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By J. P. Gous, M. Tangstad, J. D. Steenkamp

In April of 2013 a 48 MVA submerged arc furnace producing silicomanganese was excavated in South Africa. One of the areas excavated systematically was the furnace taphole. The aim was to obtain a refractory wear profile of the tap-hole area, together with affected hearth and sidewall refractory. Subsequently, thermodynamic modelling was applied to quantify the potential for chemical reaction between refractory and slag and refractory and metal in the tap-hole area.

Jan 1, 2014

By Jr. Foot

The Bureau of Mines, U.S. Department of the Interior, investigated flotation methods for recovering fluorite and byproduct beryllium from the Fish Creek deposit of Nevada. The preferred method includes (l) fluorite rougher and cleaner flotation, (2) de sliming at 20 micrometers, (3) muscovite flotation, (4) silicate flotation, (5) hypochlorite wash of silicate concentrate, and (6) beryllium rougher and cleaner flotation from the silicate concentrate, Laboratory results showed that over 94 pct of. the fluorite was recovered in a concentrate containing 96 pct CaFz. Beryllium flotation produced .concentrates .containing in excess of 5 pct BeO with recoveries over 70 pct. A 1.00-lb/h continuous flotation unit was constructed to demonstrate this procedure,

Jan 1, 1985

By J. Basi, D. F. Rucker

"A review of historic operating practices of the heap leach pads at the Los Filos Mine, Mexico, revealed periods of restricted cyanide addition, reduced leach time, and insufficient irrigation flow. These issues all led to the buildup of partially leached recoverable gold inventory within the leach pads. Drawing down this inventory represented an opportunity to bring value forward. This paper outlines the strategic initiatives which were implemented as efforts to accelerate the inventory drawdown, including geophysical mapping and pressure injection.INTRODUCTION Los Filos is a heap-leach operation located in the Guerrero gold belt in southern Mexico. Operational and hydraulic challenges at the Los Filos Mine have led to a buildup of gold in inventory within the leach pads. Operationally, periods of restricted reagent addition, reduced leach time, and insufficient irrigation flow have compounded over the last eight years, and resulted in significant inventory growth. Hydraulically, the leach pad has issues with low permeability and solution channeling due to the fines and clay content of the ore. The leach pad is storing high-grade pregnant leach solution (PLS) as perched aquifers above areas that are compacted and difficult to drain. These operational and hydraulic challenges made it particularly difficult to spatially predict the precise locations of the inventory build-up. Fortunately, the challenges at Los Filos are not unique to the mine, and others have taken steps elsewhere to reduce metal inventory through a program that targets areas for inventory drawdown. For example, Ghorbani et al. (2016) noted that a method of injecting barren reagent solutions, applied directly to specific areas of a leach pad to reduce inventory, was presented by Wan and Brierley (1997) and Wan (1997). Seal (2004; 2007), Seal and Jung (2005), and Seal et al. (2012) have put the injection methodology into practice in Nevada and Colorado gold mines with a technology called Hydro-Jex®. The goal of Hydro-Jex has been to supply reagents at a high pressure over a short duration, followed by periodical low pressure rinse periods to remove leached metal and resupply fresh reagent to the ore."

Jan 1, 2017

By A. A. Campoli

A stress control design strategy was developed to minimize the explosive failure of highly stressed pillars, during room-and-pillar retreat mining conducted between stiff immediate roof-and-floor strata. A confined core coal pillar strength model was based on in-mine geotechnical evaluations of successful room-and-pillar and longwall bump control designs. Tributary area and linear shear angle approaches were used to estimate development and gob side abutment pillar loads for supercritical section widths. Subcritical width sections separated by barrier pillars to control stress within total extraction panels were optimized with the boundary element program MULSIM/NL.

Jan 1, 1994

By D. W. Leyshon

The fluidized solids technique for the calcination of phosphate rock has been well established for over 10 years. This paper is intended to review the recent performance of many of the Dorr-Oliver FluoSolids* calciners. In addition, design features of these three compartment refrac¬tory construction reactors will be described and a comparison made with fuel requirements for single compartment calcination. Also presented will be certain, aspects of the use of the rock including a discussion of non sulfate sulfur in the rock. A system is described for producing a blended mixture of calcined and uncalcined rock.

Jan 1, 1972

By Chas. L. Emery

"The laws of rock mechanics apply equally well to all rock structures, and open pits are not exceptions. The concepts and some arguments about the emphasis to be placed on various aspects of open-pit design are discussed in this article.RocksROCK can be described as a granular material consisting of grains and glue. The grains may be fragments of other rocks or polycrystalline aggregates. The glue may be ferruginous, calcareous, argillaceous, siliceous or other material connecting the grains. In a crystal intergrowth, the outer layers of the crystals in contact with each other may be considered to act as a glue. Water may be a glue in clay or a grain in a crystal structure. Air and other fluids or gases are grains if they occupy spaces in a granular mass. Such grains are functional either chemically or mechanically or both."

Jan 1, 1966

By Fazel G. Jahromi, Ahmad Ghahreman

"Atmospheric leaching of arsenical sulfide concentrates, and especially enargite leaching, is one of the major challenges within the current hydrometallurgy research area. One of the recent processes developed for sulfide ore treatment is atmospheric leaching in the presence of AF 5, a novel carbon based catalyst, in chloride media. The quantification of different ion concentrations during enargite and chalcopyrite leaching in the presence of AF 5 were measured and the copper recovery rates of 97% and 96% were achieved. The objective of this study is to shed light on the leaching mechanism of the sulfide minerals. Based on the speciation of iron and copper by different titration methods, the AF 5 catalyst first reduced ferric and cupric ions and then oxidized ferrous, cuprous and arsenite ions. The oxidation behavior of the catalyst enhanced the leaching results. The AF 5 catalyst also caused in situ precipitation of scorodite in leaching experiment. The speciation of ions in the chloride media were simulated by Phreeqc software and the dominant species in the leaching solution were determined.INTRODUCTION The hydrometallurgy of copper has been used for several decades and is still under development for more complex copper sulfide minerals due to their refractory nature. Most of the world copper reserves are in the form of chalcopyrite; and enargite is known as a major contaminant. Pyrometallurgical processing of enargite is problematic due to arsenic release and tight environmental regulations (Peacey, Gupta, and Ford n.d.). On the other hand, lower recoveries in the hydrometallurgical processes make most of these processes impractical. Several leaching processes have been developed for the leaching of copper sulfide minerals. Some of the common treatment methods for copper sulfide minerals are pressure oxidation leaching (POX), CESL, Activox, Albion process, atmospheric ferric sulfate leaching, Dynatec, Galvanox, and Hydro copper process (Barr, Defreyne, and Mayhew 2005; Conner and Anderson 2013; D.G. Dixon, Mayne, and Baxter 2008; Hyvärinen and Hämäläinen 2005; Palmer and Johnson 2005; Rohner, Bartsch, and Ngoviky 2012). Generally it is not viable to dissolve copper sulfide minerals at ambient pressure in mild acidic media and dissolution of these refractory minerals requires harsh conditions in the presence of oxidant materials (Biswas and Davenport 2002). Ferric ions have been used as an oxidant in different media in copper sulfide leaching processes. U. S. Bureau of Mines’ Reno Metallurgy Research Center in 1969 (Haver and Wong 1971) investigated ferric chloride leaching of chalcopyrite. Dutrizac and Macdonald (1972) studied ferric sulfate leaching of enargite. Based on this study, 50% of the copper was recovered at 80-85 ºC after 7 days of leaching. Cupric ions can also be used as an oxidant. Parker, Paul, and Power (1981) stated that cupric/cuprous couples are more effective than ferric/ferrous couples in chloride media because they are rapid and reversible. The Hydro Copper process leaches copper sulfide minerals in chloride solution catalyzed by cupric ions. In this process, copper dissolves as cuprous ions in presence of cupric ions (about 10 g/L) (Hyvärinen and Hämäläinen 2005)."

Jan 1, 2017

By M K. Singh

Mining is nothing but an art - besides being a science - of extracting valuable minerals from the womb of the mother earth. In this gigantic task, a large number of machinery and equipment are employed judiciously. Wire ropes play a vital role in lifting or hoisting men and materials under hostile/adverse working conditions and constitute a major item of investment on machinery/equipment. The economy of using a wire rope is a concern for engineers, users and the planners. The economic use of wire ropes for mining purposes largely depends on the following factors;Mechanical design considerations - which include tensile strength of wires, elasticity, resistance to abrasion and crushing, fatigue values, static and dynamic loads on wire ropes, factor of safety, fleet angle, etc. Metallurgical consideration - Composition and heat treatment of wire materials, defects like inclusions and voids, surface quality factor, lubrications, micro structural parameters. Operational consideration - Seizing and cutting of rope, storage, care and maintenance, cutting back, etc. Environmental consideration - Temperature and humidity, pit condition, dust, corrosive atmosphere, etc. In the present paper, an attempt will be made to suggest steps for achieving optimum economy while using the wire ropes for extraction of precious minerals and coal keeping in view the points noted earlier. Once technical viability is established, economy is the ultimate consideration for an industry for safe hoisting of men and material.

Jan 1, 2000

By J. S. Godard

The mining developments in western Quebec have shown the ores of this district to be more complex in character than was at first expected. When the initial discoveries were made it was thought that the ores would be similar in character to those of Kirkland Lake and Porcupine areas. Developments have since shown that although the ores along the southern margin of the belt are somewhat similar, those within the belt, constituting by far the greater proportion, are vastly different, being complex mixtures of base-metal sulphides carrying values in the precious metals. These mixtures of base-metal sulphides of copper, zinc, and iron, present several problems to the metallurgist, especially in their concentration into marketable products. For the purpose .of this paper the following classification may be made of the ores of the district. Group I. - Milling Ores: (a) Ores in which~ arsenopyrite is the predominating sulphide. In this class of ore the gold occurs in fractures in the quartz and is associated to a lesser extent with the arsenopyrite and pyrite. Examples of this class of ore are the Granada, south of Pelletier lake, and the O'Brien and the Thompson in Cadillac township. (b) Ores in which iron pyrite is the predominating sulphide and gold is the valuable constituent. This may also be classed as a concentrating ore-Group III.

Jan 1, 1928

Summary of the morning's events with a Written Contribution to Paper No. 4 and author responses

Jan 1, 1947

By Akira Yazawa

In the field of pyrometallurgy, the equilibrium evaluation has recently become easy by use of thermodynamic software, but it is strongly desired to estimate the amounts of non-equilibrium minor components to simulate practical processes. However, simple physico-chemical technique can not be applied to evaluate practical non-equilibrium components for many reasons. As an engineering solution for postulated equilibrium system, the activity coefficient is modified and introduced as the simulation parameter referred to as the "adjustment coefficient." This modified thermodynamic calculations were adopted to various sulfide roasting processes where many solid phases are participating and the system is not necessarily in equilibrium. Successful simulation was realized by assigning suitable adjustment coefficients for minor components which form a pseudo solid solution in the calcine. Some examples from sulfation roasting and dearsenizing roasting were discussed. In the smelting system, the loss of copper in slag is caused by equilibrium and non- equilibrium reasons, that is, chemical dissolution and entrainment of copper in slag. The total copper content of slag was simulated by use of the adjustment coefficient for entrained copper.

Jan 1, 1998

By S. R. Borrowman

Mill tailings from conventional uranium extraction processes contain nearly all of the radium originally in the ore. Such tailings require controlled storage in perpetuity to safeguard the surrounding environment from radioactive contamination. Alternatives to controlled storage of the tailings are (1) removal of the radium from the tailings for separate storage or use or (2) removal of the radium when processing the uranium ore. In laboratory tests conducted by the Federal Bureau of Mines, radium was leached from tailings using either hydrochloric acid or ethylenediamine tetraacetic acid. A hydrochloric acid leaching method was used to extract both radium and uranium from the ore to yield tailings containing less radium than those produced by either conventional sulfuric acid or alkaline leaching processes. From 77 to 94 percent of the radium in mill tailings was concentrated by sedimentation in slime fractions representing nearly 25 weight-percent of the original sample.

Jan 1, 1975

By H. Z. Kuyumcu

Associated with the development of a novel microbiological oxidation process for the conditioning of iron hydroxide slurries from ferrous mine waters, there is a realistic chance to make the contained iron available for a material utilization. The transformation of ferrous into ferric compounds is coupled with the precipitation of iron hydroxisulphate mostly in terms of the mineral Schwert-mannite. The further treatment of the iron hydroxisulphate has to be aimed on the processing for product recovery and product refinement. For many potential applications, e.g. in the ceramic industry, the pigment industry or for metallurgical applications, the removal of sulphate is essential. For the dehydration of the iron hydroxisulphate and the sulphate removal, microwave heating technology is a beneficial method. In contrast to conventional thermal heating processes the supply of energy in microwave application takes place directly within the material through the dissipation of electromagnetic energy, i.e. no heating medium is needed. It is a volumetric heating process regardless of the surface of the material. The rapid and targeted energy supply and the good controllability of microwave heating systems are advantages which have led to a wide variety of applications in industrial processes. Among the diverse use for heating of temperature-sensitive, chemical and pharmaceutical products as well as foodstuffs the number of applications also in mineral and solid processing increases. At the Department for Mechanical Process Engineering and Solids Processing of the Technical University Berlin the use of microwave technology for the treatment of iron hydroxisulphates has been investigated systematically within the framework of a cooperative research project. The paper at hand shows results from material conversion tests subject to a variation of the relevant process parameters. The reaction products are characterized and the process is compared with the conventional heating in a rotary kiln.

Jan 1, 2014

By Michael Arnold, Robert Bachus, Michael Bracher, Jamey Rosen, Robert Roff

"For a high hazard USACE facility, the Center Hill Dam in Tennessee, several disparate streams of data were compiled into a single geospatial and relational enterprise data management system to store, analyze, visualize and distribute the data collected during installation of a deep cutoff wall. These data streams included historical drawings and pre-construction plans and grouting records; geological data from boreholes; attributes of barrier wall elements; element verticality data analyzed from multiple measurement methods; and concrete field and laboratory analytical data. A previously developed data management system developed by the authors, WallTracker, was extensively modified to also include manually collected and real-time measurements from several types of dam monitoring instruments. The system now uses enterprise database technologies with Geographical Information Systems capabilities to manage and relate these data streams into a common platform and allows access to the raw and interpreted data via web and desktop-based interactive tools, including interactive map and cross-sectional viewers and other graphical and tabular reporting tools. One of the primary benefits of this system is the neartransparent interaction that is possible with the Nashville District of USACE on the project. These techniques can now be effectively incorporated into systems that address the unique construction and data management tracking requirements for dams, dikes, and levees.IntroductionThe Center Hill Dam rehabilitation, as with other deep foundation installations, requires the contractor to collect a substantial amount of information over the course of the project, both for internal quality control of construction progress and methods, and for demonstrating compliance with owner specifications. This paper discusses techniques used at Center Hill Dam for consolidating, visualizing and analyzing construction and instrumentation data using relational database and Geographic Information Systems (GIS) technology, collectively referred to as an Information Management System (IMS).The remainder of this paper presents the needs and objectives of the IMS, the components and data flows involved, the capabilities and user interfaces of the systems, and the benefits for the end users."

Jan 1, 2017

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By Knut L. Sandvik, Erik Larsen

Crystalline silicon solar cells are the most important solar cells manufactured today. This will most probably remain the situation the next decade. The future silicon feedstock is most likely not reject from the production of electronic-grade silicon. There will probably be a more direct solar-grade silicon route, excluding the electronic-grade silicon "detour". Estimated global solar energy demand in 2001 required approximately 5,500 tons of silicon feedstock. This required 65,000 tons of quartz. If the trend continues, the solar energy demand in 2010 would require approximately 30,000 tons of silicon feedstock and 350,000 tons of quartz, although the need for quartz probably will be lower than this. Quartzite has been regarded as the most suitable primary raw material used in the silicon solar cell production chain. This may change as the raw material requirements for the production of metallurgical-grade silicon are most likely to change. In addition, quartz or other silica-containing minerals from other rocks may be of a higher purity or contain lesser amounts of the most harmful elements. This favours increased beneficiation of primary raw materials in the future solar silicon feedstock production chain.

Jan 1, 2003

By Lanre M. Oshinowo, André Bakker

"An understanding of the parameters that govern the just-suspended impeller speed, Njs, and the distribution of solids, is critical to the efficient operation of hydrometallurgical and other processes involving solid-liquid suspensions. In this paper, the distribution of solids in stirred tanks under a range of solids loadings (0.5 to 50 vol%) was predicted using CFD and validated against experimental data obtained from the literature. The multiphase flow is modeled using the Eulerian Granular Multiphase model. This paper will also review the established design parameter Njs in the context of scale-up and compare it to the quality of solids dispersion as a means of assessing correct scale-up in suspension tank design. The results of this study will describe a straightforward procedure to obtaining comprehensive information about reactor behavior with complex CFD models.The performance of hydrofoil impellers and a 45° pitched-blade turbine at suspending solids under different agitation speeds was studied. Both single and dual impeller operation have been evaluated. The settled solids fraction for speeds below N js, and the cloud height for impeller speeds above Njs were predicted. The CFD predictions are in good agreement with experimental literature data on velocity distribution and cloud height."

Jan 1, 2001

By Luis R. Bittencourt

Research efforts have been made to characterize a refractory Brazilian bauxite ore composed basically of gibbsite, kaolinite and quartz. Detailed polished-section microprobe analysis of the unbroken ore has been used to describe the liberation characteristics and the association between mineral phases. The linear grade distributions for selected particle size fractions were determined by means? of a particular implementation of King's Random Fracture Model that uses the exponential model for the distribution of linear intercepts through both dispersed (kaolinite) and continuous (gibbsite) phases. The corresponding volumetric grade distributions were then determined by means of a constrained optimization technique for the solution of the transformation equation. Batch flotation experiments were carried out to determine the kinetics for particles of different sizes and the results correlated with the liberation spectrum for each size class.

Jan 1, 1991

By D. Kang

The adsorption behavior of silver in ammoniacal solutions on to activated carbon has been studied. The parameters affecting the adsorption of silver on to activated carbon included temperature, agitation speed, concentration of cations and anions as well as that of ammonia. It was found that the adsorption of silver from ammoniacal solutions was dependent upon the initial silver concentration in the solution and other factors. The recovery of silver from ammoniacal solutions was found to be not so effective as the case with gold reported earlier. The adsorption rate was relatively slow overall, despite a rather fast initial adsorption. The apparent activation energy for the adsorption was measured to be 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1998

Heap leaching has become one of the prime technologies used for the recovery of precious metals from low-grade ores over the past ten years. The recovery process involves mining and stacking the ore on engineered leach pads, with or without crushing and/or agglomeration, followed by leaching with a low concentration sodium cyanide solution. The metal-bearing, pregnant solution is then processed by zinc precipitation or activated carbon absorption to extract the precious metals. The leaching process continues until all economic metal values are removed at which time the spent heap leach pads, the leached materials and excess process solutions require decommissioning. The management of these solutions may present a potential challenge for successful and environmentally sound decommissioning due to their composition, volume or continuity of generation from the spent ore even though active leaching has been terminated. The principal objectives of solution management in decommissioning spent heap leach pads are to meet all operative environmental regulations in a cost-effective manner and to leave the pads in a condition where they do not present a long-term liability either to the operator or to the environment. This involves the reduction in volume of the residual process solutions and/or treatment of these solutions to where they meet applicable water quality criteria. In the past, the environmental and economic aspects of decommissioning and solution management have been overlooked or under-estimated during the planning of mining operations. As a result, there is a potential for long-term liabilities and costs to be recognized only at the end of active leaching, a time at which operating revenues and cash-flow are minimal. Therefore, the decommissioning process requires addressing at the mine planning stage and agencies now require that a plan for solution management after the cessation of operations be submitted prior to initiation of mining. This paper discusses aspects of process solution management during decommissioning, both in terms of quantity and quality, and how potential issues may be recognized and planned for in the initial stages of heap leach design.

Jan 1, 1992