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By Onuralp Yucel, Ahmet Turan, Murat Alkan, Hasan Ozer

SHS (Self-propagating High-temperature Synthesis) is one of the important methods to synthesize B4C powders. The process contains the reaction of boron oxide powders (B2O3) with magnesium reducing agent and carbon black carburizer. SHS products are leached in HCl media to purify synthesized B4C powders in the following step. In the present study, effects of various functional additives (KClO3, KHSO4, MgSO4.7H2O, NaCl, MgO and Na2SO4) in the SHS stage were carried out. Various proportions of the additives were mixed with the initial SHS charge mixtures. Two different molar ratios were employed in the initial SHS mixtures as 1:3:0.8 B2O3:Mg:C and 1:2.5:0.8 B2O3:Mg:C. After the SHS step, HCl leaching process was applied to the SHS products. Filter cakes were dried and characterized by using X-Ray Diffraction Spectroscopy, BET and chemical analysis techniques.

Jan 1, 2015

By H A. Linn, K Winn, C W. Lee

The Q-slope method for rock slope engineering was developed to enable engineering geologists and rock engineers to rapidly assess the stability of excavated rock slopes in the field and make optimal adjustments to slope angles as rock mass conditions become apparent during construction of road cuts or benches. An empirical relationship between Q-slope and long-term stable slope angle is now supported through over 500 cases studies from Asia, Australia, the Americas and Europe. This paper presents about the stability analysis by first-ever applying Q-slope method on abandoned quarry wall in Singapore. The 30 m high rock slope which is composed of monzogranite rock was severely damaged by blasting operation. As the rock slope is intended for public view the objective was to retain the natural outlook and without any artificial support application thus manual scaling was carried out to clear the loosed rock blocks. In the end stable slope angle of clean rock face is determined once again by Q-slope method.

Nov 29, 2022

By Aris Tambunan, Nella Lubis, Nurafrianti Saala, Komang Widhiayanto, Herry Saputra, Rudolf Sitorus

Maximizing mining recovery rates and minimizing ore loss are pivotal objectives for economic efficiency and operational effectiveness. This study explores methods to address these imperatives by enhancing ore production and recovery through improved blasting techniques and spillage control in the Martabe Gold Mine Project in North Sumatra Province, Indonesia. Between 2018 and 2021, the average mining recovery rate stood at 93%, resulting in a potential annual ore loss of 7% and a potential quarterly financial impact of close to $2 million. Maintaining and enhancing mining recovery became crucial, with a planned 30% increase in total material movement for 2022. The mining recovery target for 2022 was set at 96% based on best achievement historical data from 2021 to increase ore tonnage by 203 KTon per annum. To achieve the primary objective of increasing ore production by improving mining recovery, the study focused on predicting and controlling the movement of blasted ore to reduce spillage and enhancing the grade control model to reflect actual conditions post-blasting. Several alternative solutions were explored, primarily emphasizing drilling and blasting activities. Essential methods included capturing the actual blasting movement to adjust the ore block based on blasting design data and post-blasting muckpile topography. This approach minimizes ore loss by providing output as ore block adjustment based on post-blast movement data. In addition, the tie-up design was adjusted to control ore spillage outside the pit ridge. The implementation of these methods yielded significant improvements. Adjusting the ore block based on actual blasting movement contributed $1,545,764 in benefits. Controlling ore spillage outside the pit ridge achieved a 10% reduction in spillage, contributing $79,184 in benefits. These enhancements successfully met the 2022 mining recovery target of 96%, marking a 3% increase from 2021. Consequently, ore loss was reduced by 178 KTon throughout 2022, resulting in a financial impact of $7.3 million. The study underscores the significance of precise blasting techniques and effective spillage control in enhancing mining recovery rates.

Jan 21, 2025

By T. Nesane, S. S. Mnyakeni-Moleele, L. C. Murulana

The effectiveness of two synthesized ionic liquids, 1-(benzyloxy)-1-oxopropan-2-aminium 4-methylbenzenesulfonate (1-BOPAMS) and 4-(benzyloxy)-4-oxobutan-1-aminium 4-methylbenzenesulfonate (4-BOBAMS), were evaluated for mild steel corrosion inhibition in 1.0 M hydro-chloric acid solution, using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), and gravimetric techniques. Organic moieties responsible for the adsorption process on mild steel surface were investigated using Fourier transform infrared spectroscopy (FTIR). Gravimetric analysis revealed that the inhibition efficiency of 1-BOPAMS and 4-BOBAMS increased with concentration, with maximum inhibition values of 90.32% and 97.91%, respectively, at the highest concentration of the inhibitors. Gibbs free energy (ΔG°ads) values indicated a strong interaction between the mild steel surface and the molecules of the ionic liquids, and that the adsorption process was spontaneous. These values also show that the inhibitive nature of ionic liquids against mild steel corrosion is caused by a mixedtype of adsorption film formed on the steel surface. The Langmuir adsorption isotherm was used to describe the adsorption of ionic liquid molecules onto the mild steel surface. Polarization curves showed that 1-BOPAMS and 4-BOBAMS have a similar effect on both the anodic and cathodic half-reactions, indicating that they prevent the dissolution of mild steel through both physical and chemical process. Nyquist plots were defined by incomplete semicircle capacitive loops, showing that the charge transfer mechanism controls the corrosion of mild steel in acidic solution.

Apr 1, 2021

By COLIN A. LAWRENCE, Anthony Del Vescovo

All Rights Reserved. Printed in the United States of America. Information contained in this work has been obtained by SME, Inc. from sources believed to be reliable. However, neither SME nor its authors guarantee the accuracy or completeness of any information published herein, and neither SME nor its authors shall be responsible for any errors, omissions, or damages arising out of use of this information. This work is published with the understanding that SME and its authors are supplying information but are not attempting to render engineering or other professional services. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher. Any statement or views presented here are those of individual authors and are not necessarily those of the SME. The mention of trade names for commercial products does not imply the approval or endorsement of SME.

Dec 1, 2017

By E. Lee Bray

"Editor’s note: The editors thank those who make this annual issue possible. A special thank you goes out to the Industrial Minerals Annual Review editor, to the Industrial Minerals & Aggregates Division Technical Committee chair and vice chairs, and to the authors of the individual commodity profiles.Jim Norman, member SME, of Tetra Tech Geo, is the industrial minerals annual review editor. Edgar Blanco, member SME, of Freeport- McMoRan, is chair of the Industrial Minerals &Aggregates Division’s Technical Committee.The technical committee vice chairs include:• NickTushar Gupta and Sallie Gaillard, of the USGS, members SME, agricultural materials.• Abhishek Choudhuryand Xihui Yin, members SME, of Montana Tech and Kemira, repectively, ceramic and refractory materials.• Bobbi Strange and Riddhika Jain, members SME, of Outotec, Martin Marietta and Outotec, respectively, chemical raw materials.• Snehamoy Chatterjee, Alyssa Kendir and Alind Chandra, members SME, of BMT, Universityof Kentucky and Michigan Tech, respectively,construction aggregates.• Subham Verma, Gauran Soni and Freddy Sime, members SME, fillers and pigments.• Kaiwu Huang, Thomas Hilderbrand and Ricardo Santander members SME, of Virginia Tech, Thiele Kaolin and Carbo Ceramics, respectively, sorbents, filters and process aids.• Rhaghay Dubey and William Rapier, members SME, of Outotec and a consultant, respectively, specialty minerals.On behalf of ME readers, the editors thankTwo U.S. alumina refineries produced an estimated 1.5 Mt (1.65 million st) of alumina from imported bauxite in the United States in 2018. The 500-kt/a (550,000-stpy) refinery in Burnside, LA, owned by Almatis Inc. produced specialty alumina used in the abrasives, ceramics, chemical and refractory industries. The 1.2-Mt/a (1.32 million-stpy) refinery in Gramercy, LA, owned by Noranda Alumina LLC produced alumina mostly for use in aluminum smelters but also produced specialty alumina. An upgrade project at the Gramercy refinery to convert 200 kt/a (220,000 stpy) of capacity to produce more profitable specialty alumina was completed in the first half of 2018, and another project to increase capacity was started but a completion schedule was not available. The amount of new capacity was not disclosed, but it would be used to produce nonmetallurgical grade alumina. The 2.3-Mt/a (2.5 million-stpy) refinery in Point Comfort, TX, which was temporarily shut down in March 2016, remained closed throughout the year."

Jul 1, 2019

By Raymond O. Dannenberg

The gas-combustion retort developed by the Federal Bureau of Mines at the Rifle Oil Shale Project near Rifle, Colo., is a continuous, gravity-feed retort. The heat required to convert the kerogen in the oil shale to liquid oil is generated by the combustion of product gas and carbonaceous residue remaining on the retorted shale after the kerogen has been converted to oil, gas, and residue. A study of the effects of the process variables on retort operation, product yields, and product properties is important to the successful solution of the problems encountered in the development of a satisfactory process. Statistical methods were used to design the experiments and analyze the effects of the rate of shale throughput, the composition of dilution gas, the height of the shale bed above the air entry, air-gas distributor design, shale size range, and the ratios of the flow rates of the various gas streams entering the retort to the rate of shale throughput.

Jan 1, 1960

By W. H. Oppelt

The continuous gasification of lignite in an externally heated alloy-steel re-tort was investigated by the Bureau of Mines, Grand Forks, N. Dak., from 1945 to 1951. The main objective of the long-term experimental program was to obtain data on the mechanical performance of this type of gasification retort, particularly the alloy-steel heat-transfer surface of the retort, when operated on large pilot-plant scale. At the same time, extensive experimental data were obtained concerning the effect of process variables and the effect of a limited number of design modifications on gasifier performance. In the period covered by this progress report 4 pilot-plant runs totaling 2,879 hours of operation were completed with the rolled-plate, 310-alloy reaction tube. Over 30 million cubic feet of gas, having H2-CO ratios from 2.1 to 4.4, was made by the partial gasification of 636 tons of 1-1/2-by 3/8-inch natural lignite. Rates of gas generation were from 8,200 to 14,300 cubic feet per hour. Three of the four runs were carried out with the lowered gas offtake or continuous-annulus design modification of the gasification retort. In the final run of the series, gasification of lignite from seven different mines in North Dakota and Saskatchewan, Canada, was investigated at similar combustion-space temperatures and lignite and steam feed rates.

Jan 1, 1955

By William O. Vanderburg

This paper gives the results of a reconnaissance of the mining districts of Mineral County, Nev., made during the month of June and the first 10 days in October 1936.3/ During the field work virtually all the mining districts in the county were visited and many data were obtained relative to active and inactive properties. The report covers the location of the various mining districts, nature of deposits, ownership, information on past and current activity, data on economic conditions, and general information likely to be useful to operators and investors and others interested in mining. The geology of the deposits is discussed only in a general way. For nearly three-quarters of a century mining tin Mineral County has been the principal if not the only industry of importance. At times it has reached a very low ebb, and at other times it has been attended by the wild excitement that usually accompanies valuable discoveries of precious metals.

Jan 1, 1937

By Donald F. MacDonald

This report aims to discuss, from the viewpoint of the mining geologist, the bearing of topographic and geologic conditions on cer- tain problems that arose in the construction of the Panama Canal. T+ is published by the Bureau of Mines as a contribution to engineer- ing liters ure because it presents information that shows how geology and topography must be considered by the mining engineer in plan- ning excavations and in removing loose material and solid rock in the safest and most efficient manner. The printing of this bulletin has been approved by the governor of the Panama Canal, as it was impracticable for the Panama Canal to give this information to the general public in any of its publications. The "sword cut" of Goethals and his men did not sever the Isth- mian barrier; it merely clove the hills to a depth of 40 feet above sea level. This cut and the great areas of low valleys at both ends of it have been covered with fresh water to the 85-foot level. This high-level lake held by dams at either end, the 85-foot locks, by which ships enter it, and the dredged approaches from the two oceans constitute the Panama Canal. In the preparation of accurate estimates concerning the cost of large excavations information regarding the geologic conditions, as obtained by a study of natural features, is necessary. Drill holes and test pits will furnish supplementary geologic information, but without a gen- eral knowledge of the geologic conditions it will not be possible for the constructing engineer to answer such questions as the following: (1) What rock units will be encountered in the excavation and in what proportion? (2) What will be the cost of drilling each for blasting (3) How far apart and how deep must the drill holes be to efficiently break the rock of each to the proper size-not too fine nor yet too coarse? In this connection jointing, fissuring, bedding, toughness, and other physical characteristics must be considered (4) How steep will the slopes of the excavation stand, and to what extent will they wash and trench on exposure to the atmosphere? (5) What proportion of the material to be excavated is of such physical character that it may be utilized in any other part of the project, such as in concrete construction, road making, wharves, breakwaters, riprap work, etc.

Jan 1, 1915

By N. A. C. Smith, E. W. Dean, W. A. Jacobs, H. H. Hill

Fractional distillation is the most important process in the commercial refining of petroleum. The same procedure, conducted on a small scale, is the basis of a number of analytical methods of wide application in the petroleum laboratory. The Bureau of Mines has studied apparatus and procedure for the distillation analysis of petroleum, and this report is presented as a record of developments up to the present time. The work is incomplete, but the extensive information that has been obtained to date is made available as a guide in handling laboratory distillation problems. The analytical distillation of petroleum is commonly made to determine range of boiling points or to separate the oil. into fractions for detailed examination, or both. When only one of these two ends is sought the procedure involved is notably simpler than when, as is more common, information is required regarding both boiling range and properties of fractions. Moreover the degree of minuteness of measurement and the accuracy of the data required from analytical distillations differ considerably. Often the simplest sort of comparative figures are satisfactory; other tests require complicated and highly tedious procedure. No one distillation method is universally applicable, and it is impossible for anyone group of investigators to foresee all the different kinds of requirements that may occur in the industry.

Jan 1, 1922

By R. Gerritsen, Erwin de Jong, E. van der Velde, C. te Boekhorst

"In recent years the market for Mixed-In-Place soil mix techniques in the Netherlands has been growing rapidly. Initially the technique was used to create cut-off walls near river dikes and as a vibration free method to create retaining walls for building pits. Studies have been undertaken and projects are executed in order to strengthen the dike itself by the use of Mixed-In-Place techniques. In February 2012 Bauer Funderingstechniek started the construction of the first polder in the Netherlands with their approved Mixed-In-Place cut-off walls. This article explains the background of the use of this cost-effective and durable construction method and discusses how the challenging requirements from the client were fulfilled, both in design and execution. The quality assurance and quality control consisted of preliminary soil and mixture investigations, extensive measurements during construction and leakage detection through geophysical methods. The information is presented in 3 case histories, all subprojects of a large infrastructural project ‘Leeuwarden Vrij-Baan’ in the Netherlands.INTRODUCTIONThe Netherlands have a worldwide reputation in creating their own country by reclaiming land from the sea. Since the 15th century the Dutch have been creating “polders”, areas of reclaimed land below sea level, surrounded by dykes and with a mechanically maintained water level. In the 20th century the use of artificial polders became an interesting construction method for creating underpasses below motorways and canals using watertight geomembranes to create an impermeable layer that separated the polder from its surroundings. These kinds of structures have one big disadvantage, they need a lot of space. The main idea of such a structure is that the upward water pressure under the geomembrane has to be in balance with the remaining soil on top of it. For this reason, the geomembrane has to be placed at a depth significantly deeper than the polder surface, depending on the hydraulic head in the aquifer. Slopes of 1:3 (1 vertical : 3 horizontal) are most commonly used, resulting in very large open excavations and massive earthworks, even for relatively small underpasses. Special measures can be taken to reduce the spatial use with vertical limits, but these measures will increase the building costs (Gerritsen et al. 2014)."

Jan 1, 2015

By T. M. Barczak

The term "resultant load vector" is defined as the representation of the forces applied to a longwall roof support element by strata activity through a single, quantifiable measure of support resistance. The relatively complex kinematics of the shield structure prohibits determination of support resistance simply from the summation of leg forces. In the research reported in this Bureau of Mines study, the mechanics of the shield structure were evaluated, and a technique was developed whereby the resultant shield loading could be determined by instrumenting supports with pressure transducers and strain gauges to measure leg, canopy capsule, and lemniscate link forces. This technique has been laboratory tested in the Bureau's Mine Roof Simulator. Functional relationships among variables were assessed, and confidence intervals were established for prediction of the resultant load vector parameters. Resultant load measurements were taken on five instrumented shields on an active longwall face in Colorado. Results were analyzed and found to be consistent with shield mechanics and anticipated roof behavior. Benefits to be derived from this research, future efforts, and long-range goals are discussed.

Jan 1, 1986

By C. H. Herty

Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility, steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis is easy to obtain, provided that a normal top discard is taken, as is al¬ways the case in steels poured with hot-top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel. For a large tonnage of steels which go into articles manufactured by deep-drawing processes, killed steel has never been successfully applied because with the present deoxida¬tion practice, low-carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, - that is to say, deoxidized with manganese and perhaps a small amount of aluminum, - the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper-central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low-carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel. These defects would be minimized by clean killed steel.

Jan 1, 1931

By Gary W. Hudiburgh

The gangue in some magnetite ore bodies contains feldspar; the alkali content of the feldspar reduces the usefulness of these iron ores. One method of decreasing the feldspar content in magnetite concentrate is froth flotation. The amine flotation of feldspar from magnetite concentrate was investigated using zeta potential measurements, Hallimond tube flotation tests and laboratory-scale flotation tests. The zeta potential of various feldspars (microcline, albite, anorthite, oliqoclase and anorthoclase) were determined as a function of pH; the point of zero charge ranged from pH 1.4 to 2.5. Hallimond tube flotation tests using two amine reagents were conducted on the feldspars. Hallimond tube flotation tests using six amine flotation reagents were performed on the cobber tails (quartz, albite and microcline) from a magnetite concentrating plant; in all cases, over 85 percent flotation recovery was obtained at pH 8 and 10-5 to 10-4 [M] collector addition. Laboratory-scale (667 grams) flotation tests were performed on the magnetite concentrate in an attempt to float the feldspar which had reported to the concentrate. The effects of three different collectors, two levels of collector concentration, three pH levels, starch and HF acid were investigated.

Jan 1, 1975

By Jr. Herty

Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility, steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis is easy to obtain, provided that a normal top discard is taken, as is always the case in steels poured with hot-top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel. For a large tonnage of steels which go into articles manufactured by deep-drawing processes, killed steel has never been successfully applied because with the present deoxidation practice, low-carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, - that is to say, deoxidized with manganese and perhaps a small amount of aluminum, - the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper-central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low-carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel.

Jan 1, 1931

By Ross W. Smith

Microorganisms are increasingly finding use in mineral processing and hydrometallurgy both for the enhancement of mineral engineering operations and for the remediation of mineral industry wastes. Some of the applications, such as biologically assisted leaching of sulfide ores and biooxidation of refractory sulfide gold ores, are established commercial processes. Others, such as the use of organisms for the removal of heavy metal ions from dilute aqueous streams, are nearing commercial application. Other uses of microorganisms are potentially possible. These include use of microorganisms in leaching non-sulfide ores, the flocculation or flotation of minerals and remediation of toxic chemicals discharged from mineral engineering operations.

Jan 1, 1993

By Manuel Gomez, V. F. Parry, John B. Goodman

"INTRODUCTION The need for an accurate and precise analytical method for determining moisture in coals of high water content has been recognized by the coal industry as well as the fuel technologist. Interest in this particular phase of coal technology extends back to the early work of German investigators on the brown coals of Central Europe. Studies by these workers led to the establishment of a direct immiscible liquid-distillation method 4/ as the accepted moisture determining technique in European laboratories. Direct moisture determining methods, those methods that utilize various techniques to drive off the water from a given sample of coal and either collect the water in a calibrated receiver or selectively trap the water driven off in a suitable absorber, have found little favor in the United States. They have been treated merely as research tools.5/ The problem of moisture determination in low-rank coals of the United States has not been given much consideration because such coals contribute only about 2 percent of the total United States production. With renewed activity in low-temperature carbonization and with the growth of interest in coal and coal-tar hydrogenation, the American coals of lover rank containing 20 to 40 percent bed moisture will be subjected to extensive investigation. If the low-rank coals of the United States are to be accurately appraised, the need for qualitative and quantitative analytical proceeded becomes more pronounced. These coals, especially the lignites of Texas and North Dakota, are highly susceptible to oxidation, a process that proceeds to a greater or less extort when low-rank, high-moisture coals are treated by oven-drying methods. The extent of this atmospheric oxidation has been described and evaluated by numerous workers. 7/In many respects, the problem of moisture determination in low-rank coals, those found in the United States and the high-moisture coals of Central Europe, is similar. Conversely, the problem of moisture determination assumes a different aspect when the coals of the eastern and the middle-west sections of the United States are considered. Present methods, the loss in weight gravimetic-type procedures, serve adequately to test these low-moisture coals. The determination of moisture in coals containing 20 to 40 percent water should be approached from a direct method rather than from an indirect gravimetic-type procedure because of the oxidative tendencies of these coals and the demonstratrated inability of a loss-in-weight technique to remove all the water in a given sample of coal."

May 1, 1953

By W. D. Walker

This information circular is offered to the coal-mining industry for use as a guide in selecting, placing, and caring for fire-fighting equipment in coal mines. Its purpose is to suggest minimum requirements for fire protection underground, and it is presented with the hope that it will aid in establishing adequate standards that will provide reasonable protection against underground fires in coal mines. Potentially, a coal mine is a hazardous fire area. Coal itself is a combustible substance, easily ignited. In addition, large quantities of other combustible materials must be present in the area of operations; these include materials for roof support, track ties, doors, ventilation stoppings, lubricants, etc.

Jan 1, 1953

By William P. Diamond

This report presents results of a cooperative research project between the U.S. Bureau of Mines and BethEnergy Mines, Inc. Four coreholes (two before mining and two after mining) were drilled at a longwall mine operating in the Lower Kittanning Coalbed to obtain coal and rock samples from over-lying strata to determine their gas content at various times in the mining cycle. The results of those tests indicate that 91 pct of the gas removed from the overlying strata came from coalbeds. Material balance calculations were made to compare the volume of gas produced both from gob gas vent holes drilled on the panel and gas removed by the mine's ventilation system with the volume of gas removed from strata directly overlying the panel to a height of 275 ft. This analysis indicates that only 40 pct of the total gas produced from the panel actually came from the strata directly overlying the panel. The remaining volume of gas production probably migrated to the longwall gob from overlying, and perhaps underlying, strata immediately adjacent to the panel and perhaps from greater distances downdip because of the establishment of a long-term pressure gradient in the study area.

Jan 1, 2010