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By I. L. Nichols

The inplace cyanidation leaching of gold from placer deposits is a potential method for treating gravels too deeply buried and too low in gold content to be processed economically by conventional dredging methods. Laboratory experiments were made to evaluate those placer cyanidation factors adaptable to small-scale studies. The variables investigated included gold particle size and location in sand beds, cyanide solution flow rate, and cyanide solution strength as factors affecting gold solubility rates. The solution flow rate, in turn, was influenced by variables such as bed slope, solution head pressure, and sand size, and the effects of these factors were studied. Free gold, minus 150-mesh and finer in size, is rapidly dissolved by dilute cyanide solutions from mixtures of gold and silica sand prepared to simulate placer deposits. About 94 percent of minus 325-mesh free gold was extracted in 5 hours from silica sand mixtures, and 94 percent extraction of minus 150-mesh gold was obtained in 21 hours with 0.1 percent NaCN solutions. Moving solutions were almost twice as effective in leaching free gold from silica sand mixtures than stagnant solutions.

Jan 1, 1971

By R. Schaller, Ch. Karcher, A. Thess

"Electron beam evaporation of liquid metals is an innovative technology increasingly used in industry to produce very thin coatings of high purity. In this process the surface of a metal ingot, placed in a water-cooled copper crucible, is heated by bombarding it with a high-energy electron beam gun. The material melts, forming a free surface and eventually starting to evaporate. The rising vapor cloud condensates as a thin film on a moving substrate. The strong energy input at the free surface gives rise to vigorous thermos capillary and buoyancy driven convective motion within the melt, leading to unwelcome heat losses. This paper aims to show how these losses can be reduced by optimizing the geometry of the crucible and by using external magnetic fields. We present both experimental and numerical results.IntroductionElectron beam evaporation of liquid metals [l] is an innovative PVD-technology which is excellently suited for the industrial production of high-quality coatings. In this vacuum process a high-energy electron beam heats up the surface of a metal ingot. The ingot melts and forms a free surface. A schematic view of the arrangement is shown in Figure 1. When the temperature of the free surface exceeds the actual (pressure-dependent) saturation temperature of the ambient gas, the liquid starts to vaporize. The rising vapor cloud finally condensates on a moving substrate located at some distance above. To guarantee a superior quality of the coating the melt is typically confined in a water-cooled copper crucible. The intensive cooling is necessary to avoid chemical reactions between the melt and the crucible walls, that is, crucible materials and their reaction products are practically excluded from evaporation."

Jan 1, 1999

A. Bement, Chicago,Ill. (communication to the Secretary*):— Formerly it was the general practice of engineers to designate coal that is free from moisture and ash as " combustible," notwithstandirig that it contains oxygen and nitrogen. The origin of this practice was more particularly due to the requirements in connection with boiler-testing, which demanded a consideration of that portion of the fuel which took part in the combuition-process because results based on a unit of either moist or dry coal were not comparable, since both moisture and ash were recognized as variable quantities. Thus, a pound of " combustible " became a standard of value, and was treated as a constant before employing measurements of heating-power and calculating therefrom the percentage of efficiency. The recognition of this term " combustible " was an advance to be credited to the engineer rather than to the chemist, because the latter, not having to do with the interpretation of analyses in practice outside the laboratory, usually saw no reason for reporting results in terms other than those of the moist-coal composition. Some years ago I needed a table of fuel-composition in terms of moist, dry, moisture-free and ash-free coal, and of the combustible components. This table required the use of the word combustible in its proper sense, for the purpose of designating carbon, hydrogen, and sulphur, instead of including these three elements with oxygen and nitrogen, to which aggregate the term combustible was formerly applied. To make such a tabulation involved either the use of the inconvenient and cumbersome term, "ash- and moisture-free coal," or of some other representative term, and for this purpose I adopted the expression pure coal, which is short, simple, convenient, and technically correct. It is also harmonious, because it agrees

Jan 1, 1909

By A. Bouajila1

Minerals processing organisations will be more and more under intense competitive pressure. Major changes are being experienced with intense respect to resources, processes, production strategies and markets. As result of international competition, only the most productive and cost-effective operations will survive. That is why operators in the minerals industry have always aimed to obtain better performance from their processes along the mineral extraction cycle starting from exploration up to the smelting step if any. A principal ingredient and perhaps the most important one in the process of evolution toward improved productivity is the achievement and implementation of an error-free production synonym of an ignorance-free operation. This is, at the same time, a guarantee for quality, a minimising factor for waste materials production, handling and disposal, and a maximising factor for labour utilisation. The notion of ?error or ignorance-free? -usually identified as a ?made in Japan? manufacturing mythology, will sound, at first impression, like a pious ideal, to be striven for but impossible to attain. Nevertheless, the introduction of measurement and detection technology in the minerals industry along the last century should benefit from the today?s sensors and control systems that explosively expanded beyond their traditional production base into far-ranging commercial ventures. The fastness and spread of those technologies will play an important role in the survival of innovative plants. Their role in information assimilation, and control of operations to maintain an error-free production environment, will help many plants to stay effective on their competitive course. In this paper the feasibility of the zero process ignorance concept as applied to the comminution circuits will be discussed and the challenge behind this ambitious move toward improved productivity will be outlined. Examples of pre-competitive R&D projects started at COREM in order to fulfil this prerogative will be presented.

May 1, 2001

By G. S. Walker, W. van Bronswijk

The accurate determination of free cyanide and metal cyanide complexes is of increasing interest to Carbon-in-Pulp (CIP) gold extraction operations as cyanide consumption is an important economic factor in the processing of complex ores. Characteristically complex ores are high cyanide consumers and these ores usually contain a range of sulfide minerals e.g. covellite (CuS), digenite (Cu1,S), chalcocite (Cu, S), Pyrrhotite (Feci-x)S), marcasite (FeS2), arsenic and antimony sulfides and zinc sulfide. These minerals can consume significant quantities of cyanide, e.g. various copper(!) cyanide complexes such as CuCN, Cu(CN)2·, Cu(CN)/ and Cu(CN)/ can form, depending on the cyanide to copper ratio in solution. Measurement of free and complexed cyanide is thus a prerequisite for efficient cyanide dosage control. Free cyanide can be determined potentiometrically or amperometrically but the methods are prone to error and are laborious [1]. Metal cyanide complexes can be determined by reverse phase HPLC, however, the species ofa single cation (e.g. Cu(CN)i-, Cu(CN);2 and Cu(CN)/) elute as one species [2]. Additionally the high amount of suspended matter in CIP leach solutions tends to introduce errors. Raman spectroscopy has the potential to be used as an in­line or on-line method of analysis. Free cyanide and the cyanides of gold, silver, copper and iron have been studied in aqueous alkaline solutions with a view to developing such a method. Spectra were obtained with a Bruker RFSl00 FT-Raman spectrometer using a 1064 nm laser delivering 800 mW of power at the sample. Depending on the solution, 250, 1000 or 4000 scans at 4 cm-1 resolution were accumulated. The cyanide stretches observed were relatively narrow (10 15 cm-1 full width at half height) and well resolved (Figure 1 ).

Jan 1, 1995

By Gaifeng Xue, Lijun Lu, Honghui Fang, Jiannyang Hwang

"Steel slag has been stockpiled in many steel mills due to its poor performance in various construction related applications. Free lime in steel slag has been considered as a major barrier for its utilizations. Composite of steel slag and powders of granulated blast furnace slag have been found an excellent cementitious material for concrete. Portland cement is not required in this kind of concrete. Concretes with various amounts of steel slag and powders of granulated blast furnace slag additions have been investigated. Physical and chemical properties of the products were examined. High performance concrete can be obtained. Field testing of the concrete products was conducted for various applications, including buildings and pavements, and the results demonstrated the soundness of the concrete. Drill cores of field tested concrete, with ages up to 26 years, were examined for the microstructures under SEM.IntroductionIn the steel industry, a major source of the solid waste is steel slag. Steel slag has poor stability in construction applications. This is a major reason that only a small amount of steel slag has been utilized. Some of the reported applications include the land filling/creation in the sea, road base materials, soil treatment for acid neutralization and micronutrients supply, and sintering aid in the sintering plant of the steel industry [1].To solve the stability problem for using steel slag as construction materials, the common approach is to find a method capable of depressing or eliminating the expansion of steel slag. Free lime in steel slag is the major component that causes the expansion. Aging and hydration pretreatment of free lime in steel slag are the well known methods for increasing the steel slag stability. However, there has been limited success on these approaches due to that a large portion of free lime is locked in the grains during the pretreatment process."

Jan 1, 2012

A price list of publications of the Geological Survey, complete to May, 1931, and with separate monthly notices of publications to (late, will be sent upon application to The Director, United States Geological Survey, Washington, D. C. A leaflet is issued each month listing new publications; it will be sent upon application to the Director, as well as Circulars containing information about topographic maps. Book publications of the Survey include (1) Annual Reports, (2) Monographs, (3) Professional Papers, (4) Bulletins, (5) Water Supply Papers, (6) chapters and volumes of Mineral Resources of the United States, (7) Folios of the Geologic Atlas of the United States and the World Atlas of Commercial Geology, (8) Topographic Folios and Topographic Maps that bear descriptive texts. Monographs, Folios of the Geologic Atlas of the United States and the World Atlas of Commercial Geology, and Topographic Folios and Topographic Maps, are not distributed free. A publication of one of the other classes can be distributed free only until the end of the fiscal year following that in which it was issued. No person can obtain more than one free copy of the same publication, and general requests for free publications, such as all of any series or all on any subject, can not be granted. In ordering publications one is requested to give both the series designation, as Bulletin 738 or Professional Paper 122, and the title. Give full address, plainly written, including county. Prepayment is required and may he made by postal, or express money order payable to the official charged with the sale of the publications. requested, as indicated in the discussion of each classification following; or it may be made in cash-exact amount -at sender's risk. Postage stamps are not accepted in payment for publications.

Jan 1, 1933

By G. V. R. Landman

In the early days of underground coal mining, the use of explosives to break coal resulted in a large number of disastrous methane and coal dust explosions and consequential loss of life. Research by the British, French, US authorities, amongst others, introduced many practices that significantly reduced the occurrence of such incidences. The use of explosives designed to be safe in a methane atmosphere, plus the creation of a second free face were two such practices which became commonly used in coal mines all over the world including southern Africa. With its associated coal cutting equipment and labour, the cost of creating a second free face is significant and this, together with the constant drive to reduce mining costs in a competitive market, causes mine management to regularly question the need for the second free face. Also, the safety and nature of permitted explosives has changed considerably since the days of black powder and nitroglycerine-based explosives with the introduction of water-based explosives. In southern Africa mining regulations pertaining to the blasting of coal has its origins in British research which was largely done in the first half of the twentieth century. More recent research by the US Bureau of Mine has resulted in a deeper understanding of some of the mechanisms of methane ignition by explosives and suggests that some of the earlier regulations can be relaxed to a certain extent without compromising safety. This paper gives an overview of the original research done in Europe and the more recent work in the USA, to give mine management and regulatory authorities a deeper understanding of the important safety issues when using explosives in a methane atmosphere. It also suggests that blasting off the solid is no less safe than using a second free face providing certain safety procedures are followed.

Jan 1, 2000

By R. Clarkson

"Free gold particles occur in many base metal and precious metal mines throughout the world. Due to the high density and malleability of gold, large circulating loads of free gold particles can build up over time in grinding circuits. This gold is often deposited in unintended traps throughout the mineral processing system.These unidentified free gold deposits represent a serious security risk as well as an inaccessible inventory of gold. Deposits of free gold particles often remain undetected by mine management until they are accidentally discovered while repairing mill equipment.Nuclear tracers have been used to determine the free gold recovery efficiency of gravity recovery equipment, drills, and sampling equipment (Clarkson, 1994, 1995; Walsh and Rao, 1986; Walsh and Kelly, 1992). In November, 1993, the author inspected the grinding circuit at La Mine Doyon in Rouyn-Noranda, Quebec and made recommendations to recover coarse gold and to eliminate gold traps from the circuit. In 1995, the author salted mineral processing circuits with radioactive gold particles. The gamma and X-ray radiation from gold’s nuclear isotope (Au198) were detected through steel, in pipes, and in moving equipment using scintillometers. The radiotracers proved to be a safe, rapid and accurate method of identifying gold traps and improving security.Nuclear TracersWhen particles of gold are placed in a nuclear reactor, some of the gold atoms (Au197) absorb another neutron in their nucleus to form gold’s radioactive isotope (Au198). In the process of radioactive decay, this isotope emits high energy gamma rays and X-rays which are easily detected (even through steel) with scintillometers.Radioactive gold (Au198) has a very short halflife of 2.7 days. At the relatively low activity levels used for tracing, the particles remain detectable with a small hand-held scintillometer for about 10 to 14 days. After 14 days the irradiated gold is close to background levels and within two months it is essentially non-radioactive. The radiation has no effect on the recovery characteristics of the gold particles. The gold radiotracers are very safe due to their very low level of radiation, short half-life, and their inherent physical and chemical stability. However, the use and possession of even mildly irradiated gold is strictly licensed and regulated."

Jan 1, 1997

By J. F. Barkley

[There is a general concept in the, coal trade that the moisture- and ash-free B.t.u. of coal from the same seam, and. surely from the same mine, is substantially a constant; that calculation of the -moisture- and ash-free B.t.u. value from the proximate analysis and B.t.u. determined in the laboratory will reveal whether a coal came from a given area or sears; and that, having this constant, the B.t.u. value of a coal sample can be calculated fairly closely upon a dry or as-received basis from the moisture and ash values of its proximate analysis.]

Jan 1, 1941

By N. W. Johnson

The behavior of non-sulphide gangue in chaloopyrite flotation circuits has been investigated. Plant and laboratory tests were carried out on five different ores, and linear relationships were found to exist between the rates of recovery of water and free nonsulphide gangue in the concentrates although there was evidence from pilot plant tests that these were linear approximations to parabolic curves over the limited regions which were observed. There was evidence that the free non-sulphide gangue enters the concentrate by hydraulic classification and a classification function has been proposed to define this behavior. This function is suitable for inclusion in a mathematical model of the process.

Jan 1, 1972

By L. C. George

The Bureau of Mines measured vapor pressures of selected mixtures in the binary system SnCla-ZnC12 by the static pressure method. Equations expressing the vapor pressure) and the heat and free energy of vaporization) as functions of temperature were developed by numerical analysis based on the sigma-plot method. It was found that the vapor pressure of any SnCl2-ZnCl2 mixture) at any temperature within the range of this investigation) could be accurately calculated from the derived values for the heat and free energy of vaporization for the mixture, with a probable error of 0.01 cm Hg or less.

Jan 1, 1967

By Joseph Cervik

Gas occurs in coalbeds in an adsorbed and a free gas state, Adsorbed gas is stored in the micropore structure and its transport is governed by Fick's law. The free gas occurs in the. fracture system and flows according to Darcy's law. These two modes of mass transport are interdependent. Production decline curves of coal-gas wells are of the constant percentage decline type and, thus, show no indications of flow characteristics peculiar to coal-gas reservoirs. The effectiveness of surface boreholes as a degasification scheme depends upon both good fracture permeability and a high fracture density. Conventional methods of reservoir engineering analysis are not applicable to coalbeds.

Jan 1, 1969

The American Gas Association, 420 Lexington Ave., New York, N. Y. The Proceedings and Reports of the American Gas Association are concerned with the technology and utilization of gas, and research along those lines. A list of publications will be sent upon request. Publications are classified under the general headings: Accident Prevention; Accounting; Commercial; General; Rates; Industrial; Publicity and Advertising; Technical; and Testing Laboratory. As' illustrations of the type of paper presented, the following are cited from the Technical classification: Evaluation of gas oils (1930), 40 cents; Agglutinating value of American coals (1927), free; Composition of coal in relation to spontaneous combustion (1927), free; Physical and chemical

Jan 1, 1933

By A. J. Lynch, N. W. Johnson, D. J. McKee

The behavior of nonsulfide gangue in chalcopyrite flotation circuits has been investigated. Plant and laboratory tests were conducted on five different ores. Linear relationships between the recovery rates of free nonsulfide gangue and water were observed. From pilot plant tests, there was evidence that the linear relationship was actually a linear approximation to a parabolic relationship. There was evidence that free nonsulfide gangue is transported from the pulp to the froth in the water and that the gangue is subjected to hydraulic classification in the froth column. A classification matrix has been proposed to define this behavior. This matrix is suitable for inclusion in a mathematical model of the process.

Jan 1, 1975

By Joseph Cervik

Gas occurs in coalbeds in an adsorbed and a free gas state. Adsorbed gas is stored in the micropore structure and its transport is governed by Fick's law. The free gas occurs in the fracture system and flows according to Darcy's law. These two modes of mass transport are interdependent. Production decline curves of coal-gas wells are of the constant percentage decline type and, thus, show no indications of flow characteristics peculiar to coal-gas reservoirs. The effectiveness of surface boreholes as a degasification scheme depends upon both good fracture permeability and a high fracture density. Conventional methods of reservoir engineering analysis are not applicable to coalbeds

May 1, 1969

By David Turnbull

In most reactions involving solids the transformation kinetics may be represented by the combination of two processes —those of nucleation and of growth. For example, Mehl and his coiq-orker in their studies on the transformation of austenite to pearlite in steels have been able to describe the kinetics in terms of the rates of nucleation and of growth. By micrographic examination of their specimens they determined the nucleation rate (rate of appearance of pearlite colonies) as a function of time, of percent transformation, and of temperature. They observed that after an incubation period in which no nuclei are observed, the number of nuclei appearing per unit time per unit of untransformed grain boundary area, increases at an increasng rate with time. When recrystallization rates have been interpreted in terms of rates of nucleation and growth and the rate of nucleation determined, an incubation period followed by an increasing rate of nucleation has also been reported. Among the studies in which this phenomenon has been observed are those of Kornfeld and coworkers3 on cold-drawn aluminum wire, of Anderson and Mehl4 n the recrystallization of aluminum sheet, and of Stanlcy and Meh15 on the recrystallization of silicon ferrite sheet. The existence of an incubation period during which no nuclei are observed does not appear to have been reconciled with the generally accepted Volmer-Becker theory of nucleation in condensed systems. This theory ostensibly requires the rate of appearance of nuclei to be independent of time. Volmer-Becker Theory In order to form a stable nuclcus of a new phase B in a mother phase A, the molecules or atoms of the mother phase must surmount a free energy barrier whose height is determined by the volume free energy change accompanying the transformation and the energy of the surface separating the two phases. The free energy difference between nuclei of various sizes and the molecules or atoms of the mother phase is plotted schematically in Fig I as a function of the radius of the nucleus r. This free energy difference is plotted for two values of the change of free energy per atom, (Jb — ja) accompanying the transformation when the volumes of the two phases are infinite. One of these values of (Jb—Ja) corresponds to a temperature above the temperature To at which the phascs A and B are in equilibrium, and the other to a temperature below To. In order for a nucleus of phase B to be stable at a temperature T² < TO, its radius must be equal to or greater than the critical value r* for which the free energy of formatioil of the nucleus is a maximum, the of phase B having radii equal to or less than r* will be called embryos hfehl and Jetter," in discussing the kinetics of nucleation in solid systems, suppose that embryos of critical size are formed

Jan 1, 1949

By David Turnbull

IN most reactions involving solids the transformation kinetics may be represented by the combination of two processes-those of nucleation and of growth. For example, Mehl and his coworkers 1,2 in their studies on the transformation of austenite to pearlite in steels have been able to describe the kinetics in terms of the rates of nucleation and of growth. By micrographic examination of their specimens they determined the nucleation rate (rate of appearance of pearlite colonies) as a function of time, of percent transformation, and of temperature. They observed that after an incubation period in which no nuclei are observed, the number of nuclei appearing per unit time per unit of untransformed grain boundary area, increases at an increasng rate with time. When recrystallization rates have been interpreted in terms of rates of nucleation and growth and the rate of nucleation determined, an incubation period followed by an increasing rate of nucleation has also been reported. Among the studies in which this phenomenon has been observed are those of Kornfeld and coworkers3 on cold-drawn aluminum wire, of Anderson and Mehl4 on the recrystallization of aluminum sheet, and of Stanley and Mehl5 on the recrystallization of silicon ferrite sheet. The existence of an incubation period during which no nuclei are observed does not appear to have been reconciled with the generally accepted Volmer-Becker theory of nucleation in condensed systems. This theory ostensibly requires the rate of appearance of nuclei to be independent of time. VOLMER-BECKER THEORY In order to form a stable nucleus of a new phase B in a mother phase A, the molecules or atoms of the mother phase must surmount a free energy barrier whose height is determined by the volume free energy change accompanying the transformation and the energy of the surface separating the two phases. The free energy difference between nuclei of various sizes and the molecules or atoms of the mother phase is plotted schematically in Fig I as a function of the radius of the nucleus r. This free energy difference is plotted for two values of the change of free energy per atom, (fB - fA) accompanying the transformation when the volumes of the two phases are infinite. One of these values of (fa-fA) corresponds to a temperature above the temperature To at which the phases A and B are in equilibrium, and the other to a temperature below To. In order for a nucleus of phase B to be stable at a temperature T2 < To, its radius must be equal to or greater than the critical value r* for which the free energy of formation of the nucleus is a maximum, ?f*. Aggregates of phase B having radii equal to or less than r* will be called embryos. Mehl and Jetter,6 in discussing the kinetics of nucleation in solid systems, suppose that embryos of critical size are formed

Jan 1, 1948

In the leaching and recovery of gold from copper containing gold ores using cyanidation, some copper minerals also dissolve which can have a detrimental effect on the process efficiency and economics. There are also environmental concerns with current operations discharging cyanide and copper cyanide species into tailings dams, and strict regulations prohibit this for greenfield plants. Cyanide destruction however is not an economic option for new plants treating copper-gold ores. This paper evaluates a potential recovery process to overcome the copper cyanide problem. Despite gold dissolution occurring in copper cyanide solutions having no free cyanide, gold recovery from ores is lower compared to free cyanide. Thus, cyanide addition has to be optimised to maximise the gold recovery whilst endeavouring to eliminate free cyanide at the completion of leaching (CN:Cu less than 3:1). Subsequently, copper cyanide can be recovered using activated carbon. The loaded copper cyanide is easily recovered from the carbon with a cyanide soak and distilled water wash such that the eluted CN :Cu ratio is less than 4:1. The copper could be recovered efficiently by electrowinning, by decreasing the pH of the eluant to 5. The remaining cyanide solution, after electrowinning, is then neutralised to form NaCN and recycled.

Jan 1, 2005

By K. Kar, M. Gautam, J. T. Jurewicz

The 10-mm Dorr-Oliver cyclone has been widely used as a personal sampler for size selective sampling of particles within the respirable range (Dp < 10 gm). Because of their inertia, the particles are unable to follow the swirling flow (outer vortex) within the cyclone. The particles migrate to the bottom of the cyclone, depending on their size, and get trapped into the inner vortex which leads to an eventual blow-off from the top of the cyclone. By measuring the size distribution of the particles in the free stream and in the collected sample, the aspiration efficiency of the cyclone can be calculated. Velocity difference between the free stream and sampling velocity. Inlet orientation, particle impaction and deposition, particle inertia and free stream turbulence result in the departure of the aspiration efficiency from unity and this, in turn, leads to inlet bias. Although the effect of inlet bias on sampling efficiency has been investigated in past, the results lack detailed information and show only some general trend. In this effort, a systematic, in-depth experimental work on the effect of inlet bias on the sampling efficiency has been undertaken using non-intrusive Laser Doppler Anemometry (LDA), Aerodynamic Particle Sizer (APS) and impactors.

Mar 1, 1992