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By D. R. Parker

"This paper canvasses emerging trends in public policy and law, which may influence the zinc industry's interest in recycling. There are forces at work beyond direct economic benefits that will drive recycling of zinc, including:• corporate determination to pursue sustainable practices and product stewardship.• public perceptions and pressure,• customer and investor demand,• workforce recruitment, and• protection and expansion of marketsIn this paper, these ""indirect"" forces are examined with particular focus on the zinc industry: It is concluded that, in today's world with an emerging precautionary approach to policy and law making, public perception concerning the environmental implications of metal products, and the need to conserve resources for future generation, a strong industry response is required."

Jan 1, 2000

By V. I. Ryaboy, V. P. Kretov, S. E. Levkovets, I. V. Ryaboy

"Using the flotation of a gold-containing ore from a deposit in Kazakhstan as an example, we have conducted a study designing dialkyldithiophosphate collectors, in addition to xanthates, for the flotation of hard-toenrich gold-containing ores to increase gold recovery.The increased flotational ability of the dialkyldithiophosphates was determined by their surface activity at the liquid-gas interface and their hydrophobic ability, the changing of which allowed us to control the collecting power and selective ability of the dialkyldithiophosphates. The studying of the surface activity of aqueous solutions was done using the stalagmometric method and the evaluation of the hydrophobic ability was done in percentage of the relative value of the zinc ion binding in the solution in standard conditions.Studying the influence of surface activity in our designed dialkyldithiophosphate collectors, with their close hydrophobic ability, showed that even with a small increase in surface activity in their aqueous solutions, gold recovery increased by 2-3% in laboratory conditions. Using this enabled us first to apply the dialkyldithiophosphate collector BTF-161 at a plant in Kazakhstan, and then to introduce the specially designed dialkyldithiophosphate collector BTF-163, which has been in use since. Further study of dialkyldithiophosphate activity based on this concept showed us that for the range of short-chain dialkyldithiophosphate collectors with a chain length of up to ?5, the effectiveness of ore processing became lower the higher their surface activity got, with relatively small differences in their hydrophobic ability. For long-chain dialkyldithiophosphates with a chain length of over ?5, ore processing effectiveness increased with the increase of their hydrophobic ability.Based on these studies, a new effective dialkyldithiophosphate collector, BTF-1517, was designed. Using this reagent in continuous gold recovery tests allowed us to reach an 84.21% recovery with a concentrate quality of 15.66 g/t, while using the applied collector BTF-163 in similar conditions led to the recovery of 82.87% with a concentrate quality of 15.65%. As a result, the Kazakhstan processing plant decided to conduct industrial tests with the BTF-1517 collector."

Jan 1, 2018

By J Player, R de Vries, E Villaescusa, H Saw, R Hassell

The use of cemented rock fill (CRF) for support of open stope walls has increased in the Australian underground mines operations over the last five years due in part to its low capital cost. In open stoping the exposed CRF masses require adequate strength and stiffness, in order to resist the forces and to limit the displacement associated with movements in the rock mass surrounding the excavations. The CRF material preparation often involves the use of large particles, either from crushed rock or from development mining waste sometimes up to 1 m in diameter. However, the use of waste rock, which has a poorly graded particle size distribution may not achieve the required minimum target strength due to segregation and large air voids within the fill mass. This paper describes the optimisation of CRF strength by either crushing the waste rock or the addition of sand to the mix. Both methods increase the level of fines in the mix design. Cylindrical samples having 400 mm diameter and 800 mm heights were prepared for uniaxial compressive strength (UCS) testing. The UCS test was determined using the Western Australian School of Mines (WASM) large-scale static test frame. The laboratory results were compared with a database of large-scale CRF strength mixed without sand from a number of mine sites around Australia. The comparison shows a significant strength development in the CRF mixing with addition of sand for a given cement percentage. Due to the higher strengths achieved by the addition of sand and the crushing of the waste material these CRF types require less cement to achieve the same strength. This has the potential to improve the overall economics of open stope mining due to less dilution of the exposed fill mass.CITATION:Saw, H, de Vries, R, Player, J, Hassell, R and Villaescusa, E, 2017. Optimisation of cemented rock fill strength for open stope support, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 85–90 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

In the estimation of recoverable resources, geostatistical techniques such as Multiple Indicator Kriging require a change of support correction to derive theoretical recoveries based on an assumed level of mining selectivity. The change of support models most widely used in practice entail model based generalized corrections either on a global or local basis. Examples include the affine and indirect lognormal methods. Change of support corrections derived empirically through short-scale conditional simulation realizations often show notable differences compared with theoretical corrections determined using model variogram parameters. The existing changes of support models are reviewed and an alternative method is proposed.

Jan 1, 1999

By Maurice Hall Haycock

ONE result of the higher price of gold has been the exploitation of many low-grade deposits, the successful treatment of which depends upon obtaining high recovery of the contained gold. Modern methods have made it possible to recover gold from many ores formerly regarded as impossible to treat economically, but in order to apply these methods efficiently it has become desirable, and indeed in many cases indispensable, to gain precise information concerning their mineralogical and physical character. The most successful means of doing this is the use of the reflecting microscope. Reflecting microscopes had long been employed by metallurgists for studying polished surfaces of iron and steel when, thirty years ago, Dr. W. Campbell, of Columbia University, advanced the idea of using similar methods for studying opaque minerals (1). The immediate result was the completion of two microscopic studies, the first on Cobalt silver ores (2) and the second on Sudbury nickel ores (3). The idea was surprisingly slow in being adopted, and not until 1911 did it begin to spread through the universities of this continent. From then on, ore microscopy, or 'mineragraphy', made rapid progress, and, during the next fifteen years, research in universities of North America and Europe led to the development of somewhat specialized apparatus and technique. This phase of development, which resulted largely in contributions of a descriptive nature, furnished a mass of data from which the possibility of economic applications was soon recognized. Ore microscopy became an aid to the mining geologist in solving many problems of ore deposition. This soon led to its application in the study of ores and mill products in connection with their treatment. Its usefulness in this latter field has been very marked and has led to its widespread adoption by the mining industry.

Jan 1, 1937

By Guanghui Li

In the paper, the recovery technology of gallium from zinc-leaching residue by cold-bonded coal-based direct reduction process following magnetic separation was developed. The results show that the scattered metal Ga can be concentrated obviously after the reduction of zinc-leaching residue briquette and magnetic separation of reduced product. At the same time, the volatilization of Zn in the residue is enhanced during the reduction. When the residue, bear¬ing 18.60% Zu.21.18% Fe and 527 g/t Ga, was reduced with coal at 1100°C for 150 min, the results of Zn volatilization of 9842% and Ga recovery of 89. 10% were obtained in reduction. After magnetic separation of the reduced product, the concentration of Ga in sponge iron is 2164 g/t, and the separation recovery of Ga reaches 92.42%. The enriched mechanism of Ga during reduction -separation process was studied by using electron microscope, scanning elec¬tron microscope, energy spectrum and mineralogical analysis. The investigations show that there is no formation of independent phase of Ga during reduction process. The Ga occurs mainly in metallic iron phase (the concentration of Ga in metallic iron phase is 0.04%-0,4%), in addition, there exists a little Ga in poorly crystalline sulphide (o.08%-0./5Y& Ow). But Go does not exist in most of glass and silicate phase. The affinity of Ga for metallic iron is the enrichment basis of Go in reduction, and it is also in favor of recovering Go during magnetic separation. Key Words: Gallium Zinc-leaching Residue Cold- Bonded Direct Reduction

Jan 1, 2003

By P. E. Cavanagh

"The Davis tube test has been used for many years as a laboratory method for determining the magnetic iron re-coverable from a magnetite iron orebody. This paper de-scribes a method for determining the recoverable iron from ores of the Labrador Trough type, with the usua1 flow sheet utilizing spirals followed by magnetic separation.The mechanical structure of a metamorphosed iron ore, resulting from recrystallization over long periods of time, is the basis for the laboratory method developed. Similarities between the structures of such recrystallized ores and the structure of annealed and recrystallized steel are noted.A laboratory technique to determine the size of the different grains of gangue and iron ore minerals is de-scribed and the application of this information to arrive at recommended grinding techniques and flow sheets is demonstrated. The use of the method to determine recoverable iron in such ores is compared to actual iron recovery in the pilot-plant and commercial concentrations of the same ore.The use of a specified lower limit of recoverable iron as determined by this method, in order to design open-pit limits, achieves practical results when compared to designing a pit based on an arbitrary lower limit of total soluble iron. The Ungava Iron Ore deposits are used in giving an example of the resulting pit design changes."

Jan 1, 1968

By E. J. Mayhew

Bentonite and newly discovered deposits of sepiolite, saponite, and hectorite are now being processed and marketed from the Amargosa Valley of Nevada. All of these deposits are large. The bentonite has been known for decades and is the whitest known. The only other sepiolite deposit is in Spain. The only other commercial hectorite deposit is at Hector, California. No other saponite deposit is known. All the components except bentonite are hydrous magnesium silicates. The bentonite is mixed layer Na-Ca. All the materials have characteristics unique to their locale and type, such as high yield point for drilling muds and liquid suspending agents. The sepiolite has geothermal stability. Figure 1.

Jan 1, 1979

By Z. Cheng, Y. Han

"For non-sulphide minerals such as oxidized minerals, fluoride minerals, and oxysalt minerals, there are generality in the molecular structure of their floating collectors, and similarity in crystal structure of the minerals. In the paper, adsorbing mechanism of these collectors on the surface of these mineral particles in different pH pulp was investigated by means of Pauling's rules & valence bond theory, Valence-shell electron pair repulsion theory (VSEPR) theory, Crystal and ligand field theory, and quantum chemistry simulation by DMol3 and CASTEP modules of Material Studio software. Besides, the role and status of hydrogen bond in the floating adsorption mechanism were studied emphatically, and the confirmation and characterization of hydrogen bond were explored also based on the test results. What is more, the conclusion “the effect of hydrogen bond can not be overlooked in adsorbing mechanism of flotation collectors on the minerals” and a new viewpoint of multi-polarity collaboration and hydrogen bond coupling were summarized eventually based on analysis of the measurements. Finally, a novel collector 2-Amino-3-Methyl Heptyloxy-Propylamine (AMHP) was developed based on the new viewpoint of molecular structure design, and its collecting performance was exhibited.INTRODUCTIONWhen it comes to the recovery of flotation, it is necessary for researchers to investigate the flotation mechanism of collectors. In traditional theory, when collectors were used to collect minerals, the attractions between collectors and minerals were divided into chemical, electrostatic and physical attractions (Wills, B.A., 2006). Especially, because of the reaction between sulphide minerals and sulphydryl collectors is complex and various mechanism has been proposed (Yoon and Basilio, 1993), when collectors were used to collect non-sulfide minerals, it can be classified into oxyhydryl anionic collectors and cationic collectors. In traditional theory, the adsorption of oxyhydryl anionic collectors were due to water-repulsion, and the adsorption of cationic collectors were due to electrostatic attraction between the polar head of the collector and the charged electrical double layer on the mineral surface (Wills, B.A., 2006)."

Jan 1, 2018

By S. K. Pan

The process flow-sheet adopted in treating hematite iron ore in India through wet circuit generates not only 15-25% slime of Run-of-Mine (ROM), but also results in loss of very high quality fine iron ore particles along with it. As the reserves of hematite iron ore is depleting, it is necessary to explore the possibility of upgrading other types of low grade iron ore and slime for recovery of iron minerals; extensive research in this field is being carried out. While beneficiation of low grade ore is yet to be established, slime beneficiation has been quite successful and many installations of slime treatment plant are underway. In SAIL mines, the slime is mainly the discarded particles from Classifiers, which are less than 0.2 mm sizes. R& D initiative has been focussed on the beneficiation of the slimes (49-60% Fe, 3-10% Al2O3 & 4-10% SiO2) of Dalli mines to generate concentrates assaying 62-64% Fe, 2-3% Al2O3, 3-4% SiO2 and a few innovative facilities for the same has been introduced at this mines of Bhilai Steel Plant (BSP). At Dalli mines, the slime is of very poor quality. A typical slime analysis assays 48.54% Fe, 15.1% SiO2, 8.5% Al2O3 and consists nearly 60% (by wt.) particles less than 38 micron. Slime analysis revealed substantial quantity of very high density mineral particles, those causes jamming of Thickener due to faster settling. A novel technique has been implemented to classify the concentrate ore particles from the gangue mineral particles by processing through Fluidized Bed Classifier (FBC) system, which is a gravity concentrator, to treat 50% of the slime generated and the rest is treated through de-sliming hydro-cyclone followed by Medium Intensity Magnetic Separator (MIMS). A special self-vibrating launder has been designed and introduced into the system to recover tiny iron ore particles, which could not get captured by the permanent Neodymium rare earth magnet in MIMS. The classified iron mineral particles from FBC are further treated in a battery of hydro-cyclones followed by modified Slow Speed Spiral Classifier (SSSC) unit. Multiple feed entry system to the SSSC unit is unique and use of particular feed entry point depends on the desired quality of the product and thus converted to a beneficiation equipment rather than mere de-watering unit. By processing slime in FBC system, the valuable iron ore particles with 62.5% Fe, 5.2% SiO2, 2.23% Al2O3 has been recovered from the slime at a material yield of 30%. And very high valued concentrate particles with more than 65% Fe has been sorted out through the magnetic separation route. The overall extra production of beneficiated slime concentrate is 40-45 tph with 63-64% Fe from a slime feed of 120-130 tph solid. This paper outlines few new approaches in iron ore slime beneficiation at Dalli mines for maximum recovery of valuable minerals. Keywords: fluidized bed classifier (fbc), iron ore slime of dalli mines, medium intensity magnetic separator, slow speed spiral classifier (sssc)

Sep 1, 2012

By John F. Oyler

The performance of high alumina refractory subjected to high compressive loads and high temperatures is an area in which operating experience is quite limited. This paper documents the results of five months of operation of a combustion chamber lined with 83 pct alumina brick subjected to compressive stresses as high as 45psi and hot face temperatures of about 2750°F. It also describes a method for predicting long term subsidence results based on the limited information available in standard hot load limit tests. Descriptions of the chamber itself and the pilot plant upon which its design was based are included.

Jan 1, 1978

By A. S. Tawadrous

Fines are produced in any blasting application. Depending on the application, fines may or may not be a desirable product of the blast. In most quarry and construction applications, fines are considered an undesirable product since it does not constitute a sellable product and there are costs to the operation for disposal. On the other hand, in most open pits fines do not represent as much of a problem since the ore has to be crushed and ground after being blasted. Therefore, fines in such operations may reduce the energy consumed in the downstream operations.

Jan 1, 2012

By M. Niinae

Electrokinetic soil remediation by electroosmosis and ionic migration is restricted to soluble sub-stances. At a higher pH, the soil particles sorb more heavy metals, such as cadmium, than at a lower pH and the precipitation reactions of heavy metals are promoted. Both mechanisms make heavy metals immobile, rendering clean up more difficult and electrokinetic extraction inefficient. There-fore, the acidification of soils is very important to increase the clean up efficiencies of heavy metals, such as cadmium by electrokinetic method from contaminated soils. In the present study, acidification of soils and cadmium transport are predicted with a numerical method in which electrical flow is coupled with hydraulic flow, and the sorption process in the soils is induced in the model. The effects of some factors such as electrode configuration, electric field strength and electrode spacing for saturated soils are investigated using this numerical model. The results obtained this study are summarized as follows: The two-dimensional electrode configurations containing cathode surrounded by three or more anodes rapidly acidify the soils and remove cadmium from soils compared with one-dimensional electrode configuration. However, two-dimensional electrode configurations develop spots of inactive electric field between cathodes. A larger electrode spacing increases the processing time required, and it was also found that a larger electric field strength reduced the processing time required.

Jan 1, 2014

By J. G. Zafiratos

The leaching of a Greek low-grade manganese dioxide ore, not amenable to conventional mineral processing operations, was studied using a mixed culture of Thiobacillus sp. bacteria. The experiments were carried out in specially designed continuously aerated and stirred tank reactors arranged in two-tank series. The first tank of each series was loaded with an elemental sulfur culture suspension while the second was loaded with a manganese ore high density slurry. The bacterial culture had been previously adapted to grow on elemental sulfur and also in the presence of manganese ore and dissolved manganous ion. A two level full factorial design was constructed in order to study the effects of the ferric ion concentration in the leach solution, the "elemental sulfu weight to ore weight" ratio, the ore pulp density and the composition of the dispersed gas. The responses which were investigated included percentage manganese recovery, co-dissolution of iron and manganese dissolution rate. Parameters with constant values throughout the experiments were the leach solution pH, the nutrient medium composition, the dilution rate and the ore and sulfur grain sizes. It was found that the ferric ion concentration was the most significant factor and had a positive effect on the final percentage extraction of manganese from the ore and also on the rate of manganese solubilization from the ore. The effects of the other factors studied are discussed in detail.

Jan 1, 1997

The need for an integrated approach to optimization of unit operations in both the pit and the mill has long been recognized, but the complexity and nature of the overall problem has up to now resisted solution. This paper reports on a modeling methodology which couples symbolic and numeric computing to unify operations in both the pit and mill. The ultimate goal of this work is to optimize all operations that are influenced by blasting. Blasting plays a key role in all facets of operations. Obviously, drilling and blasting costs are determined by blast design, but the down-stream costs that are closely related to blasting results are often treated as separate functions: loading, hauling, cleanup, and crushing and grinding are all heavily influenced. Diggablilty and bucket fill factor are a function of fragmentation, the condition of the floor and uniformity in the shape of the muck pile. Likewise, cycle times and loading delays partially determine haul cycles, while fragmentation distribution and size determines the efficiency of truck loading. Removal and breakage of oversize causes loading delays and increases cleanup costs. The influence of blasting doesn't stop at the crusher. Mill productivity, power consumption, and maintenance are a function of the feed. Even at the SAG mill a reduction of a critical particle size during blasting can increase throughput. Thus, a bottle-neck for production far removed from unit operations in the pit can be alleviated by a modification in blast design. The question is: how do we optimize blasting with respect not only to itself but to al\ related mining and milling operations? For that matter, how do we even model blasting so that we can control the results of a blast?

Jan 1, 1991

By Russell J. Denny

"A 25m deep cut-off wall is required for environmental remediation of a Former Chlor-Alkali Plant. Extensive trials were conducted to verify the effectiveness of the mixes proposed, with the requirements of the cut-off wall to include limiting criteria for hydraulic permeability, vapour permeability and strength, over a 100 year design life. A limited number of field CSM trial panels were installed on a nearby site with similar stratigraphy, and a variety of mixes and mixing methodologies were used, together with the extraction of deep wet grabbed samples from the panels, which were tested for strength, hydraulic permeability and gas permeability. Test results obtained from these trials revealed a trend which allowed the construction methodology to be decided. Further to this, the mix design needed to be resolved, together with sensitivity analysis on the variations in the mix which might occur during construction, as a result of normal unavoidable variations in construction technique. Laboratory sampling would be used at lesser expense, to resolve the final mix design and analyse the sensitivity of the possible mix variations. An initial series of laboratory mixed samples were prepared using soil samples and groundwater obtained from the site, and testing carried out. However the test results in this initial series of laboratory tests could not match the results which had been achieved in the field trials. Closer scrutiny and investigation and rounds of sampling and testing, then revealed laboratory techniques for mixing and sampling which provided a logical way to match the actual field test results. CSM Construction is due to commence soon and will provide more extensive results which can be compared back to the laboratory trials. This project provides a valuable opportunity to resolve methods of laboratory sampling so that they compare well with results from in-situ deep mixing.INTRODUCTIONThe former chlor-alkali plant at Botany, NSW, which operated from 1945 until 2002, used mercury cell technology and brine solution to manufacture chlorine, caustic soda, hydrochloric acid, sodium hypochlorite and ferric chloride. Mercury contamination is present in the permeable alluvial soil profile beneath the site. The mercury is present in the form of elemental and inorganic mercury, together with dissolved methyl mercury in the groundwater and soil profile beneath the site and also down-gradient of the site, to depths of up to 25m. Residual clay and sandstone bedrock at approximately 25m depth are relatively impermeable and limit the contamination plume. A cap and contain approach has been recommended by consultants Golder Associates, and this involved a subsurface containment wall, or cutoff wall, to restrict groundwater ingress and egress, and lateral subsurface vapour migration. The cut-off wall is situated on the perimeter of the site, with a total length of 430m and passing through alluvial Botany Sands, with a nominal key into the underlying residual clay or sand stone at 20 to 25m depth. An HDPE liner insert was proposed for the upper 7m of wall above the water table, to further limit gas permeability."

Jan 1, 2015

By A. Consigny

New "clean technologies" to treat mining and metallurgical effluents containing dissolved metals have been successfully applied at mine sites in North America and Asia, treating water flows up to 24,000 m3/day. These clean technologies offer significant benefits compared to conventional alternatives and provide a sustainable solution that eliminates residual waste sludge, improves water conservation, generates revenues from wastewater, and delivers overall improvements to the environment. This paper will profile these technologies, and provide best practice case study examples of their application at mining operations, including data for water chemistry, flows, water quality, capital and operating costs, and life cycle costs of treatment.

Jan 1, 2011

By Merete Tangstad, Gabriella Tranell, Jeff Kline

"Raman spectroscopy as an instrumental technique for the determination of silicate structure is widely accepted. This method was utilized for analysis of structural modifications associated with the addition of network modifying species. Silicate melts are described by the extent of oxygen bridging. Therefore, understanding the effect different oxides have on modifying the silicate structure will provide valuable information regarding the removal of boron from silicon in slag refining processes. Samples ranging from CaO/SiO2 = 0.56-1.2 were evaluated with and without varying concentrations of B2O3. The addition of CaO to SiO2 revealed Q2 species constitute 45% of the Qn species and addition of B2O3 to the high concentration CaO system results in an increase in Q2 and a decrease in Q0 . The disappearance of the Raman band associated to the three-member ring in the low concentrated CaO system indicates boron addition and destruction of the ring.IntroductionExtensive studies on the structure of silicate systems have been performed using Raman spectroscopy with consensus on the Raman shift associated with different bridging oxygen units [1]. Most of these studies are motivated by the lack of a fundamental understanding of the processes involved in petrology. Due to this, an opportunity exists to build on the knowledge obtained from these studies and conduct more research on slag structures relevant to industrial applications, as these systems are often compositionally similar to magmatic melts. Raman spectroscopic studies of industrial slags will provide insight into the possible structural modifications necessary to enhance removal of impurity species from the metal phase to the slag phase."

Jan 1, 2012

By M. Beale

Fuzzy logic and neural networks are new technologies being applied in many areas of engineering and business. While it is not always clear which kinds of problems are best suited to these technologies, and which problems are best approached with more standard methodologies, both fuzzy logic and neural networks appear to show great promise in the field of control systems. This paper demonstrates two advantages that these technologies offer: Easy controller design in the absence of a mathematical model of the plant to be controlled, and adaptive control capable of quickly responding to changes in the plant.

Jan 1, 1994

By F. H. A. Abdalla

A process is described for the recovery of valuable nonferrous metals from steelmaking dust by suiphatizing roasting using ammonium sulphate. Maximum recoveries of soluble metal sulphates achieved at optimum conditions were> 99.0 %. Selective metal separation of the soluble sulphates in the leached liquors were performed either by controlling the roasting temperature or by adjustment the pH values of the leached liquor ranging from 3.6-6.2. Either pure zinc oxide orland tin oxide could be obtained at optimum conditions, and the products were evaluated chemically and by X-ray analyses. The residues rich in iron oxide can be removed and recycled. The mechanism of sulphatizing roasting process was considered. A general flow-sheet for the overall process of treatment the steel making dust to recover its valuable nonferrous metals was suggested, which ca be applied for other nonferrous bearing materials.

Jan 1, 1996