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By Chenyang Zhang, Zhigang Yin, Jianyong He, Yuehua Hu

"A lot of floatation reagents (collectors, inhibitors and regulators) for the beneficiation of copper ores have been well developed in the past century. However, it is still unclear about the micro interaction mechanism of these flotation reagents with copper ores. In this paper, the interaction mechanism of these flotation reagents with the copper atom on chalcopyrite has been systematically investigated by first principle DFT (density functional theory) calculations. Thirty-four specific common functional groups linked with the same hydrocarbon chain (ethyl) are optimized at a B3LYP/def2-TZVP level, the solvation effect was included with the SMD solvation model. The analysis of the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO) and nature bond orbital (NBO) charge of these reagents reveals their potential applications to other types of copper-bearing mineral. Further investigation of the thermodynamics calculations gives more reliable data to screen collectors or inhibitors for copper-bearing mineral. The flotation results from carefully reviewed literatures are in good agreement with the calculation results. This work might also shed new light on the development and discovery of highly efficient and selective flotation reagents with low cost based on the computational methods.INTRODUCTION Froth flotation,(Shean & Cilliers, 2011) a mineral processing approach, is applied to efficiently enrich valuable minerals from the mixture, which is achieved according to the dictinctive surface properties of minerals. In the past century, researchers have develped an aboundant of flotation reagents by extraction or synthetize, and many carefully selected reagents might die in the bench tests or the pilot tests before the pratice.(Bulatovic & SrdjanM, 2007) Generally, it involves a lot of cost and tedious works by conducting flotation tests to screen flotation reagents. Flotation reagents have been boomed robustly with the developing of the organic synthesis.(Liu, Yang, & Zhong, 2017) Reseachers found the specific properties of a reagent are determined by its functional groups and the length of the hydrocarbon, where the functional group is assigned as the adsorption site to adsorb onto mineral surfaces and the hydrocarbon chain is called as a hydrophobic group."

Jan 1, 2018

By P. V. Malyarov

"This paper examines the grinding and wear processes in drum mills. A summary of the industry’s long-term experience with the proposed linings is presented. A method is proposed for assessing the efficiency of the grinding energy distribution between the successive stages. A case study is presented of grinding energy redistribution at Talnakh Concentrator by replacing spiral classifiers with a drum-type hydraulic screen. The problems of the kinetics of grinding processes in ball mills and semi-autogenous (SAG) mills are examined. It is demonstrated that in ball mills the feed particles are disintegrated by triaxial compression in the mill zones where discrete slippage of the charge occurs at major force interactions between the layers. Mechanism underlying increases in the specific energy consumption in grinding circuits based on SAG mills is shown.The problem of improving the throughput and reducing the specific energy consumption in mineral feed grinding is highly relevant because of the significant energy intensity. Up to 80% of the consumed energy is used to disintegrate ore fed into the drum mill. At all development stages of the drum mill grinding theory, the researchers have paid a great deal of attention to studying the patterns of the charge motion and the kinetics of the feed particles disintegration processes. In [1], it was shown that, due to the slippage between the charge layers being lifted, drum mills at concentrator plants operate in a mixed cascade and waterfall mode. A feature of the mixed mode is the toe zone, where the charge contacts the lining and the transition to a circular path takes place. Studies of the charge motion in the toe zone made it possible to develop a method for designing cross-sectional profiles of lining plates [2] for ball mill drums. The method is based on the principle of interaction between the balls and the lining, where the non-working rear surfaces follow the relative motion path of the balls before impacting the lining, while the working surfaces are orthogonal to the rear ones. Lining with the proposed profile provides contact with the charge and slippage-free transition to a circular path. This ensures an longer service life of the lining, a reduction in specific energy consumption, and an increase in the mill’s feed rate. The proposed method is applicable when designing lining plates of various materials. Steel liners with the proposed profile have been successfully operated [3] for more than 40 years at a number of projects in the industry."

Jan 1, 2018

By H. Staton, N. Michaelson

"INTRODUCTION Lundin Mining’s Eagle Operation, located in Marquette County, upper Michigan consists of a mine and concentrator that process a Ni-Cu-(PGE) ore. The mine itself is an underground operation and the ore is trucked from the Eagle mine site 66 miles to the Humboldt mill where both nickel and copper concentrates are produced. Operations began in 2014 and continued with an average production of approximately 23,000 tonnes of Ni and 20,000 tonnes of Cu per year for the first three years of operation. The Humboldt Mill, currently operated by Lundin Mining, processes the nickel/copper ore from Eagle Mine and performs the concentration through several stages of flotation. Originally built in 1954, the Humboldt Mill began operations as an Iron Ore processing facility, and was converted to a gold processing plant during the 1980s. Various groups owned the site after closure of the gold operation. Eagle purchased the Mill in 2008 and invested more than $280 million to clean up historic mine waste and refurbish the plant (see flowsheet in APPENDIX). This paper will overview the ramp-up of the operation, and discuss some specific areas that went well and some that could have gone better during the design phase. HIGH LEVEL DESIGN CRITERIA Coarse ore arrives from the mine and is stored in a building with a capacity of 10,000 tonnes. Ore is crushed in three stages to a final product size of 100% Passing 12mm. Crushed ore is conveyed to the mass flow fine ore bins, which have a live capacity of 3000 tonnes. Crushed ore is fed to two parallel 900 HP ball mills, charged with 3” high chrome grinding media, and ground, in closed circuit with hydrocyclones, to a p80 of 110 microns in the flotation feed. Soda ash is added to the mills based on process water hardness. Cyclone overflow passes to the bulk conditioner where Sodium Isopropyl Xanthate (SIPX) and Methyl Isobutyl Carbinol (MIBC) are added. The slurry is pumped to the rougher bank for bulk flotation. Rougher concentrate is fed to a 500HP vertically stirred regrind mill and is ground to a p80 of 50 microns, using 5/8” high chrome balls. Rougher tailings report to the tailings thickener. The regrind cyclone overflow is sent to the single stage cleaner bank followed by two scavenger banks. The cleaner concentrate is pumped to the copper-nickel separation circuit. Cleaner tailings report to the tailings thickener. In the copper-nickel separation circuit, the pH is raised to 11.5 and a copper concentrate is recovered from the bulk cleaner concentrate in two stages, namely the copper roughers and the copper cleaner columns. The concentrate from the copper flotation columns is the final copper concentrate. The tailings from the columns return to the head of the copper-nickel separation. The nickel concentrate is the copper rougher tailings stream."

Jan 1, 2018

By Duong Huu Hoang, Nathalie Kupka, Urs A. Peuker, Martin Rudolph

"The froth ability, froth stability and the froth structure are strong influences in flotation process i.e. on water recovery, bubble size, entrainment of gangue particle, flotation rate constants, grade and recovery. The labscale flotation of rich apatite ore with a high mass pull leads to significant changes in pulp and froth properties over time. The froth stability decreases with increasing the flotation time. These changes can be related to different solid contents, reagent concentration, froth heights and bubble size distributions. This study presents the results from froth studies and discussions on the particle size of fully liberated silicates and degree of entrainment based on automated mineralogy size-by-size analysis. The change of entrainment in a rich apatite ore batch flotation with time will describe more precisely by measuring froth properties using a Dynamic Foam Analyzer. It is concluded that the degree of entrainment is not only dependent on particle size but also the pulp density due to its effect on particle settling and also froth properties in varying resistance to particle drainage. Furthermore, entrainment models are applied to predict the effect of size, flotation time on entrainmentINTRODUCTIONFroth flotation belongs to the group of heterocoagulation separation techniques. Froth flotation is classically divided into two active zones, the pulp zone (where particle collection occurs) and the froth zone. A schematics drawing of the interaction between both zones is plotted in Figure 18 (Yianatos and Contreras, 2010). In froth flotation, the collision probability in the collection zone is governed by the physics of the process or hydrodynamics (Wills and Finch, 2016). The true flotation event in the pulp occurs when the hydrophobic valuable mineral particles collide with bubbles and formation of a stable particle-bubble aggregates moving upwards against gravity to the froth phase (Yianatos et al., 2009)."

Jan 1, 2018

By Michael Arnold, Jonathan Delgado

In 2017, Bauer Foundation Corp. (BFC) was awarded the contract to install the deep foundations for the new 17-story Hotel Tower and the Low Rise Casino Expansion at the Seminole Hard Rock Hotel and Casino in Tampa, Florida. The site was underlain by extremely challenging Florida Limestone geology and surrounded by occupied existing buildings and infrastructure. To overcome the challenges of the difficult subsurface conditions, and to successfully complete the foundation installation without impact to the surrounding buildings and casino operation, Langan Engineering (EOR) and BFC were required to modify both the design and installation techniques during construction. The scope of work included 147 temporarily cased drilled shafts to depths up to 230 ft (70 m) below ground surface (BGS), 76 permanently cased micropiles up to 200 ft (61 m) BGS, and more than 300 augered-cast-in-place (ACIP) piles up to 125 ft (38 m) BGS. Voids and zones of high permeability in the limestone created many challenges for execution of the foundation scope including ACIP piles overbreaks of more than 400% above neatline volume, and construction induced ground subsidence/collapses adjacent to structures supported on shallow foundations. This paper will discuss site limitations, design and construction challenges, difficult geology, varied soil conditions, and lessons learned. PROJECT The project is located at Seminole Hard Rock Hotel and Casino Tampa, Florida, as shown in Fig. 1. Seminole Tribe, the owner, started the construction of a new 17-story Hotel Tower and the Low-Rise Casino Expansion at the beginning of 2017.

Jan 1, 2018

By D. E. Cameron

"INTRODUCTION Grade control requirements for base and precious metal projects are an important input to both conceptual and feasibility mine plans. It’s the author’s experience that grade control input is insufficient at these critical stages. The few exceptions are a stimulus for this paper. A significant portion of CRC’s practice has involved assisting operations to solve grade control issues which were finally recognized as contributing to negative production variances. Even in operations perceived to be successful, deficiencies in grade control are often masked by measures taken by an operation to compensate a deficiency in one area with outperformance in another. The advantages in having a realistic and adequate grade control plan developed at an early project stage by a geologist(s) with considerable operations experience are manifold. It’s important for the geologist to prepare clear inputs into the mine plan backed by detailed supporting information in usable, flexible formats. When the decision is made to advance a project, the exploration team passes its model to a mine planner. The team doesn’t usually provide a detailed grade control plan with the block model, thus the planner tends to treat grade control as an activity to be rolled into a broader operating category. The consequences of highly compartmentalized mine planning can be severe in the long run. Once a plan is tabled, and especially once production begins, it is very difficult to improve grade control outside the fixed parameters of the operation. Major fixes tend to be costly in terms of time and dollars. Implementing needed changes to the grade control practices and culture in an established mine can present almost insurmountable difficulties. Hypothetical examples of grade control planning are presented to illustrate the author’s points. The diagrams are conceptual and schematic; any resemblance to actual deposits is coincidental. BEYOND 50¢/TON In more than a few cases, grade control cost is buried in a subcategory of mining cost with little more consideration than a plugged number. It is possible to do a word search in 43-101 Technical Reports on advanced projects and without finding reference to “ore control” or “grade control”. The idea is to reach the orebody by the shortest and least expensive means, achieving production and investor payback at the earliest possible occasion. This entails a low stripping ratio pit or a decline ramp with sills on ore to prepare the first stopes. The processes to achieve the target production, one of which is grade control, will fit into this framework. After all, there is a block model and the planner can see the grade and tons in each block. The exploration geologist whose responsibility was to bring a large percentage of the deposit into mineral resource owns the model and has released it to planning. Now comes the planning stage. Mine geologists haven’t been hired yet and they will be phased in with production. What could go wrong? Larger companies may have the geologists with operating depth who will be inserted into the mine planning discussions, but it’s not a given. Junior companies must often delegate the conceptual and detailed planning tasks to consultant groups. Is a senior-level grade control review part of the scope of work for the mine planning? If a good grade control plan is in place before the mine geology team is staffed, a key element of success is assured."

Jan 1, 2018

By Francisca San Martín, Martin Rudolph, Willy Kracht, Tomás Vargas

It has been shown that bacteria Acidithiobacillus ferrooxidans can be used to depress pyrite in seawater flotation at natural pH, which opens the possibility for its use as an alternative to lime to depress pyrite in copper sulfide flotation. In order to have a better understanding of the mechanisms involved in pyrite depression with A. ferrooxidans, an exploratory experimental campaign was carried out, including attachment density and contact angle measurements, and the effect of adding bacteria before or after collector. Biodepression of pyrite improves when increasing pH from 3 to 8, with a decrease in recovery from 92% to 36%. This increase in depressing capability is accompanied by an increase in attachment density, from 2.58×108 bacteria/g to 1.99×109 bacteria/g at pH 3 and 8, respectively, suggesting that the mechanism of depression is related to the attachment of bacteria to the pyrite surface. It was observed that the conditioning sequence with collector and bacteria influences the biodepression capacity of A. ferrooxidans. Having as a reference a value of pyrite recovery equal to 97%, when using only xanthate in seawater flotation at pH 8, the effect of both conditioning with bacteria-followed-by-xanthate and xanthate-followed-by-bacteria were assessed. When bacteria were added before the collector, the recovery of pyrite decreased to 36%. On the other hand, when bacteria were added after collector, the recovery was 64%, showing that biodepression of pyrite with Acidithiobacillus ferrooxidans is more efficient when the conditioning is carried out first with bacteria. The contact angle values show that there is little effect of the second component added to the system, i.e., if pyrite is first conditioned with bacteria, the contact angle does not change significantly once the xanthate is added (bacteria-followed-by-xanthate). The same was observed when the conditioning sequence was xanthate-followed-by-bacteria.

Jan 1, 2018

By G. Pahomova

"It developed an alternative to traditional flotation enrichment refractory of complex lead-zinc ores to obtain conditional lead and zinc products. The scheme involves the use of the processing method of gravitational enrichment of the primary cycle and the combined gravity-flotation-hydrometallurgical in finishing. The method has a high level of comprehensive utilization of mineral raw materials in relation to the elements that are extracted in the process of enrichment in lead concentrate, and the increase in recoverable value of processed ores. INTRODUCTION The primary source of lead are complex sulphide lead-zinc ore, lead ore actually rarer. The value of lead and zinc ores (except lead and zinc) is determined by the presence in them of a wide range of associated components: silver, contained mainly in galena; gold; bismuth in the form of its own minerals, but is associated with galena; cadmium contained mainly in the sphalerite; indium, thallium and gallium contained in sphalerite and galena; selenium and tellurium are present as impurities in the sulfide, tellurium is also found in the form of its own minerals. Of note harmful impurities antimony, which is often associated with lead sulphosalts and arsenic, having a substantially own minerals. By quality (content of lead, or the total content of lead and zinc) lead-zinc ores are divided into rich, ordinary and poor; by oxidation - to sulfide (with a lead oxides content less than 15% and zinc oxide content less than 10%), mixed and oxidized (50% oxide); the latter have a subordinate importance as a source of zinc and lead. Traditionally, the most contrasting technological properties of sulfide ores of nonferrous metals considered flotation properties, which determines the priority in the selection of flotation technology of their enrichment. Other methods of enrichment - gravity (jigging and enrichment in heavy suspensions), radiometric sorting (separation) are used as preliminary operations whose main purpose is to increase the content of lead and zinc in the ore sent to flotation, as well as the removing of part of empty rock in dumping tails prior to flotation. Effective implementation of these methods is possible at large size emphasizing in the ore of lead and zinc minerals, which is typical of the rich ores and which so far mainly worked. At the same time, non-ferrous metal ores (polymetallic, lead-zinc, copper-zinc, etc.) have a sufficiently high contrast to gravitational properties since ore minerals have a higher density compared with a rock minerals. But the gravity of the practice of non-ferrous ores enrichment is not widely used, despite its high degree of environmental safety and lower cost expensive."

Jan 1, 2018

By S. Banisi, A. R. Hasankhoei, A. R. Ghasemi, E. Razi, G. A. Parsapour

At the pelletizing plant of the Gol-E-Gohar mining and industrial company two parallel dry closed grinding circuits, each with the average throughput of 300 t/h, are used. Each grinding circuit consists of a burner, a dry ball mill (6.2 m×13 m) and an air separator. The ball mill consists of a 2 m-long drying and an 11 m-long grinding chambers. The iron ore concentrate is fed to the drying chamber by a feed chute. The first 1.35 m of the drying chamber consists of 56 flights in two rows to decrease the feed moisture from 5% to below 0.2% and the rest of dryer chamber consists of deflectors to pass the material to the grinding chamber. It was found that when the feed moisture content increased from 1.3% to 3.5%, the throughput decreased by 12% (35 t/h) indicating a low performance of the dryer. Monitoring the wear rate of flights for a period of 12 months showed that the first 0.8 m length of the flights length did not experience any wear. This means that about 59% of flights do not contribute in material distribution and drying. A DEM simulation of feed chute and the drying chamber demonstrated that due to the inappropriate design of feed chute most of materials do not get in touch with the first 0.8 m length of the drying chamber. To overcome this problem, various feed chute designs with different geometries were simulated by the KMPCDEM© software. With the aim of arriving at a proper material trajectory, where the total length of the flights are used, a new feed chute was selected. The simulation results indicated that if the height of the flights is increased from 1.60 to 2.26 m and the slope is increased from 45 to 48 degrees the material arrive at the first 0.48 m of drying chamber. In this manner, the unused part of the drying chamber decreases from 59% to 36% of the length. After installation of the new feed chute, during a period of three months the throughput increased by 36 t/h.

Jan 1, 2018

By A. Mainza, H. Hill, L. S. Bbosa

"Impact breakage is the most elementary size reduction mechanism in comminution devices. In comminution research, characterization of breakage is primarily concerned with the energy expended to cause it. The main challenges of this approach have been quantifying the actual energy requirements of impact breakage and developing mechanistic models to accurately describe the process. For engineering load analysis, fracture is characterized in terms of strengths such as yield stress and ultimate tensile stress, which govern the maximum loads specific materials can be subjected to before irreversible inelastic deformation and subsequently complete fracture occur. With this approach, the main challenge has been to elucidate the underlying mechanism, in the means that the load causes weaknesses in the material microstructure to act as sites for stress concentrations, leading to crack initiation, propagation and eventual failure. Studies dedicated to investigating particle fracture under impact loading have led to the development of several devices for conducting breakage characterization tests. These devices include the drop weight tester, split Hopkinson pressure bar, rotary breakage tester and the short impact load cell. All these have different particle loading and breakage methods, and thus can yield distinct information which can be compiled together to study a material and the nature of breakage. This work analyses the single impact breakage data obtained across the listed devices. A homogenous ore commonly known as blue stone is used for all breakage tests. The work is conducted using standard procedures specific to each device as closely as possible. Drop weight and rotary breakage tests were used to obtain hardness parameters based on an existing t10 breakage model, while split Hopkinson pressure bar and short impact load cell measurements provided properties based on conventional engineering load analysis. The results were used to highlight the significance of the loading geometry, impact mechanism and impulse on the extent of breakage."

Jan 1, 2018

By K-O. Mickelsson, S. Töyrä, H. Esbensen

Accurate information of physical, chemical and metallurgical quality characteristics such as moisture content, iron grade and particle size are crucial for successful process control and for producing products within customer specifications. Correct moisture content of pellet feed is an important variable for successful balling of iron ore pellets and to minimize power consumption in the sintering process. Control of the filtering process in the pelletizing plant is therefore essential for both productivity and high product quality. The current measurement systems for moisture content at LKAB are based on two types of manual grab sampling, subsequently analyzed with rapid moisture determination methods. Previous studies of the measurement systems have indicated high sampling variability resulting in lowered possibilities for successful process control. The objective of the present study is to evaluate an alternative filter sampling approach and testing of on-line Infra-Red analysis (IR-analysis). On-line IR-analysis has the advantage of eliminating physical sample extraction and allowing for continuous monitoring of moisture content. However, this approach is sensitive to the surrounding environment, making careful calibration and control crucial for the quality of measurement results. Furthermore, as IR-sensors only target the surface of the conveyed pellet feed, several incorrect sampling errors need to be considered and counteracted to eliminate sampling bias and reduce the remaining measurement variability. Variographic characterization was applied to the two current grab sampling approaches of combined filtered material, to the alternative filter sampling method, and to the On-line IR-analysis. The results indicate that both the sampling of separate filters (using composite sampling and ISO-standardized moisture analysis), as well as a calibrated and well- maintained IR-sensor can improve the relative variability significantly, by lowering the total measurement system variance from 60% to 25%.

Jan 1, 2018

By B. McFadzean, S. Geldenhuys

"Dynamic froth stability tests have found widespread application to quantify froth performance. However, little to no attention has been given to scale parameters in the performance of these measurements. One of the most frequently changing scale parameters in the laboratory scale is the column diameter as this directly influences the amount of material needed for testing. Four different column diameters (50, 100, 200 and 300 mm) were used for this study. Column diameter experiments were done on an industrial scale by means of manual tracking of froth growth versus time. An increase in measured dynamic stability was seen with increasing froth column diameter, which reached a limiting value at large column sizes. It is thought that this behaviour is controlled by the differences in drainage rates of the bulk froth compared to froth in contact with the wall. The column diameter required to represent full-scale froth stability is proposed. A ratio of column surface area to total bubble surface area was used to correct for different column diameters.INTRODUCTIONThe froth phase in flotation contributes significantly to the overall performance of the process (Zanin, et al., 2009). Numerous parameters have been investigated to quantify froth performance, most notably froth recovery (Feteris, et al., 1987; Seaman, et al., 2004; Vera, et al., 1999). Experimentally gathering data to determine froth recovery is challenging and for this reason froth stability has been highlighted as a possible alternative.Froth/foam stability is defined as the time of persistence of the froth/foam and is affected by numerous factors, such as: drainage of the liquid in the lamellae (gravitational and capillary), viscosity at the bubble surface, thickness of the electrical double layer and gas diffusion through liquid films caused by pressure differences between bubbles (Aktas, et al., 2008; Beneventi, et al., 2001). It is well documented in both froth and foam literature that froth/foam stability will heavily influence the performance and appearance of the froth/foam phase (Ata, 2012; Farrokhpay, 2011; Weaire, et al., 2005). Experimentally this has been explicitly proven as an increase in froth stability, characterised by water recovery, usually results in an increase in both valuable mineral and solids recovery (Wiese, et al., 2011; Banford, et al., 1998)."

Jan 1, 2018

By S. V. Volkova, S. V. Mamonov, T. P. Dresvyakyna

"The purpose of the work is complex processing of sulphide-magnetite ores with the separation of iron into iron concentrate, copper and noble metals into copper concentrate.The work shows the research results of the material composition of the sulfide-magnetite ore in the South part of the Peschanskoye deposit. According to the research results it is found that ore contains 0.59% of copper, 66% of which is related to chalcopyrite; 39.9% of iron, 81% of which is magnetite and 3.87% is sulfur, 42% of which is associated with pyrrhotite, 65% of which is a monoclinic modification. According to the results of the mineralogical analysis, it is found that the main iron-containing mineral in the ore under study is magnetite, the content of which is 45%. In addition to magnetite, iron is found in carbonates, pyroxenes, amphiboles, chalcopyrite, pyrrhotite and pyrite. The main copper mineral in the sample is chalcopyrite; covellite, chalcosine, bornite have a subordinate value. The total content of copper minerals in the sample is about 1%. The processing technology provides the three-stage grinding of the ore to a size of 65% of the class-71 µm; a cycle of copper flotation; a cycle of pyrrhotite flotation; wet magnetic separation of flotation hosts. The following optimal parameters are established for the ore under study: the alkalinity of the slurry is 250-280 g/m3 of free calcium oxide in the liquid phase of the slurry; the duration of the main copper flotation is 20 min; the consumption of butyl potassium xanthate is 20 g/t; the consumption of the foam generator T-92 is 15 g/t; the consumption of copper sulfate for the activation of pyrrhotite is 300 g/t; the magnetic field strength is 1500 Oersteds.A complex flotation-magnetic technology for the enrichment of sulfide-magnetite ore has been developed in the laboratory in order to produce a copper concentrate containing 21.6% of copper with 91.7% extraction and an iron concentrate with 66.5% of iron mass fraction and 1.2% of sulfur with an extraction of iron into the concentrate of 87.9%."

Jan 1, 2018

By J-C. Lv, S. Zhao, F-L. Zhang, T. Yan

"To eliminate nozzle clogging during continuous casting of ship plate steel and reduce the calcium addition required, the composition of CaO-MgOAl2O3 inclusions in the liquid phase region must be controlled. Thermodynamic calculations using FactSage show that when the balanced Al content is 0.03 mass %, aCa in the liquid steel is 1–10 ppm, and aMg is 0.01–0.3 ppm; and when the balanced Al content is 0.06 mass %, aCa in the liquid steel is 1–30 ppm, and aMg is 0.05–0.9 ppm. The CaO-Al2O3-CaS inclusions can be controlled in the liquid region below 1600°C at aCa values of 5 ppm, 15 ppm, and 30 ppm, and the balanced Al content should be controlled in the range of 0.001–0.050, 0.005–0.250, and 0.010–0.50 mass %, respectively. Based on theoretical analysis, the refining slag composition should be controlled to 45–53 mass % CaO, 30–37 mass % Al2O3, 6–12 mass % SiO2, and 6–8 mass % MgO. Optimization of the slag system and steel composition can reduce, or even eliminate, the requirement for calcium treatment. The total oxygen content in the slab can be controlled to 15–21 ppm, with typical micro-inclusions ??10 ??m in size, with compositions in the CaO-Al2O3-MgO and CaO-Al2O3-CaS systems. Introduction With the rapid growth in steel output in China and the changes in the macroeconomic environment, competition in the steel industry has become more intense. The technology for economical cleaning of high-grade steel is important for improving product quality and reducing production costs. However, the functions of refining equipment have not been fully taken into consideration, and the combination of refining methods has not been optimized completely. These problems have become a bottleneck, restricting modern steel enterprises from developing an economic clean steel production process. Ship plate steel produced by the converter long process has been selected as the example in this study. The composition of the steel is shown in Table I. This steel is a high-strength low-alloy steel for rolling media and heavy plates, mainly used for ocean-going vessels and other steel structures. The carbon content in the steel is far from the peritectic point, and the crack sensitivity of the slab surface is weak, so impurities and gas content are strictly limited. Therefore, the process route BOF (basic oxygen furnace) – LF (ladle furnace) – CC (continuous casting) needs to be studied."

Jan 1, 2018

By Shazad Hosein, Bill Birch, Catherine Johnson, Toby White, Liam Bermingham

Air overpressure (AOP) from blasting can give rise to a significant number of blasting complaints from residents living adjacent to blasting operations from mines, quarries or civil engineering projects. High amplitudes of AOP are usually associated with the lateral movement of a vertical free face, but it can also be caused by the upward lifting and the venting of gases through the surface of the blast area.

Jan 1, 2018

By Lénaick Menot, Anne-Sophie Alix, Charline Guérin, Sébastien Ybert, Ewan Pelleter, Florian Besson

Ifremer, on behalf of the French government, holds an Exploration Contract with the ISA for polymetallic nodules in the CCFZ. As part of its exploration activities, the NODULE (2015) cruise was conducted to acquire a 50 m resolution bathymetric coverage of the eastern sectors of the Contract. In 2017, Ifremer initiated an update of the Contract’s mineral resource estimate. Metal grades and nodule abundance were modelled using ordinary kriging. The inferred mineral resource is 436 Mt (wet) of polymetallic nodules at an average abundance of 10.7 kg/m² with a cut-off grade of 7 kg/m². Based on the geological data, seamounts, sedimentary basins and steep slopes contain no nodules. Technical studies of most of the contractors have determined that nodule collectors could not maneuver on slopes above 5 to 10°. Thus, Ifremer has selected a quite conservative slope threshold of 7 % (about 4°) and a backscatter threshold of -29.5 dB to delineate nodule-free areas. This has a significant impact on the resource estimate, as about 54 % of the eastern Contract areas are excluded. Near-seafloor high-resolution mapping and photographic transects, associated with finer-spaced box-core sampling could constitute a next step to better constrain the mineable areas and to get a higher level of confidence in the resource estimation.

Jan 1, 2018

By P. Asadollahi, M. Invernizzi

"This paper describes the innovative full-face conventional tunnel excavation technology, with its advantages in terms of savings and safety. The full-face approach has been developed throughout the experiences gained in tunnel construction. The innovative design approach is focused primarily on the deformation response of the ground acting first and foremost ahead of the face, which is analyzed, predicted and controlled by pre-confinement of the core. The advantage of this method is particularly evident in difficult grounds. This paper will present the outstanding benefits given by the adoption of the full-face approach in two projects, the “Sochi” and the “Visnove” tunnels. THEORY AND DESIGN ASPECTS OF THE FULL-FACE EXCAVATION The main challenges in tunnel and underground construction industry are gathering the design data from the ground that is being excavated and foreseeing the critical stage during construction, where the materials are in its most critical configuration. These challenges shall be addressed during excavation when the lining and the excavation disturbance have not yet reach the equilibrium. The in situ stresses in the ground are redistributed (forming an “arch-effect”) around the opening, with zones of increased stresses around the walls of the excavation (Figure 1). The distribution of the stresses can be close or far from the excavation profile, depending upon having a ground capable of withstanding the deviated stresses well or unable to withstand them, respectively. In the latter case, the ground will plasticize and deform in proportion to the volume of ground involved in the plasticization phenomenon. When the ground completely cannot withstand the stresses redistribution, it will cause the collapse of the excavation. While in the first case, the arch effect occurs naturally, in the second case, it does occur naturally only when the ground is stabilized properly. In the case of collapse, the arch-effect must be produced artificially operating on the ground prior excavation. The design should be based on the understanding of if and how the arch-effect can be mobilized during tunnel excavation and ensure that is formed by calibrating excavation and stabilization operations appropriately. The arch-effect is function of the medium that is being excavated, the action taken to excavate and the reaction expected following the excavation."

Jan 1, 2018

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

By V. P. Yakushkin, B. S. Ksenofontov

"Multistage model designed and used for more detailed description of floatation process. The study develops a new model of flotation kinetics description. It defines flotation as process that consists of several stages: air bubbles and particles are separate, air bubbles and particles form a raising aggregate, aggregate raises to froth layer. This description significantly differs from commonly used model, which is much simplified. The multistage model gives an in-depth description and considers different aspects of flotation. Experimental approval of the new model resulted in its accuracy.The model is to be used for description of all flotation processes’ kinetics of wastewater treatment. It helps in accurate designing of flotation treatment plants and may be used for further research of flotation process. Columnar flotation installation was designed by using multistage model. This installation consists of new tubular aerators with special ejectors, froth pressing system as well as unit of thin-layering lighting to catch microflotocomplex “particle – bubble”. Usage of tubular aerators allowed to aerate the overall volume of pulp. Due to use of special ejectors with longer mixing camera we state higher volume of small-sized floto-active bubbles. Use of multistage model allowed to optimize and get higher technological results of potash salts enrichment. Tests were conducted on centrifuges-floatation installation system. Meanwhile, froth concentrate contained mainly thin hydrophobic particles sized circa 0,1 mm. As a result we set that during floatation cleaning process of froth concentrate 95-98% of chloride potassium (KCI) is derived from foam.The final product satisfies production quality. Columnar floatation installation productivity was 17 – 21 m3/m2h, which is a high technological result. Columnar floatation installation is one of the best examples of concentrating equipment using nearly all technological indices."

Jan 1, 2018

By K. Matsuura, M. Ohno, T. Tokunaga

"Recently, weight saving of automobiles has been strongly required to solve the global environmental problems. Mg alloys are one of the promising candidates as a new material for automobile components. However, the application of the Mg alloys is limited due to their poor corrosion resistance. In the authors’ preliminary study, an Al/Mg/Al clad sheet was fabricated by hot extrusion and subsequent hot forging. The clad sheet exhibited a high corrosion resistance and excellent super plasticity. More specifically, the elongation of the clad sheet was as high as 550%.Importantly, despite that the elongation of Al itself was only 40%without cladding with Mg, the ductility of Al was greatly improved in the form of the clad sheet. In the present study, in order to clarify the mechanism of the superplastic deformation of the Al part in the clad sheet, the microstructure evolution of the Al during the tensile de formation is investigated. The tensile tests were conducted at a temperature of 573 K and at a strain rateof1.0×10-3s-1. The Al exhibited fiber-type texture at the beginning of the tensile deformation, and brass-type texture after the elongation of 50%.INTRODUCTIONMg alloys have been gaining attention because of their excellent properties e.g. light weight, good recyclability and high electromagnetic shielding. However, their practical applications have been limited due to their poor corrosion resistance. In the authors’ previous study, in order to solve this problem, Al coating on Mg alloy by hot extrusion has been proposed, and the Al-coated Mg alloy plate was fabricated(Tokunaga, Matsuura, &Ohno,2012). The plate was hot-rolled and an Al/Mg/Al clad sheet was fabricated. No cracks or debondings were observed at the Al/Mg interface. The sheet exhibited a high corrosion resistance in a comparable level as pure Al. Also, the sheet exhibited a large and uniform elongation of 550%in a tensile test at a temperature of 573 K and at a strain rate of 1.0×10-3s-1without any breakings or debondings of the Al part(Tokunaga, Matsuura, &Ohno,2014).Mg alloys have been known to exhibit a superplastic characteristic when the grain size is small. However, it is known that the pure Al does not generally exhibit the super plasticity. As mentioned above, the Al-coated Mg alloy sheet exhibited 550% of elongation in the authors’ previous study (Tokunagaet al., 2014). However, the pure Al itself showed only 40% of elongation, while the Mg alloy itself exhibited 800% of elongation. Thus, it has been demonstrated that the pure Al was super plastically elongated when it was bonded with the Mg alloy. Generally, deformation mechanism of the super plasticity of the Mg alloy is known as a grain boundary sliding. On the other hand, the mechanism of the superplastic elongation of the pure Al is still unclear. The purpose of the present study is investigation of the deformation behavior of the Al part in the Al/Mg/Al clad sheet during tensile de formation."

Jan 1, 2018