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By Ricardo Chavex, Adrien Letellier

Flyrock remains one of the most critical issues in open-pit blasting. Despite the significant improvements made with modern surveying methods, the necessity remains to define sensible danger zones around blasting areas. Therefore, many semi-empirical models predict flyrock distances based on trajectory calculations and probabilistic adjustments. However, most are merely based on nominal parameters, even though a considerable amount of precise data is nowadays available thanks to modern measurement techniques using lasers, GPS, drones, and probes. These data provide accurate information about the actual field circumstances of a blast concerning geometry and rock-mass conditions. So how can we use and integrate them into existing flyrock models? The answer to this question can significantly improve the accuracy of flyrock prediction models and enhance safety. This paper will present a method to adapt existing models to actual field data using appropriate software and digital tools during the blast design process. In addition to calculating a more pertinent danger zone perimeter, this method provides an efficient and practical tool that helps prevent flyrock incidents. Indeed, it allows the blast designer and shot firer to be warned if there is a hazardous critical deviation due to local conditions. Moreover, it also enables blasters to communicate better and share the visualization of the blast-specific evacuation zone. The paper will also discuss how this method can be calibrated and how it has been used to analyze some actual flyrock incidents.

Jan 21, 2025

By Jan Drzymala, Przemyslaw B. Kowalczuk

"Flotation is possible when the forces operating between a bubble and the attached particle are properly balanced. There are many forces operating in the bubble-particle aggregate. The magnitude, location and direction of the forces depend on the type of process. The simplest arrangement in flotation is when a spherical bubble is attached to a spherical particle and both are immersed in water. In such a system there are four essential forces which shape the stability of the bubble-particle aggregate. They are excess pressure and interfacial solid/liquid, solid/gas and liquid/gas forces. A proper analysis and balance of the size, location and direction of these four principal forces lead to a general equation delineating the stability of the spherical particle–attached bubble system. Specific cross sections of the system and solution of the general equation lead to different relationships including the Young formula as well as the well-known geometrical relation between contact angle, particle and bubble radiuses. The arrangement of forces in the proposed graphical representation of the Young law is different from that presently used in literature for a bubble attached to an unmovable solid particle. Many real solid/liquid/gas systems are more complex due to the presence of additional forces which change the regular curvature of the liquid/gas interface leading to advancing and receding contact angles.INTRODUCTIONThere are numerous papers (Athukorallage, Aulisa, Iyer & Zhang, 2015; Chau, Bruckard, Koh & Nguyen, 2009; Drzymala, 1994; Lubarda, 2012; Pellicer, Manzanares & Mafe, 1995; Wang, Cui, Zhou, Xu, Sun, & Zhu, 2014; Young, 1804) and books (Davies & Rideal, 1963; Defay & Prigogine, 1966; Lee, 2013; Lyklema, 2000) dealing with the solid/liquid/gas system. Many of them concern the three involved phases having the shape of a sphere or spherical cap and the formed contact angle. The contact angle is usually measured through the liquid phase and can be either smaller or greater than 90o. The essential part of these publications is a graphical representation of the system with the Young equation shown as a result of balance of only three forces that is the excess Gibbs (or Helmholz) free energy per unit area of the three involved interfaces (Davies & Rideal, 1963; Defay & Prigogine, 1966; Israelachvili, 1985) (Figs. 1a-c). The Young equation, when the gravity force/buoyancy is neglected, is:"

Jan 1, 2016

By Berk. A. A.

"INTRODUCTION Corrosion of sections of piping used in steam-heating systems is frequently regarded as unavoidable, and periodic replacement is provided. Surfaces exposed to newly condensed steam appear to be especially vulnerable to attack. As an added nuisance, solid products of the corrosion tend to accumulate, plugging return lines.The trouble is ascribed in the main to carbon dioxide and oxygen 3/ 4 / 5/ 6/ dissolved in the condensate. When oxygen is the principal factor, the corrosion usually is characterized by pitting. Carbon dioxide tend3 to cause an acidic condensate which dissolves the metal more uniformly and produces the familiar failure at threaded areas where the piping is relatively thin, and where high stress may tend to acceletate the attack. Carbon dioxide enters the system with the feedwater, generally in a combined form such as carbonates and bicarbonates. Oxygen enters both with the raw feedwater-and as air leaking into lines under partial vacuum. The larger central-heating plants have sought to reduce corrosion by eliminating these gases as much as possible. A smaller plant ordinarily lacks the equipment and technical supervision required for this purpose."

Jun 1, 1944

By R. Hogg, S. Chander

"An overview of various physical and interfacial characterization methods for use in mineral processing is presented in this paper. The availability of a large number of characterization techniques and commercial instruments requires that the reliability and limitation of each be carefully examined. The choice of a method may depend upon the manner in which the information is to be used, for example in development of new processes, plant and process design, plant control, problem solving, etc. IntroductionThe behavior of particulate systems, in mineral processing and other applications, is primarily affected by the physical characteristics (size, shape, surface area, pore structure) of the particles and the nature of the different solid-fluid interfaces present. Mineral processing operations in general are either designed to modify and/or control physical and interfacial properties (grinding, classification, agglomeration, etc.) or are strongly influenced by them (flotation, flocculation, solid/liquid separation, etc.). Characterization of physical and interfacial properties should be an integral part of the development of new processes, plant and process design, and routine plant operation.Our purpose in preparing this article has been to present an overview of the current status of characterization, to point out areas of weakness, and to discuss the reliability and limitations of the various techniques, procedures, and instrumentation available. For more detailed discussion of methods, etc., the reader is referred to standard references.Sampling particulate solids.Sampling is a critical factor in any procedure for characterizing particulate materials — the reliability of characterization data is ultimately limited by the extent to which the sample used was truly represen¬tative of the population from which it was taken.Sampling from particulate solids involves two basic problems: (1) the selection of a random', unbiased sample and (2) choice of the appropriate sample size.The problem of sample selection involves the design of a sample collection procedure that ensures that every kind of particle in the population has the proper chance of being included in the sample without bias. Specific procedures such as the well-known cone-and-quarter technique have been developed and are discussed at length in the literature on particle characterization (Allen, 1981: Herdan, 1960: Gy, 1982)."

Jan 1, 1989

By J. Stiksma, R. Kalanchey, M. J. Collins, G. Owusu, R. Raudsepp, K. R. Buban, L. A. Barta, L. Masters

This paper describes the results of testwork for the treatment of Ambatovy laterite by an acid pressure leach process, with recovery of the soluble nickel and cobalt values as mixed sulphide intermediate by precipitation with hydrogen sulphide, and subsequent refining of the mixed sulphide to nickel and cobalt metals. These process development studies were carried out primarily in 2004, as part of a bankable feasibility study for the Ambatovy Nickel Project.

Jan 1, 2004

By Boqiang Wu, Ganggang Xu, Xiaodong Wang, Hai Wang, Shibin Zhu

"Using a paste-like slurry as a filling from the ground surface to the goaf, artificial pillars can be built in the cavity goaf to support the goaf roof to prevent roof collapse and ground subsidence. If the accumulation laws of paste-like slurry are known well, the filling technology can be optimized. The laws can establish the foundation for finding out the best methods for building artificial pillars and filling technology. In order to understand the accumulation laws of paste-like slurry in the cavity goaf, Aeolian sand with wide distribution in northwestern China was selected as aggregate, and Portland cement was used as cementitious material to prepare a paste-like slurry. A test model of the cavity goaf was built to simulate the filling process by pump from the ground surface to the goaf to study accumulation laws of the paste-like slurry. The results show that the whole process of expansion and accumulation of the paste-like slurry could be divided into stages: free expansion, fill tightening expansion, and stable expansion. The angle of repose of the accumulation body of the paste-like slurry is constant in the stage of stable expansion, and it is the final angle of repose of the accumulation body. The angle of repose of the accumulation body is highly relevant to the slump of the paste-like slurry, and it is unrelated to the distance between the floor and roof. Under certain conditions of the cavity goaf, reducing the slump of paste-like slurry is one of the effective ways to obtain cost-effective pillars.INTRODUCTIONA large number of cavity goafs of coal mines were left in northwestern China; they were formed in the mining process by room-pillar or strip mining. Safety coal pillars were used to support the roof to keep long-term stability in the goaf, so the ground subsidence was not obvious (Fu, Deng, and Zhang, 2011; Xie, 2014). With gradual weathering, destruction of coal pillars, or additional load from ground surface buildings and structures, there could be a risk of instantaneous collapse of the roof in the goaf. This would affect the safety of existing structures on the ground and adjacent mines (Qu et al., 2017; Li, Xiang, and Jia, 2011; Tan, Guo, and Zhao, 2016; Tan et al., 2017). For disaster prevention of the falling cavity goaf, the current common practice is full filling (Hu et al., 2008; Liu, Zhu, and Huang, 2015; Pan and Wu, 2010). However, for buildings and structures with lower deformation requirements, full filling is excessive. For example, it is acceptable for goaf treatment under general roads and industrial sites to control the maximum deformation and keep the deformation continuous (Liu, 2011; Liu, 2012)."

Jan 1, 2018

By D. Harrington

The primary objective of this paper is to discuss the hazards and furnish a list of recommendations for the safe operation of quarries and related works. They have been compiled from Bureau of Mines publications covering the safety experience of engineers before and during the year in the mineral industry,5 from a publication of the National Safety Council, Inc.,6 from explosives recommendations made by various explosives manufacturers,7 and from suggestions obtained from quarries visited. The second objective is to describe and illustrate safety devices, practices, and quarrying methods. The quarrying and related industries of the United States had a lower accident-frequency rate than either the metal- or coal-mining industry as reported for 1942.8 However, the quarry industry ranked eleventh in 15 major industries during 1942 in lost-time accident fre¬quency; metal mining ranked fourteenth and coal mining fifteenth.

Jan 1, 1950

By Brian J. Gorva

The key objective of forming a cartel is to increase profits to members of the cartel by taking the following action: a) control output; and b) control price. However, while attempting to obtain monopoly profits the cartel members have to contend with costs associated with cartelization and such costs include the following: political costs; the cost of coordinating output and price; organizational costs (such as cheating); and administrative costs (such as the cost of attending cartel meetings). The objective of commodity exchanges is to provide an open, free market where buyers and sellers may openly complete transactions and pricing information can be immediately disseminated. These transactions include the following: a) to provide facilities for "hedging", or transferring price risk from buyers and sellers of physical commodities to "speculators" through the medium of buying and selling futures contracts, and b) taking physical delivery of metal on due dates.

Jan 1, 1983

By James M. Stuckey

In a search for improved methods of upgrading tar obtained by low-temperature carbonization of coal, monoethanolamine (MEA) was found to be effective in extracting tar acids from coal tar distillates derived from a subbitunwous and a lignite coal. Patch extractions showed that both yield and purity of the extracted acids improved with increasing volume ratios of monoethanolamine to tar acid, varied from 1:4 to 8:1. Yield improved, but purity decreased as the concentration of monoethanolamine was changed from 30 to 70 volume-percent, and as the concentration of tar acid in distillate was increased ad from 14 to 45 percent. In a continuous countercurrent extraction employing a double solvent (monoethanolamine and hexane) approximately 80 percent of the tar acids was extracted from 170° to 350° C. tar distillate when using 1.6:1 volume ratios of amine:tar acids. Tar acids isolated from his extract, although of improved purity, contained appreciable quantities of neutral oils and some tar bases. Aqueous monoethanolamine was not effective for extracting the last 10 to 15 percent of tar acids in 170° to 350° C. distillate oil from lignite coal. The highest yield of isolated tar acids and the best recovery of monoethanolamine were obtained by diluting the extract with water and saturating with C02. Some losses of solvent were encountered when aqueous monoethanolamine solutions were heated through decomposition of the amine with the liberation of ammonia.

Jan 1, 1960

By C. Dorfling

Experimental work was performed using a bench scale autoclave to evaluate the effects that leaching temperature, pressure, initial acid concentration, and the solid to liquid ratio have on the behaviour of base metals and platinum group metals in a high-pressure sulphuric acid oxygen leaching system. The concentrations of metals in the leach solution were measured over time at different leaching conditions. At the conditions investigated, the initial acid concentration had the largest influence on the copper leaching kinetics, while the leaching rates of the other precious metals (OPMs: rhodium, ruthenium, and iridium) were highly dependent on the leaching temperature. A set of chemical reactions that can be used to describe the leaching chemistry was proposed, and the associated reaction kinetics were quantified. As a first estimation, the rate expressions were considered first order, and the rate constants were determined using the method of least squares, considering the experimental and predicted concentrations obtained for the different leaching conditions. Of the OPM compounds, the sulphides showed the fastest dissolution rate, followed by OPM alloys, and finally the OPM oxides. During the initial leaching stages, base metals and OPMs competed for the available dissolved oxygen, with oxygen being preferentially used for copper leaching. Precipitation of OPMs during the initial leaching stages can be ascribed to copper and nickel dissolution according to exchange reactions between dissolved OPMs and copper present as digenite or nickel present as polydymite. Control of the autoclave residence time is of particular importance to enhance the selectivity of this leaching step, given the dependence of the PGM leaching rates on the extent of copper dissolution.

Sep 1, 2012

By Abid Adekunte

"In recent years, developers have had to deal with complexities associated with numerous cases of deep basement construction in built-up areas. Design and construction of deep excavation support systems in urbanised zones come with many technical challenges. Restricted working spaces often render the use of temporary struts as wall restraint systems unpopular, as working space needs to be maximised. Also, tie-back anchors are often inapplicable due to the existence of adjacent structures. Therefore, developing alternative restraint systems for deep basement structures in builtup areas is becoming increasingly important to the present day basement engineer.This paper is centred on the design, construction and monitoring of enabling works for deep basement structures on three sites in the United Kingdom and Republic of Ireland. Traditional tieback anchorage and propping systems were inapplicable on the sites. As alternatives, separate novel wall restraint systems were developed and adopted, to enable excavation on each of the three sites.Performances of the novel wall restraint systems, as well as the responses of adjacent structures were monitored. Numerical modelling and field monitoring results show the three alternative wall restraint systems to be safe and effective. The paper also highlights the advantages of the novel solutions over conventional methods.INTRODUCTIONRecently, deep basement structures have become popular components of urban building developments. As pointed out by Pearlman et al., 2004, this could be attributed to the inadequacy of surface parking spaces in urbanised zones, while underground parking facilities are also believed to improve both aesthetic and commercial qualities of urban structures.However, while the incorporation of basement structure into new urban development appeals to developers and architects, the engineering design and construction aspects of basement works typically come against a whole lot of complexities and challenges. As highlighted by Wong, 2002, engineering problems associated with basement construction in built-up areas are numerous, some of these include; complicated sub-soil conditions, dealing with excessive active pressures, complex temporary works, proximity of sensitive adjacent structures, high level hazards to construction workmen and surrounding community, inadequate working space, etc."

Jan 1, 2015

By J. E. Tiffany, N. A. Tolch

The Pittsburgh Experiment Station has made a survey of the properties and characteristics of the brands of fuse manufactured in the United States ; 25 samples were procured from 4 manufacturers representing the different brands offered on the market when the investigation was begun . It is believed that the field was completely covered except for special fuse made to order for a particular job .

Jun 1, 1934

By E. G. King

Cerium and thorium sulfides have found use as crucible materials for melting certain radioactive metals. However, thermodynamic treatment of these sulfides has been hampered by lack of experimentally derived entropy values. This Bureau of Mines report describes heat-capacity measurements between 51° and 298° K, and entropy evaluations at 298.15° K, for cerium monosulfide (CeS), cerium sesquisulfide (Ce2S3), and thorium disulfide (THS2). The entropy values, with Literature results for the heats of formation, are used to obtain free energies of formation at 298.15°K. MATERIALS The samples used in this work were supplied by Prof, Leo Brewer of the Department of Chemistry, University of California. The methods of preparation and some of the physical and chemical properties of these sulfides were given by Eastman and coworkers.3 4/ Chemical analyses, conducted in our laboratory, gave the following results:

Jan 1, 1959

By David E. Swanson

The U.S. Bureau of Mines undertook a basic investigation of collimated abrasive water-jet behavior because a more complete understanding of the fundamental process may lead to further technical advances. Laboratory experiments used 2-mm water-jet nozzles and new entrainment apparatus to analyze collimated abrasive water jets operating under varied conditions. Maximum water pressure was 69 MPa to permit use of conventional hoses with a burst-to-operating-pressure ratio of 4. Nozzle and induction line pressures, abrasive induction rates, and jet reactive thrust forces were recorded for each operating condition. Average jet velocity and power were determined from component mass flow rates and reactive thrust force measurements. Relative velocity and cross-sectional distribution of abrasive particles were determined using impact analysis techniques. Other jet characteristics were determined photographically. Properties of free water jets, collimated water jets, and collimated air-water jets were determined for comparison.

Jan 1, 1989

By Hani S. Mitri

Strainbursts in brittle rock are common to deep underground mines. The state of stress at the boundary of mine openings is dictated by a biaxial stress/loading condition. This paper reports the results of a series of biaxial compression tests carried out on 100 mm cubic samples of norite rock, under different horizontal-to-vertical stress ratios. The results indicate that the biaxial compressive strength is considerably higher than the uniaxial one. It is found that the norite sample behaviour under biaxial loading mirrors field behaviour where shearing and progressive spalling of the opening boundary are observed prior to strainbursting. Sample failure is initiated by rock spalling at the sample free faces, i.e. in the plane of biaxial loading. Finally, it?s the out-of-plane shear failure mechanism that causes the sample to collapse. Shear failure takes place violently and abruptly and is accompanied with considerable audible noise.

Apr 1, 2005

By H. Masuda

The lijima Zinc Refinery started operation in 1972, and has today an annual capacity of 200, 000+-Zn. The hematite process was employed for the first time and the ideal of waste-free refinery has been pursued for 30 years. In recent years, however, only half of the hematite produced would be sold to the cement industry and hence a reduction of arsenic level has been necessary in order to sell the entire amount produced, The arsenic cementation process with zinc powder, developed through a long time laboratory research was found among some options as the best for the hematite process. The construction work started in 2000 and the facility was put into operation in 200 I. As a result in the same year all hematite were sold to the cement industry. The outline of this project, present operations and technical issue are reported in this paper.

Jan 1, 2003

By L. Berwick, A. Karunanayake, D. Skutt, H. Heath, J. Wang

Thallium (Tl) is a highly toxic heavy metal, soluble over a wide pH range. Tl levels may exceed discharge limits in mining-influenced water associated with processing gold, lead, cadmium, zinc, and copper ores. In this work, the effect of sodium permanganate (CARUSOL® C liquid permanganate) on Tl removal from mining wastewater was studied. Factors influencing Tl removal, namely permanganate dosage/demand, coagulant and flocculant use, order of chemical addition, and co-existing metal ions were examined. The results show that permanganate addition is very effective at removing Tl to below target limits and can provide a unique solution for improving wastewater quality and optimizing overall treatment costs. In addition, several on-line monitoring techniques were evaluated for process optimization. The Hach DPD Free Chlorine method was optimal, allowing plant operators to rapidly and easily spot check effluent samples for excess permanganate dose.

Mar 2, 2022

By J. Avraamides

Some operational difficulties have been encountered in the transfer of carbon-in-pulp technology to Australian conditions. Many gold mines? are located in remote and arid areas where the available ground water is highly saline. There is a gradual depletion of free milling oxidised gold ore reserves resulting in the necessity to treat deeper primary sulphide .deposits which can be refractory. Some near-surface ore-bodies and tailing dumps are contaminated by natural vegetative matter which can interfere with the adsorption of gold from the cyanided pulp,. Advances which have been? made include potable water conservation in elution, a new type of regeneration kiln, inter-stage screens, alternative leaching systems transportable carbon-in-pulp plants and efficient open-cut mining methods. Academic and applied research is well supported by government and industry and the results are normally rapidly disseminated and put into practice by the gold mining industry.

Jan 1, 1989

By M M. Collisson

The Synthetic Rutile (SR) plant operations, North Capel, produce electrostatic precipitator (ESP) fume and kiln scrubber residue. Typically ESP contains about 18 per cent Ti, 13 per cent Fe, 0.5 per cent Mn, eight per cent Si, six per cent Al, 16 per cent C, 0.9 per cent Zn, 0.6 per cent Pb, 300 ppm As, 300 ppm Cr and 5 ppm Cd. These wastes are held in a storage dam together with neutralised acid effluent (AE) liquor. A project was initiated to treat the fume and produce a benign residue that could be delivered to landfill, reducing dam space storage. Plant AE, containing free acid (9 - 14 g/L), Fe (6 - 7 g/L) and Mn (1 g/L), was used to leach ESP. The degree of extraction achieved for various elements include about 20 per cent Zn, almost 50 per cent As, five per cent Al, 0.4 per cent Pb and 15 per cent Cd. Extraction was most effective at pH The residue from AE leaching still contained Pb. TCLP tests of the leach residue produced Pb extraction significantly higher than the 0.1 ppm stipulated by Class 2 landfill guidelines. Other elements (eg As, Cd, Cr) successfully met the limits. Further leaching of the residue with EDTA extracted up to 65 per cent of Pb content. TCLP tests on treated residue showed Pb leaching potential of Lead was removed from the leach circuit as the sulphate by acidification of EDTA leach liquor, allowing EDTA to be recycled. The study showed that one waste stream can be used to treat another and help reduce plant waste.

Jan 1, 2001

By L. M. Oshinowo

The incorporation of advanced analysis tools, such as CFD, into the process plant design process has become possible through advances in commercially available computational fluid dynamics software and faster computers. Multiphase modeling is now typically employed in the design phase of process plant design at Hatch. The multiphase models include Lagrange-Euler and Euler-Euler treatment of the multiple phases. Additionally, mixture models with interface-sharpening algorithms are applied to the prediction of free-surface flows in complex geometry. CFD is applied to applications where traditional design rules are not applicable. The additional rigor of CFD modeling in 2D and 3D allows process engineers to come closer to realizing true virtual plant design. The objective of this paper is to outline the benefits and pitfalls in the application of multiphase modeling for rigorous design. Several application examples in the hydrometallurgical field will be presented.

Jan 1, 2005