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By John V. Beall

Since the U. S. Metals Refining Co. works was established, around the turn of the century, near the town which is now called Carteret, N. J., it has grown to be a major producer of refined copper and the main source of that special brand known as "oxygen-free high-conductivity copper." Owing to the complex metallurgical problems arising from handling a variety of raw materials such as copper concentrate from Matahambre, Cuba, copper and brass scrap from the New York area, and domestic blister copper, the organization is geared from top management down through its 2000 employes to maintain a high degree of flexibility in plant operation. The Company is a subsidiary of The American Metal Co. Charges for the smelter furnaces, one reverberatory furnace and one blast furnace, are made up in. bedding bins so that they may be tailored to the production of a constant grade of blister copper. The reverberatory furnace smelts the .sulphide charge, which may be a blend of ten different materials but principally the Cuban concentrate, and the matte from the process is poured into a converter. This reverberatory is 80 by 20 ft, silica lined with a slag bottom, fired by pulverized coal, and continuously side-charged from the top by bottom-dump cars which keep the side walls covered. It produces a 40 to 50 per cent copper matte. The fuel-charge ratio is 4.35 tons of solid charge per ton of coal. The furnace has a capacity of 10,000 tons of charge per month and produces from 5000 to 6000 tons of slag per month which must be disposed of. About 5000 tons of converter slag is produced monthly and returned molten to the reverberatory furnace. The converter gases go through a spray chamber to a Cottrell precipitator and thence to the flue system. Smoke from the

Jan 1, 1948

By W. F. M. GOSS

For the purpose of procuring data that could be used in estimating the value of the briquetting process as applied to American fuels, the United States Geological Survey, in cooperation with other interests, began in 1904, at the Louisiana Purchase Exposition, certain experiments involving the production and use of bituminous-coal briquets. It installed at St. Louis, and later at Norfolk, machines for the manufacture of such briquets, and the output of these machines has been tested in locomotive service on several different railroads in comparison with natural fuels. An elaborate and carefully executed series of tests involving the use of natural coals and of briquets made from the same coal, previously crushed, was carried out on a locomotive mounted at the testing plant of the Pennsylvania Railroad Company at Altoona, Pa.; and some preliminary experiments involving the use of briquets in marine service were made in connection with one of the Government's torpedo boats. A description of these tests is presented herewith. The results sustain the following general conelusions: 1. The briquets made on the Government's machines have well withstood exposure to the weather. and have suffered but little deterioration from handling. 2. In all classes of service involved by the experiments, the use of briquets in the place of natural coal appears to have increased the evaporative efficiency of the boilers tested. 3. The smoke produced has in no test been more dense with the briquets than with coal; on the contrary, in most tests the smoke density is said to have been less when briquets were used. 4. The use of briquets increases the facility with which an even fire over the whole area of the grate may be maintained.

Jan 1, 1911

By Galen H. Clevenger, MARTINUS H. CARON

Although there are exceptions, oxidized silver ores containing the higher oxides of manganese are generally refractory to hydrometallurgical methods of treatment. When these ores are of high enough grade they can be smelted; indeed, some rather low-grade ores of this type have been smelted at a profit because of their fluxing value. In the past, when these ores could not be smelted, they either were not treated or were treated at low efficiency, generally by cyanidation. The need for thorough investigation of the problem was therefore evident for some time before the writers began their research. The problem of treating manganese-silver ores seems to have been recognized first about 35 years ago by C. W. Goodale in applying pan amalgamation at Tombstone, Ariz. He attributed the low extraction of silver to the fouling of the mercury by manganese rather than to the presence of a refractory compound of manganese and·silver. Although definite knowledge as to the cause of the poor extraction of silver was lacking, a more or less effective preliminary treatment, that is, a chloridizing roast, was applied. E. M. Hamilton, in 1909, was perhaps the first to define clearly the problem as it affects the cyanidation of silver ores and to suggest possible methods of preliminary treatment. Most of the work done in the interval between the appearance of Hamilton's paper and the assumption of the investigation by the authors was in the nature of routine tests covering suggestions already made rather than of research directed to a fundamental study of the problem. No practical application has so far been made of any of these proposed processes. The investigation described in this bulletin has proved that there s a refractory compound of manganese and silver-probably a manganite- insoluble in cyanide solution and other common solvents for silver. Although this compound has not been isolated from natural ores, it has been made synthetically, and shows all the characteristics of the natural product. Furthermore the authors have shown definitely that heating in air a relatively small amount of a silver compound with a large excess of silica (in the proportions ordinarily occurring in a commercial silver ore) renders

Jan 1, 1925

By Z. Y. Lan

Bioleaching of marmatite with various mixed cultures of microorganisms was investigated. The experiments were carried out in shaking flasks with iron-free nutrient and the pulp density of 10% wt/vol at the temperature of 30?. The results show that zinc is preferentially leached before iron. The leaching rate of zinc with the mixed culture of Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans is 62% in 18 days. The leaching rate of zinc with the mixed culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans is nearly the same as that with the mixed culture of Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans (45% versus 50%). SEM and EDX analysis of the leaching residues indicate that a solid product layer composed of iron sulfide, elemental sulfur and jarosite accumulates in the mineral surface and becomes a barrier to the dissolution of marmatite. The bioleaching of marmatite follows the shrinking core product layer model. When the product layer increases and becomes insoluble, the leaching rate is controlled by the diffusion through the product layer and slows down. When the product layer decreases or becomes a porous layer, the leaching rate is controlled by chemical reaction and enhanced dramatically.

Jan 1, 2014

Ground and air vibrations induced by large surface blasts have been monitored. These field results, as well as a large number of published results, have been used to assess the performance of existing predictors and for the development of improved prediction methods. Field monitoring has been performed, with four seismographs giving complete wave records, at limestone quarries, coal strip mines and an open pit copper mine. Conventional analysis includes least square fitting of peak particle velocities and peak air overpressures with scaled distance formulations. Frequency content has been analyzed, and correlated with blast design (detonation sequence). Two new methods have been developed for predicting ground vibrations induced by blasting. The proposed analytical predictor accounts explicitly for inelastic attenuation and geometrical spreading, and calculates the peak particle velocity as a function of charge weight and distance. Statistical analysis of case studies confirms the consistent improvement over conventional scaled distance predictors. The second new predictor is a computer program simulating blasts, including blast geometry, charge distribution and detonation sequence, and simulating propagation of individual pulses to any point of interest, where effects are summed. A complete blast vibration results, allowing prediction of frequency content and duration as well as peak velocities.

Jan 1, 1983

By M. Mentser

The exchange of oxygen between carbon dioxide and carbon monoxide that occurs reversibly on carbon surfaces was studied at temperatures of 750° to 850°C and a pressure of 1 atmosphere. Carbon-14 was used to detect and measure the exchange reaction. The extent of oxygen exchange was a linear function of com- position of the gas mixture, and this relationship was used to evaluate the forward and backward rate constants of the reaction. Equilibrium constants, directly determined for oxygen exchange in this study, agreed well with values in the literature that were derived only by indirect procedures. This result establishes the validity of oxygen exchange in the mechanism of carbon gasification by CO2. Rates of carbon gasification were less than an order of magnitude slower than rates of oxygen exchange. Activation energies for these two processes were 58 and 53 kcal/mole, respectively. The closeness in the activation energies argues against any change in the rate-controlling step over a wide temperature span at atmospheric pressure. The role of CO as a retardant on the CO2-C reaction, and the nature of the carbon-oxygen complex are also discussed in view of the data obtained.

Jan 1, 1973

By R. S. Dean

In an earlier paper Dean and Hersberger5/ gave preliminary results a d discussed briefly the use in flotation of organic reagents of the type known in the textile industry as "wetting agents.? These reagents are those with a molecular structure comprising a long hydrocarbon chain attached to a. highly molar or hydrorhile group in such manner that ionization is nearly complete in dilute solution and the resultant ionic grouping has a very considerable hydrophile-lipophile unbalance in the structure. As a result of this characteristic structure these reagents are more or less powerful frothers and emulsifiers. Ten the degree of hydrophile-lipaphile unbalance is sufficiently great and specific chemical factors are absent these compounds behave in flotation as noncollecting frothers insensitive to reason¬able changes of pH.

Jan 1, 1937

By R. S. Dean

In an earlier paper Dean and Hersberger5/ gave preliminary results a d discussed briefly the use in flotation of organic reagents of the type known in the textile industry as "wetting agents.? These reagents are those with a molecular structure comprising a long hydrocarbon chain attached to a. highly molar or hydrophile group in such manner that ionization is nearly complete in dilute solution and the resultant ionic grouping has a very considerable hydrophile-lipophile unbalance in the structure. As a result of this characteristic structure these reagents are more or less powerful frothers and emulsifiers. Ten the degree of bydrophile-lipaphile unbalance is sufficiently great and specific chemical factors are absent these compounds behave in flotation as noncollecting frothers insensitive to reasonable changes of pH.

Jan 1, 1937

By Jogeshwar P. Singh, Mohamed Ashour

The Soil-Foundation-Structure-Interaction (SFSI) problem involves Kinematic Soil- Foundation Interaction occurring during large (cyclic and permanent) ground deformations as well as Inertial Foundation-Structure Interaction occurring during shaking all of which take place while the soil and possibly structural properties degrade with time. The design of the deep foundations for liquefaction induced lateral spread loads include estimation of passive pressure applied by the liquefied material as well as the amount of anticipated displacement. Coupled analyses for SFSI problems that account for liquefaction induced lateral spread and their interaction with the deep foundation system can be performed using sophisticated numerical modeling techniques based on finite element and/or finite difference methods using computer programs such as FLAC or OPENSEES. Such complete SFSI analyses are very tedious and expensive and not feasible for most projects. In 2011, California Department of Transportation (Caltrans) released guidelines for foundation loading and deformation due to liquefaction induced lateral spreading. This simpler prescriptive approach combines empirical and analytical methods through decoupled analyses using computer programs such as LPILE and SLOPE-W together with liquefaction induced lateral spread estimates based on published empirical equations. Pile group effects and pile caps are accounted for using a concept of super-pile. In this paper, we discuss the solution of the same lateral spreading related SFSI problem using computer program CGI-DFSAP (CGI-Deep Foundation System Analysis Program) based on the strain wedge theory that can account for liquefaction, lateral spreading, pile groups, pile caps and nonlinear behavior of piles in a more coupled manner to analyze the foundation system under the lateral spread loadings. CGI-DFSAP can be used to analyze piles in sloping ground conditions as well as piles beneath the abutments near a free-face slope. We have included Strain Wedge Model (SWM) solutions using CGI-DFSAP of several field and laboratory case studies of lateral spreading related to pile foundations. Finally, we have also included the SWM solution of one of the Caltrans (2011) example problems.

Jan 1, 2015

By V. V. Ramarao

Grinding and flotation operations deliver better-optimized performance when they are monitored and controlled in terms of the minerals they process rather than as elemental assays that we usually refer to. Mesh of grind (MoG), liberation, floatability, grade and recovery etc. are more directly related with the minerals and their characteristics rather than the elemental assays. Hence, online analyzers only provide the status for the grade and recovery of metals and not the direction for the enhanced performance. Central Research and Development Laboratory (CRDL) and Rampura Agucha Mine (RAM) mill section of Hindustan Zinc Limited (HZL) jointly undertook various survey campaigns in the grinding and flotation process streams. Grinding circuit surveys involved systematic collection of representative samples from different grinding circuit streams under stabilized conditions for monitoring particle size and process mineralogy details across individual grinding circuit. Flotation survey campaigns included study of fort-nightly / monthly composites of un-ground flotation feed, lead concentrate, lead tailing, zinc concentrate and final tailing samples for size distribution details in the 150 ? 38 micron range, chemical analysis and mineral characterization through optical microscope. This work details the investigations results and their implications on beneficiation performance. Grinding circuit survey campaigns supported the task for modifying the originally installed configuration of hydrocyclones, to limit recovery losses due to excess grinding of soft galena and related silver minerals. Flotation plant surveys helped in adjusting flotation circuit process parameters to reduce loss of liberated and floatable galena and sphalerite grains into their respective tailing streams. Keywords: grinding circuits, survey campaign, hydrocyclones, mineral liberation and locking, lead-zinc ore beneficiation operation

Sep 1, 2012

By E A. Mitchell

In the fall of 1961, Cominco dis-carded its long-established system of feeding the lead blast furnaces by narrow-gauge tram and V-cars, and installed an elevated monorail bucket system. This system automatically loads buckets of sinter, along with the correct proportion of coke, and delivers them to any of several designated furnaces. Direct labour usage has been reduced by nine men per day; improved coke proportioning has been achieved; and a major safety hazard has been eliminated. Introduction I N THE fall months of l 961. the system of feeding the lead blast furnaces at the Trail, B.C., smelter of The Consolidated Mining and Smelting Company of Canada Limited was altered from the tradition-al narrow-gauge railway and V-car method to one employing mono-rail carriers. The change was in keeping with a recent trend at Trail to replace narrow-gauge tramming with alternative methods of materials handling. In the case of the blast furnace feeding, the

Jan 1, 1963

By Chao Lian, Hongxu Li, Hao Bai, Wei Wei

"Application of high-emissivity coating on inner walls in industrial furnaces increases the furnace thermal efficiency. The coating with high emissivity strengthens radiation heat transfer in the furnace, however, according to Wien's displacement law and Planck's radiation law, under heating temperature, the wavelengths of the radiation transfer are mostly between 1-5 µm, implying that increasing emissivity of the coating in near infrared band is more effective for higher thermal efficiency. In this paper, a new CuO-ZnO-based coating material sintered at 1600K was developed. The emissivity of the samples were measured and the result shows that, in near-infrared band, the emissivity of the sample reaches 0.98 at 773K with 13at.% of CuO doped in ZnO. In addition, the effects of CuO doping and use temperature on emissivity were also discussed. Furthermore, crystallization behaviors of ZnO-CuO sintering were investigated by DTA,XRD and SEM-EDS etc., which offered information for possible optimal design of the material.1. IntroductionIndustrial furnaces are widely used in various industrial heating. For example, the metal smelting furnace, ore sintering furnace in metallurgical industry; the distillation furnace, cracking furnace in petroleum industry etc,. The research on efficient energy saving technology has important significance. High emissivity coatings are widely used in many high temperature applications to effectively transfer the heat by radiation [ 1]. The theoretical calculation and experimental studies have shown that, coated high emissivity coating in the heating surface is an effective method to enlarge the infrared radiation power [2].At present, the infrared high emissivity coating has been widely used in China, and have been achieved remarkable energy saving effect. According to Wien' s displacement law and Planck' slaw, most energy of the black body at high temperature is radiated in the wavelength range of l-5µm; however it happens that many materials have the low emissivity within this range. Thus, it is important to improve the near-infrared band emissivity of materials [3]."

Jan 1, 2013

By G. Bonnivard

"A complete laboratory process for the treatment of lateritic ores containing a high proportion of iron, as well as chrome and alumina, has been established. The ores treated originate from the tropical zones and result from superficial climatic alteration. According to recent estimates, the known reserves of such ores reach many billions of tons, thus representing huge potential reserves for the elements they contain.The process used is based on the alkaline roasting of pelletized ore in the presence of sodium carbonate. This treatment results in the separate recovery of pellets of upgraded iron ore, pure chrome oxide and hydrated alumina. The research described in the paper aims at determining the best experimental conditions for obtaining the highest extraction of the required oxide from this type of ore."

Jan 1, 1967

By Zbigniew Zurecki

The selection of atmosphere composition is critical for controlling surface quality of reactive aluminum alloys during solution treatments. An improper selection of annealing atmosphere can result in surface blistering in AI-Mg and sub-surface depletion of lithium in AI-U ingots. To determine optimum atmosphere compositions for homogenizing A1-Mg and Al-Li alloys, Ii number of exploratory experiments were carried out in air, nitrogen, and carbon dioxide based atmospheres including reactive impurities or additive such as moisture and sulfur hexafluoride. This paper describes the influence of these atmospheres on high-temperature oxidation and sub-surface defects. The results are discussed in terms of the change in Pilling-Bedworth ratio.

Jan 1, 1996

By Baisheng Nie, Longlong Yang, Tao Yang, Wenjie Jia

"Gas adsorption in coal is an exothermic and physical process. Temperature might change during the dynamical process. In order to get the temperature variation of gas adsorption process, the experiment system which can test the temperature variation and analyze the thermal effect was established. Gas adsorption experiments under different conditions were done by using the test system. The results show that temperature increases during the adsorption process. It is an exothermic reaction process. Also, the temperature variation and the variation gradient increase with the increasing of equilibrium pressure. The temperature variation value is smaller if the experiment temperature is higher. The paper will provide basic experimental data for explaining gas adsorption mechanism better.INTRODUCTIONChina is the largest coal producer in the world while it also has the most serious coal mine disasters. According to the statistics, there are nearly a thousand coal mines in China including more than 110 the key state-owned mines risking to happen coal and gas outburst. Hundreds of coal and gas outburst occur each year which often causes serious casualties and economic losses (State Administration of Work Safety, 2007). With the continuing exploitation of the coal resources, the depth of the Chinese coal mines increases about 100 meters every year which causes the situation of gas accident becoming more and more serious (Xie et al., 2006).At present, the real mechanism of gas adsorption, desorption and the diffusion process in coal and the influence factor of it are not so clear. And because of the limit of prediction method and the technological level caused gas accident prevention theory and technology not so valid."

Jan 1, 2015

By Jacques Magnaudet, Julie Cranga, Didier Huin, Pascal Gardin

"With the aim of controlling steel grade in steelmaking reactors, IRSID and IMFT are developing a numerical description of the evolution of bubbles in the vicinity of a liquid steel/ slag interface. The objective is to identify the main parameters affecting the hydrodynamics of the various phases. The goals of the present paper are:• To describe the numerical technique developed to predict the multi phase flow including bubbles, liquid metal and slag layer.• To analyze the influence of the absolute pressure on the bursting of bubbles in a RH degasser. Validation is given by comparison with results available in the literature. The major point concerns the distinct behaviors observed whether the pressure is low or high.• To study the influence of the properties of the slag layer (thickness, viscosity and interfacial tension) on the entrainment of liquid metal in the wake of the bubble and on the nature of the projections from the bath surface.IntroductionMost of secondary steelmaking processes use gas stirring for homogenization, removal of nonmetallic inclusions or decarburization under reduced pressure. The bursting of gas bubbles at the metal or slag layer surface produces a beneficial ejection of metal droplets in the low pressure atmosphere, provided that there is no violent projection, which may have detrimental effects on the process.Our objective is to develop a numerical tool to study the phenomena occurring in the vicinity of the bath surface, in particular bubble bursting under reduced pressure and entrainment of metal in the slag layer. In this paper we report the first conclusions of our study. In the first section we describe the numerical model used to describe the three-phase flow and the expansion of the gas bubbles under the effect of the ferrostatic pressure. The second section is devoted to the study of pressure effects on bubble rise and bursting. The third section reports some computational results about the rise of a gas bubble through the interface between the two liquids."

Jan 1, 2001

By James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity ? up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonnes of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle ? particle contact. The small gap, high electric field, counter current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in the North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Sep 1, 2012

By Steven M. Shope

An essential element of the Bureau of Mines electromagnetic location and communication system for trapped miners is a quantitative knowledge of the surface and above-surface electromagnetic fields created by an underground transmitter. The field solutions given in this report use approximations in which the displacement currents are negligible for low frequencies. The earth is represented by a homogeneous half-space model in which a dipole source is immersed. The vertical magnetic field equipotential contours at and above the surface are graphically mapped. The volumes of the regions bounded by these contours are directly related to the geometrical zones of signal detectability. Knowledge of the detectability zones will enable the proper search strategies to be developed for airborne detection of trapped miners.

Jan 1, 1983

By John Wallace

"Monitoring compound semiconductor crystal growth using multifrequency eddy currents for sensing illustrates some of the extreme problems of measurement and interpretation that are not often seen in metallic systems. Using sensor arrays and scanning sensors have produced a qualitative and quantitative understanding of some of the high temperature electrical conductivity mechanisms in several compound systems. A detailed review of the CdTe/CdZnTe data is presented showing some of the complexity in the data as opposed to what is found in elemental semiconductors.HistoryThe most common goal in the use of eddy current measurement in crystal growth is to deter-mine the curvature of the liquid solid interface during growth to test if the heat transfer estimates of the thermal design were adequate for single crystal growth[l]. This aim could be met but represented only a small fraction of the data that was produced observing a growth cycle. A secondary consideration was what could be discovered in the recorded data about the growth and subsequent heat treatment as the boule cooled. This is usually a more difficult task because a crystal growth process is not a controlled experiment so much as a process that continually sees modification. Using a sensor arrays or a scanning loop has produced a qualitative and quantitative basis for understanding some of the high temperature electrical conductivity mechanisms. The implication of the these measurements of electrical conductivity variations are important in that they reflect the complex defect states that will occur on cooling and heat treatment following crystal growth. In contrast to the complex behavior of the conductivity of these compound semiconductors in the solid and liquid state we have the very well characterized system silicon to compare. Initially the interest on using eddy currents to monitor compound semiconductors came from G. Westphal at the Texas; Instruments Company in 1987 to monitor aspects of growth and compounding of GaAs. This was followed by work on solution growth of HgCdTe with D. Witter. The initial interest in the use of eddy cur-rents for monitoring CdTe crystal growth came from Prof. Wilcox at Clarkson University in the practical interest to determine and control the crystal interface curvature during vertical brigdeman growth. The first actual work was done by one of his former students. G. Neuge-bauer at the II-VI Corporation which was carried on by G. Rosen at Clarkson and R. Shetty at II-VI Corporation and with A. Socha at Johnson-Matthey Electronics. The work on CdTe extends over four years and yielded sufficient data to allow one to evaluate the utility of the information produced as compared to what could be obtained from monitoring an elemental semiconductor such as silicon."

Jan 1, 1997

By S. W. Parr, T. E. Layng

There is presented below the results of experiments made on six samples of Utah coals furnished through the U. S. Bureau of Mines , under an agreement dated June 16th , 1920. The details of all values for all runs are tabulated and presented herewith . Clear The samples, consisting of approximately 150 pounds each, were received at the University of Illinois , on June 15 , 1920 , and are listed as follows : Creek , Wattis , Castle Gate , King , Standard , and Aberdeen . The proximate and ultimate, analyses of the various ccals from that region , representing all the types included in these samples , have already been made by the Bureau of Mines , and are available . * Similar determinations were also made on the particular samples forwarded for purposes of these experiments . The results obtained on the coal as received did . not very in any material feature from the values reported by the Bureau, they are shown in Table 1. It is of importance to note only that the oxygen content is uniformly high , namely approximately 9.5 to 11.5 per cent of the as- received coal , while the oxygen - hydrogen ratio is also high, being on the average approximately 2 ( oxygen) to 1 ( hydrogen) .

Sep 1, 1921