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By M. Dadvand, G. Kipuros, A. Dadvand

"The ability to codeposit fillers within a nickel matrix has led to the production of a new generation of cermet coatings with properties useful for various applications. Hexagonal boron nitride (hBN) is a ceramic-type particulate matter with thermal conductivity, thermal stability, inertness, and lubricity properties that allow it to be codeposited. In this paper, a method was developed for modifying hBN surfaces to allow them to be uniformly dispersed in water-based solutions such as an electroless nickel plating bath. hBN surface modification improved wear performance of the electroless plated cermet due to enhanced interaction between the particulate and nickel matrix. RÉSUMÉ La capacité à effectuer un dépôt simultané de charges dans une matrice nickel a abouti à la production d’une nouvelle génération de revêtements cermet (une combinaison de céramique et de métal) dotés de propriétés très utiles pour diverses applications. Le nitrure de bore hexagonal (h-BN) est une matière particulaire de type céramique utilisée pour ses excellentes conductivité et stabilité thermiques, son inertie ainsi que son caractère lubrifiant, qui permettent son dépôt simultané. Cet article explore une méthode mise au point pour modifier les surfaces du h-BN de manière à ce qu’elles se répandent uniformément dans des solutions aqueuses telles qu’un bain de dépôt autocatalytique de nickel. La modification des surfaces du h-BN a amélioré la résistance à l’usure du placage autocatalytique du cermet en raison d’une interaction accrue entre la matière particulaire et la matrice nickel.INTRODUCTION Electroless nickel alloy coatings can be used for many applications; however, the need for improved tribological properties such as higher wear resistance and better lubricity has increased interest in incorporating particulates (fillers) into the nickel matrix by codepositing the particulates with nickel during the plating process. The selection of the particulate type depends on the desired properties (Sahoo & Das, 2011; Sudagar, Lian, & Sha, 2013). In terms of tribological applications, electroless nickel-based composites are categorized mainly into lubricating and wear-resistant composite coatings depending on the type of particles incorporated. The electroless nickel-phosphorus (Ni-P) composite coatings are composed of codeposited solid lubricants such as polytetrafluoroethylene (PTFE), graphite, WS2, MoS2, and hexagonal boron nitride (hBN) and, compared to nanocomposite electroless Ni-P coatings, they demonstrate a lower coefficient of friction. On the other hand, the nickel-phosphorus wear-resistant composite coatings are composed of hard particles such as silicon carbide (SiC), aluminum oxide (Al2O3), boron carbide (B4C), silicon nitride (Si3N4), diamond, tungsten carbide (WC), and zirconium oxide (ZrO2) and, compared to nanocomposite electroless Ni-P coatings, they have higher hardness and better wear resistance (Sahoo & Das, 2011; Sudagar et al., 2013; Parucker, Klein, Binder, Ristow, & Binder, 2014; Chakarova, Georgieva, Petrova, Dobreva, & Stoychev, 2016)."

Jan 1, 2018

By Glan Dale Coe, Will H. Coghill

"INTRODUCTION Characteristics of the mineral products that are to be contrasted herein are net energy consumed in grinding to a definite top limiting size and size distribution of the ground products. Through contrasts of these grinding characteristics this paper to differences in related mineral products and in unlike products. For,example, in anticipation of the data to follow, although Joplin chert and Babeitt taconits are running mates in defying the best crushing machinery, taconite is one of the more docile and Joplin chert one of the most refractory mineral products ordinarily fed to a grinding Routine grinding tests on a great variety of ores and tabulation of the findings have been covered amply by Lennox 4/ and by Maxon 5/ and associates. In contrast to that work, the present paper is a record of random tests made over a long period, and each answered an urgent question at the moment. The work was done at the Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama. The pressure of war work prevented an organized investigation."

Apr 1, 1943

By A. W. Storm

Vertical shaft furnace design and operation have their roots deep in antiquity. There is substantial evidence to indicate that iron was reduced from its oxides to serve mankind's needs long before recorded civilization - - actually prior to 3500 B .C. For at least 5500 years man has been matching wits with Nature to find better methods of extracting this most common, yet essential, metal from her, grasp. And, during nearly all of this period, the vertical shaft furnace has played a principle role in this dramatic struggle.

Jan 1, 1962

By R. Pelton, Z. Dai, S. Yang

ABSTRACT Hydrophobic polystyrene nanoparticles were evaluated as potential flotation collectors for pentlandite. The flotation of hydrophilic glass beads demonstrated the nanoparticles’ ability to induce flotation. Deposition of nanoparticles on glass surfaces increased the contact angle and enhanced adhesion of the beads to air bubbles. High flotation recoveries were achieved when 5–10% of the bead surfaces were covered with nanoparticles. Surface functionalization—the addition of vinylimidazole to polystyrene nanoparticle surfaces—caused the nanoparticles to selectively deposit onto pentlandite surfaces in the presence of Mg-Si slimes. Ongoing work includes attempts to identify specific applications where nanoparticle collectors might be cost effective. _ KEYWORDS Flotation, Nanoparticle collector, Coverage

Jan 1, 2014

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017

By B. Panton, J. Carvalho, E. T. Brown

"A major consideration in the design of high capacity tiedown anchors for dam, bridge and tower foundations is the tensile resistance of the rock mass to pullout, typically as a result of overturning moments or hydrostatic uplift. Rock mass pullout capacity for installed anchors is developed from the tensile strength and fracture propagation properties of intact rock, the orientation and physical properties of the discontinuities and anchor confinement at depth. The typically assumed, but generally conservative, design approach is to calculate anchor pullout capacity using the dead weight of a uniformly shaped inverted “cone” with an assumed initiation point and breakout angle. In some cases, some tensile or shear strength is considered across the area of the assumed pullout cone, however, these strength estimates are based primarily on based on limited historic testing data, empirical relationships for rock mass strength developed for other applications, and engineering judgement.As an alternative to the current foundation anchor design method, this paper presents a new approach to the rock cone pullout problem using Discrete Fracture Networks (DFN) combined with numerical simulations. The simulations presented in the paper investigate the influence of fractures in a synthetic rock mass on ultimate anchor strength. In addition, the global influence on fracture network statistics on rock mass pullout failure is also discussed and it is contended that some of the aleatory and epistemic uncertainty inherent in the design of rock anchors can be reduced by considering fracture statistics in anchor design."

Jan 1, 2015

By J. O. Claassen

"Homogeneous populations are required to perform descriptive, probabilistic, and inference statistics and to support stable, predictable mining operations. The geological and downstream processing environments are, however, highly heterogeneous. The complex nature of mining environments requires means to identify and define multipopulation environments that could affect the performance of mining value chains. A study performed at several operating mines suggests that the impact of heterogeneous or variable geological, mining, and plant processing environments on overall mining value chain performance may not be a key focus area at these operations. This was illustrated through the use of basic and spatial statistics, which included the log-probability plot, a modified range equation, and chronovariography. The findings reflect high relative variability in the geological and processing environments studied and mining operators’ inability to effectively deal with the sources and consequences of variability. The study suggests that a focus on heterogeneity in complex mining operations may significantly enhance overall mining performance. IntroductionHeterogeneity and why it mattersHeterogeneity refers to a state or quality of being variable/diverse and comprising different non-compatible elements or parts. In statistical terms a heterogeneous population can refer to a population comprising different non-compatible sub-populations or a multipopulation environment. The latter is commonly found in natural environments such as geological environments (Bardossy and Fodor, 2001). The inherent heterogeneity of complex geological environments is also referred to as spatial heterogeneity. Heterogeneity or variability, however, also occurs over time at mining operations. A case in point is variable ore composition on a conveyance system feeding a processing plant or product stockpile.Heterogeneity associated with the mining environment can significantly influence key aspects of day-to-day mining operations such as sampling, the use of descriptive, probabilistic, and inference calculations, and an operation’s ability to manage and control the mining value chain as a whole."

Jan 1, 2016

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

By C. L. Chaney

Investigations were conducted to develop spectrochemical methods capable of determining 0.01 to 100 micrograms of metals in 50 milliliters of solution. The use of gallium hydroxide (Ga(OH)3) as a carrier-precipitant to concentrate metallic ions is described. A porous-cup graphite electrode is used to collect the precipitate. A specially designed plunger permits the electrode assembly to serve as the sample-containing electrode in the subsequent spec-trographic analysis. Analytical curves are presented for antimony, arsenic, beryllium, and zinc. Sensitivities of detection are given for 13 elements. The techniques were applied to identify impurities separated from tungsten, to determine trace impurities in solutions containing high concentrations of magnesium, cobalt, or nickel, and to identify trace impurities in hydrofluoric acid. Laboratory glassware was a serious source of contamination when low levels of zinc were determined.

Jan 1, 1963

By P. I. James, M. R. Baker

Este artículo analiza la nueva producción de cobre a partir de "minerales de desecho" de baja ley usando la tecnología de Blue Planet Strategies DEMET™ (Dynamic Electrode Mining Effluent Treatment, por sus siglas en inglés), que tiene como objetivo salvar la brecha de procesamiento entre la solución débil de lixiviación en operaciones de extracción por solventes/electrowinning (SX/EW), removiendo electroquímicamente los metales a partir de corrientes débiles y a la vez generando productos concentrados en metales objetivo en un análogo funcional de extracción por solventes (SX). Se estudió el tratamiento de la débil solución de lixiviación pregnant (PLS por sus siglas en inglés) y se usó para estimar los impactos económicos y de producción para una hipotética lixiviación en pilas de cobre brownfield y una operación aumentada DEMET usando SX/EW para tratar el "mineral de desecho." Se presenta la remoción de cobre a un 86% de eficiencia en las placas por debajo de 0,1 g/L de cobre con un consumo de energía de 0.55 kWh/lb de cobre y una concentración del producto mayor a 10 g Cu/L. El modelamiento arrojó aproximadamente $2/ lb para la producción total de cobre y costos de tratamiento menores o iguales a $1/lb con un inmediato aumento del margen bruto de operación del 12% para el brownfield incrementado. Se indicó también un aumento de la vida de la mina con un margen bruto promedio de 38% en la producción aumentada de "mineral de desecho" con valores de cobre de $3.25/lb.

Jan 1, 2014

By Rami Abousleiman, Gabriel Walton, Sankhaneel Sinha

"Although conventional coal mine designs are conservative regarding pillar strength, local failures such as roof-falls and pillar bursts still affect mine safety and operations. Previous studies have identified that discontinuous, layered roof materials have some self-supporting capacity. This research is a preliminary step towards understanding these mechanics in coal-measure rocks. Although others have considered broad conceptual models and simplified analogs for mine roof behavior, this study presents a unique numerical model that more completely represents in-situ roof conditions. The discrete element method (DEM) is utilized to conduct a parametric analysis considering a range of in-situ stress ratios, material properties, and joint networks to determine the parameters controlling the stability of single-entries modeled in two-dimensions. Model results are compared to empirical observations of roof-support effectiveness (ARBS) in the context of the coal mine roof rating (CMRR) system. Results such as immediate roof displacement, overall stability, and statistical relationships between model parameters and outcomes are presented herein. Potential practical applications of this line of research include: (1) roof-support optimization for a range of coal-measure rocks, (2) establishment of a relationship between roof stability and pillar stress, and (3) determination of which parameters are most critical to roof stability and therefore require concentrated evaluation.INTRODUCTIONRecent studies on pillar design have suggested that the assumptions utilized in traditional methods such as tributary area theory (TAT) (i.e. overburden has no self-supporting capacity, infinite pillar array, and CHILE material properties) are invalid in many geo-mining conditions (Esterhuizen, Mark, and Murphy, 2010; Frith and Reed, 2017). Although TAT is conservative with respect to pillar loading, and mine fatalities have steadily decreased since 1990, roof-falls and pillar bursts still occur and injure hundreds of miners per year (Mark, Pappas, and Barczak, 2011). Even though large-scale global mine failure has not occurred in a US coal mine since 2007, the mechanics of global and local stability as governed by the relationship between geologic parameters, mine geometry, and engineering design are still not well-constrained.Numerical methods are a highly effective tool that can be used to gain further insight into these relationships. When using such an approach, calibration to existing empirical relationships is imperative to ensure that numerical model results are realistic. In this study, we utilize the discrete element method (DEM) approach in Itasca’s Universal Distinct Element Code (UDEC v. 6.0) (Itasca, 2010).DEM accounts for explicit separation and contact of individual deformable blocks (Jing, 2003) and captures how discontinuities can affect system behavior. Discontinuous and anisotropic rockmass properties are typical features in coal-measure rock which contain various horizontal (bedding) and sub-vertical (joints) fractures depending on their depositional environment, diagenesis, and historic and current stress states."

Jan 1, 2019

By A. J. Dickson, A. M. Starfield

This paper reviews the progress made to date in the development of computer models of heat and moisture transfer from rock surfaces to the ventilating air in deep-level mines. The application of these programs to ventilation planning and design is discussed.

Jan 1, 2014

By W L. Daniels, C Stilson, C Zimmerman

Mineral sands mining for ilmenite, rutile and zircon has disturbed over 1000 ha of prime farmland in Virginia (USA) since 1997 and additional areas are likely to be disturbed in Virginia and North Carolina (USA) over the next 15 years. Full-scale mining operations at the Old Hickory Project in Virginia were initiated in 1997 by Iluka Resources Inc. and restoration protocols have continued to evolve in response to a variety of economic, technical and social issues. Early on, the return of these lands to agricultural row-crop production was complicated by vertical stratification of tails + slimes and lateral variability in soil physical conditions in the reclaimed pits and by limited topsoil return. Virginia Tech and Iluka have worked cooperatively with all stakeholders for over 20 years to review the pre-existing research base, conduct new and innovative site-specific research and thereby provide reasonable expectations of post-mining soil productivity levels. In 2004, Virginia Tech, Iluka Resources and a local leaseholder (Carraway-Winn family) agreed to jointly manage a 45 ha research demonstration farm where the long-term effects of alternative soil reconstruction practices are being rigorously monitored for both row crops (corn and wheat) and forage production. All mined land crop yields are also compared to an adjacent undisturbed exceptional quality prime farmland soil. Row crop yields between 2005 and 2010 were significantly above county average yields (regulatory target level) and approximately 75 - 80 per cent of undisturbed adjacent prime farmlands. The state regulatory authority has recently relaxed its position on the necessity of topsoil return versus use of topsoil substitutes based on appropriate on-site research results and the ability of the reclaimed soils to meet comparative local county crop yield targets. This cooperative effort allows all clientele groups to objectively assess the post-mining productivity of these mined lands while providing an invaluable educational opportunity for the mining industry. CITATION:Daniels, W L, Stilson, C and Zimmerman, C, 2012. Development of effective rehabilitation protocols for mineral sands mining in Virginia, USA, in Proceedings Life-of-Mine 2012 , pp 97-104 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By M. W. Barger, J. K. H. Ma, J. Y. C. Ma, V. Castronova

The objective of this study was to investigate the effects of various bisbenzylisoquinoline (BBIQ) alkaloids on respiratory burst activity of alveolar macrophages and to characterize the interaction of these drugs with alveolar phagocytes. BBIQ alkaloids were chosen for study because they exhibit a wide range of antifibrotic potencies in a rat model, with tetrandrine being very effective and tubocurarine being ineffective. These drugs inhibited zymosan-stimulated oxygen consumption with a potency sequence of tetrandrine (IT) = fangchinoline (FA) > berbamine (BE) ., cepharanthine (CE) "" cycleanine (CY} ~ tubocurarine (TU). This inhibition of respiratory burst activity could not be attributed to a drug-induced decline in the ATP content of these pneumocytes. Drug binding to alveolar macrophages was directly dependent on temperature and drug concentration. The sequence for binding capacity was FA > TT = BE = CY > CE ~ TU. Therefore, there was no simple relationship between binding capacity and inhibitory potency. Binding capacity was not related to lipophilicity of these alkaloids. In addition, tetrandrine failed to bind to metabolically dead cells or sonicated macrophage preparations. These data suggest that the interaction of BBIQ alkaloids with phagocytes is not simply nonspecific binding to membrane lipids. Alteration of the cytoskeletal system with vinblastine, taxol, or cytochalasin B decreased tetrandrine binding by approximately 33% when adtkd separately and by 93% when added jointly. Pre-exposure of alveolar macrophages to stimulants increased the ability of BBIQ alkaloids to inhibit both oxygen consumption and superoxide release. These data suggest that the mechanism by which BBIQ alkaloids inhibit activation of phagocytes involves microtubules and bules and microfilaments. Pre-exposure of macrophages to stimulants would change the conformation of cytoskeletal components and may make these structures more susceptible to drug interaction.

Mar 1, 1992

By David A. Edgecombre

This paper discusses modern practices in the extrusion of steel. Particular emphasis is given to a description of the Ugine Sejournet method of extrusion, involving the use of glass as a hot work lubricant. Other methods are also mentioned. A brief history of extrusion is presented; present practices in the quality extrusion of tubing and solids are described; and the future potentials of the) process as a tonnage producer are briefly discussed. The advantages of extrusion and the reasons for the use of a glass lubricant, as well as the various methods of using glass, are given. The process, as described, is being used in the manufacture of large commercial quantities of stainless steel tubing and sections. This extrusion process is an essential and unique means of forming such atomic-age materials as titanium, zirconium, molybdenum and other super alloys all of which are materials required in the creation of nuclear installations.

Jan 1, 1963

By Stober, Frank Allan

The paper describes the development of components in an lntegrated Furnace Control system for shielded-arc smelting focusing on operation and crucible integrity enhancement. The paper reviews the mechanisms of power, feed and energy input and losses into the shielded-arc smelting process and describes the furnace control system module development and integration to tailor the process. The ultimate success of a furnace control system application is transfer of knowledge, training, and operational support during furnace start-up and ramp-up phases and a model for how this has been achieved is discussed. The control modules of a shielded-arc laterite smelting furnace are described in detail including measured results and screen captures from application in a laterite smelting furnace. This paper focuses on developments in Integrated Furnace Controls tailored to shielded-arc laterite smelting but development of common furnace control modules for improved crucible and tapping operation integrity applied to other furnace processes, including immersed-arc smelting, is also covered. Keywords: IFC, Power, Feed, Supervisory, Control

Jan 1, 2004

By Wm. W. Odell

This report comprises a brief outline of the experimental cracking of natural gas in a water-gas generator at Louisville, Kentucky, and a discussion of the results obtained. The work was done under a cooperative agreement by the U. S. Bureau of Mines with the Louisville Gas & Electric Co. The re-forming or partial cracking of natural gas is not a new process, but one which has been employed in the manufacture of city gas for a number of years. However, the apparatus used heretofore was not a water-gas generator containing a bed of ignited fuel, but instead it was a plurality of connected chambers containing spaced and arranged checker bricks, with means for heating the bricks and for admitting the natural gas. The procedure previously followed was quite different from that used during the tests at Louisville; likewise the results obtained were different. It is not uncommon for companies distributing natural gas to provide gas-generating equipment for producing manufactured gas which is used, mixed with natural gas, during periods of peak demand. Because this equipment is idle much of the time, in some instances being in use only for a few days a year, some of the gas companies have considered using it, during off-peak periods, in the manufacture of some gaseous products and for carbon black which might he produced and marketed with profit. There is one plant of this kind at Louisville. Kentucky. Its maintenance in condition ready to be operated is necessary because of the limited supply of natural gas and because of the variation in demand. The engineers of the Louisville Gas & Electric Co. considered in particular the possibility of cracking natural gas in a water-gas generator by injecting the gas into the incandescent fuel bed, thereby producing a gas comprised largely of hydrogen (H2) and carbon black, an appreciable amount of which is entrained in the gas as it leaves the generator, Because power and gas are available at low prices, Louisville was believed to be a satisfactory location for a plant which could use hydrogen. It was evident that this method of treating natural gas might directly benefit the gas company by: 1. Lowering, the cost of manufactured gas.

Jan 1, 1930

By R. K. Singhal

In an underground coal mining environment, a frictional ignition may be defined as the ignition of an explosive air/ methane/coal dust mixture by mining machinery. As the use of power loading equipment has become more widespread, frictional ignition incidents have increased. There have been many fatalities and injuries from this cause including the death of eleven miners in Sydney coalfield of Nova Scotia, Canada in 1979. This paper reports on the findings of a preliminary study carried out under the auspices of the Coal Research Laboratories, Department of Energy, Mines and Resources Canada. The objective of this study has been to identify a Longwall face cutting system that is inherently safer than the conventional shearer loaders used in Nova Scotia.

Jan 1, 1985

By J. S. Lee

Alkyl hydroxamates are well known collectors for oxide copper minerals as evidenced by the large amount of published literature. Our studies on a wide variety of copper ores from around the world have shown that alkyl hydroxamates will recover most of the "floatable" oxide copper minerals from an ore. They are available commercially, and they offer many advantages over alternative technologies for oxide copper recovery. In spite of this, the full potential of hydroxamates has not been exploited in the industry. The objective of this paper is to provide relevant practical aspects and guidelines to facilitate successful application of hydroxamates in operating plants. A critical analysis of the available information and data, based on several case studies, notation testing, and microscopic analysis indicates that alkyl hydroxamates can effectively recover well-defined oxide minerals of copper, but not copper occurrences such as Cu-bearing goethite (often misidentified as cuprite) which report as Acid Soluble copper in chemical assays. Prior to any notation testing with hydroxamates, it is necessary to assess the various modes of occurrence of Acid Soluble copper using microscopic and microprobe analysis.

Jan 1, 1998

By N. Ripepi

"The Langmuir model has been widely used for the coal-methane sorption process via an isothermal test. However, even though the temperature-dependent Langmuir model were recognized theoretically and experimentally, the quantitative relationship between the Langmuir’s constants (a & b) and temperature have not been clarified and confirmed by lab test data. This paper collects 158 methane-coal sorption data under different temperatures, which apply the Langmuir model to consider the relationship between Langmuir’s constants (a & b) and temperature (see APPENDIX I). Even though the Langmuir model cannot be used to show the physical state of methane adsorption on coal, it is widely used because of its simplicity and the reasonable explanation of its parameters (a & b). The results from these published isothermal tests confirm that 1) there is no consistent relationship between Langmuir’s constant-a and temperature; 2) the Langmuir model is a temperature-dependent model, and the temperature-dependent feature is mainly shown by the relationship between Langmuir’s constant-b and temperature; 3) The relationship between Langmuir’s constant-b and temperature can be described by both the exponential and linear relationship with dried coal. This paper provides a database for temperature-dependent Langmuir’s model, which can be used for reservoir simulation of coalbed methane reservoir, coal seam degasification modeling for underground coal mines considering the heating effect induced by geotherm and heat injection (via hot water, hot steam, ultrasonic, etc.). INTRODUCTION The isothermal test for gas sorption on coal is one of the fundamental tests in Coalbed Methane (CBM) recovery fields, such as underground coal mine methane degasification, CBM gas-in-place estimation, and carbon dioxide sequestration in un-minable coal seams. Generally, two methods, volumetric and gravimetric, are employed to obtain isothermal data (Bush, A. & Gensterblum, Y., 2012). Based on these two approaches, a series of commercial and self-assembled instruments are built and several calculation methods are used to obtain isothermal data (Bush, A. & Gensterblum, Y., 2012, Gasparik, K., 2014; Goodman, A. L., et al, 2004; Zhang, L., et al, 2013). In the post-processing stage, many models are provided to analyze isothermal data in order to understand the storage mechanism of gas in coal. Common models include the Langmuir model (and its extended forms), the pore-filling model, multilayer adsorption model (BET), and the Gibbs’ model. Among these models, the Langmuir model is the most widely used for its simplicity and functionality. The Langmuir model is expressed as follows:"

Jan 1, 2016