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By Sebastiaan Peelman

NdFeB permanent magnets are the best available magnets used in many technology applications. However, at their end-of-life (EoL) most of magnets and the contained REEs are lost during the recycling of the bulk metals. The REEs are classified as the most critical raw materials in the European Union, and recycling of REEs from EoL products will reduce their criticality and contribute to the sustainability of REE. Various technological routes have been reported, but most of the methods are effective for highly concentrated magnets or magnet scrap, which is greatly dependent on expensive pre-dismantling processes. This paper presents various innovative metallurgical solutions to the effective REE recovery from current industrial practice for WEEE recycling, including the ferrous scrap from WEEE shredder products and shredder residues from computer hard disk drives. Both hydrometallurgical and combined hydro- and pyrometallurgical REE recovery routes are developed after demagnetization and physical upgrading.

By Moris Fresko, Julia Sun, Charles C. Golembewski, Vytas Svalbonas

"A history of mill strain gaging at Metso is presented. The output of these strain-gaging programs is compared with calculated stress ranges from different finite element solutions. These comparisons expose the amount of approximation that exists in the analytical solutions, starting from geometry, and material properties, and ending with different forms of internal load models. The influence of strain gaging results on mill design and analysis practices is also discussed. While these instrumentation programs are valuable in identifying areas of high stress in mills, and locations of stress concentration factors, they are by no means extensive or comprehensive enough to verify general internal load models. The vast majority of the programs were aimed at getting additional data about potential failure points, rather than describing overall mill stress behavior. This is especially true since the more recent gaging programs have not included the difficult task of gaging the mill rotating structure interior. This paper tries to avoid the novice path of leaping to general conclusions on the basis of insufficient data."

Jan 1, 2014

By G. Bonin, A. Jamal, G. Preciado, S. Gillis

"Accurate, easy to obtain, and reliable methods of measurement are the cornerstone of shaft and tunnel developments - during their sinking, operation and maintenance, or in some cases, remediation. This paper presents a new methodology to capture existing shaft conditions in such a manner that they can be transferred from the field to a digital copy, where they can be stored and used for engineering design purposes in a space not directly affected by the costs associated with schedule and equipment performance. The methodology utilizes basic principles of excavation alignment (plumb lines and survey instruments) while adding modern LiDAR, geolocation and survey control tools that can more completely capture the surrounding environment. The complete cycle of collection, processing, and delivery of pertinent information underground can take under an hour. During sinking, capturing data as a live stream measurement and being able to assess the alignment of the shaft liner can be critical to meeting rigid design tolerances. As sinking progresses, small changes in alignment or liner deviations can be captured and immediately corrected. Likewise, post-construction as-built conditions can be recorded and digitized, which will allow the mine personnel to compare the proper working condition to the actual condition years later. Observed changes can be identified and planned as future shaft repair works. This methodology has been developed and successfully deployed during the on-going sinking works of the two shafts at the Jansen Potash Project in south-central Saskatchewan and is described in greater detail in this paper.INTRODUCTION Light Detection and Ranging (or LiDAR) scans of the BHP Jansen Production and Service shafts during construction identified sections of both shafts where the internal radius of the temporary primary liner was insufficient to accommodate the tolerances of the permanent liner that was to be installed inside the temporary liner. These locations are referred to as “tights”. The “Tights Removal Program” was designed to collect high resolution point clouds of the shaft, using stringent survey control, that could be compared to the design profile to generate a heat map of locations for removal of up to 75 mm of steel-fiber-reinforced, 70 MPa concrete liner. This work was all on critical path, which made it valuable to save time on the schedule. Because concrete removal was a time-intensive task, it was essential to locate and remove only the concrete that would encroach on the planned permanent liner, while attempting to maximize the amount of cutting time. Removal was carried by a road header attached to a Brokk(R) 160, a small multi-attachment demolition machine."

Jan 1, 2019

By L. Ya Agapova

Emissions from pyrometallurgical processing of copper concentrates are usually subjected to wet scrubbing. The washing sulphuric acid so produced contains up to 0.2 g/L of rhenium, which is recovered by solvent extraction in the form of crude ammonia permeate (NH4ReO4). The mother liquor, obtained from the sulfuric acid wash, contains up to 35 g/L of rhenium and significant amounts of impurities. Crude rhenium salt is commonly processed by double recrystallization to produce marketable salt. A ton of high grade NH4ReO4 can be produced using 3.0-3.5 m3 of mother liquor. We propose an efficient technology of mother liquor pre-treatment aimed at removal of water-soluble organics with subsequent electrodialysis. Electrodialysis of mother liquor in a multichamber electrodialyzer resulted in the production of pure rhenium acid, from which a marketable NH4ReO4 is precipitated using ammonia solution. Multiple steps of recycling consisting of dissolution of NH4ReO4 salt, rhenium acid production from NH4ReO4 salt by electrodialysis and precipitation of NH4ReO4 from rhenium acid made it possible to upgrade the purity of obtained rhenium compounds by 1-2 orders of magnitude. A rhenium metal powder of 99.997% purity was produced by high-temperature reduction of high-purity NH4ReO4 with gaseous hydrogen. Rhenium metal powder of high purity can be produced from sulfate solutions of NH4ReO4 by non-platinum anode-based membrane electrolysis processes also. Keywords: rhenium, mother liquors, membranes, electrodialysis, rhenium acid, ammonia perrhenate, reduction, powder, electrolysis

Sep 1, 2012

By Sahendra Ram, Arnn Kr Singh, Dheeraj Kumar, Rajendra Singh

"Inherent existence of different rooms (openings) along the extraction line in a depillaring panel provides an easy path for the goaf to encroach the working area. Each of these openings in a mechanized depillaring (MD) operation along the extraction line is supported by the roof bolt-based breaker line support (RBBLS) to restrict the goaf encroachment. Different field studies by Council for Scientific and Industrial Research - Central Institute of Mining and Fuel Research (CSIR-CIMFR) found that the RBBLS works effectively during the depillaring under the shadow of stable surrounding ribs/fenders only. It is observed that, generally, these natural supports experience high value of induced stresses after a large amount of void creation inside the goaf. The induced stress creates spalling/loosening of the sides of the natural supports. Field studies also found that the positions of the RBBLS at the goaf edge need to be adjusted according to the depth of this spalling/ loosening. However, a systematic study in field for the correct positioning of the breaker line as per the spalling/loosening under different site conditions is difficult. Therefore, on the basis of the data and guidance provided by these field investigations, a detailed parametric investigation was conducted in the laboratory on simulated models for an effective design of RBBLS in a MD panel. FLAC3D is used for the simulation of the depillaring, and the available empirical formulations for Indian coalfields are used for subsequent calibration. An analysis of stress redistribution for different stages of the MD in simulated models showed the significance of the nature of overlying strata/induced stress for the RBBLS design. Discussing some results of field studies, this paper presents results of the laboratory investigations for an effective design of the RBBLS.INTRODUCTIONContinuous Miner (CM)-based mechanized depillaring (MD) is an important issue for Indian coalfields, where huge amounts of coal are locked up in standing pillars (Dixit and Mishra, 2010). Considerable variations in site conditions of these developed pillars bring a number of technical challenges into consideration during their final extraction. One of these challenges is goaf encroachment/overriding during caving of the competent roof strata. Goaf encroachment/overriding can effectively be controlled, mainly, by suitable design of natural supports (rib/snook/fender). However, there is a requirement of applied supports against the immediate roof as a considerable portion of this roof is exposed due to the presence of different openings along the line of extraction. These applied supports act as a fulcrum at the goaf edge between the working area and the goaf to facilitate the break out of the hanging roof inside the goaf. This is called breaker line support. An effective breaker line support is important for the efficiency of a depillaring operation. Generally, MD adopts roof bolt-based breaker line support (RBBLS) at the goaf edge (Singh, et al., 2014). For the first time in India, roof bolts were applied at the goaf edge as RBBLS in a CM-based MD (Leeming, 2003). In the beginning, three rows of roof bolts were installed as primary and secondary breaker lines support. On the basis of the observations of instrumented bolts, only two rows of roof bolts were used as secondary RBBLS (Ram, et al., 2014). Now, most of the MD operations in India are using only two rows of bolts as RBBLS (Table 1). However, the strata mechanics studies at different MD operations showed interesting characteristics resulting from this support (Ram, et al., 2015)."

Jan 1, 2016

By R. A. King, B. G. Hunt, C. E. T. White

"This paper reviews the history, occurrence, properties, and uses of indium, and describes the commercial production and fabrication of that metal by The Consolidated Mining and Smelting Company of Canada, Limited (Cominco), at Trail, B.C'. Indium is produced commercially at Trail from dross retreatment furnace D.R.F.) slag, a complex by-product of the lead smelting operations. Furnace feed prepared from this slag is smelted with coke and limerock in an electric furnace. The e1ectric furnace bullion is parted electrolytically, producing a market-able lead-tin alloy containing about 8 per cent tin, and leaving the indium in the anode slime. Recovery of indium from the anode slime involves roasting the slime with sulphuric acid, followed by leaching with water, purifying the leach solution, recovering the indium by sponging with zinc or aluminum, and re-fining electrolytically. This process yields standard grade (99.97+ per cent) indium which is either sold or refined •to high purity ( 99.999 per cent) indium for special uses requiring higher purity metal."

Jan 1, 1959

By Richard D. Hagni

Polished sections of pyrometallurgical intermediate products from a simulated commercial flash furnace were examined by reflected light microscopy, scanning electron microscopy-energy dispersive spectrometry and electron backscatter analysis, and microprobe analysis for phase and textural relationships. The smelter feed is a copper concentrate from a porphyry copper deposit. The concentrate consists primarily of chalcopyrite, bornite and pyrite with smaller amounts of covellite, chalcocite, molybdenite, magnetite, galena, and sphalerite. The flash furnace reactions for pyrite and chalcopyrite can be observed by reflected light microscopy. Reacted angular particles of pyrite exhibit successive rims of fibrous pyrrhotite and hematite or magnetite. Reacted angular chalcopyrite particles show successive rims of bornite, digenite, and chalcocite. Spherical particles, formed by the complete melting of former pyrite particles, consist of variable amounts of granular pyrrhotite with magnetite rims and minor hematite. Spherical particles, formed by the complete melting of former chalcopyrite particles, exhibit exsolution intergrowths with varying proportions of intermediate solid solution, bornite, digenite, and chalcocite and have rims of hematite, magnetite, and copper-iron spinel. Sphalerite and molybdenite do not show evident mineralogical reactions.

Jan 1, 1987

By Sunil K. Tripathy

Particle characteristics such as size, density, liberation and magnetic susceptibility play vital role in magnetic separation technique. To understand the performance of magnetic separation process for chromite beneficiation industry, particle characteristics need to be analysed. However, to date, this has been an expensive and time consuming task, thus only minimal amounts of this type of data are available in the literature. Several new methods are being developed, that will produce the required mineralogical and liberation data to provide processing information rapidly and inexpensively. Among these, QEMSCAN is a unique and advanced characterisation equipment used for liberation analysis for different ore whereas S.G. Franz Isodynamic Separator for determining the magnetic susceptibility. In Indian chromite deposits, the content of iron bearing minerals in the ore is typical which controls the Cr:Fe ratio in the product while treating in gravity based beneficiation plant. In the present investigation, detailed characterisation of two distinct chromite ore samples from Sukinda chromite deposit, India, was investigated which includes advanced mineral characterisation using QEMSCANand magnetic susceptibility measurement by using Frantz Isodynamic separator, etc.. Presence of haematite and gibbsite along with chromite mineral were identified as major gangue minerals in the high grade ore from XRD pattern whereas Goethite, Quartz, Haematite, Kaolinite, Ringwoodite identified in the low grade ore. The mass magnetic susceptibility of low grade ore is very high 5.2 cm3/g compared to 2.7 cm3/g for high grade ore, due to the presence of abundant quantity of iron bearing minerals. Subsequently, these two types of ore were subjected for magnetic separation for improving Cr:Fe ratio by using different magnetic separators viz. induced roll magnetic separator, wet high intensity magnetic separator, rare earth roll magnetic separator, rare earth drum magnetic separator. The results of magnetic separation studies indicated that, Cr: Fe ratio of the chromite ores can be improved to 3.99 and 1.97 from the feed assaying 3.09 and 1.29 respectively. Studies on rare earth roll magnetic separator indicated that both the ores were upgraded to a maximum Cr:Fe ratio level at optimised condition. Keywords: characterization, QEMSCAN, magnetic separation, rare earth roll magnetic separator, industrial mineral, chromite

Sep 1, 2012

By K. Yamaguchi

To contribute highly efficient and environmentally conscious copper smelting process, several topics in chemistry of the continuous converting were discussed. Through the reviewing the authors' thermodynamic simulations, it is recognized that small amount and low copper content of the coexisting slag is preferable. Some discussions were added to the Takeda's diagram for Cu20-Fe0x-Ca0 ferrite slag, and the activity curves of the constituents were derived. Thermodynamic calculations were carried out on the copper contents of the slag during the blister copper formation. The dissolution of copper in slag decrease somewhat with increasing temperature, but the effects of increasing S02 pressure and decreasing %S in copper are considerable to increase in copper content of the slag. The optimum oxygen enrichment in the supplied air, and regulation of the oxidation degree for the blister copper are important in practice. The gypsum phase separation in the calcium ferrite slag was also evaluated thermodynamically, and concluded that decreasing temperature, increasing CaO content or S02 pressure, and extensive oxidation of the blister copper tend to separate CaS04. 0

Jan 1, 2007

By C. M. Campbell

IN 1934 Newfoundland, after extravagant operation based on exaggerated ideas of what she had to work with, became bankrupt, ceased to be a self-governing Dominion, and passed into the hands of a Commission. Since the days of Dawson, Canadians have been taught that no country in the world is as rich as their own. This idea has become a religion; contrary views are heresy, and are suppressed even by technical organizations and government departments. Following the alleged habit of the ostrich, we have buried our heads in the sand and have refused to face the facts. This policy of "to have today and to hell with tomorrow" is now bearing fruit. After forty years of operation on the basis of unlimited natural wealth, with resulting over-expansion, wholesale depletion of capital assets, and huge borrowings, we are, now that our wealth has been shown to be very limited, face to face with the status of Newfoundland. Already, in this Province, commission government of bankrupt municipalities is not uncommon. The ostrich is referred to as the most foolish bird in the world. That is not the case-no ostrich ever hid his head in the sand. In the clear air of his home on the South African veldt, an area characterized by low bushes, he is a conspicuous object. When danger approaches, he lowers his head; matches his background, the bushes; and danger passes him by. This leaves the Canadian, with his head still in the sand, to fill the r61e cast for the ostrich. Fortunately, a few Canadians never did get their heads covered; others are getting them out far enough to see what is going on. Their comments are very much to the point. "Nowhere in the world," says Mr. Meighen, "has more harm been done to any country by an exaggeration of its resources and potentialities than has been done in Canada'.

Jan 1, 1941

By D Johansson, A Nordqvist, D Mihaylov, N Petropoulos, M Wimmer

The flowability of the caved rock masses in the sublevel caving (SLC) mining method is of great importance. During the blasting process of a SLC-ring, the caved rock mass in front of the ring is compacted. As a result of this compaction, the mechanical properties of the fractured rock masses change, for example void ratio, angle of internal friction and structure of the compacted material. The changed mechanical properties of caved rock mass and recent blasted material can influence the mobility of the material, which could result in blockage of the flow path of the material. The identification of the involved mechanisms in this process can be done after a series of tests in different scales. However, there is no available equipment for dynamic measurements during blasting, ie velocity and displacement of the burden and in the caved masses. This study focuses on the development and laboratory evaluation of a measuring system that can be installed in a borehole. The first trial was carried out in a pillar, where two blastholes had been drilled (9.5 m) parallel with the drift and two measuring holes (16.5 m) were perpendicular to the drift. Two measuring systems were installed in the measuring holes. Some preliminary tests were carried out to find suitable initiation procedures for the emulsion explosive. Applicability and robustness of the developed measuring system were also evaluated. In addition to these tests, an expandable cement mixture was developed to firmly anchor the measuring systems in the boreholes. The measuring system consists of an anchor, armoured cable in a pulling tube and a protective case. The anchor is equipped with uniaxial and triaxial accelerometers. A potentiometric measuring system for displacement up to 2 m is installed at the end of the pulling tube and connected to an extendable spiral cable. All sensors are connected to a data acquisition system (DAS). Both measuring systems have their own DAS to acquire data in case of failure of one of the systems. The measuring system was tested in laboratory conditions with impact velocity up to 10 m/s. It was proven to be functional and gave reliable results.CITATION:Petropoulos, N, Mihaylov, D, Johansson, D, Wimmer, M and Nordqvist, A, 2015. Design of equipment for dynamic burden measurements, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 493–500 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By P. Lind, A. Gagnon

"Goldcorp has embarked upon an ambitious, industry-leading, multi-year water use reduction effort. This is a proactive, voluntary effort that reflects our commitment to truly sustainable mining. This effort will focus on increasing water re-use and recycling, and reducing water inputs ultimately towards zero. All of our operating mines are expected to contribute to this effort and are currently in the process of developing plans to meet short and long term objectives. One of the largest needle movers to increase water re-use and recycling is in the area of tailings management. Within five to ten years at Goldcorp, it is envisioned that the need for wet tailings dams will be eliminated and that all new tailings facilities will consist of only filtered or dewatered tailings. Filtered tailings is developing into a mature technology with wide application in mine waste management. This paper describes a conceptual level evaluation on the transition from a slurry to a filtered tailings operation at the Cerro Negro mine in southern Argentina. Key benefits and challenges are highlighted.INTRODUCTION Goldcorp’s Cerro Negro operation is located in the Santa Cruz province in the Patagonian region of Argentina. Cerro Negro has been in operation since 2014 and commercial production was achieved on January 1, 2015. The processing capacity of the plant is 4,000 tonnes of ore per day and in 2016 produced 363,000 ounces of gold and 3.1 million ounces of silver (Goldcorp Inc., 2017). As the mine is located in a semi-arid area, it is important to evaluate technologies that could reduce freshwater consumption and maximize water re-use and recycle rates. The current tailings operation at Cerro Negro incorporates pumping of tailings slurry into a conventionally lined Tailings Storage Facility (TSF). Water is reclaimed from the tailings supernatant pond to the process plant via pumps, however, water losses occur due to evaporation and solution retention within the slurry tailings voids. Converting to a filtered or dewatered tailings operation would allow for increased water recovery prior to tailings disposal, and decreased water losses from evaporation and from retention in the tailings solids void space. This paper describes a conceptual level evaluation on the transition to filtered or dewatered tailings with the primary objective of moving closer Towards Zero Water."

Jan 1, 2017

By A. Becker, C. Gauvreau, L. S. Collett

"A scale model was designed to simulate the airborne Barringer INPUT time domain electromagnetic system. The amplitude of the response to a vertical conductive dyke varies considerably with the conductor's thickness conductivity product (TCP). The response increases from a minimum detectable level at a TCP of about 2 mhos, rises to its maximum value at a dyke TCP of 15 mhos and then falls again so that conductors with a TCP exceeding 500 mhos would probably remain undetected. Measurements made with both standard receiver coil configurations (maximum or minimum coupled) indicate comparable effectiveness for both systems, either from the viewpoint of vertical conductor detection or from the viewpoint of discrimination against overburden anomalies."

Jan 1, 1972

By J. Visman

"SummaryThis paper is presented as part of a programme to show the steps taken by industry and others interested in supplying a solid fuel of constant quality to 'satisfy a consuming market. The paper deals with the general principles underlying quality control in coal preparation plants, namely, constant quality and close adherance to acceptance limits. It also describes how control of ash content is ""generally hampered by the problem of coal sampling .and the long duration of the ash analysis and how these difficulties may be overcome.Quality control can be effected in several ways. Thorough blending wll reduce variations appreciably, except those of long trend. The latter can be detected by automatic sampling and quick ash analysis. At present, under favourable conditions, a system of half-hourly ash determinations with an accuracy of 0.5 to 1.0 per cent can be realized, to the effect that trends with a 'wave length' of more than two hours cu be eliminated within the limits of accuracy of the ash figures. The general solution of the problem is a combination of blending, accurate sampling, quick ash determination, and statistical analysis of the pattern of ash distribution.The use of statistical methods of analysis, such as the t test and F test, is •discussed at some length in order to emphasize the importance of the correct evaluation of observational data if there is to be confidence in the validity of test results.General ConsiderationsCOAL, as a fuel, is too cheap for a long haul across the country. The limiting distance depends on the price of the local competitive fuels, and, as the price depends to a great extent on quality, so does quality, to the same extent, command the market."

Jan 1, 1952

By J Mukhopadhyay, J Gutzmer

Most world-class high-grade (60 - 67 wt per cent Fe) hematite iron ore deposits are the product of enrichment of Precambrian iron-formations but processes responsible for enrichment are still unclear. Different models, ranging from syngenetic and diagenetic (King, 1989), deep-seated hydrothermal (Powell et al, 1999; Barley et al, 1999; Taylor et al, 2001; Gutzmer et al, 2002) and ancient supergene (Morris, 1980; 1985; Van Schalkwyk and Beukes, 1986) to modern supergene (MacLeod, 1966) have been suggested. The high-grade hematite deposits stand in contrast to martiteûgoethite ores which are generally accepted to be the result of supergene enrichment of iron-formation because they are found along Cretaceous to Tertiary lateritic weathering profiles (Morris, 1980; Harmsworth et al, 1990). Uncertainties about the origin of the high-grade hematite ores appear largely due to the monomineralic composition of the ores. They are almost exclusively composed of hematite (as microcrystalline hematite and martite), a mineral with wide stability field and very simple chemical composition that reveals little about its origin. Second, many of the deposits have been overprinted by later deformation and chemical weathering obscuring primary ore characteristics and zonation (Taylor et al, 2001). Third, surprisingly few detailed geological studies have been undertaken on the deposits with the aim of unraveling ore genesis. Most studies focus on the present-day structure of orebodies and their general physical-chemical composition for mining and beneficiation purposes. A more thorough understanding of the origin of high-grade hematite iron ore deposits may be gained by combining available mining-orientated data with systematic petrographic-geochemical analyses of different ore generations and hematite phases. This paper presents a first summary of results of an ongoing study, started some two years ago, of high-grade iron ore deposits in South Africa, India and Brazil, including a comparison with the rather well studied deposits of the Hamersley Province in Australia.

Jan 1, 2002

By N. A. Warner

Fundamental studies on the reaction of limestone or dolomite at high temperature with S02 are extended to the realm of large scale primary copper smelting. Whereas flue gas desulfurisation in the electric power utility industry is concerned with S02 concentrations normally less than 0.5 percent, high temperature smelting gases can have S02 levels approaching 100 percent. The reaction involved is very exothermic so proposals are made in this paper for returning the heat generated in sulfur fixation directly back to the copper smelting process. This integration leads to metal production with lower energy requirements than current technology. The anhydrite reaction product can either be disposed of locally with minimum adverse environmental impact or upgraded to a value-added product. It is assumed, of course, that no viable market exists to support sulfuric acid production.

Jan 1, 1996

By Kari Niiranen

LKAB (Luossavaara-Kiirunavaara AB) is operating iron ore mines, concentration plants and pelletizing plants in Northern Sweden. The largest of the apatite magnetite deposits and the mines are Kiirunavaara with annual production rate of approximately 27 Mt crude ore underground. LKAB produces two varieties of pellets: blast furnace pellets and direct reduction pellets (LKAB DR Oxide Pellets). Meanwhile the concentration process in a sequence of the low intensity magnetic separation (LIMS) and flotation at the concentration plant. In spring 2007 there were noticed great fluctuations of SiO2 grade in the crude ore. The high SiO2 grade is particularly problematic in the case of direct reduction pellets. In consequence, a project was started (called Silica in the Mine) to define exactly the problem related with silica and to find out, if possible, the reason for the great fluctuation of SiO2 grade in the crude ore going to the processing plant. A further target of this project was to develop a simplified method at the laboratory scale, to predict SiO2 grade in the magnetite concentrate in the future, but also predict the physical properties of the ore with respect to mineral processing. The essential stage of systematic characterization of the ore body for mineral processing properties is the estimation and simulation of different parameters from the laboratory scale to the large scale at the concentration plants using empirical data collected at the mineral processing by LKAB in Kiruna. Further a target was also to find useful physical parameters for mineral processing and implant those parameters into the existing geological 3D-model of the deposit. This information will be used for making prognosis of the future mining and the quality of the crude ore. It will also give better control and improve the production planning in the mine and the performance at the concentration plant in Kiruna concerning the decrease of the SiO2 grade of the magnetite concentrate.

Sep 1, 2012

By Gaballah Djona M.

Spent hydrorefining catalysts contain about 5 % of CoO and/or NiO, 12 % of MoO3 and up to 10 % of V205. They are generally supported by alumina and contain up to 25 percent of C, S and hydrocarbons. Such materials are potentially hazardous to the soil and to water resources. Selective chlorination of raw unroasted samples with Cl2 + air gas mixture had been investigated. At temperatures lower than 600 °C, it was possible to recover more than 90 % of nickel and cobalt chlorides, about 99 % of the molybdenum and up to 75 % of vanadium chlorinated compounds. CoCl2 and Ni/Cl2 were extracted from the chlorination residues by their dissolution with acidified water. Molybdenum and vanadium chlorinated compounds were recovered by selective condensation from the vapor phase. The chlorination of Al2O3 could be limited to less than 6 %. The scale up of this treatment was successful and a flow-sheet is proposed.

Jan 1, 1995

By Paul Van Negan

During the last decade, MHO has continued to diversify the feed. of its Hoboken smelter. The range of feed materials including larger proportions of precious metals has been extended and the production of minor metals has been developed. These diversifications have required further improvements at the smelter. Attention has been particularly focussed on an increase of productivity, compliance with emission standards and achievement of the highest recoveries of valuable elements. The assaying and sampling facilities have been considerably expanded and the different processing steps of the smelter are now also systematically controlled and managed by simulation models. The charge preparation at the sinter plant, returns handling, sinter conditioning and corresponding ventilation systems have been completely renewed. The annual smelting requirement is now achieved with two blast furnaces instead of three. This is the result of rebuilding and enlarging one of the furnaces and, of a completely new concept of the charge proportioning and charging systems, together with oxygen enrichment and blast air preheat. Ventilation capacity has also been drastically increased. A 7 MVA electric furnace for cleaning the slag from both blast furnaces. contributes to improving the overall metal recovery.

Jan 1, 1990

By A. L. Engel

This report is a compilation of results of preliminary concentration tests of nine manganese-ore samples in 1953-1954. Three samples were from Nevada and the other six from California. These samples represent marginal or low-grade ores from deposits that have been mined selectively in the past. The present interest lies chiefly in the possibilities of concentration of the remaining low-grade ores for economical exploitation. The treatment methods included gravity concentration and flotation in most cases. Results were sometimes unsatisfactory, particularly when the ore was too fine grained for liberation of the minerals within economical grinding range. The contaminating gangue minerals, such as quartz and iron oxides, were locked with the manganese to an extent that prevented separation of high-grade concentrates with satisfactory recovery. In cases where fairly good concentrates were made, it was at the expense of recovery, a condition typical of low-grade ores.

Jan 1, 1955