed with respect to time . This apparatus consists essentially of a horizontal precision- bore glass tube connecting a small reaction chamber in a furnace to a large constant - temperature reservoir . A drop of mercury in the tube separates the two sides of the system and serves as an indicator that moves at a speed proportional to the rate of gas consumption . The sensitivity of the apparatus depends inversely on both the density of the gas in the system and the cross - sectional area of the tube ; with a tube having an area of 0.079 cm² , the sensitivity for oxygen at 308 ° K and 0.5 atm is 20 cm/mg . The reproducibility of data with the volumetric apparatus is good .

Jan 1, 1964

By Lewis C. Karrick

This paper is based on data obtained in the course of the oil - shale investigations of the U. S. Bureau of Mines , conducted in cooperation with the State of Utah . The amount and quality of oil that can be produced from any shale may be made to vary to an important degree by changing the temperature relations existing in the shale charge during destructive distillation . The rate at which the oil is formed from the shale is affected by the rate of heat supply , and therefore by the temperature of the shale during its thermal de composition . The quality of the oil formed may be controlled by altering the temperature of the shale , and therefore , the rate of formation of the oil . Variations in the yield and quality of shale oils may be caused by inherent properties of the retort used , but in any event the properties of the crude oil and yield are very largely the result of the extent to which the thermal de composition has progressed . Recognition of these principles will aid in explaining to a large degree the reasons for the wide variations in oils produced from the same shales by different " processes " . These principles also may be applied in the operation of different types of retorts in order that crude oils of a type most profitable to the operator may be produced . The Bureau of Mines has conducted an extended series of tests in the dee structive distillation of oil shales , in order to determine the wide variations that may be effected in the quality and yield of shale oil by changing the rate and temperature at which the oil is formed . These tests furnished interesting information on the four related points : yield of oil , quality of oil , temperatures required to distill shales , and time required for distillation .

Mar 1, 1923