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By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By J. J. Moore

The application of plasma technology to process metallurgy is briefly discussed. Experiments involving in-flight reduction of minerals (taconite, chromite, in particular) with a solid-based carbon reductant are described. The resultant metallic and slag product analysis is discussed with respect to thermodynamic and kinetic considerations.

Jan 1, 1985

By R. D. Wilson

Ten to twelve million tons of dust is produced by cement kilns annu-ally in the United States, resulting in a serious waste disposal problem. The Bureau of Mines investigated two alkali volatilization methods for converting this dust into materials for making portland cement and a useful potassium product. Portland cement kiln dust was found to be composed of finely ground cement raw materials (CaC03 and 8i02) having a layer of alkali sulfate (K2S04 and Na2S04). In this form, it cannot be directly recycled to cement kilns because concrete is weakened by a reaction between the alkali and the aggregate. Portland cements with 28-day strengths above 5,000 psi were produced from low-alkali residues using sintering and melting methods. For nearly complete removal of alkalies, primarily potassium sulfate, from cement kiln dust, a temperature above 1,300° C and a reducing atmosphere were required.

Jan 1, 1986

By P. R. Pereira

This paper presents a comparison between the simulations of a semi-empirical model and a theoretical model for the prediction of radial stress in rock. The results of the simulations were compared to the results of a field test. The comparison of the radial stress predictions shows that in the semi-empirical model use of the plane wave approximation as the basis for the prediction of the radial stress provides a much better result than the theoretical model. The theoretical model includes the correct elastic wave geometry and theory but fails twice, firstly by considering the charge as a point (unit) energy source therefore; and secondly by using a Delta function with a very sharp rise and decay time to simulate, with no distinction between non-linear and linear zones, the attenuation of the energy per unit volume at the shock wave front as the wave moves away from the borehole. The results of the semi-empirical model were within the same order of magnitude as the results from the field test whereas only one result from the theoretical model came close to the result of the field test. However, even this closer result for the theoretical should be taken with caution as there was no measurement in the field test made at this distance from the borehole. Finally, because of its potential portability, convenience, and cost-effectiveness the theoretical model can be a most valuable tool for mining and civil construction operators in the early design of blasting rounds and of the mining operation itself.

Jan 1, 1993

By Brian Hart, Stamen S. Dimov

"The naturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. It can adversely affect the process of gold recovery during the cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution.Treatments of carbonaceous ores with chemical surfactants as blinding agents to limit preg-robbing have shown promising results but at the same time have demonstrated that, if not properly used, could have a strong detrimental effect on the gold recovery process. High dosages of surfactants used as passivating agents for carbonaceous matter could lead to unwanted partial passivation of the activated carbon added during the CIL process and severely impact the gold recovery. Optimal dosage for various surfactants would strongly depend on the ore mineralogy and the parameters of the pulp (temperature, pH, surface area and maturity of the carbonaceous material, etc).This paper describes an experimental study on the effectiveness of various commercially available blinding agents used to minimize the preg-robbing capacity of naturally occurring carbonaceous matter. The scope of the study was to: i) establish the optimum addition of blanking agent (surfactant) to minimize the preg-robbing capacity of the CM in the ore, and ii) establish maximum threshold amounts of blanking agents to be used before it negatively impacts the preg-robbing capacity of the activated carbon used in the CIL process. The study procedure involves standardized doping tests to evaluate the maximum preg-robbing capacity of treated CM, coupled with surface analysis with ToF-SIMS to monitor the presence and the degree of loading of these chemical surfactants on both the naturally occurring CM and the added activated carbon.INTRODUCTIONNaturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. Thus, it can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution. The preg-robbing properties of this naturally occurring carbonaceous matter can vary widely between ores, and within a single ore body (Dunne et al.,2013;Helm et al.,2009;Miller et al.,2005). The degree of preg-robbing related to the CM within an ore is defined by several parameters: total organic carbon (TOC) content, surface area, maturity (i.e., crystallinity) of the CM and the presence of various functional groups on the surface of the CM. Preg-robbing gold ores continue to be a significant challenge because of the lack of a single or universal solutions."

Jan 1, 2016

By Gerry Houlahan

"The 2015 Outstanding Project Award (OPA), which recognizes the superior work of DFI members, was awarded for the San Francisco- Oakland Bay Bridge New East Span. The award was presented to representatives from Caltrans and the T.Y. Lin International/Moffatt & Nichol Joint Venture at the DFI 40th Annual Conference on Deep Foundations in Oakland, Calif. A committee selected this project based on size, scope and challenges of the project; degree of innovation and ingenuity exercised; and the uniqueness of the solution to the difficulties of the job. A bridge across the bay between San Francisco and Oakland was proposed as early as 1872, but it took until November 12, 1936, until it became a reality. The bridge spans to the west of Yerba Buena Island were conventional suspension spans, while the east spans used a steel cantilever truss design and simple steel truss spans. This double-deck bridge served the Bay Area well until 1989. In that year, the magnitude 7.1 Loma Prieta earthquake damaged the East Span of the San Francisco-Oakland Bay Bridge. The resulting interruption to service across the bay demonstrated the vital role this bridge plays in the economic and life safety activities of the Bay Area. The project owner, California Department of Transportation (Caltrans), determined that the safest, most cost-effective solution was a total bridge replacement. The Engineer-of-Record, T.Y. Lin International/ Moffatt & Nichol Joint Venture, working closely with Caltrans, the Metropolitan Transportation Commission (MTC) and the California Transportation Commission (CTC), was charged with developing a comprehensive design strategy that met the project’s stringent criteria for seismic safety. These criteria included the new bridge’s designation as a regional Lifeline Structure that must open to emergency traffic shortly after the occurrence of a 1,500-year return period earthquake"

Jan 1, 2015

By Janene Barter

Telfer Gold Mine treats both gold/copper oxide and sulfide ores in a remote location in the Great Sandy Desert, Western Australia. Currently, the oxide gold ore is treated in a conventional CIL circuit by blending the low and high grade copper ores to minimise cyanide consumption and allow smooth operation. The sulfide ore is treated through a flotation circuit to produce pyrite and copper concentrates. The pyrite concentrate is treated in the CIL. Copper concentrate is stockpiled and sold to a smelter for further processing. In recent times, as the depth of the pit has increased the copper head grade has also increased, to the point where the ore was becoming uneconomical to treat. In addition, it was desirable to reduce the amount of cyanide reporting to the tails dam both from an environmental and economical viewpoint. Newcrest Mining Limited engaged GRD Minproc Limited to evaluated a process to reduce the amount of cyanide entering the tail dam with consideration given to copper recovery. From this investigation, the Sulfidisation, Acidification, Recycle and Thickening (SART) process was selected. A detailed testwork program for SART was undertaken with the objective to design and construct a SART plant at Telfer. This paper outlines how the SART process was chosen and summarises the testwork that led to the design of the SART plant. It also touches on some of the important issues for designing this type of process.

Jan 1, 1998

By M. Blagojev, R. Tomanec

"Studies reported in this paper used polymetallic Pb-Zn-Sb-As-(Ag, Au) ore from Dražnja, Kosovo. The ore is comparatively rich in Zn (6.56%) and Pb (2.87%), but with high rates of Sb and As. Conventional lead and zinc concentration by flotation produced galena and sphalerite rich concentrate with high recovery, but with excessive As and Sb. After chemical analyses, which could not detect the reason for the excessive elements, ore minerals were identified under the ore microscope, their texture characterized, and degree of liberation of useful minerals was assessed. Microscopy of the mineral concentrates revealed complex intergrowths of galena and marmatite minerals mostly with sulphosalt minerals (boulangerite, jamesonite and bournonite) and also with arsenopyrite mainly responsible for the unsatisfactory quality of the concentrate. These complex sulphosalts, among other things have similar behaviour during the flotation concentration, and in spite of their interlocking with galena, therefore inadequate liberation, sulphosalts remain in the lead concentrate. Microscopic analyses indicated that a better galena concentration product is possible with a higher rate of mineral liberation, and then by selective floc flotation of some sulphosalt minerals. Purpose of this work was to show that only chemical analysis is not sufficient, according to that we solved the problem by precise mineral identification and time consuming mineral liberation measurements. INTRODUCTION The polymetallic Pb-Zn-Sb-As-(Ag, Au) ore body of Dražnja, Kosovo, fairly rich in Zn (6.56%) and Pb (2.87%) was repeatedly explored and once even worked. Mineralization at Draznja was primarily represented by sphalerite, galenite and marcasite/pirite. Some sections comprise massive sulphides, and others are lower grade zones of semi-massive sphalerite/galena or marcasite/pyrite dominant sulphides. The ore body II was formed in the southern gallery in the structure Çukë – Lajthishtë (with content of 3.16% Pb and 7.31% Zn). Pb-Zn ore with increased content of As, Sb sulphosalts is not rare phenomenon in the world. While previously treated as unprofitable, economical uninteresting ore, today with development processing and new reagents (organic, ecologic), are the topic of scientific papers. The examination of Pb-Zn ore with high content of sulphosalts we find in deposits as: The hydrothermal vein deposit of Harja in the Baia Mare area, contain a wide variety of sulphosalts [Cook, N. & Damian, G., 1997]; also the deposits Fankou Mine in Guangdong Province and the Dachang Mine in Guangxi Province, where the flotation concentration of galena and jamesonite takes place [Runqing Liu et al. 2015], [Zhang Ting, Qin Wen-Qing, 2015];. On a samples from Tibet in China flotation separation test of galena and jamesonite was conducted [Sun Wei, Han Haisheng, Tao Hongbiao, Liu Runqing, 2015]. According to history of investigation, the mineralized area of Dražnja has a long history of exploration and possible exploitation activities [Slowey, Galen, 2009]. Recent workings were carried out in three stages through the 20th century."

Jan 1, 2018

By E. T. Pecina

Bioleaching is a viable option for the processing of auriargentiferous refractory ores with high arsenic content. The application of mesophilic (A. ferrooxidans and ?L. ferrooxidans?) and thermophilic bacteria of the genus Sulfolobus (S. solfataricus and S. acidocaldarius) as oxidant treatment before the cyanidation of an industrial arsenical pyrite concentrate is presented. The results show that extraction of gold and silver increases due to bio-oxidation caused by mesophilic bacteria and results in a maximum gold recovery of 68%. In all strains studied, biooxidation resulted in an average silver recovery of 50%. The results showed that all evaluated strains were sensitive to solids content (5 to 20%) and average particle size (75 and 38 µm) of the concentrate.

Jan 1, 2010

By Yoichi Takeda

Copper solubility in Si02-CaO-FeOx slag equilibrated with copper matte in 10% S02 atmosphere at 1573K was estimated. Essential parameters are activity coefficients of copper oxide and sulfide, oxygen and sulfur potentials and activity of copper in the slag-matte system. A large number of experiments provide proper parameters to calculate copper solubility in slag. A classical thermodynamic model postulating CUOO.5 and CuSo.; molecules assists in estimating copper solubility in slag. Additions of Si02 and CaO reduce copper solubility almost in any condition. Copper loss, that is function copper solubility and slag volume, in the silica saturated Si02-FeOx binary slag is minimally equilibrated with less than 66% copper matte while copper loss in the 50% FeOx-SiOrCaO ternary slag saturated with 2CaOSi02 is minimally equilibrated with over 66% copper matte. This slag composition has potential for continuous copper converting, direct copper production or high-grade matte production.

Jan 1, 2003

By Kenneth McGowan

"The aluminum industry is the 5th largest consumer of energy and the largest consumer of energy on a per-weight basis. Process heating accounts for 25% of the energy consumed to manufacture aluminum. Consequently, the generation of this energy results in the production of a significant amount of CO2 (over 3.75 million metric tons in 2003)1. As a result, the Aluminum Industry Technology Roadmap of 2003 listed the development of improved refractory materials as a goal to reduce energy use and decrease greenhouse gas creation. The result of a R&D effort addressing this desire is the development of patented microporous refractory materials for metal contact applications in all furnace areas including the belly band. It has been demonstrated that this material can reduce energy consumption up to 38% in furnaces and significantly reduce heat loss in launder and trough systems. Furthermore the material developed is non-wetting and remains un-penetrated by metal throughout its lifetime. The material does not contribute to the formation of corundum. As a result, the energy efficiency of an older lining remains intact compared to standard refractory materials which may have an initial high insulating value (such as lightweights and board) or standard dense refractory (even with penetration inhibitors) both of which show a rapid increase in thermal conductivity as the refractory is penetrated with aluminum and formed corundumIntroductionThe aluminum industry is the second largest producer of metal in the United States, behind the iron and steel industry. It is the 5th largest consumer of energy and the largest consumer of energy on a per-weight basis. Process heating is required to melt, hold, purify, alloy, and heat treat the metal and accounts for 25% of the energy consumed to manufacture aluminum. As such, process heating is the second largest energy consuming operation. Smelting, which utilizes an electrolytic reduction process is the largest energy consuming operation1.Most process heating is accomplished through the use of fossil fuels, either directly or indirectly. The choice of fuel is dependent on a plant’s location and fossil fuel availability. Table I shows the processes impacted by refractories and the calculated BTU’s generated by usage of the respective fuels as well as the Metric Tons (MT) of metal passed through each process in 20001."

Jan 1, 2009

By S Gomez-Hernandez, P D. Munro

Filtered dry stack tailing storage facilities offer many advantages over thickened tailing storage facilities and yet, most of the mining companies still prefer the latter.Some of the advantages of filtered dry stack tailing storage facilities are: increased structural integrity of the tailing storage facility, which is even more critical in areas of high seismicity, close to nearby communities or environmentally sensitive areas; maximised water recovery which is particularly important in arid environments where water is an extremely valuable resource and its supply is regulated; optimised recovery of valuable metals in the process water, avoiding high cyanide concentration going to detoxification (both aspects haven’t been emphasised enough in technical papers on this subject); optimised space to store the tailings in mountainous regions; minimised elevation of embankment height, providing a safe option to store the tailings in places where there is limited area available; simplified license approval to operate where the tailing facility is a big issue; and avoidance of potential problems with nearby communities.Filtered dry stack tailing storage facilities have some disadvantages such as: technology limitations in operations that process high throughputs (eg >50 000 tpd) as they require many filters resulting in high maintenance and operating costs; higher capital cost; low efficiency in the filtration process, particularly in ores with high clay content increasing operating problems and capital cost; the new technology risk with possible debottlenecking issues and a longer time to achieve the design throughput; and the need to treat larger water flow rates when the water balance is negative.This paper analyses: the operating practices of Mexican gold and silver operations using filtered dry stacking storage facilities; implementation issues, advantages and disadvantages; quantifiable reductions in gold and silver losses and actual lower detoxification cost; and current trends to use filtered dry stacking storage facilities in new projects. The data gathered raises questions about (a) the need to collect data on tailings filterability, and; (b) reducing the current high operating cost of tailings filtration.CITATION:Espinosa-Gomez, R, Gomez-Hernandez, S and Munro, P D, 2018. Tailing filtration practices in Mexican gold and silver mines, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 275–282 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By J. van Deventer

Volatile gold prices in the face of rising costs for mining and refining is causing the mines to look for new ways to reduce costs and increase recoveries. This task is complicated by the fact that the gold in hereto unexploited reserves is associated with increasingly complex ores - either preg-robbing, refractory, associated with high concentrations of copper, or all of the above. Ion exchange resins can play a significant role in this quest for improvement. Although ion exchange resins have been used in Former Soviet Union (FSU) countries for the recovery of gold for many decades, it is still not widely used in the Western World. Synthetically manufactured ion exchange resins can be tailor-made to suit the chemical and mechanical characteristics of a specific application. As such, ion exchange resins can be used in a variety of solution matrices (e.g. cyanide, thiosulphate and acid), and process designs (recovery from clear liquor after solid-liquid separation or directly from the leached pulp). In this paper, a number of applications are discussed along with a review of recent developments in ion exchange technology.

Jan 1, 2014

By E L. Kotova

Completeness of extraction of a mineral from ore depends on many reasons. First of all it is a function of quality of disintegration of ore. It is supposed that two basic factors: character of structure and texture of the ore aggregate and a disintegration technique influence the quality of the mineral aggregate destruction, æopeningÆ of its internal boundaries. In this paper, the problem of technological mineralogy from the point of view of genesis of the mineral aggregate, its typomorphical features and methods of their quantitative description are discussed. The purpose of this research is to provide information for technologists. It should enable the development of a rational flexible scheme of disintegration of ore with full extraction of a useful component, without its losses and without unnecessary expenses of energy. For achievement of this purpose the mineralogical information should have ½number and a measure+. By the authors, the technique of the quantitative analysis of fabric of the mineral aggregate based on several models û thermodynamic, crystallographic and geometrical is offered and discussed. The leading role in the quantitative analysis of a fabric of ore belongs to internal bounders. But internal bounders of the mineral aggregate by bounders or faces of the mineral individuals or mineral grains are formed. Their geometry, orientation concerning own (mineral grain) crystallographic lattices, orientation and distribution in space of the ore aggregate are proportional to the energy accumulated at origin and the further growth. These characteristics of mineral individuals are consequences of conditions of their formation. That is why the named triad of models is used. From crystallography it is known that faces of different stability and mobility form borders of crystals. They also contain different quantity of energy. Mineral grains also are faceted by different energy borders. They form intergrowths with each other according to a principle of balance or unbalance. That is why in addition to traditional parameters of the description of a fabric of the mineral aggregate (mode and grainmetrical composition) it is necessary to add new. For example, length and the square of intergrowthing bounders of mineral individuals differentiated (in couples), crystallographic symbols of borders, their roughness and so forth. Consequently, solving a problem of the geometrical characteristic of borders, we define also its power characteristic. In this paper experience of application of our technology in studying ores of one of deposits of Urals Mountains is presented. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices, which are carrying out the analysis in a semi-automatic mode, are possessed. Structure and texture of rock or ore aggregate reflect its formation and transformation conditions. It is important to understand that disintegration energy cannot be more than aggregation energy, the energy of intergrowths formation. The square and orientation of mineral individuals borders vary at pressures or stresses of mineral aggregate evolution. These phenomena often cause selective increase in the square of borders at constant average grain size, ie the granulation. Granulation presents the increase in quantity of mineral individuals while their modal share remains constant. At the same time their average mineral grains size. Some mineral individuals increase in size at increased pressure. When lithostatic or lateral pressure drops the majority of mineral grains increases in volume at the cost of intersticial or film solutions or fine grains. These are only special examples of the ontogenesis of the mineral aggregate. They illustrate our statement that all changes in fabric of the mineral aggregate are a reaction on varying external (ie geological) conditions. It is possible to consider that structurisation of totality of mineral individuals as a whole is a process of adaptation of the mineral aggregate, which forms and exists in varying force and energy fields. Differential and integrated geometry of total internal boundaries of the mineral aggregate serves as adaptation mechanism of the mineral grains system. Boundaries form intergrowths of the mineral aggregate. Thus, it is possible to consider that the most informative parameters of the stereometric analysis for restoration of the ontogenesis of the mineral aggregate are the following. First of all, it is a quantitative estimation of the volumetric shape of the ore mineral in crystallographic coordinates, a total area of borders of all mineral grains in the aggregate, the specific square of their boundaries, the specific square of intergrowth boundaries of the ore mineral separately with grains of each minerals of the matrix of the mineral aggregate as well as traditional grainsmetric and modal composition. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices that are carrying out the analysis in a semi-automatic mode are possessed.

Jan 1, 2008

By T. K. Mukherjee, C. K. Gupta

"The importance of the processing of secondary resources such as solid industrial wastes and liquid effluents as well as byroducts for the recovery of the associated metal values hardly needs any elaboration. Such processing contributes in no small measure towards the augmentation of the availability and the supply position of resources. As an added benefit, it leads to a reduction in environmental pollution caused by the undesirable waste materials. As some typical examples of secondary resources in the Indian scenario, mention can be made of spent catalysts, metal/alloy scrap, ash, consumed batteries, flue dust, slag, sludge and slime, pickling solutions, spent acids, plating rinse solutions, spent etchants, waste water from synthetic fibre manufacture and from tanneries etc .. These wastes constitute a source of a variety of non ferrous metals. In the processing of secondary resources like these, the techniques of hydrometallurgy such as solvent extraction playa pivotal role.This paper outlines the efforts made to use solvent extraction to recover (1) base metals such as copper, zinc, nickel and cobalt from a number of secondary resources like cake, and sludge (2) refractory metals like molybdenum and vanadium from sulphidic byproducts and spent catalyst and (3) nuclear metal like uranium from phosphoric acid. In the case of base metals, process flowsheet involving the use of acidic extractants such as DEHPA and PC88A have been optimised. The problem of iron removal from the leach liquor, which influences the metal recovery process significantly, has drawn a special emphasis. In the case of refractory metals, basic extractants like Alarnine 336 has been pressed into service to produce kilogramme quantities of pure salts of molybdenum and vanadium. Finally, the paper gives a brief account of plant experience in recovering uranium from phosphoric acid, using a solvent system comosed of DEHPA and TOPO."

Jan 1, 1996

By R. H. Jefferson

An electrochemical method to selectively determine sulfur dioxide in the presence of sulfur trioxide was investigated. A hydrophobic gas-permeable membrane separates the gas sample solution from an internal filling solution containing a fixed quantity of chloride ion and a sufficiently large excess of sodium bisulfite so that its concentration may be considered constant. Sulfur dioxide diffuses through the membrane to dissolve in the internal filling solution and liberates an equivalent quantity of hydrogen ions. The electromotive force between a precision-ground, flat-ended pH electrode, which acts as the sensing element, and a chloride sensing electrode, which acts as the reference element, gives a direct measure of S02 in the gas sample solution. Calibration curves in water, tetrachloromercurate (TCM) , and citrate buffer absorption solutions were closely parallel with slopes in their linear segments, ranging from 57 to 52 mv/decade of S02 concentration. The slopes compare reasonably well with the theoretically expected slope of 58 millivolts at 21° C. The water standard curve was linear with respect to the logarithm of S02 concentration from 1 to 1,000 ppm S02; the TCM standard curve was linear from 10 to 2,000 ppm S02; and the citrate standard curve was linear from 30 to 5,000 ppm S02' The high efficiency and nontoxicity of citrate favor it as a substitute for the conventionally used TCM in the absorption solution.

Jan 1, 1976

By Malcolm Black

Introduction The circumstances under which the gold mining industry was forced to curtail operations a few years ago are well known to all. The effect of those circumstances is particularly noticeable when one enters some of the larger mills that were designed, in better times, to treat relatively large tonnages. On their grinding floors one will observe that a number of grinding units are lying idle, and the ravages of rust are everywhere in evidence. The same applies to other equipment throughout these mills. In 1941, we found it necessary to reduce tonnage considerably in the Wright-Hargreaves mill. With the assumption that a lower tonnage would be of long duration, we began to focus our attention on some of the idle equipment with a view to re-arrangement of the flow-sheet for greater economy of operation. In an article by the writer published in the Engineering and Mining Journal (March, April, and May issues, 1939) , it was pointed out that in designing this mill there was a very limited floor space available. The choice of thickening equipment was imposed solely by the necessity for space: conservation. Thickening by gravity would have required 5,000 square feet of floor space, whereas Genter thickeners required only 1,200 square feet. As a consequence, the Genters were chosen. The decision to add flotation to the circuit was made primarily to save space. On a cost-plus-tail basis, 80 to 100 hours agitation on all pulp would produce similar overall results, but would require much more space.

Jan 1, 1948

By Berger. P.

The accepted definition of the function of an edge protector fails to specify adequately the several tasks which it must perform to be functionally effective: detailed analysis of these tasks leads to the reasoned conclusion that they cannot satisfactorily be fulfilled by the conventional types of "edge-strips". The true cost of edge protector failure is cumulative: renewal costs are dwarfed by the increased operating expenses and production losses which result from but partial or incipient failure of the edge-strip; yet, the several supposedly improved types, for use with starter-blanks, generally were "built down to a price", prolonging the agony, as it were. Clearly, a fresh appraisal of the problem was overdue, and more especially so with the advent of "permanent" cathodes. As a result, new methods of edge .protection have been developed, including the so-called "EDGEWISE" system in which the present author as patentee *) has a vested interest-which he hereby declares. Due mention is made of recent progress in protecting the edges of aluminium "Jumbo" cathodes in zinc electrowinning operations, although the present Paper is more concerned with edge protection of starter-blanks and permanent cathodes in copper ER/EW processes, where most of the "old" problems now may justifiably be claimed to have been overcome, Mention is also made - albeit at this time necessarily only briefly, and confined to edge protection - of "rigidized" metal blanks and permanent cathodes: a most recent development**) which may prove to represent a "breakthrough": time will tell.

Jan 1, 1987

By A. J. Oliver, C. E. O’Neil, I. J. Itzkovitch, V. A. Ettel

A new solvent extraction process for the separation of cobalt, copper and zinc from nickel sulphate process streams has been developed. It involves selective extraction of these elements with a quaternary ammonium thiocyanate dissolved in an aromatic diluent. The chemical principles of this process have been investigated and are described, together with background physico-chemical data relating to the use of this solvent. Long-term testing in a continuous "mini-plant" circuit gave high-purity nickel and cobalt products (Ni/Co —200011 and Co/Ni ~1000/1 respectively).

Jan 1, 1976

By D. D. Tannant, H. Ozturk

Thin spray-on liners are increasingly being used as rock support in underground mines. The adhesive strength between the liner and the rock surface is an important design parameter. Adhesion tests were conducted to assess the impact on adhesion of the presence of oil, water, and dust on a substrate, and the roughness and grain size of different substrates. Other factors such as curing time, loading rate, and liner thickness were also considered. Adhesion was measured using a pull test of a 33 mm diameter elevator bolt attached to an over-cored section of liner with strong epoxy. Most tests were performed using Tekflex liner material, although five other liner products were also tested. Adhesive strengths of about 2 MPa can be achieved with Tekflex under optimal conditions. Long-term creep tests showed that the adhesive strength could drop by at least 50% when the liner carries load for about a month. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa. As the thickness of the liner increases, the adhesive strength to a substrate appears to decrease.

Jan 1, 2007