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By Robert Hopler

GEO. M. MOWBRAY’S REFRIGERATOR CAR FOR THE SAFE CONVEYANCE OF EXPLOSIVES. It is a fact well known to all miners who have used nitro-glycerin, or any of its adulterations, commonly known as dynamite, rendrock, Hercules’ powder, dualin, vigorite, etc., that when congealed, these compounds cannot be exploded, and in this congealed state — say at temperatures below 40° F. — they can be handled with no more danger than a box of soap or a can of lard. If, then, the atmosphere by which this class of explosives is surrounded, during transportation, be maintained below 40° F., explosion is practically annihilated. Therefore, I constructed a refrigerator car, with cells for every box of the explosive; and two years of railroad transportation confirms our ten years’ experience in teaming in wagons, that this class of explosives can be transported in perfect safety, as above described.

Jan 1, 2011

By Melvin H. Miles

"Considerable research has been conducted on the anodic oxidation of methanol in fuel cells. The electrochemical reduction of carbon dioxide in aqueous solutions to form methanol is the same reaction in reverse, i.e. CO2 + 6 H+ + 6 e- ? CH3OH + H2O. The same catalysts and conditions may operate for both reaction directions. This carbon dioxide reduction reaction, however, must be able to compete with the electrochemical reduction of water to form hydrogen gas. Thermodynamically, the reduction of CO2 to form CH3OH is slightly more favorable than the reduction of water. The use of nearly neutral electrolytes rather than acidic electrolytes makes the reduction of CO2 kinetically more favorable. The thermodynamics of various reaction steps are presented. Similarities exist with the electrochemical reduction of CO2 and the green-plant photosynthesis process that converts CO2 to carbohydrates.IntroductionVirtually all of the oxygen in the earth’s atmosphere is of biological origin having been generated by green-plant photosynthesis from water and carbon dioxide [1]. The net reaction can be represented byCO2 + H2O ? O2 + [CH2O] (carbohydrates, etc.) (1)Chlorophyll and enzymes promote this reaction, and the energy required comes from sunlight. The actual photosynthesis process is a complex multistage reaction and requires 469 kJ mol-1 of energy supplied by the sun. Isotope tracer experiments using 18O have shown that both the oxygen atoms in the O2 molecule originate from H2O, whereas oxygen atoms in the carbohydrates come from CO2 [1]. The total amount of water on the earth is split by photosynthesis and reconstituted by respiration and combustion once every 2 million years or so. The photosynthetically generated oxygen gas temporarily enters the atmosphere and is recycled about once every 2000 years [1]. The carbon dioxide is partly recycled in the atmosphere and oceans after an average residence time of 300 years and is partly fixed by precipitation of CaCO3 and other carbonate minerals [1]."

Jan 1, 2008

By N. Moelans

A method using an ex-situ electrochemical measurement device was developed to determine the oxygen potential of non-ferrous metallurgical slags. The electrochemical cell consists of the molten slag sample, an inert Ir electrode, a stabilized Zr02 solid electrolyte and a NiINiO reference electrode. Different slags from non-ferrous pyrometallurgical processes were analysed at 1100 and 1200°C and pO2 values between 10-3 and 10.12 bar were obtained. The measurements were evaluated with? thermodynamic calculations and using processing considerations. It was found that the reproducibility and stability of the measurement was significantly improved by shielding the molten slag from the atmosphere by a thin layer of carbon, especially for slags with a low oxygen potential.

Jan 1, 2003

By Hiroyuki Matsuura

The effects of P2OS or Na2O addition on the reaction rate of CO2 dissociation on the surface of FexO-base molten oxides was investigated at I 773K by isotope exchange method 1-6. The rate constant decreased with increasing P2Os content of molten oxides and the residual rate constant was observed at high P2OS content. On the other hand, the rate constant increased with increasing Na20 content for FexO-SiO2 melts, The rate constant was evaluated by the composition of oxides and the rate controlling step of CO2 dissociation was discussed.

Jan 1, 2003

By G. B. Amicucci

A Denver Autometrics Particle Size Monitor, PSM-400, was installed at Golden Sunlight Mines, Inc. in October 1988. The PSM-400 measures the grind product's particle size and percent solids. The particle size is used to control grind size by automatically adjusting mill feed rate. The PSM's continuous response to ore changes has improved grind product uniformity and mill throughput. Metallurgical testing has shown the PSM's accuracy to be +/-1 % + 150 µm (100 mesh).

Jan 1, 1991

By A. J. Pearce

MOST mines have a model of some kind to illustrate either geological structure, mining operation, or some special condition or feature of the property. The type used depends on the particular feature or use for which it is intended. At Dome Mines we have developed an interesting and practical application of the horizontal-type model. This model shows the workings of each level horizon plotted on glass. These glass panes are set in frames which, in turn, rest on drawers equipped with rollers which can be pulled out as desired into a light chamber. The features of this model are its rigid steel construction and that any desired number of level plans can be pulled out, eliminating any other interference from other levels. Figures 1 and 2 are photographs of the model cabinet and show its construction and general features. The cabinet is of steel construction with the following overall dimensions: width, 6 ft. 5 in.; depth, 6 ft. 7 in.; height, 5 ft. 2 in. When not in use it can be completely closed-in, making the cabinet practically dustproof. There are 30 drawers, one for each of the 29 levels and one for the surface. The glass in each drawer is divided into two panes, 36 in. by 36 in., of flatdrawn double-diamond 'lustraglass' with about l/32 in. between adjacent edges. The panes are held rigidly in the frames, which are lined with felt strips, and may be adjusted by set screws, four of which on each drawer are shown in Figures 1 and 2. The level workings, on a scale of 1 inch equals 100 feet, are traced in ivory black Windsor & Newtons artist oil paint. Co-ordinate lines are shown in crimson lake, and main geological contacts are shown in their respective colours. Figure 3 is a photograph looking down on one of the levels. The lighting consists of 14 30-watt fluorescent bulbs, with reflectors, under frosted glass. These lamps are much more satisfactory when operated by 60-cycle rather than 25-cycle and, as we had available nearby a source of direct current, this was used. The electrical unit consists of a rotary converter from d.c. to 60-cycle. This arrangement gives perfect lighting, allowing most colours to be easily distinguished. Figure 1 was photographed using this source of light, Figure 2 using an outside floodlight.

Jan 1, 1945

By W. M. Houston

Pebble phosphate deposits of Florida have been established from south of Hardee County to north of the Georgia state line or a distance of over 200 miles and mining has been carried out in an ever-increasing scale since 1885. Deposits that can be mined on the economical standards of today, however, are confined in a roughly circular area about 30 miles in diameter, generally within Polk and Hillsborough Counties, in the central part of the State. The phosphate deposit, which is in the Bone Valley formation of the Pliocene age, is covered by Pleistocene terrace deposits of unconsolidated quartz sand. The matrix is composed of approximately 1/3 clay slimes, 1/3 silica sand and 1/3 phosphate pebbles. The phosphate occurs usually as rounded pebbles, ranging in size from about 1 inch down to approximately 400 mesh. The phosphate may vary from well- defined hard pebbles to soft weathered rock. The color and character of the phosphate will range from smooth buff pebbles to black and white or "salt and pepper rock." The screen size distribution varies considerably between locations and the recoverable phosphate varies may extend down to the 400 mesh size in some areas, while in others the phosphate may cut off sharply at about 35 mesh.

Jan 1, 1962

By Y. F. Vasyuchkov

In general a term "unconventional mining or "non-traditional mining technology" getting more and more familiar to the mining engineering media. There are several alternating terminological combinations such as "in situ mining", "borehole mining", "shaftless mining", "mineless mining", "geotechnology" etc.; specific terms denote particular method of unconventional mining technology: "underground coal gasification in situ", "underground coal combustion in situ", "borehole hydraulic coal mining" and others. Principal scheme of unconventional coal mining technology is shown in Figure I:

Jan 1, 1997

By D. Greene

Close integration of mine planning and operation is a long-sought goal. Success is achieved in varying degrees depending upon mine complexity, size, and sophistication, but too often is more limited than desired. Despite tremendous strides in the development of computer-aided mine planning, digital plans usually must still be converted to error-prone paper maps and physical ground surveys for actual excavation and reclamation. However, advances in GPS, operator displays, and mobile computers now enable equipment operators to work directly from on-board digital plans. CAES offers reduced survey costs, faster field transition time and improved excavation accuracy coupled with faster, more informed decision making regarding key mining operations.

Jan 1, 1997

By Se-Won Chang

This is a part of the joint KIGAM-GNS-NIWA 3-year study of ferromanganese nodules on the Campbell Drift, east of Campbell Plateau to determine age distribution, growth rates and geochemical evolution in relation to geographic setting. During the research voyage SAA3 by R/V Tangaroa (TAN 9909) in July-August 1999, seafloor sampling and camera towing were conducted along the two transects across the known flow path of the Deep Western Boundary Current (DWBC) perpendicular to the lowermost margin of the Campbell Plateau and Bollons Seamount. The four major nodule facies, SHH (slope hydrogenetic nodules with high density), AHH (abyssal hydrogenetic nodules with high density), ADH (abyssal diagenetic nodules with high density), and ADL (abyssal diagenetic nodules with low density) were identified. Two additional minor nodule facies, SIB (slope irregular nodules with ice-rafted boulders) and SHB (slope hydrogenetic nodules with boulders and crust), of localized distributions are also identified.

Jan 1, 2003

By Olli Haavisto, Heikki Häkkänen, Tommi Kauppinen, Navid Khajehzadeh

Raman analysis is a well-established method for finding the abundant minerals in an ore sample. In this study, Raman spectroscopy is tested as a method for rapid and contactless on-line mineral analysis. Rapidness might enable on-site analysis of rock drillcore, which in turn would lead to more cost-efficient solutions in mineral exploration. This paper discusses the use of Raman analysis to identify minerals and to measure their concentration. The sample set under study consists of rock drillcore collected from Agnico-Eagle Kittilä Mine, Finland. Selected parts of the sample set are measured by Raman spectroscopy and the minerals are identified using reference spectra from a public source. Moreover, the direct measurement of concentration of different minerals with the help of Non-negative least squares (NNLS) optimisation algorithm is considered. The optimisation algorithm was constructed to form a linear combination of reference spectra which best represent the measured spectrum, or an average of measured spectra, from an ore sample. The results show that NNLS can identify abundant minerals in a given sample. Also through this method of analysis the results of a traditional point-count method can be expanded: It was observed that, due to grain size, multiple minerals consistently appear in the spectra measured over an area, which means that point-count method is not a proper way to interpret the spectra. This can be seen as a new result, as formerly the discussion has attended to other methods.

Jan 1, 2014

By Harold S. King

TWO summers ago I had the privilege of visiting No. 18 colliery at Glace Bay. Underground, we travelled along the haulage-way behind a powerful electric locomotive. The motor in this locomotive began to smoke badly and a carbon tetrachloride type of extinguisher was used several times during the trip. At the time, I noted a strong odour of phosgene. On my return to Sydney, I spoke to Mr. Harold Gordon, Assistant to the General Manager of the Dominion Steel and Coal Corporation, and warned him of the danger of using this type of fire extinguisher in confined spaces, since it is a well known chemical fact that phosgene, a dangerously toxic gas, is formed by the decomposition of carbon tetrachloride. This danger does not seem to be widely recognized, so it seems advisable that a more general warning be published. Attention was first drawn to the danger by the death of two men in the United States Navy Department subsequent to breathing fumes from carbon tetrachloride used in a fire, and when an employee of the Bureau of Mines also was overcome while fighting a fire with carbon tetrachloride liquid. These accidents led to an investigation of the decomposition products of carbon tetrachloride by a group of workers in the Research Laboratory of the Pittsburgh Experimental Station, U.S. Bureau of Mines, the results of which were published in the October, 1920, number of the Journal of the .Franklin Institute (1). Their experiments were conducted by two methods. The first consisted in applying the liquids to actual fires and -to hot metal in a closed room of 1,000 feet capacity, where the gaseous products, mixed with air, could be retained and analyzed. The second method was to pass the vapour:s in air through heated tubes of iron or quartz, where the humidity of the air and the temperature could be controlled.

Jan 1, 1939

By Jeff Mattern

"Slope performance monitoring, dependable operational practices and ongoing collection of geologic data in openpit slopes all provide valuable information for quantifying potential steepening of subsequent slopes. Mining at the Goldstrike openpit has been ongoing since the early 1980s, having its share of slope instabilities. In areas where slopes have remained stable, consideration has been made for potential slope steepening of final walls.While technology can be efficient, interesting for collecting needed data, slope design fundamentals based on that data can be applied to create much added value.With the proper available equipment, steepening of bench face angles via presplit blasting is not an uncommon method for steepening of interramp slope angles. As an alternative at Goldstrike, the commonly used Modified Ritchie Criteria for empirical catch bench width has been adjusted, resulting in quantified, rock-specific formulas for bench width and rock fall berm placement. The result is an inter-ramp slope angle increase of 2° on a 305- m (1,000-ft) high slope, without the necessary purchases and procedural changes that would be required for presplit drilling and blasting. The result has shown significant net benefits through reduction in mined waste tons and an increase in gold reserves.LocationThe Goldstrike openpit is located in the Great Basin, on the northern end of the Carlin Trend gold belt in northeastern Nevada (Fig. 1). The mine has produced more than 1.2 kt (43 million oz) of gold during the past 30 years."

Dec 1, 2018

By R. Woods

"Comments on the paper ""Formation of hydrogen peroxide by chalcopyrite and its influence on flotation,""by A. Javadi Nooshabadi and K. Hanumantha Rao (Minerals & Metallurgical Processing, 2013, Vol. 30,No. 4, pp. 212-219)The formation of hydrogen peroxide from water during the grinding of chalcopyrite in a nitrogen-sparged environment, as reported by Javadi Nooshabadi and Rao (Minerals & Metallurgical Processing, 2013, Vol. 30, No. 4, pp. 212-219), is questioned on the grounds that oxidation of water by the mineral is unlikely to be thermodynamically feasible. It is argued that it is more likely that any peroxide that had been formed would have been generated from residual oxygen in the nitrogen-flushed system than from the oxidation of water.The formation of hydrogen peroxide by finely divided pyrite had been reported by a number of authors (Borda et al., 2001; Borda et al., 2003; Cohn et al., 2006; Schoonen et al., 2006; Schoonen et al., 2010; Jones et al., 2011; Javadi Nooshabadi et al., 2013). That hydrogen peroxide is formed in the presence of oxygen in solution can be comprehended from wellestablished mechanisms. Pyrite in aerated solution is known to oxidize by an anodic process that is coupled with the cathodic reduction of oxygen (Holmes and Crundwell, 2000). The latter process has been shown to occur through the formation of hydrogen peroxide (Biegler et al., 1975; Ahlberg and Broo, 1996). The pH dependence of cathodic oxygen reduction at other sulfide minerals, including chalcopyrite (Biegler et al., 1977; Rand, 1977), implies a similar mechanism at these surfaces."

Jan 1, 2015

By E. G. King

Thermodynamic data for the hydrated varieties of alumina are sparse, and those for the common clay minerals are virtually nil. This paper partly fills the vacuum by reporting low-temperature heat-capacity measurements and entropy evaluations of diaspore (A10(OH)) and three clay minerals of the composition A12Si207?2H20 - kaolinite, dickite, and halloysite. The heat-capacity measurements were made in the temperature range 510 to 298.15° K., and the entropies were evaluated at 298.15° K. Diaspore has an unusually low heat capacity and entropy compared with boehmite (another mineral of the same chemical composition). The entropies of the three clay minerals differ too little for entropy to be the important factor relating to differences in the thermal stability of these substances.

Jan 1, 1961

By Ch. Enkhbold

Underground mining of minerals is becoming an increasingly complicated technological and ecological problem. It can be explained both by worsening of geological conditions of mining and by a specific character of mining industry, which, in contrast to processing branches of industry, intrudes into one of principal components of the nature ? the Earth's interior. At a traditional organization of mining industry, the entire volume of the produced rock mass is brought to the Earth's surface, where valuable components are extracted. This entails not only power over expenditure for long-distance transfer (especially in the vertical direction) of the waste rock forming a part of the original mineral, but also the formation of huge volumes of worked-out spaces. The latter leads (nature cannot stand emptiness!) to an irreversible development of geomechanical processes of shifting of overlying rock masses resulting in an irreparable damage of all surface structures located on the territory undermined by deep mining. Owing to their high productivity combined with low power consumption and instrumental compactness, novel bifunctional technological processes of minerals dressing successfully solve the problem of rock mass processing in underground conditions with subsequent operative disposal of final tailings of such underground dressing in the worked-out space. Besides, an integration of two processes into one is achieved, for example, a decrease in the rock mass coarseness with a simultaneous precise separation of valuable and waste components.

Aug 1, 2013

"WELFARE…Welfare endeavor in connection with both the metal and the coal mines of Utah has shown gratifying progress during recent years and both the operators and their employees are deserving of much credit for the efforts put forth to better living, working, educational and receational conditions in most of the mining camps of the state.In the older metal mining camps of Utah, where the towns are incorporated and independent of the mining properties operating in the vicinity, less opportunity is pre¬sented for the companies to exercise efforts looking towards improved welfare conditions than is the case of camps located on company ground and under the full control of operators.Even in such camps, however, as illustrated in Bingham, the companies can do much to better welfare conditions. In this camp the Utah Copper Company has spent $800,000 since 1 920 in the erection of modern brick cottages, apartment houses and the Gemmell Memorial Club. The cottages and apartments have every convenience to be found in up-to-date city homes. The Gemmell Memorial Club, erected and equipped at a cost of $1 75,000, was provided by the company for the benefit of the Utah Copper Company employees living in the canyon and has been made the recreational center for the camp."

Jan 1, 1925

By G. Merazchiev

In the selection of copper ? molybdenum concentrates with the use of reagents containing sulfide ion ? sodium sulfide, sodium hydrosulfide etc for depression of copper minerals and pyrites, big part of depressor is oxidized by oxygen, which is dissolving in pulp during aeration with air in flotation machines and it is expended unproductively. This is the main reason for the big expenditures of depressor, reaching up 15~20 kg/t collective concentrate and the high exploitation expenditures for the copper ? molybdenum selection. Effective direction for lowering expenditure of depressor and increasing of the technical ? economical effectiveness of moly production is the conducting of the selection in nitrogen medium. In the paper are shown the results, obtained by applying of this direction in selection of collective copper ? molybdenum concentrate from the porphyry copper deposit ?Ellatzite? ? Bulgaria, in which the ratio Mo:Cu is over 1:120. In laboratory conditions, through comparative experiments in medium of air and nitrogen are defined: expenditure and initial concentration of NaHS in pulp for effective depression of copper minerals and pyrites; kinetics of flotation process of molybdenite; influence of pulp density; emf (negative milivolts) of pulp and the expenditure of nitrogen on tech-nological indexes of molybdenum flotation. When working in nitrogen medium decrease of NaHS in rougher molybdenum flotation from 40% to 45% is settled. When nitrogen is also fed in cleaner stages, the total expenditure of depressor is lowered by 64%. The quality of end molybdenum con-centrate is raised with over 5%. On the ground of the results of laboratory studies and of world practice data, an industrial installation for selection of copper ? molybdenum concentrate in nitrogen medium in Wemco inert ? gas machines.

Jan 1, 2014

By N. S. Dalal, X. Shi

"With a view of elucidating the role of glutathione (GSH) in the biochemical pathways of the chromate-exposure related carcinogenesis, we carried out electron spin resonance (ESR) spectroscopic investigations of the chromate-GSH redox reactions. The ESR measurements, employing spin-traps, provide evidence for the involvement of the glutathione (GS•) radical, as well as an isolable Cr(V)-glutathione intermediate. These results indicater a new mechanism for the reduction of chromate by GSH in cellular environment and help understand the (unexpected increase in Cr(VI)-induced DNA strand breaks at elevated GSH levels.We report here indirect electron spin resonance (EGR evidence for the involvement of the glutathionyl (GS) radical and direct evidence for a Cr(V) intermediate in the reactions of glutathione ¬(GSH) with chromate for the first time.. This work was undertaken to clarify the biochemical pathway of the reduction of chromate by GSH, since this reduction process is thought to be a critical step in the pathogenesis of the chromate-exposure related carcinogenesis. This follows from the literature reports which show that (a) Cr(VI)compounds have been proven to be carcinogens in laboratory animals as well as in human studies2-4, (b) Cr(VI) and not Cr(III) compounds are mutagenic 5-7, (c) Cr(VI) and not Cr(III) compounds can penetrate cell membranes 8.9 (d) the final state of Cr(VI) in cellular reductions is Cr(III)', (e) by itself chromate (or Cr(VI)) cannot be directly mutagenic since Cr(VI) is known not to interact with isolated DNA under physiological conditions 10, suggesting the significance of Cr(VI).reduction processes. One of the major reductants in cellular environments is thought to be the GSH, both outside and inside the ce11s 11-13. Other evidence for the role of GSH in the chromate toxicity is seen from recent studies showing that exposure of hamster cells to non-toxic levels of added selenite increases the levels' of GSH as well as the Cr(VI)-induced DNA strand beaks 14, and thatsuch DNA strand breaks in hepatocytes also change in direct proportion to their GSH content 15,16. These observations wereinterpreted as implying that the reduction of chromate by GSH, to some reactive intermediate is an important step in the chromatecarcinogenicity 15,16. The following reaction steps were,suggested 15, 16"

Jan 1, 1988

By Cao rong-jiang, Tang Xin-he

"In ordinary manufacture process of tungsten powder, a preferable intermediate product used is ammonium paratungstate (APT). The particle size of tungten powder made from it through W2OO58 is larger than 1. 0 um. In order to obtain ultrafine tungsten powder with narrow size distribution, a new type of tungstate, hydraziniull tungstate, was studied. Its formula is 5(N2H5)2O·12 WO.s , with tetragonal crystal structure of a=5.821 , c=18. 468. Three methods for preparing hydrazinium tungstate (ART) were set up and ART can be produced by current industrial APT process with little modification of operation and without any change of equipment.Under certain PH and operation condition of the solution from which ART was produced, an autoreduction of tungsten occured, which produced a lower valency tungstate with blue color when ART was heated at different temperatures, in N atmosphere, tungsten bronze, tetragonal W0290 and W02.7E could be obtained respectively. They all have the superiorities, in the production of tungsten powder, of superfine size and narrow size distribution [average size of 0.5um or even smaller.The rate of autoreduction of ART is very fast at elevated temperature. The reduction reaction, which gaves tetragonal WO290, could be handled smoothly without explosion. To research their behaviors at autoreduction temperatures and the products of autoreduction will be new advances of tungsten chemistry and may also serve tungsten industry with new processes and materials."

Jan 1, 1988