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By B Andrew, L Krois

Ground control systems, including ground control management, play an integral role in the effective and efficient extraction of copper ore at the Xstrata Copper û Mount Isa Copper Operations (MICO). Rock mechanics engineers and support technicians at Xstrata Copper have undertaken a wide range of investigations and actions over the past few years. Outcomes from this work have resulted in the evolution of ground control management practices on the site. Specific areas of improvement include the installation of efficient one pass ground control systems, greater application of sprayed concrete for areas requiring rehabilitation and the addition of new improved products, the removal of obsolete and less efficient products used in standard ground control practice. In some areas underground, the most effective methods to manage ground control hazards continue to be a variation on proven methods that have been in use for many years in the MICO. Ground control systems for developing through the basement contact zone are very similar to that developed in the late 1980s. Similarly, ground control systems have gone through repetitive evolution, whereby some systems fall in and out of favour subject to perceived costs. For example the pouring of concrete shuttering around drawpoints in poor ground conditions has recently been re-accepted as an effective means to manage this poor environment û despite having been previously cast aside as too expensive. Ground control management systems continue to evolve towards the goal of creating a workplace that is free of rockfall-related injuries and provide for higher levels of efficient and effective techniques by which ore is extracted from the ground.

Jan 1, 2005

By D. François-Bongareon

"In previous publications by the author, significant advances and generalizations of the theory of sampling of broken ores, prompted and confirmed by experimental results, have been presented. This paper shows how to implement these theoretical results in practice. The models to be used are reviewed, with a description of the various sampling parameters involved. Then the methodology for the experimental assessment of those parameters, including segregation factors, is described in simple and practical terms, along with the use of handy sampling protocol charts. Finally, the particularly important case of processing data from a sample-tree experiment is detailed, and examples of applications covering all situations and types of experiments are provided.IntroductionThe reliability of a sample of crushed material , i.e. the expected (average) deviation between its true grade and the true grade of the lot it comes from, mostly depends upon six factors:• the size (mass) of the sample (and to a minor extent, for small lots, the size of the lot);• the size of the rock particles (degree of comminution)• the nature of the mineralization at microscopic scale (i.e., within even the smallest particles);• the geological nature of the mineralization and mineral of interest;• the grade of the lot in the mineral of interest; and• in some cases, the state of segregation of the lot.In practice, one should first disregard segregation problems, and assess sample variability in the segregation-free case. Once the numerical parameters governing this variability have been assessed, then segregation factors can be assessed in turn. In the case of laboratory standard sample preparation procedures, segregation can usually be disregarded altogether."

Jan 1, 1993

By Aditya Rana, A. K. Mishra, M. M. Singh, N. K. Bhagat

Many cases of derailments, train accidents and traffic interruptions due to the slope failure and rockfall have been reported in the past on Konkan Railway trackline because of unstable rock slopes. The authorities installed stability enhancement measures such as wire netting, rock bolting and shotcreting which were found insufficient. The failed geotechnical measures prompted authorities to excavate the unstable slopes. Rock blasting is generally not preferred for the excavation of slopes along the transportation route. Stabilisation and widening of slopes by blasting need closure of the route for a considerable time. Discontinuing traffic on Konkan Railway route was undesirable as it connects two important port cities Mumbai and Mangalore. The paper presents an innovative directional controlled blasting (DCB) technique for excavating three unstable slopes (i.e. cuttings) in hilly terrain without disturbing the traffic. New empirical formulae for small geometry blasting to estimate burden and throw have been developed. A unique sequence of firing and excavation with powder factor varying between 0.04 and 0.39 kg/m3 irrespective of the actual free face was used for rock blasting. The process controlled the throw of blasted material over the track and resulted in a smooth and stable wall. The slope angle has been changed from 80 to 82° to 45–47° and probability of wedge, planar and toppling failures was eliminated. About 100 such accident-prone slopes (52 km cumulative length, 7% of total route) situated at discrete locations along Konkan Railway route were stabilised using the technique. No incident of rockfall and slope failures along these slopes has been observed after the stabilisation.

By Bora Derin, Onuralp Yucel, M. Seref Sonmez, Murat Alkan

"Latest stage in the production of boron carbide by metallothermic methods using magnesium was the leaching process. Boron carbide particles obtained by self-propagating high temperature synthesis contained several impurities such as magnesium oxide and magnesium borates after the metallothermic reactions. Removal of such contaminates by hydrometallurgical methods required to produce high purity boron carbide. Leaching by concentrated hydrochloric acid solutions resulted in the production of pure boron carbide together with high magnesium and boron containing solutions. Removal of such ions from the spent liquor was the necessity to have dischargeable solution. In this study, precipitation of magnesium and boron compounds from relevant chloride containing spent liquors and the production of saleable products was aimed. The effects of chemical reagents, pH of the solution on the precipitation efficiency of magnesium and boron compounds were investigated in the study. Chemical analysis and the characterisationof solid phases by using x-ray diffraction analysis were the latest stage.Introduction A variety of advanced ceramics, inter-metallic, organic and inorganic compounds, oxygen free single crystals, and polymers can be synthesized by using different SHS techniques [1, 2, 3]. In the SHS process, after initiation, reaction becomes self-sustaining and propagates in the reactant mixture. A high amount of heat which is generated during the process accelerates the reaction rate and thus it makes the process highly productive and economically feasible for different production scales. After the SHS process obtained powder mixture needs to reacted with acidic solutions to purify the product. In this case B2O3 was reacted together with C and Mg to synthesis fine B4C powder resulted in the production of MgO as well according to the Eq. 1 and then MgO was removed from the mixture by leaching with the concentrated HCl solution as shown in Eq. 2, respectively [4, 5]."

Jan 1, 2008

By C. Richard Tinsley

Investment activity in the Pacific Rim of Fire has seen a phenomenal surge from epithermal gold exploration. Individual countries are attractive because of lower up-front minerals lease costs (United States, Canada), better geological prospects (Chile, Indonesia), or cheaper equities (Australia). Since the October 1987 stock market crash, large companies are shedding minority joint venture interests to focus on core businesses. Some vertical integration is evident in Japanese coal investments in the Pacific Rim. This article does not cover the aluminum industry oligopoly, which is multinational in character. Nor does it cover the many Canada to US minerals investments. It will be interesting to see if the new US-Canadian free trade treaty will reverse that investment flow. Cross-border investments The following examples should dispel any doubts about the significance of cross-border investment in the Pacific Rim. BHP, Australia's largest public company, has invested $US 4.5 billion in the JS for the following transactions 1984 $2 billion Utah Minerals 1984 $500 million Energy Resources 1985 $745 million Monsanto Oil 1987 $400 million 50.7% Hamilton Oil 1989 $378 million Pacific Resources Placer Dome, mainly through 76% owned Placer Pacific, has the following gold mine developments in hand including the date the project began, Placer Dome's ownership, project name, its location, and capital expenditures: • 1985, 53.1 %, Kidston, Queensland, $A 139 million; • 1989, 37.9%, Big Bell, Western Australia, $A135 million; • 1989, 60.6%, Misima, Papua New Guinea, $C252 million; • 1990,45.5%, Granny Smith, Western Australia, $A95 million; • 1991, 50%, La Coipa, Chile, $US276 million; and • 1991, 25.3%, Porgera, Papua New Guinea, $C1.1 billion. Australia's Western Mining Corp. (WMC), through a foray of off-market acquisitions in late 1987, acquired con¬trol of five Canadian gold companies for a $A488-million outlay ($C452 million) as follows:

Jan 1, 1990

By Victor V. Karmazin

"The appearance of the precise equipment for analysis of results of the laboratory tests with using of the computer processing allows raising accuracy of the estimation of the expected indexes of the mineral processing. Certainly, laboratory tests will not be able to substitute completely industrial ones, but allow reducing the amounts of the industrial tests, that vastly reduces the cost of technological forecast and preparation of data for projection.Calculation of the potential indexes of mineral technology (mass yields and the metal content in products) is fulfilled on the base of results of measurements of the mineralogical liberation parameters using special formulas.The quality of the concentrate ßc = a + ?l • ?s • ?i (ßt - a) can be achieved on a level of the theoretical metal content of a mineral - ßt only if coefficients of mineral processing, of liberation ?l and selectivity ?s of grinding, effectiveness of separation, will reach 1 (a - metal content of the row ore).Increase ?l by overgrinding automatically decrease ?s, and only by destroying of particles of ore along surfaces of accreting of minerals (?i = 1) and when values of all three coefficients will aim to 1, then ßc ? ßt.The degree of liberation of the useful mineral is the ratio of mass of free grains of the useful mineral in the product to general mass of the same mineral in this product. The factor of the liberation, which is defined by curves of dressability by angle of slop of the curve of the elementary faction - ?, is Kr=1 – tga. Kr changes from 0 to 1 when a changes from 45o to 0o. The liberation is reached by grinding of the material, although degree of the liberation, as a rule, is lower than the degree of the grinding."

Jan 1, 2003

By Niels Hansen

Dispersion-strengthened aluminum products consist of an aluminum matrix containing finely distributed ceramic or intermetallic particles. Examples of the two types of product are SAP, in which the dispersed phase is aluminum oxide, and materials made from atomized aluminum alloy powder, in which the dispersed phase can be FeA1, particles.' A fundamental difference between the two types of product is that the elongation of aluminum/aluminum oxide products decreases with increasing temperature, whereas the elongation of aluminum- FeA13 products, like that of aluminum alloys, increases with increasing temperature. As regards the structural stability, aluminum/aluminum oxide products are stable to temperatures above 600° C as aluminum oxide does not react with aluminum, whereas prolonged heating at above 400°C of aluminum-FeA1, products leads to coarsening of the intermetallic phase and loss of strength.' On the basis of these results it is supposed that a dispersion-strengthened product combining strength, ductility, and stability at elevated temperatures may be obtained if the dispersed phase reacts with the matrix in such a way that the reaction does not proceed at any significant rate at the application temperature. Different ceramic or intermetallic compounds may be selected as the dispersed phase, and, as alloying of the matrix phase may also influence the reaction, many possibilities exist for each metal. In the present study, aluminum products containing different oxides have been examined. For a reaction to take place between the dispersed oxide and the aluminum the free energy of formation of the oxide (MeO) must be greater than that of aluminum oxide; the difference should, however, not be too great in order to limit the reaction rate. Furthermore the aluminum alloy formed when aluminum reacts with the dispersed oxide should have a melting point near

Jan 1, 1969

By T. S. Lundy, C. J. McHargue

HE diffusion rate of v48 in single crystals of bee vanadium has been determined at temperatures from 1002° to 1888°C. Standard techniques of lathe sectioning were used for specimens annealed above 1500°C while sectioning by grinding was used for specimens annealed at lower temperatures. As will be seen, the lower-temperature data is enhanced on an Arrhenius-type plot relative to values expected by extrapolation of the high-temperature data. Single crystals were obtained from Linde Co. In Table I the analysis supplied by the vendor is compared with an analysis at Oak Ridge National Laboratory of a sample after a diffusion anneal. The isotope v4' was prepared by the Isotopes Division of Oak Ridge National Laboratory. Proton bombardment of a titanium target in the 86-Inch ORNL Cyclotron was followed by a carrier-free chemical separation. Nineteen specimens, 1/2 in. diam and 3/8 in. long, were cut from the as-received vanadium single crystals. Each specimen was machined with the flat face perpendicular to the longitudinal axis. Specimens were polished through 1/0 emery paper and were etched with 25 pct HF-10 pct H2SO4-10 pct HNO3-55 pct H2O. The polishing and etching steps were repeated until a satisfactory surface finish was achieved. The isotope was electroplated onto the specimens from a neutral solution. Counting rates of the deposited layers were approximately 100 counts per sec. At temperatures above 1200°C specimens were annealed in a tantalum resistance furnace under an argon atmosphere. Temperatures were measured with a Pyro micro-optical pyrometer and a Pt-Pt 10 pct Rh thermocouple. At lower temperatures the specimens were sealed in evacuated quartz ampoules and annealed in Kanthal wire-wound horizontal tube furnaces. A severe reaction occurred at 1200°C between the quartz and the vanadium. This

Jan 1, 1965

By T. S. Lundy

Anand and Agarwala recently determined diffusion coefficients by the residual activity (Gruzin) method for several tracers in large-grained, high-purity aluminum. D values at any particular temperature in the range of 400" to 630°C were about four orders of magnitude lower for cd115, 1n114, sn113, and pdlm than for Ag. Corresponding values for Do and Q in the Arrhenius equation were also quite small. It was pointed out previously that unusually low diffusion coefficients within the region of a specimen near a free surface may be the major cause of such anomalous results for impurity diffusion in silver and in aluminum.44 Anand and Agarwala considered this possibility but rejected it because their penetration profiles were "homogeneous" and "yielded diffusion coefficients obeying the Arrhenius plot". Neither of these two criteria satisfactorily prove or disprove the presence of a near-surface effect. Such can be accomplished only by direct serial sectioning in which the chips ground from the specimen are assayed for tracer content. In fact, such experiments always should be done prior to use of the somewhat indirect Gruzin method where the finer details of the transport process cannot be determined. There have been several other reports of unusually low D, Do, and Q values for impurity diffusion in silver and aluminum.1"4 It is interesting to note that all of these studies made use of the Gruzin method. Also, in all cases where the same systems were examined by use of a direct serial sectioning technique, large near-surface effects were observed. One must conclude therefore that the reported anomalous diffusion parameters for cd, In114, sn113, and pd in aluminum are due to some near-surface effect, while the results for Agl10 indicate that no such effect was encountered for this system.

Jan 1, 1969

By R. P. McLaughlin

EXACT information as to performance of the gas lift from the mechanical engineering standpoint is hard to obtain. Several hundred wells are now producing in California fields by means of the gas lift, and a survey of results shows that the gas lift has increased production at these wells by approximately 60 percent. Similar or even larger figures describe results in Mid-Continent fields. Such an increase in output of oil is so satisfactory, to the average oil producer, that it may not encourage investigation looking to more efficient operation. The cost of lifting oil by compressed gas varies from 3 c. to 15 c. per bbl. of oil, depending upon the efficiency of the gas lift. A difference of 10 c. or 12 c. per bbl. of oil is immediately noticed by an oil operator and the cost in production is as real to him as is the price of his product. Therefore, the efficiency of gas-lift process deserves more consideration than it has been given in some quarters. It has been found that there is a wide variation between different operators and at different wells in the amount of gas used per barrel of oil lifted. Some of the most efficient operations show oil being lifted with only slightly over 400 cu. ft. of gas per bbl. of oil.1 On the other hand, wells are being flowed and using as high as 3000 cu. ft. per bbl. of oil. The cost of compressing gas to 300 or 400 lb. varies from 3 c. to 5 c. per 1000 cu. ft. of free gas. This figure has been obtained from a number of sources and as a matter of fact is the basis of actual business transactions involving gas compression. The cost of lifting oil with compressed gas is thus determined.

Jan 12, 1926

By S. Ramachandran, R. A. Walsh

Many investigations have shown that the manganese enhances the deoxidation power of silicon. Here it is suggested that this phenomenon could be explained in terms of the formation of impure silica. Data of Hilty and Crafts on the Fe-Mn-Si-O System has been evaluated on the basis of the reaction S_i + 20 = (SiO2) where (SiO2) denotes silica of variable activity. The activity of silica in this system is a function of aMn/aSi and the temperature, and can be described by the equation 12700 l°gaSiOz = -6.85+ - - 0.5 log aMn /asi PRACTICAL melting experience has shown that it is helpful to maintain a certain range of Mn/Si ratio in deoxidizing quality alloy steels. Herty,1 as early as 1932, reported a strong association between manganese and silicon as did schenck2 and Korber and Oelsen3 in later work. More recently, Hilty and crafts4 have studied the solubility of oxygen in the Fe-Si-O system, both with and without manganese. Their study confirmed the marked ability of manganese to increase the deoxidizing power of silicon. This phenomenon has remained unexplained in the liter,ature5 since it has been shown that manganese has virtually no influence on the activity coefficients of silicon or oxygen.= In this paper, an explanation for the role of manganese is suggested and equations are devised for quantitatively describing this influence. DISCUSSION Hilty and crafts4 equilibrated their melts under an argon atmosphere and the system established equilibrium with a self-generated slag which was not always the oxide of lowest free energy. Drawing on the early work of Korber and Oelsen,3 it was reasoned that the formation of complex Fe-Mn-silicates

Jan 1, 1963

By R. Schuhmann, J. Th. Overbeek, P. L. De Bruyn

W. E. Ewers (Commonwealth Scientific and Industrial Research organization, Melbourne, Australia)— Any attempt to elucidate further the meaning of the contact angle, particularly if it deals with the magnitudes of those mysterious quantities rsa and YRL, is certain to receive attention from those interested in the fundamentals of flotation. It is imperative, therefore, that attention should be drawn to a serious defect in the treatment by de Bruyn, Overbeek, and Schuhmann. Their Eq. 5 dy = — ld/u — Th2odiH2n states correctly the relationship between the change in surface free energy dy, the surface excesses Tx and Th2o of the components x and H2O and the changes du, and dph2o in the chemical potentials of these components. This equation applies for constant pressure and con- stant temperature and for the interface of the solid in contact with the solution of X. The relation remains valid when 1.1 is defined so that TH2O becomes zero and the equation becomes dr = — r:dur [17] From this equation de Bruyn et al. correctly concluded that increased adsorption of the collector at the liquid solid interface would reduce the interfacial energy ysl. Their second conclusion, however, that an increase in the contact angle, corresponding to a greater decrease in rsa than in rsL can be attributed to greater adsorption of X at the solid-air interface than at the solid-liquid interface is quite unjustified. The portion of the solid surface from which the collector solution has been displaced by air must be considered in terms of the equilibria between the gaseous phase and the surface. If the pressure and temperature

Jan 1, 1955

By H. E. Stauss, G. Sandoz

THE purpose of this note is to draw attention to the possibility that a melt may be contaminated by a material not in direct contact with it by means of gaseous intermediate agents. In recent years silicon has assumed a position of importance because of its use in rectifiers and transistors and close attention has been required to control of both purification and contamination during all stages of preparation.' This note reports the observation that a graphite heater may have contaminated silicon ingots without direct physical contact through reactions that developed gaseous products. Several ingots made with the equipment of Hino and Stauss,2 using a graphite heater in a dried helium atmosphere, were found to have a small amount of a very hard substance on the free surface. X-ray analysis by F. W. von Batchelder showed the sub- stance to be Sic. Similar contamination was not found when the heater was tantalum, indicating that the carbon had not come from an original impurity in the silicon powder. One source of the carbon could have been volatile matter released from the graphite heater. This heater had been used about ten times at the time of the observations. A second source of carbon could have been a direct reaction between the quartz crucible and the graphite heater to form CO, or an indirect reaction involving a crucible-melt interaction and volatile SiO as an intermediate product. Such reactions should have developed Sic on the heater; and in fact a yellow powder did form on the inside of the graphite heater although its composition could not be determined. References 'H. C. Torrey and C. A. Whitmer: Crystal Rectifiers (1948) Chapter 10. New York. McGraw-Hill Book Co. 2 J. Hino and H. E. Stauss: Trans. AIME (1952) 194, p. 656; Journal of Metals (June 1952).

Jan 1, 1954

By M. Wu, A. Kharicha, J. Bohacek, A. Ludwig

"During the horizontal spin casting of rolls, vibrations and mould deformations seems to have a significant effect on the final quality of the product. Sources for vibrations can be found in the poor roundness and a static imbalance of the chill itself. The bending of the mould axis is also considered. Both, vibrations and axis bending, are used as an input for CFD simulations of the flow dynamics of the liquid metal inside the rotating cylinder. The aim is to study the feedback of the free surface behavior in terms of wave propagation and various wave shapes. Introduction The horizontal spin casting process (HSC) is a casting process that has several advantages over the traditional gravity casting processes. Centrifugally cast products have a high degree of metallurgical purity and homogeneous microstructure. A significant gain is observed for the rupture strength, the rupture strain, and the Young modulus. These properties naturally depend on the centrifugal force and thus, the best mechanical properties can be found at the largest distance from axis of rotation. However proper selection of the angular frequency has to be done in order to prevent the so-called ""metal rain"" i.e. metal droplets can fall down from the upper part of the cylinder due to a too weak centrifugal acceleration. In the same time excessive speeds can lead to the appearance of longitudinal cracks caused by the hoop stress in the initially solidified layer. From empirical knowledge other parameters have important influence on the casting products, it includes the pouring temperature, the pouring rate, the mould coating etc. Recently the presence of natural or forced vibrations have been identified as possible additional factors to be taken into account [1-2]."

Jan 1, 2012

J. L. JONES,* Pittsburgh, Pa.-If a nickel anode is cast under commer-cial conditions, will it contain nickel oxide? Will the nickel oxide affect the rate of corrosion in a double sulfate solution; or will the nickel oxide dissolve in a double sulfate solution? I would also like to ask whether a 98 per cent. pure nickel anode will corrode as fast as a 96 per cent. nickel anode; whether electrolytic nickel will corrode less rapidly than nickel containing a small amount of carbon; and whether the materials some-times used in coating molds for casting nickel anodes will affect the rate of corrosion of the anode? In other words, whether an electrically non conducting coating is likely to be present that will prevent the nickel anode from corroding rapidly. JOHN F. THOMPSON.-The nickel oxide will not dissolve in the double sulfate solution, as far as we know. We do not make the ordinary nickel anode of commerce, but we supply nickel to the nickel anode makers. Those makers almost invariably buy a high-carbon nickel shot, ranging around 0.45 per cent. carbon. In their process, they even further, car-burize it so as to get nickel that will melt easily and be fluid enough to fill the mold, so that the ordinary cast anode on the market is unquestion-ably oxide free. The only time that such an anode will have oxide will be through an error in melting. Some cupola makers of anodes have had trouble with oxidation, but as a rule the anodes are thoroughly carburized; so much so that they probably carry a couple of per cent. of carbon of which around. 1.6 per cent. is graphite.

Jan 12, 1919

By M. H. Lampen

The SILAG Material Tracking System MTS monitors and controls the complete material flow throughout the plant - and even companywide. The customized system developed by Siemens especially for bulk material handling applications enables companies to track bulk material from the mine to the harbor, to the steel mill or to the power plant. All relevant material data is available at every single step of the material’s journey. SILAG is an open, scalable system based on Windows NT / 2000. Using standard interfaces of Windows NT, like API, ODBC, SQL and socket technology, the system is very flexible and can easily be tailored to meet different requirements. SILAG can be used as a stand-alone solution or - if complete plant control and visualization is required - as a component of a fully integrated automation system with the Win CC HMI system and the PCS7 process control. In contrast to conventional material tracking systems, SILAG offers many advantages. - The Material Tracking System is an object oriented, online to the process, linked system. All changes in the plant during operation e.g. selecting another conveyor route, start and stop etc. will be automatically detected and will influence the calculation. - The systems is able to split and blend material (quantity and quality).Measurements of tonnage, volume or quality analysis can be linked online to the system. Each movement of material is monitored by the system and leads to online recalculations of the images and databases. - All material data is based on 3D-stockpile images, which are calculated by an internal mathematical model based on quantity and quality information. - If a laser scanner is available on a stockyard machine it can be taken to update the profile directly from the piles. - Efficient control and report functions are available on each, free selectable point of the total plant.

Sep 1, 2001

By O. E. Kiessling

Viewed from the standpoint of an economist, the task which faces the petroleum producing industry is one of intelligent adjustment so that technology can perform the job of efficient exploitation, while at the same time the interests of producers and consumers remain adequately protected. The crux in the task of making this adjustment lies in the difficulty of arranging the instrumentalities of production to accord with the physical characteristics of oil. For example, oil is exploited under a competitive economic system based on private ownership and contract, with the hope that profits will attract capital and enterprise, and with competition supposedly acting as the regulative factor. Whether such a scheme of industrial organization works is partially dependent upon the ability of the producer to withold or produce his commodity as he sees fit, in accordance with market demand. But in the oil industry, the enterpriser does not have complete control over the expansion and contraction of production, for, because of the decisions of the courts that ownership in oil depends upon its possession, desire for immediate output becomes the controlling force in production. Consequently, the theoretical commands and restraints of free enterprise are not operative because there is no security of property, and the result is loss due to the following economic maladjustments: (1) Production not completely responsive to price control. (2) Production at excessive cost. (3) Loss of oil, a highly exhaustible natural resource. If economic maladjustments are to be eliminated, there should be a change in the organization of production so as to provide efficient exploitation of the oil and at the same time to insure individual property interests. The latter is necessary if economic considerations are to become primary factors in regulating production. To attain these ends, the entire pool should be developed as one big engineering project and some scheme

Jan 1, 1928

By A. H. Redfield

BITUMENS have been defined by Abraham1 as substances of variable color, hardness, and volatility; composed principally of 'saturated hydrocarbons, substantially free from oxygenated bodies, sometimes associated with mineral matter; the nonmineral constituents being fusible and largely soluble in carbon disulphide. The principal bituminous substances other than petroleums known to commerce are: (1) native asphaltites, such as gilsonite, grahamite, and glance pitch, distinguished by their hardness and relatively high fusing point; (2) native asphaltic pyrobitumens, such as wurtzilite, distinguished by their infusibility and comparative insolubility in carbon disulphide; (3) mineral waxes, such as ozokerite, distinguished by their high content of crystallizable paraffins; (4) native asphalts, containing varying amouqts of mineral matter, distinguished by the comparative absence of crystallizable paraffins; and (5) bituminous residues obtained from the distillation of petroleum. GILSONITE Gilsonite, a black native asphaltite 98 to 99.9 pct pure, characterized by a hardness of 2 (Mohs), a specific gravity of 1.01 to 1.10, and melting point of 230° to 400°F (K and S), is mined commercially only in northeastern Utah. It occurs in parallel, almost vertical veins, from a few inches to 18 ft wide and 8 to 30 miles long, that cut across the Tertiary limestone and shale of the broad Uinta Basin. The bitumen is believed to have been distilled by heat from oily material in the underlying Green River shale. At the Rainbow mine of the American Gilsonite CO.,† the gilsonite, formerly extracted in an opencut by a system of slopes and benches, is now mined by shafts and horizontal drifts. Little timbering is required. The mining methods of the Raven Mining Co., Chicago, and of the American Asphalt Association and the Utah Gilsonite Co., both of

Jan 1, 1949

By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2'-bipyridine (bipy) (1), 6-alkyl-2,2'-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2'-bipyridine (bipyR') (3), R' = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

1. Any society of undergraduates at a technical school, comprising students in any branch of engineering, metallurgy, chemistry, geology, etc., may be recognized by the Board of Directors in its discretion as an Affiliated Student Society, and its name, together with the names of its president and its secretary, may be published in Mining and Metallurgy or the Directory of the Institute. The members of such a society will not be named individually on the membership list of the Institute, but may at any time be proposed for election as Student Associates or Junior Members of the Institute, in the usual way. 2. Membership in an Affiliated Student Society, certified by the official representative thereof, and accompanied by suitable testimony as to character and qualifications, will have special weight with the Membership Committee of the Institute, in its consideration of the proposal of a candidate for membership. The Affiliated Student Societies receive the following privileges: 1. A copy of Mining and Metallurgy free; 2. The use of Employment Service; 3. The use of Mining and Metallurgy for publicity purposes, such as printing notices of their activities, etc.; 4. Assistance in obtaining speakers for their meetings, lists of moving-picture films, etc. To retain the privileges of the Affiliated Student Society, its officers must keep in touch with the Secretary of the Institute and advise him of its activities. The foregoing plan is not confined to students in mining engineering or metallurgy. Any undergraduate society of engineers may avail itself of the privileges offered. Societies desiring to be recognized as Affiliated Student Societies are requested to make application to the Secretary of the Institute, giving particulars as to the nature, membership and officers. The following list gives the names of the Affiliated Student Societies as of December 1, 1929, and their presidents and secretaries.

Jan 1, 1929