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By B. McFadzean, S. Geldenhuys

"Dynamic froth stability tests have found widespread application to quantify froth performance. However, little to no attention has been given to scale parameters in the performance of these measurements. One of the most frequently changing scale parameters in the laboratory scale is the column diameter as this directly influences the amount of material needed for testing. Four different column diameters (50, 100, 200 and 300 mm) were used for this study. Column diameter experiments were done on an industrial scale by means of manual tracking of froth growth versus time. An increase in measured dynamic stability was seen with increasing froth column diameter, which reached a limiting value at large column sizes. It is thought that this behaviour is controlled by the differences in drainage rates of the bulk froth compared to froth in contact with the wall. The column diameter required to represent full-scale froth stability is proposed. A ratio of column surface area to total bubble surface area was used to correct for different column diameters.INTRODUCTIONThe froth phase in flotation contributes significantly to the overall performance of the process (Zanin, et al., 2009). Numerous parameters have been investigated to quantify froth performance, most notably froth recovery (Feteris, et al., 1987; Seaman, et al., 2004; Vera, et al., 1999). Experimentally gathering data to determine froth recovery is challenging and for this reason froth stability has been highlighted as a possible alternative.Froth/foam stability is defined as the time of persistence of the froth/foam and is affected by numerous factors, such as: drainage of the liquid in the lamellae (gravitational and capillary), viscosity at the bubble surface, thickness of the electrical double layer and gas diffusion through liquid films caused by pressure differences between bubbles (Aktas, et al., 2008; Beneventi, et al., 2001). It is well documented in both froth and foam literature that froth/foam stability will heavily influence the performance and appearance of the froth/foam phase (Ata, 2012; Farrokhpay, 2011; Weaire, et al., 2005). Experimentally this has been explicitly proven as an increase in froth stability, characterised by water recovery, usually results in an increase in both valuable mineral and solids recovery (Wiese, et al., 2011; Banford, et al., 1998)."

Jan 1, 2018

By W. H. Eddy

The Bureau of Mines made small-scale continuous tests and large-scale commercial plant tests of a calcareous fluorspar ore near Cave-In-Rock, Ill., to determine if the application of the lignin-fluoride process of fluorspar flotation would be industrially feasible for treatment of fluorspar ores, and also to compare the lignin-fluoride process with the quebracho process, which is the method currently used for concentrating calcareous fluorspar ores. The small-scale continuous tests yielded fluorspar concentrates analyzing 93.6 percent CaF2 with a recovery of 87.6 percent of the total fluorspar in the ore. In large-scale commercial plant tests, a fluorspar concentrate analyzing 93.3 percent CaF2 with a recovery of 78.0 percent was produced by the quebracho method. About 86.0 percent of the fluorspar was recovered in a metallurgical-grade fluorspar concentrate from the lignin-fluoride circuit which analyzed 89.9 percent CaF2? with a much simpler flowsheet than that in the current commercial application.

Jan 1, 1967

By J. Qiu

By means of natural sedimentation, two different bentonite samples from Shandong province were purified, this paper studies the Hydro-properties of the two purified montmorillonite samples. Firstly, the layer charge of two purified montmorillonite samples were calculated by crystal structure formula reckon method and general hydro-properties were also measured. The research results showed that the layer charge of montmorillonite correlated well with its hydro-properties: mont-morillonite with lower layer charge had better hydro-properties, such as Mont-1, which had higher swelling volume and gelling value with lower CEC; while, montmorillonite with higher layer charge had worse hydro-properties, such as Mont-2, which had lower swell volume and gelling value with higher CEC; it proves that the hydro-properties of montmorillonite depends on its layer charge characteristics, layer charge characteristic is the inherent factors deciding the hydro-properties of montmorillonite, montmorillonite with lower layer charge has better hydro-properties than the one with higher layer charge. In this paper, the relation between the medium condition and colloid performance of Mont-1 are also studied. The results show that the hydro-properties of Mont-1 could be changed by changing slurry concentration (w/w) and shear rate or adding certain amounts of inorganic cation electrolytes, dispersants and surfactants. The viscosity of montmorillonite slurry could be enhanced by increasing slurry concentration,adding univalentcation electrolytes (less than 4% w/w) or proper amounts of dispersants and surfactants (less than critical micelle concentration); The slurry viscosity could be reduced by decreasing slurry concentration, increasing shear rate, adding proper bivalent (more than 4% w/w) cation electrolytes or proper quantities of dispersants and surfactants (more than critical micelle concentration).

Jan 1, 2014

By J. J. Rush

Neutron scattering and analysis techniques are extremely powerful, often unique, probes for the characterization of the amount, location, bonding states, and dynamics of hydrogen in all classes of materials. Developments over the past decade at the NIST Center for Neutron Research and elsewhere have greatly increased the sensitivity and dynamic range of neutron methods. In this paper, we provide a flavor of the capabilities of modem neutron instrumentation for the study of hydrogen in a number of technologically interesting systems, including metal hydrides, fuel-cell materials, fullerenes, and disordered carbons.

Jan 1, 2002

By Marietta Canty

A paper is presented in which an innovative biological process is described for the treatment of cyanide-, metals-, and nitrate-contaminated mine process water. The technology was tested for its ability to detoxify cyanide and nitrate and immobilize metals in wastewater from agitation cyanide leaching. A pilot-scale demonstration is described in which a pilot plant was constructed to demonstrate the technology on a mine process waste stream at a mine in Nevada. The demonstration was performed Jointly under the Mine Waste Technology Program (MWTP), which is funded by the U.S. Environmental Protection Agency (EPA) and is jointly administered by the U.S. Department of Energy's (DOE) Western Environmental Technology Office (WETO) and the Superfund Innovative Technology Evaluation (SITE) Demonstration Program under Interagency Agreement Number DW89938513-0 I-0. MSE Technology Applications, Inc. (MSE) located in Butte. Montana, was the contractor responsible for conducting the project, and Pintail Systems, Inc., of Aurora. Colorado, was the technology provider. The pilot-scale unit was field-tested at the Echo Bay McCoy/Cove Mine southwest of Battle Mountain, Nevada. The biotreatment process was considered to be successful in destroying cyanide in the mine process water. The process was also determined to be effective in removing metals. The pH was consistently neutralized, and nitrates were successfully removed from the mine process water. As a result of conducting these pilot-scale tests, the biotreatment process was concluded to be an innovative, cost-effective alternative for the treatment of mining wastewaters.

Jan 1, 1998

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By S. K. Kawatra

The fly ash from coal combustion often has a high unburned-carbon content. This can make it unusable as a cement admixture, which is the major fly ash utilization market. As a result, high-carbon fly ashes currently disposed of by landfilling, at sometimes considerable expense. In this paper, the use of froth flotation to remove the unburned carbon from fly ash is described. Three different fly ashes were studied, which had Loss-on-Ignition (LOI) values of 6.79, 6.90, and 11.11 %. It was found that the use of an alkanolamide/oil mixture as a froth-conditioning reagent could greatly reduce the amount of collector needed, by increasing the affinity of the collector for oxidized carbonaceous surfaces. For each of the three fly ashes, froth flotation reduced the LOI of the ash to less than 2% which is well below the ASTM specification of no ' more than 6.0% LOI for Class F fly ash. Increasing carbon content of the ash tended to increase the quantities of reagents needed in flotation.

Jan 1, 1996

By Lei Pan, Roe-Hoan Yoon

"Direct force measurement for bubble-particle interaction has been difficult due to bubble deformation, which makes it difficult to know the separation distances between the two macroscopic surfaces. In the present work, we have developed a method of monitoring the deformation accurately, while directly measuring the interaction forces. In effect, we can ‘see’ bubbles interacting with mineral surfaces under different hydrodynamic and chemical conditions and determine both the hydrodynamic and surface forces involved. In the present work, a high-speed camera has been used to record the optical interference fringes of a thin liquid film (TLF) of water formed on a mineral surface. The recorded fringes are then used to reconstruct the spatiotemporal profiles, from which one can determine the hydrodynamic pressure using the Reynolds lubrications theory. From the forces directly measured in the present work and the hydrodynamic pressures obtained from the fringes, we have determined the disjoining pressure. The results show that air bubbles interacting with hydrophilic surfaces form stable TLFs with zero contact angles. The TLF formed on a hydrophobic surface thins fast, form a ‘pimpled’ film, and ruptures to form a finite contact angle. The new information obtained in the present work may be useful to better understand the role of hydrodynamic and surface forces affecting bubble-particle interactions."

Jan 1, 2014

By Olanrewaju A. Ojo, Xu Wang, Jian Xin Dong, Lina Zhang, Jerzy A. Szpunar

"The influence of crystallographic orientation on the pitting corrosion behavior of Ni-Fe-Cr alloy 028 was studied by a combination of X-ray diffraction (XRD), electron backscatter diffraction (EBSD), potentiodynamic polarization technique and atomic force microscopy (AFM). The results show that there is anisotropy of pitting corrosion that strongly depends on crystallographic orientation of surface planes. The distribution of pits frequency in standard stereographic triangle shows that the crystallographic planes close to {100} are more prone to pitting corrosion compared to planes of {110} and {111}. The calculation of surface energy (001) and (111) shows that the planes of high packing density of atoms have low surface energy with concomitant strong resistance to pitting corrosion. A correlation function between crystallographic orientation and pitting corrosion susceptibility suggests a method not only to predict the pitting resistance of a known textured materials, but also to improve corrosion resistance by controlling materials texture.INTRODUCTIONNickel-iron-chromium(Ni-Fe-Cr) alloys are widely used in various industries and engineering sectors due to their combination of good mechanical properties and high corrosion resistance(Hibner, 2001; Thomas, 2006; Ghosh, 2005).Ni-Fe-Cr alloy 028 (alloy 028)has such important characteristics worth mentioning. Alloy 028 contains high amounts of nickel, copper and molybdenum which improve its resistant to corrosion attack in reducing medium, and presence of high level of chromium makes it more resistant to oxidizing species. Moreover, alloy 028 is less expensive because of higher amount of iron compared to other similar alloys. Currently, alloy 028 is manufactured as evaporator tubes applied in the phosphoric acid production; production tubing and casing used in deep and sour gas wells; heat exchangers employed in nuclear power plants, and seawater-carrying piping and seawater-cooled heat exchangers (Bankiewicz, 2012; Kivisäkk, 2003; Gómez, 2003; Xian, 2012; Bellezze, 2004)"

Jan 1, 2017

By Y. Pokhvisnev, S. Vandariev, A. Yatshenko-Juk, V. Valavin, V. Romenets

The technology of the liquid-phase reduction process known as Romelt was developed in the Moscow Institute of Steel and Alloys in 1979. The pilot plant was constructed at the Novolipetsky Steel Works (Russia) in 1984. Investigations into processing zinc-containing blast oxygen furnace dust and slag from the Lead and Zinc Works at the pilot Romelt plant proved the perspective of using this technology for processing zinc and lead-containing materials. In this article, the description of Romelt technology, basic technological information of trials at the Romelt plant using zinc-containing materials, compositions of charging materials, metal, slag, gas and dust are presented. The influence of flue gas composition on the composition of zinccontaining dust is shown.

Jan 1, 2000

By Th. Hassel

The application of magnesium as an absorbable biomaterial demanded the consideration of the alloy composition, the mechanical properties and the corrosion a special adapted material development in terms of the human biological system. Magnesium for technical applications mostly comprised alloying elements up to 10 wt%. Thereby often metals (e.g. rare earth and aluminum) with high toxic potentials are used to optimize the mechanical properties. To minimize toxic reactions during the degradation of a absorbable magnesium alloy, the Mg-Ca system is being selected and investigated because both elements belong to the mineral nutrients. Rods and small tubes are produced by extrusion of gravity die casting billets (Ca-content 0.4 to 4.0wt%). The positive grain fining influence of calcium and its improvement of the corrosion behavior are additional advantages. The microstructure, the mechanical properties and the corrosion attitude are investigated. The results show that an optimal composition of micro alloyed Mg-Ca and ideally processing parameters lead to 16% strain and a tensile strength up to 185MPa. Electrochemical investigations and measurements of the hydrogen production demonstrate the influence of the Ca-content to the corrosion behavior of the investigated alloys.

Jan 1, 2006

By Ali Kahriman, Olivio Angelini, Ibrahim Sefer, Burak Ekmen, Koray Arpak, Ertugrul Kaya, Yucel Karakus, Abdullah Sak, Aziz Ozdemir

In recent years, in order to bring solution to traffic intensity arising from transportation problems and facilitate public transportation in the modern world in paralel to urbanization and to the increase in population, it’s well known that, the construction of Access tunnels is inevitable. The driving of the tunnels is a subject of special interest in the technique of rock blasting. The essential factors in terms of tunnel driving and safety in tunnel blasting that is applied in metropolitan areas, an in depth knowledge of ground vibrations and the ways of reducing them to safer levels.

Jan 1, 2010

By G. Simmons

Santa Fe Pacific Gold Corporation (SFPGC) conducted pressure oxidation pilot plant studies at Hazen Research, Inc. on the Twin Creeks refractory carbonaceous gold ores during 1993 and 1994. Previous laboratory investigations demonstrated very good gold recoveries of 90 to 95%, using CIL cyanidation after batch pressure oxidation. However, results from the pilot plant showed that several ore types responded very poorly, with gold extractions of only 45 to 75%. Since these poor recoveries were unexpected, pilot plant testing was suspended for approximately four months while extensive research activities were conducted to determine the cause(s) and identify potential solutions. This paper describes the batch and pilot plant test results, the research activities that eventually identified the cause of the gold recovery problem, and the final semicontinuous and continuous pilot plant operations that confirmed possible solutions.

Jan 1, 1997

By Frank Ebbutt

In this paper it is proposed to point out certain structural factors that; have an important bearing on gold deposition. The subject will be treated; more or less generally. Although the writer has had access to a great many; of Canada's gold mines he does not wish to take the liberty of discussing; details of any particular mine or mines; the aim will be to discuss controls; that are evident in many places.

Jan 1, 1954

By Sidney Katell

An estimated capital investment of $76,499,800 will be required for a plant designed and built to produce 90 million standard cubic feet per day (std.c.f.d.) of synthetic pipeline gas through Lurgi gasification of bituminous char. This investment figure does not include the pretreatment plant, the cost of which is assumed to be reflected in the cost of the char fed to the gasification system. Shift conversion, C02 removal, and methanation are required after gasification in the Lurgi unit to make a gas suitable for pipeline transmission. Capital investment data are based upon equipment costs, January 1959. Based on a 90-percent or 330-day operating year, the operating cost before profit and Federal taxes with the char price as a variable will amount to the following: [ ]

Jan 1, 1959

By Hideaki Tokuyama

Recovery of Ni from acidic wastewater of metal surface treatment has been investigated for reuse of the metal and water. Ion exchange equilibria between Ni ion and a strong acid cation resin, DIAION SKIB, and effective diffusivity in resin particle have been studied and they related to the concentration of HCI. The amount of adsorbed Ni for unit quantity of resin decreases with the increase in HCI concentration. This trend is remarkable for acid concentration above 0.1 kmol/m3,. The exchanging ratio of Ni2+ to H+ in resin particle is I/2 and the values of equilibrium coefficient K and maximum exchange capacity Q are I.62 and 3.16 keq/m3 -dry resin, respectively. Effective diffusivity D. determined from the observed breakthrough curve increases with increasing concentration of DC!. A prototype of moving bed has been developed and applied for the recovery of Ni from model solutions of wastewater prepared by mixing HCl and NiCl2. This apparatus allows us to control the resin flow rate by changing the cross sectional area of hole I the Teflon plate installed at the bottom of resin bed. Characteristics of Ni recovery have been clarified under various liquid flow rates. In any case for Q1, Ni ion has been effectively recovered on SKIB resin and the removed fraction was more than 99.5 %. Higher loading ratio of ion is attained at larger liquid flow rate.

Jan 1, 2003

By Ashutosh Shandilya

Froth flotation is a selective separation process and rarely used for beneficiation of limestone in the world as compared to other minerals and also mostly known conventional methods of up gradation of ROM including wobbling, selective mining, sorting, preblending etc. Limestone is mainly used in the manufacture of cement, steel and chemical industries. High grade limestone deposits are depleting day by day and the requirement of the industries have to be met by beneficiating the low grade limestone deposits in the world. And because of marginal quality of limestone, it cannot be directly used in cement industry. At ACC Madukkarai cement works, Coimbatore, Tamilnadu, full fledged mineral beneficiation process is adopted to enhance the quality of low grade lime stone from 38-42 % CaO to 45-47 % CaO and silica reduced from 19-22 % to 11-13 % by use of oleic acid (commercial grade and vegetable origin) 0.38 kg/ton of limestone and caustic soda 0.05 kg/ton of limestone. Keywords: OK-8 Cells, Froth flotation process, Beneficiation studies, Low-grade lime stone, Oleic acid, % solids, Pulp density, Ph, Iodine value, saponification value, Denver cell

Sep 1, 2012

By George H. K. Schenck

Diminishing returns in management's fight to lower manufacturing expenses have added luster to savings that can be achieved in delivered costs through creative management of the distribution function. This is especially true for companies engaged in the production of bulk commodities, for which transport costs may represent 25 to 50% or more of total delivered price, A. E. Cascino, vice president of International Minerals and Chemical Corporation, recently gave an example of why top management in his firm is concerned with distribution: "The price of a ton of phosphate rock, f.o.b. mine, is about $7. The cost of warehousing, freight, and handling frequently totals an additional $11 . . . . If one of our competitors . . . discovers a way in which he can cut his distribution costs by $3, we're dead! Even if we wanted to offset our competitor's more efficient means of shipping with reduced f.o.b. price for our product-we don't have that much profit margin . . . ." In a special report on the revolution now occurring in transportation of goods, Business Week stated in its September 24 issue: "Moving and storing goods on their way from mine and mill through various sub-assemblies to their final markets costs anywhere from $50 billion to $75 billion a year- $100 billion if paperwork costs are included.

Jan 1, 1967

By Jing Zhou

In view of the state of the long time use of sodium cyanide in lead-zinc-sulfur-silver multimetallic ore production, we propose alternative reagents system through experimental research. The experiment first used TJ, sodium sulfide to adjust the flotation pulp, after that, zinc sulfate, sodium sulfite was added to low alkaline pulp to inhibiting zinc sulfur mineral and adapted MB, 25# aerofloat and diethyl dithiocarbamate combination collectors to float lead minerals. The obtained test index is as follows: lead concentrate recovery rate of small scale test was increased by 5 to 10%, the recovery rates of gold and silver in lead concentrate were increased by 7% and 11% respectively; the industrial test is conducted under the condition that the total grade of lead and zinc content in raw ore decreased by 4.81%, the total recovery rate of lead and zinc increased by 7%, recovery rates of gold and silver in lead concentrate were increased by 7.62% and 9.65% respectively. So it successfully realizes the target to replace the sodium cyanide, using low-alkaline non-toxic reagents system in mineral processing practice of three kinds of complex lead-zinc-sulfur ore of this mine. Keywords: refractory lead-zinc-sulfur ore, depressant, non-cyanide flotation

Sep 1, 2012

By A Agasty, O Langefeld, MáKellner, E Clausen

The lowering of the pollutant concentration limits at the workplace subjects the mining industry to higher requirements for dilution; this situation is worsened with the current discussions within the European Union (EU) to set new stricter exposure limits for nitrogen oxides in the workplace. This is directly reflected in the performance of the mine ventilation system, which may need to be revised to meet the new standards. The after blast re-entry time, being inversely proportional to the threshold limits, will be higher for a lower limit. This in turn increases the down time for production from the blasted area.Numerical tools have been very useful in predicting the effectiveness of ventilation. This study aims at analysing the dilution time for NOx gases from an ANFO blast in a room and pillar panel. The effect of changing the ventilation on the dilution time is studied next, which helps with the selection of a suitable ventilation system.CITATION:Agasty, A, Clausen, E, Kellner, M and Langefeld, O, 2013. After blast re-entry time for a room and pillar operation, in Proceedings The Australian Mine Ventilation Conference , pp 179-186 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013