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By William R. Opie

Considerable effort by extractive metallurgical research organizations has been devoted recently to developing pollution-free processes for treating copper sulfide concentrates. A number of hydrometallurgical processes are in various stages of development and have been subjected to economic evaluation. Although the hydrometallurgical approaches eliminate SO2 emission problems, they create objectionable effluents and residues, make precious metals recovery complex, and are not very efficient for treating chalcopyrite. Furthermore, they are consumers of considerably more energy than pyrometallurgical processes which produce blister copper that can be electrorefined to commercial grade cathodes. This paper discusses a pyrometallurgical process under development by AMAX Base Metals Research & Development, Inc. (1) The original objectives set for the process development were: 1. Sulfur control of at least 95% with elimination of fugitive emissions. 2. Copper and precious metal recoveries as good as or better than conventional processes. 3. Low capital cost. 4. Competitive operating costs 5. Use of known proven technology where applicable.

Jan 1, 1976

By J. Boisvert, E. Daniels, C. Deutsch

"INTRODUCTION Conventional mine planning is performed on a single resource model at a selective mining unit (SMU) scale deemed appropriate for the deposit and mining method. Estimation methods such as kriging and inverse distance, commonly used to construct a single model, are susceptible to histogram smoothing (Rossi & Deutsch, 2014). This can be mitigated by limiting the number of composites per estimate, therefore correctly reproducing the distribution of estimates (Boisvert & Deutsch, 2012). Search limiting techniques remedy histogram smoothing at the cost of introducing a problematic conditional bias (Isaaks, 1999) and introduces even greater spatial smoothing. Localization is an alternative, offering histogram reproduction through post processing of more robust probabilistic modeling techniques. A single localized model at the SMU scale is desirable. The correct histogram can be reproduced and a single model allows for the use of conventional mine planning and resource evaluation techniques. Despite the advertized benefits of localization, the necessary reliance on a larger panel scale as a middle step in the localization process yields unsightly “edge-effect” artifacts (Boisvert & Deutsch, 2012). Two approaches to artifact reduction are presented here. The first is a straight forward optimization approach designed to minimize an objective function that penalizes artifacts including panel edge discontinuities to generate a model free of panel edge-effects. The second approach redefines a panel in a less conventional fashion as a randomly chosen set of SMUs throughout the domain. This method produces a model void of any regular panel shape resulting in an artifact free model. Artifact reduction minimizes the obvious “edge-effect” issues of localization but local precision issues described by Boisvert & Deutsch (2012) persist. Localization is not a replacement for quantified uncertainty for comprehensive risk analysis and resource evaluation. LOCALIZATION Initially developed with Uniform Conditioning in mind, localization collapses a distribution of local uncertainty at a panel scale to an SMU scale model for mine planning (Abzalov, 2006). This process has been extended to Indicator Kriging (Hardke, 2011), Sequential Gaussian Simulation (Boisvert & Deutsch, 2012) and MultiGaussian Kriging (Daniels and Deutsch, 2014). The localization process is performed in a similar fashion regardless of which technique is chosen to create the prior model of uncertainty. Methodology There are three scales of importance considered in the localization process. The point scale, otherwise known as the data scale, is the smallest and is the scale at which experimental data is collected. The SMU or block scale is the familiar scale at which mine planning and resource evaluation takes place. Lastly, the panel scale is larger and contains a number of SMUs. Each of the three scales is illustrated in Figure 1."

Jan 1, 2015

By J. F. KENP

THE White Knob copper-deposits are situated about three miles south of Mackay, on the Salmon River .branch of the Oregon Short Line Railroad, in Custer county, Idaho. An outline-map of this district is given in Fig. 1. The deposits have been known and spasmodically worked for many years, and a total of over 3.5 miles of tunnels, shafts and other workings has been driven with a view to their development. These extensive excavations have exposed the deposits sufficiently to permit a careful geological examination. The peculiar features which give special interest to this paper are the branching, free-like form of the ore-bodies; the absence of zones of secondary enrichment in the partly oxidized pyritic deposits, and the fact that while the deposits are associated in a general way with the contact of an eruptive rock with limestone, which it penetrates, the garnetization has taken place not in the limestone, as is the usual case, but in the igneous

Mar 1, 1907

By R. J. Jula

The process of treating granular activated carbon for return to service in the recovery of gold in Carbon in Pulp and Carbon in Leach circuits has been investigated. Carbons from four U.S.A. mines, one Canadian mine and one South African mine were characterized before and after regeneration. The use of thermal gravimetric analyses demonstrated the presence of inorganic compounds on the surface of the carbon. Thermal regeneration was investigated using factorial' analysis to determine the effect or interaction of furnace temperature, retention time and the use of supplemental steam. The operation of acid leaching prior to or after gold elution was investigated. The effect of water quenching, regenerated carbon was also studied. From the data obtained in this investigation, guidelines are given for effective regeneration operation.

Jan 1, 1985

By D. G. Skinner, M. SC. Griffiths

"The natural difficulties associated with the size evaluation of dusts render absolute measurement difficult, or indeed, impossible. Assuming that the desirability of gravi­ metric sampling be conceded, it appears likely tha,t the most suitable means available for physical evaluation are the method of total turbidity measurement, to give a con­ ventional value for specific surface, together with microscopical examination, the great merit of the latter being that in the hands of an experienced operator, semi-quantitative discrimination between coal and other particles is possible.The pipette method, as modified by Fryer, probably-deserves more attention than it has received up to the present. Whatever method is used, it is recommended that in view of the lack of medical knowledge, as much information as possible should be obtained with reference to the total mass concentration, the surface area of the total dust,' and the mass and area of the particles below 5μ in size."

Jan 1, 1947

By Gary L. Hundley

As part of the U.S. Bureau of Mines program to reduce the Nation's reliance on foreign supplies for critical metals, a procedure was devised to separate and recover critical metals from mixed and contaminated super alloy scrap. The process uses both pyrometallurgical and hydrometallurgical methods to treat the scrap. The mixed scrap is converted to a matte containing 4 to 7 pct S by adding S directly to the molten metal. This matte is then granulated and ground to a minus 35-mesh particle size and leached with an HCI-CI2 solution. This process takes essentially all the Ni, Co, Cr, Fe, AI, and Mo into solution in a 3-h leach, leaving W, Ta, Ti, and Nb (Cb) in the residue. The Mo is recovered from the chloride leach solution by solvent extraction, and the Cr and Fe are recovered together by precipitation. The Ni and Co can be recovered individually by an existing solvent extraction-electrowinning process. The W is recovered by a caustic leach of oxidized Cl2 leach residue.

Jan 1, 2010

By P. M. Sullivan

The principles and application of amalgam electrolysis to the recovery of zinc and tin from secondary products were studied; this Bureau of Mines project was one phase of investigating the development of more efficient methods for processing iron-bearing zinc and tin to produce both base metals of high purity. Zinc of 99-99-percent purity was recovered from galvanizer's dross with recovery efficiency of 98 percent. Tin of 99.9-to 99.99-percent purity was recovered from hardhead with recovery efficiency of 81 percent. Both materials were treated by the same method in separate systems. Mercury was used to leach zinc from dross and tin from hardhead to form amalgams of each metal, both of which were subsequently refined electrolytically to produce high-purity metal. Impurities that were contained in both secondary products behaved as theoretically predicted; impurities that were insoluble in mercury remained as sludge in the leaching column. Except for lead, the readily amalgamated impurities were prevented from fouling the electrolyte by the blocking action of the amalgam electrode. Lead impurity in the tin-refining system dissolved and immediately precipitated as the sulfate. The primary advantage of the amalgam refining method lies in direct recovery of the extremely pure base metal from highly contaminated secondary material.

Jan 1, 1961

By M. J. Kovalik

The effect of oxidation by air at temperatures ranging from 200° to 390° C on the change of chemical and physical properties of Pittsburgh-bed coal was studied as a function of processing time and temperature. The goal was to prepare a nonagglomerating fuel from a strongly coking coal for use in continuous carbonizing processes and in fixed-bed gasifiers. The oxidized coal was carbonized in a bench-scale apparatus, and the coke strength was evaluated in a Roga tumbler. Strength of the coke was progressively reduced with time of oxidation until the coking power of the coal was apparently destroyed. Time requirements to obtain an essentially nonagglomerating product were inversely related to processing temperature. Gaseous products released from the coal during oxidation reduced the yield of the desired nonagglomerating product, which decreased with time of oxidation at constant temperature and with increase in processing temperature at equal time. Oxidation at a temperature slightly above the lower limit of the plastic temperature range of Pittsburgh-bed coal was most effective because of the short processing time required and moderate processing losses.

Jan 1, 1963

By Ralph J. Holmes, David McCallum, Alan Roberts, Rolando Orense, University of Auckland, Tobias Krull, Tom Honeyands, Kenneth Williams

"The safe ocean transport of bulk commodities like iron ore, coal, nickel ore, manganese ore and bauxite by large bulk ships is vitally dependent on the stability of the cargo under the influence of wave induced ship motion. Safety standards are set by such bodies as the International Maritime Organisation (IMO) with recommended tests for the assessment of bulk commodities. Since the 1960s, the bulk cargo code (BC Code) commenced defining methods to determine the Transportable Moisture Limit (TML) for transportation of bulk commodities. By the latter part of the 1960s, three TML test methods were defined, namely the Flow Table, Proctor-Fagerberg and Penetration tests. All three tests were predominantly aimed at determining TML values for mineral concentrates.More recently, bulk commodity producers, Maritime Organisations and Port Authorities worldwide have been investigating whether commodity based TML methods better reflect realistic safe ship transportation than the current concentrate based TML test methods. In these investigations, the relationship between the mineralogical and particulate parameters of specific commodities with respect to cargo stability and moisture retention has provided insights into the development of tailored TML test methods. To this end, an AMIRA International project (P1097) undertaken by CSIRO, TUNRA Bulk Solids, the University of Newcastle and the University of Auckland assisted the IMO Technical Working group to investigate the relationship between iron ore fines characteristics and a new TML test specific for iron ore fines bulk cargoes.A review of the three standard concentrate based TML methods and characterisation studies of iron ore fines, as well as cyclic triaxial testing to determine liquefaction resistance, resulted in the development of a modified Proctor-Fagerberg method for determining the TML of iron ore fines. Of particular importance in determining TML is mineral composition, porosity, particle density and allowing time for moisture equilibration."

Jan 1, 2016

By E. D. Eastman

There are three researches upon the specific heat of water vapor by the method of explosion that are sufficiently advanced in technique and suitable in plan to justify careful study of their results , with the double purpose of fixing the best available experimental values and indicating the attainable accuracy of the method. These three researches comprise the work of Pier , Bjerrum , and Siegel.5 The work of earlier date than Pier's suffers from obvious inaccuracy of measurement , while the experiments more recent than Siegel's , such as those of Womersley6 , of Bone and his collaborators , and of Maxwell and Wheeler , 8 are for the most part not well designed for the accurate determination of the heat capacities in question . Some of the errors to which they are especially subject have been discussed by David and by David and Thorp.

Sep 1, 1930

By T. Szendrei and S. Tose

Historical approaches to the problem of flyrock based on correlation studies and regression analysis, including artificial neural networks and similar techniques, are inherently incapable of addressing two core issues – root causes of flyrock and projection velocity. A further shortcoming of correlation techniques is that they give no information on the influence of rock size and shape on the flight distance. The scaled depth of burial model for crater blasting in the collar zone and bench face does not specifically address the question of flyrock velocity. A third approach, based on flight trajectory calculations, often neglects the very significant effects of air resistance on the trajectory. Some trajectory models incorporate air resistance but use an implausible fragment velocity model that cannot propel sizeable rocks to distances much beyond 150 m. Nonetheless, trajectory calculation incorporating the effects of air drag affords the most promising approach to the prediction of flyrock range. A unique and insightful feature of the proposed realistic flight modelling is that it collapses all suspected causes of flyrock, many of which are not well understood, to just a single parameter – the launch velocity. This indicates that the root causes of flyrock lie in the mechanisms of momentum transfer to broken rock and suggests new avenues of study.

Dec 13, 2022

By G. E. Norman, A. L. Mckague

"The new smelting process commenced operation in 1978. The pelletizing and sinter plants were replaced with slurry-fed roasters and the blast furnaces with electric furnaces. The existing converter aisle and matte handling facilities remained unchanged.Process DescriptionNickel-copper concentrate is partially roasted in two slurry-fed fluid bed roasters. After gas cleaning, the sulphur dioxide gas is transferred to the acid plant. The roaster product is conveyed to two electric furnaces for smelting to produce a waste slag and furnace matte. The slag goes to the disposal area and furnace matte containing the metal values is processed in the converters for further removal of iron and sulphur.The final matte containing about 75 per cent metal values is shipped to the refinery in Norway.The commercial smelter was designed for 2135 tonnes per day of concentrate, with an availability of 85% . Roasters and electric furnaces were sized at 117 per cent of design, or 1250 tonnes per day on each of two lines. Concentrate storage capacity in the plant is sufficient for two to three days' plant operation.The new smelting process will be discussed under the following headings:Concentrate Slurry HandlingFeed PreparationRoaster OperationRoaster Gas CleaningCalcine TransferElectric Furnace Operation and Process Control Converting and Matte HandlingUnder these headings, process control , equipment changes, and plant performance after three years' operation is reviewed. A brief discussion of accident prevention , and working environment is also included ."

Jan 1, 1984

By X Zhang, B McFadzean, C T. O’Connor, S Pikinini

The Platreef in South Africa contains one of the world’s largest reserves of platinum group elements. One of the major platinum group minerals (PGM) components in this ore is sperrylite (PtAs₂), which has been found to be slow floating compared to the other PGMs. In a study aimed at determining the reasons for the poor floatability of sperrylite and to improve its recovery, tests were carried out to determine the interactions of the mineral with a range of standard and novel collectors. Microflotation tests were carried out to determine the hydrophobicity of the minerals before and after adsorption of collectors. In addition, experiments were carried out to determine the enthalpy and extent of collector adsorption on the minerals and to investigate electrochemical interactions between sperrylite and selected standard collectors. The results indicated that poor collector adsorption was the major cause for the poor floatability of sperrylite. Sperrylite had both poor natural (14.5 per cent) floatability and collector-induced flotation recoveries, the highest recovery of 26 per cent being observed using PNBX collector at pH 9. Moreover, the rest potential tests showed that the interaction of sperrylite with standard collectors such as xanthates was poor. The decrease in potential after the addition of the standard collectors ranged from 7.9 mV to 24.9 mV under alkaline conditions. Furthermore, sperrylite rest potentials remained unchanged with a change in pH from basic to acidic, indicating its resistance to surface alteration. Surface alteration of the minerals is key for the chemisorption of collectors to take place on the mineral surface. This was further emphasised by flotation recoveries at low pH, where only certain collectors responded positively to a decrease in pH and these were shown to have undergone a structural change. This work has highlighted the difficulties associated with sperrylite flotation and provides some direction for future research.

Aug 24, 2022

By B. Cavender

Safety departments have traditionally been held responsible for the safety performance of their division or company. This approach leads to a lack of ownership of safety issues by the larger organization. An alternative paradigm is significantly more effective: the members of the work force (managers as well as workers) are fully responsible and accountable for safe production. The safety department is not extinct, however. Its role has changed, to focus on training, litigation, and external relationships such as community relations. This approach was implemented at BHP Copper's Superior mine and mill in Arizona. By obtaining the genuine commitment of the work force to accident-free production, the mill's MSHA incident rate immediately dropped from 7.4 to zero. The mill also ran one year with no MSHA citations. When this philosophy was implemented at the divisional level, the division's incident rate decreased from 9.5 to 1.1,an 88-percent reduction in six months.

Jan 1, 2000

By Nagy El-Kaddah, T. T. Natarajan

This paper describes a novel approach for modeling three-dimensional electromagnetically driven flow in inductively stirred systems, and its application to modeling electromagnetic and flow phenomena in sub-mold rotary stirring of billets. It is based on a new T-\jf potential formulation of electromagnetic field, which does not require the calculation of the field in free space. A finite element algorithm has been developed for solving the electromagnetic field and Navier-Stokes equations in the fluid flow domain. The computed results have shown that the electromagnetic force field generates a strong rotational flow within the vertical section covered by the stirrer, and a relatively strong secondary flow beyond the stirrer. It has also been shown that the rotational and secondary flows were driven primarily by the vorticity of the force field at the billet corners. The induced flow in the molten pool was found to be turbulent and the effective mixing region in the molten pool was about three times the length of the stirrer. The mathematical approach presented in this paper provides the theoretical framework for quantifying these effects for any given stirrer configuration and operating parameters.

Jan 1, 1999

By C. L. Lin

Transformation of linear grade distribution to volumetric grade distribution has been used to estimate the actual mineral liberation during wet, batch, ball mill grinding of a copper ore. The degree of liberation based on the multicomponent-multisize grinding liberation model using volumetric grade is lower than the apparent degree of liberation estimated from using King's linear intercept model.

Jan 1, 1987

By David S. Shatzer, Michael R. Purcell

Current world events have demonstrated the use of commercial vehicles, other unconventional modes of transportation and unusual materials as explosives or incendiary weapons, affecting commerce, disrupting cities and even entire societies. Since the implementation of the Organized Crime Control act of 1970 the Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF) has been investigating and studying explosives and incendiary devices and their related effects.

Jan 1, 2004

By Jinrong Zhang

Fresh cyanide solution was treated by near UV light with the assistance of photocatalysts. Cyanide was oxidized mainly to cyanate. Photochemical behavior of the anatase and rutile forms of TiO2 was compared. It is found that anatase has a much higher activity than that of rutile. Bubbling of oxygen in the reactor showed no appreciable increase in cyanide oxidation, implying that the reaction is surface controlling. A very interesting finding in this study is that a natural mineral, ilmenite, can replace chemical titanium dioxide as the photocatalyst. Ilmenite without any treatment did not catalyze the oxidation of cyanide. But, after being roasted at high temperature with oxygen, the oxidation was enhanced dramatically. The mechanisms of photooxidation of cyanide and the roasting of ilmenite are proposed.

Jan 1, 1991

By Cory Loukides, Cathy Aimone-Martin

Blaster training manuals used by the Office of Surface Mining (OSM) and others are outdated and cumbersome. A new approach has been developed using Microsoft PowerPoint with a Visual Basic overlay to produce modules on CD’s that present state of the art blasting techniques. The education modules contain enhanced information on topics such as explosives and initiation products, blast design, drilling, and vibration control. The content is based on safe practices and illustrated with numerous photographs and movies. Review questions, complete with explanations for incomplete answers, enhance the learning process and keep the blaster involved. The benefits of using an electronic format include the ability to continually change and update the training modules as new products, technology and applications become available. In addition, the blaster can work at home in preparation for class work and may reduce the time away from the job. This poster session presentation will allow potential users to view and take part in the evaluation of these modules.

Jan 1, 2004

By E. J. Roberts

Prior to 1916, thickening was an art, and any accurate decision as to what size of machine to install to handle a given tonnage of a specific ore must have been one of those intuitive conclusions, based on both intimate and extensive acquaintance with thickners and ore pulps. Then in 1916 "knowledge of acquaintance," became "knowledge about" with the publication of the Coe and Clevenger paper.' The unit operation of thickening had graduated to the status of an engineering science. The fundamental similitude relationships for the two major phases of the operation were defined so clearly that batch tests on models as small as liter cylinders could serve to specify protypes as large as 325 ft in diameter.

Jan 1, 1949