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By Oliver Bowles

"Properties and Uses.Iceland spar is a name given to a pure crystallized form of calcite (CaCo3) which is sufficiently transparent and free of defects to be used in the manufacture of optical instruments. While the actual requirements are small, the degree of purity and physical perfection demanded renders it somewhat difficult to obtain suitable material.The properties of value in Iceland spar are its transparency combined with double refraction. It is used in the manufacture of polarizing microscopes, saccharimeters, colorimeters and photometers. Its most important use is in the manufacture of Nicol prisms, which constitute an essential part of every polarizing microscope. The principle governing the construction of the Nicol prism is as follows:Ordinary light in passing through a crystal of calcite is resolved into two rays of plane polarized light vibrating in planes at right angles to each other and having different indices of refraction. Thus the two rays follow different paths through the crystal. The prism of Iceland spar is cut diagonally and cemented together again with a transparent cement having an index of refraction intermediate between the two rays passing through the prism. Canada balsam is employed for this purpose. The prism is cut at such an angle that the ray having the greatest index of refraction meets the surface of the balsam at an angle greater than the angle of total reflection, and it is thus deflected to the side of the prism, while the second ray passes through. Thus one of the rays is eliminated and polarized light vibrating in a single plane is obtained."

Apr 1, 1920

By Norman Paley, John Kells

The climate and location of the Red Dog Mine present several challenges to blasting operations. The mine is located north of 68º latitude, in an area of continuous permafrost. Ground temperatures are below freezing year-round and air temperatures range from -40 to 70°F (-40 to 20°C). Because there is no overland access to the mine, the entire year’s supply of bulk explosives, approximately 7,000,000lbs (3,175,000kg) is shipped in by barge during the 100 day shipping season when the port is ice-free. The first week in July is the earliest that new product arrives at the port. Emulsion usage is maximized from mid April through October when surface water fills the blastholes during drilling. This necessitates that a considerable portion of the bulk explosives are stored for 10 months or more before usage. The emulsion is routinely pumped from the ISO containers at temperatures of 20ºF (-7°C). The mine engineers conducted a testing program during the 2001-2 blasting season to identify the bulk explosives best suited for the conditions at the mine. A secondary goal was to decrease the usage of sensitized emulsion, as this is the most difficult portion of the explosives order to ship. To ensure repeatability when transferring the results to the day-to-day blasting operation, the majority of the testing was incorporated into normal blasting operations in the field. The mining methods used at Red Dog Mine make direct fragmentation analysis impractical and performance testing in the field relied primarily on VOD measurements. The products were also tested for their ability to be pumped in cold temperatures.

Jan 1, 2004

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By K. Fukushima, K. Baba, H. Kurokawa, M. Yamagiwa

"The Toyo smelter has expanded its anode production capacity from 126,500 to 239,000 t/year by introducing technical oxygen into blast air for flash and converter furnaces and improving smelting facilities. Significant efforts were made in the expansion not to increase the number of workers, which mean development of some automation systems for the copper converters and anode casting wheel. The efforts have resulted in the above-mentioned increase in productivity and a saving of production cost as well as a decrease in the number of workers for the anode casting operation.IntroductionThe Toyo smelter has been performing a highly stable and pollution free operation since its commencement in 1971 (1). Its distinctive features are the on-line control by process computer (2) and the high productivity without trouble. But owing to the so-called oil crisis in 1979, we were faced with a sharp increase in production cost. To decrease the production cost, some measures for saving of energy were planned and carried out, such as conversion from oil to coal in a flash furnace (3), the heat recovery from converter slag and the introduction of technical oxygen in blast air with the intention of energy saving as much as possible.The first increase in production capacity and some savings of production cost were attained in 1982 by the introduction of technical oxygen in blast air for the flash furnace without major modification of the furnace as shown in Table I. The capacity of an oxygen plant is 7,800 Nm3/H as 90% O2 . Part of oxygen from the plant is also supplied to tuyeres of copper converters through an oxygen holding tank with a volume of 830 m3 at 7 kg/cm2-G."

Jan 1, 1989

By Karl Gunnar Holter, Frank Clement

"INTRODUCTION Typically waterproofing of conventionally excavated tunnels has been done by installing pre-fabricated sheet membranes between the primary temporary support lining and the secondary permanent inner lining. The membrane acts as a separation or sliding layer between the linings, which is often desirable. The geotextile installed behind the sheet membrane provides the required drainage and protection of the system. The design of the tunnel lining is strongly influenced and limited by the use of waterproofing sheet membranes. Since primary and secondary linings are separated from each other, forming a double-shell lining system. In that case the secondary lining must be designed for all permanent loads, although the sprayed concrete primary lining continues resists ground and water loads for a long time after construction. Significant progress has been made in sprayed concrete technology over the last two decades, with advanced admixtures, as well as the improved application technology using spraying robots. The development of new admixtures like superplasticizers based on poly-carboxylates, alkali free accelerators and silica fume, enables designers to use permanent sprayed concrete linings (SCL) increasingly for long-term service life. When designed and applied correctly, sprayed concrete can be considered as permanent. The use of spray applied membranes has seen increased use over the last decade in some countries, and demonstrated functionality and cost-effectiveness in several situations. This paper describes the use of the sprayed waterproofing membrane MasterSeal 345, an EVA polymer based product, and the practical experiences from several projects. SPRAY APPLIED WATERPROOFING MEMBRANES The sprayed waterproofing membrane is polymer based and has been especially developed for underground structures. The membrane is applied between primary and secondary concrete linings and develops high bond strength on both sides to the concrete (doubled-bonded)."

Jan 1, 2016

By C. C. Li

Traditionally, strong and stiff devices, such as fully encapsulated rebar bolts and concrete lining and arches, are preferred for underground rock support. The attention is paid to the strength of the devices in such support designs. It has been observed in engineering practice that support systems composed of stiff devices are often subjected to premature failure in high stress rock conditions. In the past decade, yield support devices have been employed to improve the performance of rock support systems. A rock support system usually consists of both internal and external devices that are installed within the rock mass and on the free surface of the rock, respectively. Great efforts have been made to make support devices yieldable in the past years, but the efforts are focused on different aspects in the tunneling and mining branches. In the tunneling branch, the focus has been put on the development of external yield devices, such as Lining Stress Controller (LSC), Honeycomb element and compressible concrete, which are embedded in shotcrete liners, while in the mining industry the efforts has been on the development of yield rockbolts, such as the cone bolt and the D-Bolt. The internal and external support devices are not compatible in their deformation capacities in the current rock support systems even though yield devices have been employed. All the devices in a support system should be deformable and compatible in deformation capacity. With such a support system, premature failure of individual support devices could be avoided and the service life of the support system is prolonged. It is a trend at present to take into account the energy absorption capacity, instead of simply the strength, of support devices in rock support design.

Jan 1, 2015

By Kang-Hyun Lee, In-Mo Lee, Byung-Kyu Kim, Parkm Jinho, Seoung-Won Lee

"In this study, the TBM Resistivity Prediction (TRP) system is developed for predicting the location, thickness, permittivity ratio and electrical conductivity of anomalous zones ahead of tunnel face using the measured resistivity of the ground. The applicability of the developed system was verified by performing field tests at a construction site in which an EPB-shield TBM is used for tunnelling work. In the first field test, it was found that the rock around the tunnel face had the same resistivity and permittivity with the rock ahead of the tunnel face indicating no anomaly ahead of the tunnel face. In the second test, a stronger zone 5-m thick was predicted ahead of the tunnel face based on lower permittivity than that of the rock around the tunnel face. The ground condition assessed by the newly developed TRP system matched well with that either predicted from geophysical exploration or directly obtained from drilling boreholes or from daily observed muck conditions. INTRODUCTION During tunneling work, the emergence of unpredicted zones of relatively weaker or stronger ground can lead to delays in construction work or an increase of construction cost. Predicting anomalous zones ahead of tunnel face in advance can thus prevent time and economic loss. For these reasons, various methods to predict the ground condition ahead of the tunnel face have been studied and developed. Prediction methods using various kinds of equipment include tunnel seismic prediction, ground penetrating radar, electromagnetic surveys based on electronic antennas, and electrical resistivity surveys conducted by analyzing electric currents in the ground ahead of the tunnel face (Ryu et al. 2008). However, most of the prediction methods are only applicable to conventional tunneling job sites, which feature free access to the tunnel face. In mechanized tunneling projects, accessibility to the tunnel face is very limited because the tunnel face is occupied by the TBM."

Jan 1, 2016

By Eugene V. Cilento, R. Clark Lantz, K. A. DiGregorio

"This laboratory bas developed a sensitive electro-optical method to quantify the initial rate (R) and total amount (MAX) of superoxide (02) produced by single pulmonary alveolar macrophages (PAM). The method uses a microscope-based TV system to visualize PAM in culture, and to video record the images during the time the cells produce 02. MAX and R are calculated from measurement of temporal changes in optical density in the images due to precipitated diformazan formed by the reaction of O2-, produced by each PAM, with nitroblue tetrazolium present in the culture medium. To date, values of Rand MAX, measured due to adherence of PAM to the dish, have been compared to values obtained when quartz, coal mine dust (CMD), and kaolin . were added to the medium (in vitro). Rand MAX have also been calculated for PAM lavaged from animals exposed to quartz and CMD in the WVU Inhalation Facility. Presently, experiments are being done using which will permit PAM to be restirnulated by different dusts to help establish a dose response relation~ p and a means to study the role of lung surfactant on modifying the acute toxicity of inbaled dusts. Ultimately, this methodology should provide useful insight into establishing the role of 02 in PAM dysfunction due to inhalation of dusts, and in lung diseases such as pneumoconioses. INTRODOCTIONPAM are free cells found in the lungs which protect the lungs by removing foreign debris and bacteria. This is accomplished, in part, by the process of phagocytosis, whereby foreign matter is internalized into vesicles known as primary phagosomes. Phagocytosis also involves the chemical breakdown of inhaled dusts and the killing of microbes. Detoxification is aided by the respiratory burst, which is a metabolic response of the cell to foreign substances, that results in the production of highly reactive oxidizing agents from the partial reduction of extracellular oxygen to superoxide (02) at the surface of the plasma membrane. Superoxide undergoes either spontaneous or enzyme catalyzed dismutation reactions to form hydrogen peroxide (H202) and subsequently hydroxyl radical (OH•) and singlet oxygen (02 t ). However, while these oxygen metabolites aid in the killing of microbes they also may destroy endogenous tissue. For example, 02 has been linked to the aging process and to many diseases including emphysema, diabetes, and cancer.'' Therefore, a better understanding of the production of 02 is extremely important since an abnonnally low production could result in damage by inhaled dusts and bacteria while an abnormally high production could result in direct damage to the lung tissue by the phagocytes. Inhalation of respirable sized mineral dusts, such as quartz (silica), coal mine dusts (CMD), and asbestos, results in various pulmonary disorders. PAM are thought to play an important role since evidence suggests that the first step in fibrogenesis is an interaction of dust particles with PAM. Generally, in vivo exposure of animals to mineral dusts results in increased respiratory burst activity, migratory patterns, phagocytic behavior, and secretory potential of PAM, and for this reason these have been implicated to be pivotal events in the pathogenesis of pulmonary diseases.1 In addition to stimulation of resident PAM, an influx of monocytes into the lung and/or production of new macrophages generally occurs in response to fibrogenic dust inhalation. Further, PAM may attract and stimulate fibroblasts, which normally synthesize proteins and collagen during rep~ of tissue, by secreting chemoattractants and enzymes. Thus, PAM may be involved in pulmonary disorders through failure or partial loss of their defensive capability, or indirectly, through release of other mediators."

Jan 1, 1990

By Thomas E. Howard

Man has been engaged in the construction of tunnels in. rock for several thousand years. During that time, methods of tunneling have changed drastically. Hordes of men chipping away at the tunnel face have been replaced by mechanical drills and explosives and by tunnel boring machines. Spoil is no longer carried on the backs of humans, but is now removed by trains, trucks or conveyor systems. These and other changes have had the effect of greatly increasing the rate of tunneling, while at the same time, greatly decreasing the potential dangers to workmen. Although the techniques, equipment and material used for tunneling are being continually improved, rock tunneling is still a slow and expensive process. Significant improvements and innovations are needed to reduce the cost and time required for tunneling if we are to fully utilize the subsurface to aid in the solution of urban problems and in the conservation of resources. This report is intended to facilitate the orderly development of tunneling technology by focusing attention on the inadequacies of rock tunneling and the improvements that are needed. The data presented were derived from the results of a comprehensive questionnaire that was completed during the summer of 1969 by more than 600 individuals and organizations in 17 countries. Table 1 lists the countries and the number of replies from each. Appendix A contains a summary profile of the national responses, while the text presents the results and a brief analysis of the conclusions that might be derived from the data in the questionnaire. The data shown in Appendix A represent the consensus opinion of each of the 17 nations without regard to the number of individual replies or the amount of tunneling activity that is represented. The national consensus was determined for each country by a plurality of the individual responses, in some cases modified by the opinion of the rapporteur. Tire above procedures can lead to situations which are misleading. For example, experience and activity arc a rational basis for analysis; but, if national replies are weighted on this basis (i.e., number of responses), informed and valuable opinion of less active countries would probably be overwhelmed and lost. In analysing the data on the basis of national responses without weighting, it becomes apparent that many of the same problems exist under a given set of conditions regardless of the number of tunnels that have been driven.

Jan 1, 1970

By BARBOSA AMILTON, Denise C. R. Espinosa, David B. Dreisinger

Chelating resins can be used to recover important metals from different sources, and it is important to understand which resin is most suitable for each metal [1]. This review  benefits the mining industry because chelating resins can be used to recover metals from low-grade ores and mining tailings, increasing the industrial process efficiency [2–4]. Furthermore, the use of chelating resins in mining processes and mining tailings has the common problem of metals contamination, with iron being the main contaminant in low-grade ores and tailings. Understanding how contaminants decrease ion exchange efficiency is significant for industries [5

By YOUNIS S. MUSTAFA, GHORASHI ZAIN, ABDEL-ZAHER M. ABOUZEID, AHMED A. S. SEIFELNASSR

The present paper attempts to characterize the breakage properties of a brittle rock, quartz, at different size fractions when compressed at various loads in a confined piston die.  This is to understand the interaction between the various parameters affecting the breakage behavior of a brittle solid in a confined zone. Application of the results may lead to improving the energy efficiency in the size-reduction units, which use compression as the main stressing force. 

By P. Patnaik, F. Cuneo, D. M. Wang

Microwave (MW) energy has been used widely for several decades for communications, food processing, wood drying, vulcanization of rubber and medical therapy. Recently, this technology was found to be capable of successfully sintering ceramic and metallic powder materials, with the advantages of reducing soaking times and sintering temperatures. Unlike conventional heating, MW radiation works through the absorption of the microwave energy by a material placed in an electromagnetic field within the microwave cavity. A far more efficient heating process is produced due to the unique ability of microwaves in selectively heating a pecific part of the material with desirable dielectrical properties. This exploratory research was initiated with the objective of locally sintering the thermal barrier coating of gas turbine components using MW radiation. This novel technique may allow repairing of the component without subjecting the entire piece to unnecessary elevated temperatures and reduction of process time and cost. Y ttria stabilized zirconia was used in this study and sintering was conducted using a multimodal 1.2 kW microwave facility. Three configurations of heating setup were experimented and the preliminary results will be discussed in this paper.

Jan 1, 2006

By N. S. Dalal, X. Shi

"SUMMARYElectron spin resonance (ESR) measurements provide direct evidence for the involvement of the glutathionyl radical, as well as an isolable Cr(V)-glutathione intermediate in the Cr(VI) glutathione redox reactions. These results indicate a new mechanism for the reduction of Cr(VI) by glutathione in relationship to cellular environment and suggest that synergistic reactions of Cr(V) and GS· might be responsible for the (unexpected) increase in the Cr(VI)-induced DNA-strand breaks at high glutathione levels.INTRODUCTIONWhile the reduction of Cr(VI) by glutathione (GSH) is thought to be a critical' step in the pathogenesis of the Cr(VI)-exposure related carcinogenesis1- 4, the exact reduction mechanism is not yet understood. The following reaction steps have been suggested :(A) Initial step:Cr04 2- + GSH - GSCrOa - (1)(B) At high GSH levels:GSCroa- + GSH - Cr( IV) + GSSG (2)(C) At low GSH levels: GSC rO a - - Cr ( V ) + GS ·(3)Thus far, however, in these reactions, the GS· radical has eluded spectroscopic detection, while the evidence for the Cr(V) formation has been reported positives as well as negative2·. Her~ we present spin-trap ESR evidence for the formation of the GS· radical, and a definitive ESR detection of an isolable cr(V)-GSH intermediate in Cr(VI)-GSH reactions.MATERIALS. AND METHODSESR spectra were obtained at X-band (-9.7 GHz) using a Bruker ER200D ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR Gaussmeter (Bruker, Model ER035M) and the microwave frequency was measured with a Hewlett-Packard (Model 5340A) frequency counter. The spin probes, a-(4-pyridyl-1-oxide) -N -tert-butylnitrone (4-POBN) and 5,5-dimethyl~1-pyrroline-1-ox1de (DMPO) were purchased from Aldrich, K2Cr201 from Fisher and used without further purification. All experiments were done at room temperature."

Jan 1, 1989

By George Booth

In mining operations the cost of timber is an item of much importance, because the life of mine timbers is, in many cases, very short and, as the supply of the better grades becomes depleted, less durable kinds must be used. This, of course, tends to shorten still further the period of service-ability. While it is possible that concrete and steel may, to some extent, take the place of timber in mines, their high initial cost and the difficulty in installation will greatly restrict their use. Moreover, wood, besides being comparatively cheap to handle, possesses other desirable qualities, and for many purposes a satisfactory substitute is hard to find. Both the decreasing supply and the increasing price of timber make its more efficient utilization imperative. AGENCIES DESTRUCTIVE TO MINE TIMBERS Timber used in mines is exposed to destruction from many sources. Wear, breakage, and waste are responsible for much loss. Wood rollers and drum laggings must be frequently replaced on account of the constant wear by ropes. Unprotected timber in chutes and mills is also rapidly worn by abrasion, and track ties in main haulage ways get worn by the feet of mules, cut by ropes, etc. Large amounts of timber are broken by 'crush' and 'squeeze,' and much temporary timber is buried beyond all recovery in pillar workings and in those mines which resort to back filling. Decay and insect attack, however, cause the greatest damage. If not totally destroyed by one or both of these, the timbers frequently become so weakened that they break under the pressure upon them.

Jan 1, 1926

By J. W. Leonard

By using physical and chemical method to increase the bulk density of newly mined coal, the productivity of a mine can be significantly increased. Greater amounts of coal can be placed in fixed volume shuttle car by increasing bulk density. This can increase mine productivity by about 15%. Small, easy to achieve changes in mining operations are required to obtain the increased productivity. This article deals with chemical methods used to increase coal bulk density, the results and discussion are based on experiments performed in the laboratory.

Jan 1, 1992

By Thomas Niehoff

"Oxyfuel combustion systems are state of the art for many melting operations. Airfuel systems have been stepwise modified to oxygen enrichment, oxygen lancing and oxyfuel. Every change of the melting process will have consequences with regards to emissions and energy usage. The uniqueness of many operations requires unique skills to resolve potential issues. This paper will give some examples of how airfuel systems can successfully be converted to oxyfuel.IntroductionOxyfuel technology – meaning the combustion of fossil fuels such as natural gas, oil or coal with technical oxygen instead of air for industrial melting or heating processes is widely used in many industries these days. Even though oxygen production, storage and handling has been state of the art for decades other opinions exist. Often oxyfuel is regarded with fear and potential hazards like: “Oxygen makes the process too hot.”, “Oxygen will melt away the refractory.”, Liquid oxygen is dangerous.”, “Oxygen will cause explosions.”, ……etc.Typically a more detailed discussion about a specific industrial process and how oxygen can be applied in a safe and economic way the seeming issues go away."

Jan 1, 2010

By Liu Zhonghua

Hydrogen reduction of cobalt sulfide (Co9S8) was experimentally investigated in the temperature range 813-1053 K. The results revealed that the reaction kinetics can be described by the shrinking core mod¬el in chemical control regime at low temperatures, it is of first order with respect to hydrogen concentration, and the reaction activation energy is 67.4 kJ/mol. The SEM second electron images of the samples before and after experiments showed that the swelling of the sample above 973 K is due to the formation of metallic cobalt whiskers.

Jan 1, 1992

By Otis M. Clarke

Although most bauxite mined is used to make metallic alu¬minum, more than a million tons of bauxite is used annually in the United States in the manufacture of refractories, chemicals, abrasives, and cement. Raw material requirements are becoming increasingly difficult to meet because high-grade bauxite, required for some uses, is limited. The supply of raw material for high-alumina refractories is most critical because a low-iron bauxite is needed. Although there are substantial bauxite reserves in the world, bauxite suitable for use in refractories is limited to a few districts.

Jan 1, 1977

By Lewis T. Wright

IT is commonly believed by metallurgists that in copper-smelting, the copper in the slags, which is irreducible by continued smelting, is retained in the form of "prills" of matte. I have frequently held well-settled slag in a molten condition for a long period without being able thereby to reduce the copper-content. The slag acted as though it contained a minimum of dissolved or combined copper that could not be settled out by gravity. I have used reagents, but without satisfying myself in what form this copper existed. The same slags, by fine grinding and elutriation, could not be separated into portions containing more or less copper than the average content. By treating copper-slags in an electric furnace an impure button of copper. was produced, but the high temperature and the strong reducing-action of the furnace were influences that suggest an explanation of a result not obtainable with ordinary smelting-temperatures. If all the copper in the slag were in the form of copper-matte, and not existing as a dissolved compound with some of the elements of the slag, then the other metals in the matte, such as gold and silver, should occur in the slag in the same ratio to the copper as to the copper in the accompanying matte. This reasoning led me to study the ratio of metals in the products of smelting, and, apart from the issues discussed in this paper, the research has proved both interesting and illuminative. On the assumption of a similar ratio of metals in matte and slag, if the percentage of copper in the slag accompanying; a matte containing 50 oz. of silver and 1 oz. of gold per ton of copper was 0.3 per cent., or 96 oz. per ton of slag, there should be found 0.15 oz. of silver and 0.003 oz. of gold per ton of slag:; but, in my experience, there is less silver and much

Sep 1, 1909

By Alan Kissock

MOLYBDENUM is thought of as one of the rarer elements, for though it occurs in almost every country of the world it is seldom found in commercial quantities. In this country, however, there is one deposit which makes the term "rare" a misnomer. There are two commercially mined molybdenum minerals: molybdenite, the sulfide, and wulfenite, a lead molybdate. Of these two only the former is of any con- sequence but wulfenite is of mineralogical interest. It is frequently associated with oxidized lead ores and particularly in arid sections. Deposits, however, are usually quite superficial. It is highly oxidized and yet it does not appear to be an alteration product for it apparently disappears below water level and I know of no case where primary molybdenite, or in fact any molybdenum whatever has been identified below these surface wulfenite occurrences. The genesis of wulfenite would make an !- interesting study.

Jan 1, 1933