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By C. R. Kuzell

IN COMPARISON with recent years 1932 has yielded much less tangible evidence of progress in copper reduction and refining. The industry has been extremely quiet, especially in the United States. Design and construction has been throttled by lack of new capital expenditures. The excess producing capacity of the whole industry and the extremely gloomy outlook for the future have made it unwise to tie up more capital except under special conditions. The plants built during the previous year have, however, been placed in operation. Older plants have been abandoned, temporarily shut down, placed on part time operating basis, or continue to operate at a low percentage of normal capacity. In the United States the Phelps Dodge Corporation at Douglas, Ariz., has completed the remodeling of the former Calumet & Arizona smelter. A new roaster and Cottrell plant chimney was completed this year. Though operations have been limited the new equipment has been found to justify all expectations. The reverberatory plant addition consists of two furnaces 26 by 107 ft. inside dimensions, with a high arch, and modern steel binding of excellent design. Natural gas fuel gives good results. One of these furnaces will treat 1000 tons of solid charge per day with a fuel consumption of approximately 3,000,000 B.t.u. per ton. The larger converters have not only yielded the expected lower costs, but have simplified operations in the converter department. One of the noticeable results is the greater cleanliness in the environment and the absence

Jan 1, 1933

By Max W. Ball

Our ever-increasing use of minerals has been the outstanding fact in our American economic development. The rise in our standard of living in the past century is without equal in human history. Nowhere in time or place has the man who works lived so well, or the man who cannot work been so well cared for. We live in a new world, even the poorest of us, that our forebears of 1849 could not have dreamed. That new world has come mainly from our use of minerals. Our per capita use of nonmineral products has grown too, but by only a modest amount. Food consumption per person has grown about 15 per cent in the past fifty years; lumber use per person ,has fallen 56 per cent and that of wood for fuel 65 per cent. Of all the products of field and forest, our use, per capita, may have increased by one fifth during the present century. In contrast, our per capita use of minerals has multiplied several times. Each of us uses 2% times as much steel and 16% times as much petroleum as our fathers used in 1900. In less than half a century our per capita consumption of all minerals has probably risen by 200 to 250 'per cent. Man once built with wood; today he builds mainly with brick and stone and steel. Once he traveled by the power of hay and oats; today he travels by the power of coal and oil. Rubber made from minerals is already better for some uses than rubber tapped from trees; before long it will be better for most and perhaps all uses. Even our ladies' graceful legs are clad in mineral fiber, where once animal or vegetable fiber would have covered them. Our high standard of living is a product of the machine.. The machine is made of minerals. The machine is driven by minerals. The machine age is a mineral age.

Jan 1, 1949

By Jônatas Venancio Barbosa, Dagoberto Brandão Santos, Túlio Magno Füzessy de Melo

In this work, the mechanical and metallurgical behavior of titanium added ultra-low carbon (ULC-Ti) steel under hot and warm working conditions was studied by means of dilatometer compression tests. Double compression schedules were performed at temperatures between 700°C and 1000°C, inter-pass times of 0.5-100 s, and deformations of 0.5 and 0.3 in the first and second stages, respectively, with strain rate of 1 s-1. The analysis of the flow curves obtained allowed the evaluation of the softening characteristics of the steel. The softening and microstructure features indicate different restoration mechanisms depending on the temperature range. Static recrystallization with rapid microstructure restoration is observed at temperatures within the austenitic and intercritical field. Strain induced boundary motion and recovery mechanisms apparently control the restoration process in the ferrite region. In general, flow stress curves showed dynamic recovery behavior. Only the deformation in the intercritical region produced a peak in the flow stress curves. Isothermal holding tests associated with single hit compression indicated the presence of dynamic strain induced transformation, accelerating the softening kinetics at the intercritical region.

Oct 1, 2019

By J. P. Bellot

During the non-ferrous metal processing, the melting step under vacuum or under rarefied gas leads to volatile metal losses. It is the case of the metallurgical processing of the nickel-based, titanium-based or zirconium-based alloys where the evaporation losses don't allow a sufficient control of the alloy chemical composition. A theoretical approach has been carried out involving both a continuum description in the liquid phase and a molecular approach in the rarefied gas phase. The finite volume method is used in order to solve the coupled transport equationsin the liquid, whereas the Boltzmann equation is modelled by using a Monte Carlo method. At the liquid metal and metallic vapor interface, the volatilization and recondensation fluxes link up the two calculations. Simulation results are given for the melting and refining of reactive metals such as titanium alloys where the control of the chemical composition remains a major difficulty. The validity of the kinetic Langmuir's law is discussed for different operating conditions.

Jan 1, 1996

By Paul C. Schmall

In recent years, several geotechnical methods have been successfully applied to ash pond closure. These include modified dewatering techniques with wellpoints and wells to physically drain the material, soil mixing to create a soil-concrete material for improved accessways as well as improved ground structures within ponds to act as barriers or gravity dams, and geotechnical instrumentation to serve as an early warning of the potential for liquefaction. Given the parallels between fly ash and sluiced in place mine tailings, the application of fly ash remediation method to mine tailings shows significant potential, as illustrated in this paper.

Feb 1, 2024

By Yazn Khasawneh Ph. D. P. E., Will Tjaden, Spencer E. Ness P. E., Mohammed Nasim Ph. D. P. E.

Wind turbine components undergo many loading cycles during their operational life. Additionally, wind turbines may undergo extreme loading conditions from natural hazards, mechanical failures, or emergency stops. Current design practice for the foundations of wind turbines accounts for these complex loading conditions through a simplified pseudo-static approach based structural loading combinations. A rotational stiffness for the foundation is estimated from the pseudo-static analysis and then compared to an acceptable minimum rotational stiffness provided by the turbine manufacturer. These minimum rotational stiffnesses are based on dynamic analysis of the tower and nacelle system with the foundation represented as linear springs. This approach provides a reasonable approach to the foundation design but does not accurately capture the true dynamic performance of the entire soil-foundation-tower-nacelle system. This becomes especially important for pier-type foundations, which are being more commonly used to support modern and future generations of larger turbines. Additionally, the dynamic performance of the foundation will vary as the adjacent soil undergoes a large number of loading cycles of varying strain magnitudes. In this study, the full turbine-tower-foundation-soil system was modeled using finite element methods. An advanced non-linear soil constitutive model and dynamic loading time histories were used to investigate changes in stiffness of the soil, and the possible impact on the dynamic response of the system. Results were compared to conventional design methodologies with the goal of reducing foundation capital costs while avoiding increases in O&M costs and which can lower the LCOE of wind energy.

Oct 1, 2022

By K. C. Liddell

"Cu/Ni multilayers exhibiting giant magnetoresistance were deposited from a single electrolyte under stepped potentiostatic control. To enable transport measurements to be made without remounting the multilayer film, we developed a novel method that involved plating on a thin metallic basal layer atop a rigid non-conducting Si substrate. Rotating ring-disk electrode techniques were used to monitor the composition and thickness of individual plated layers. Transmission electron microscopy confirmed that the interfaces between adjacent layers were sharp and that the structure of the layers was uniform throughout the film. Atomic force microscopy images indicated that the film's surface was smooth and free of defects.ELECTRODEPOSITION OF THIN MULTILAYER MAGNETIC MATERIALSI. IntroductionElectrodeposition of compositionally modulated films will in all likelihood continue to be used to produce the read heads for stored magnetic data. However, the next generation of head materials will require both improved sensitivity and reduced film thickness. Certain multi layers consisting of thin alternating ferromagnetic and nonmagnetic layers exhibit giant magneto resistance and consequently are promising candidates for read head applications. We have successfully made multilayer films with giant magnetoresistance that have total thicknesses as low as 25 nm, approximately 120 times thinner than the thinnest similar films reported in the literature. This paper describes early results from our work on electrodeposition and characterization of Cu/Ni multilayers, a model system with enhanced magnetic and mechanical properties, including the GMR effect. The structure and composition of the multilayers were determined using TEM, AFM, and electrochemical methods, and their magnetoresistance was measured by the standard four-probe technique. A novel method developed in this work enabled the transport properties of the ultrathin films to be measured reliably without the need to dissolve the cathode or handle the films. To provide a context for these results, short accounts of other work on giant magnetoresistance and multilayer electrodeposition are also included."

Jan 1, 1997

By Herty, C. H.

Iron oxide (FeO) plays an extremely important part in the manufacture of iron and steel. In the three major processes- blast-furnace, open-hearth, and Bessemer converter-iron oxide is the chemically predominant compound and controls to a large ex- tent the operation of the furnaces and the composition and quality of their respective products. In order to emphasize the importance of iron oxide in each process, they will be considered individually in some detail. THE OPEN-HEARTH FURNACE. Iron oxide is introduced into the open-hearth furnace in four ways : 1. The scrap charged into the open hearth is oxidized by the furnace gases, the amount of oxide formed depending primarily on the amount and type of scrap charged. It has been found' that with large scrap, 1.7 Ib. of FeO is formed per 100 Ib. of scrap charged, whereas with scrap of medium size about 5.3 Ib. of FeO is formed per 100 Ib. of scrap charged, when the period between the charging of the scrap and the addition of hot metal is 3 hours. 2. The decomposition of the limestone sets free CO, by the reaction

Jan 1, 1957

The nature of adsorbed calcium carboxylates (oleate and stearate) has been investigated by in-situ/ex-situ Fourier transform infrared internal reflection spectroscopy (FTIR/IRS). Previous spectroscopic studies in alkaline solution have shown that adsorbed carboxylate is characterized by a C-O stretching vibration at about 1550 em?1 for less than monolayer coverage. Similar results were found in this study. More specifically, in this study such a singlet at 1550 cm-1 was found for LB monolayers of calcium distearate transferred as a condensed layer at a high film pressure to the surfaces of fluorite and germanium. Normally the spectrum of bulk calcium distearate reveals a doublet at 1575 and 1540 cm-1, characteristic of a three dimensional 7-fold coordination for calcium carboxylate complexes. This doublet is generally found for carboxylate multilayers formed by spontaneous adsorption at the surface of calcium minerals. In this regard, the spectral evidence suggests that whenever the calcium dicarboxylate is constrained at a surface as a condensed layer, the 7-fold coordination can not be satisfied and the surface carboxylate is forced into a two dimensional symmetrical coordination with a singlet at 1550 cm-1. On the other hand, if the Langmuir-Blodgett (LB) monolayer calcium distearate film is transferred at a low film pressure the doublet is observed. This analysis is further confirmed by the spectral results for LB transferred calcium distearate monolayers at a hydrophobic silicon surface. Even though these are condensed monolayers formed at high film pressure, the carboxylate group, oriented away from the surface, is no longer constrained by the surface force field, and thus exhibits the characteristic doublet of the bulk calcium distearate salt.

Jan 1, 1998

By Floyd G. Anderson

This report reviews and summarizes information on prevention and suppression of dust in mining, tunneling, and quarrying published in the United States during the years 1958 through 1960. Unpublished pertinent data developed or assembled by the Bureau of Mines during this period also are included. Silicosis statistics reported by the U.S. Public Health Service indicate a sizable silicotic population in the United States and suggest a need for greater dust-control effort. A joint medical-environmental survey was begun by the U.S. Public Health Service and the Bureau of Mines to evaluate the magnitude of the silicosis problem in the metal mining industry in the United States.

Jan 1, 1962

Comparative tests of four coals used industrially for coke production have been made by three laboratories of the Federal Bureau of Mines, each using its standard equipment and procedures for evaluating coal for coking. Two of the coals were blends used in the western and eastern sections of the United States, the third was a strongly coking coal widely used for producing coke in Alabama, and the fourth was a blend typical of those used for producing foundry coke in the Birmingham district. The coals used and the cokes produced from them covered a wide range of chemical and physical properties. The tests used at all three laboratories for determining the physical properties of the cokes were made according to ASTM (American Society for Testing Materials) methods. The excellent agreement found for the physical properties of the cokes indicated that, for the coals tested, the BM-AGA (Bureau of Mines-American Gas Association) 18-inch circular retort used at Pittsburgh, Pa" the 14-inch slot-type oven used at Denver, Colo., and the 17-inch slot-type oven used at Tuscaloosa, Ala., were substantially equivalent for evaluating coals for production of coke. Thus, added value is given to data obtained previously and independently at these three Bureau laboratories. INTRODUCTION Laboratory equipment to produce coke for evaluation has not been standardized by the industry. The results obtained with anyone design of equipment have been regarded as showing only the relative values of coal to produce coke of the requisite quality. Few systematic studies have been made to correlate results obtained in different types of equipment. Results of one, in which the Bureau of Mines participated, were published recently.2/ This

Jan 1, 1961

By C. W. Davis

This paper is the second of a series of progress reports on a study, of the hydrometallurgy of manganese which is being conducted in an endeavor to make possible utilization of the large deposits of low-grade domestic manganese ores that occur in several States. There are at least four processes in which a knowledge of the action of SO2 gas on manganese oxides at elevated temperatures may prove of value. One ,of these involves dissolution of manganese from ores. The Bureau of Mines has investigated the hydrometallurgy of manganese by a process in which SO2 gas, a waste product at many smelters, is passed into water to form a solvent for manganese. Although Several manganese minerals acre readily dissolved, rhodochrosite (MnCO3) was attacked but superficially.§. Recent experiments have shown that a roast at 650 to 900°C converts the manganese of rhodochrosite to a form that is quickly dissolved by a weak SO2 solution. Introduction of smelter gases containing as much as 5 per cent SO2 during such a roast would not add much to the cost of the operation and might result in the formation of considerable water-soluble manganese sulphate.

Jan 1, 1930

By M. R. Geer, H. F. Yancey

"INTRODUCTION With the advent of war in 1941, military operations in Alaska were enlarged on such a scale that the demand for coal in the Territory more than doubled. Coal was needed urgently for heating forts and other military establishments, for use on large construction projects, and for handling the greatly increased volume of traffic on the Alaska Railroad. -The additional tonnage required, estimated at perhaps 250,000 tons per year, probably could have been supplied by the United States, but shipping space between Pacific Coast ports and Alaska was already overburdened with military supplies and construction materials. Moreover, although of only secondary importance in wartime, the cost of coal shipped into the Territory is reported to have been as high as $40 per ton. The alternative to importing coal was, of course, to increase the Production of the Alaska mines.Production of coal in Alaska reached, 350,000 tons in 1944, or more than double the prewar' output. The responsibility for increasing coal production was assumed largely by the Army, A Coal Commission attached to the Alaska Department arranged financial assistance for some mining operations, aided the operators in producing equipment for mechanization, and provided most of the labor necessary to operate the mines. The Bureau of Mines contributed to the program in several ways. First, exploration by the Bureau in the Moose Creek district revealed a substantial tonnage of coal of better grade than any currently mined in the Territory, 4/ and drilling in the Broad Pass district, where a mine to supply coal for the army had been started, revealed that the reserves were far less than had been supposed; this operation was abandoned. Second, coal-preparation practices were studied, and recommendations for improvements made, at two of the operating mines at which the quality of the coal makes preparation a factor of vital importance. Some of the information obtained in these studies forms the basis for the present report."

Jan 1, 1946

By R. Hogg, S. Chander

"INTRODUCTION The behavior of particulate systems in general is determined by the properties of the solid and fluid phases and of the interfaces between them. As particle size is reduced, the inter facial effects become increasingly important until, in colloidal systems, they become completely dominant. Interfacial phenomena are especially important in coal processing for a variety of reasons. Because coal is naturally hydrophobic and its density is low, surface forces begin to dominate over gravity at relatively coarse sizes. Coal is thermodynamically unstable in the presence of air, so that surface oxidation occurs readily leading to important variations in surface properties with time and environment. These effects are further compounded by the inherent heterogeneity of the material.Surface characteristics and properties play a significant role in most aspects of coal processing. Comminution, for example, is a process of creating new surface, while agglomeration involves the reduction of surface area and is usually controlled by surface forces. Both solid-solid and solid-liquid separations are influenced by interracial phenomena, Gravity separations are usually performed in a liquid phase and are affected by the wetting characteristics of the various solids present and by the need to ensure proper dispersion of the individual particles. Froth notation, of course, separates particles on the basis of differences in surface characteristics. Chemical processes such as leaching generally involve interfacial reactions whose rates depend on surface area and may be influenced by electrochemical effects in the electrical double layer at the solid-liquid interface, or by adsorption of reactant and/or product species from solution. Solid-liquid separations and associated processes such as flocculation are strongly dependent on the nature and properties of the solid-liquid interface.In characterizing solid surfaces, it is important to consider first the surface area, since this determines the relative importance of the interfacial effects. The structure and chemical composition of the surface may depend on the distribution of different petrographic constituents and impurities such as finely disseminated mineral matter, on the extent of surface oxidation, and on adsorption from the environment. These, in turn, will generally determine the surface properties which define particle behavior. Since the relationships between structure etc. , and properties are not generally known, it is usually necessary to measure properties such as wettability and electrical charge directly."

Jan 1, 1989

By L. Heber Cole

The search for potash in western Canada during the years of the great war led to the staking of claims on many of the "alkali lakes" and sloughs which occur in numerous localities in the morainic areas of the prairies, as well as in British Columbia, in the hope that potash salts would be found in commercial quantities. While the search for potash, up to the present time, has been disappointing, the prospecting of these areas has demonstrated that Canada possesses large reserves of sodium and magnesium compounds, principally in the form of sulphates, carbonates and chlorides. he writer first became interested in these deposits in 1911 while investigating the sodium chloride springs of northern Manitoba. In the fall of that year a number of the sulphate ? deposits in Saskatchewan and Alberta were visited, but owing to the excessive rains at that period, all the deposits were under water and only a few brine samples were obtained. Owing to pressure of other work investigations of the alkali deposits in western Canada, by the Mines Branch of the Department of Mines, could not be undertaken until the field season of 1921, but since that time the work has been continuous. During the summer of 1918 a reported discovery of a large deposit of potash bearing salts was featured in western papers and in a short time practically all the lakes and sloughs of the prairie provinces, which showed the least indication of being saline, were staked for potash. This reported discovery was not substantiated on investigation and many of those who had staked claims allowed them t~ lapse without the slightest effort to determine the character of the material in the deposits which they? had leased.

Jan 1, 1924

By P. D. Rao

Chemical and physical properties of typical low-rank coal (LRC) ash are significantly different than bituminous coal ash. With the exception of extraneous ash, which is incorporated during mining or is due to ash partings within or between coal seams, LRC ash consists primarily of inherent ash that is bonded into the coal's organic matrix or finely disseminated mineral matter. This paper reviews the nature of LRC ash, both inherent and extraneous, and how this impacts the prospects of washing and utilizing LRCs. A literature review, as well as washability data, proximate and ultimate analyses and ash analysis of 25 Alaskan LRC seams are used as a basis for this discussion. The authors' recent research into the nature and distribution of phosphorous in an Alaskan LRC is also discussed

Jan 1, 1997

By John Dasher

The analyses reported on in this paper indicate that there are hydrometallurgical routes from sulphide concentrates to copper that are potentially competitive with smelters which are not permitted to emit sulphur oxides. The various hydrometallurgical processes, and their economics, are discussed.

Jan 1, 1973

By C. W. Davis

This paper is the second of a series of progress reports on a study of the hydrometallurgy of manganese which is being, conducted in an endeavor to make possible utilization-of the large deposits of low-grade domestic manganese ores that occur in several States. There are at least four processes in which a knowledge of the action of S02 gas on manganese oxides at elevated temperatures may prove of value.

Jan 1, 1930

By James F. Kemp

Jan 1, 1914

By F. Sorensen

ABSTRACT Electricity production by the Electricity Supply Commission of South Africa (Eskom) is the most important beneficiation process for South African coal. As one of the world’s lowest cost producers, energy-intensive industries such as ferroalloys and aluminium were introduced. However the poor were neglected. The white paper on energy policy (Department of Minerals and Energy, 1998) sought to redress this. Also, chasing economic growth to generate jobs resulted in high electricity demand and interruptions. Lifespan estimates of South African coal reserves based upon peak theory vary widely. Approaching peak, coal production in the future will be more expensive and, thus, contribute to more expensive electricity, which could inhibit industrial development unless South Africans work smarter.

Jan 1, 2011