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By Fulian He, Jianhang Chen, Shoubao Zhang

"Fully grouted rock bolts have been used in mining industry for many years. Significant research has been conducted to evaluate the load transfer behavior of fully grouted rock bolts with experimental programs. However, compared with that, less work has been conducted with analytical modelling. Therefore, in this paper, the authors used an analytical model to study the load transfer behavior of fully grouted rock bolts. To confirm the credibility of this analytical model, an in-situ pull-out test was used to validate this model. There was a close match between the experimental result and the analytical result. Following this, a parametric study was conducted with this analytical model. The influence of coefficients, Young’s modulus of the rock bolt and the diameter of the rock bolt on the load transfer performance of rock bolts were studied. Furthermore, the load distribution along the fully grouted rock bolt was analytically studied. The results show that the axial load in the rock bolt decayed from the loaded end to the free end independent of the pull-out load. However, the trend of the load distribution curve was influenced by the pull-out load. This paper was beneficial to better understand the load transfer mechanism of fully grouted rock bolts.INTRODUCTIONRock bolts have been used in the mining industry for a long time. They are used as the reinforcement tendons to keep the stability of openings in underground mining and the slope in open-pit mining. Furthermore, rock bolts are commonly used not only in the mining engineering, but also in civil engineering (Thompson, Villaescusa, and Windsor, 2012).The rock bolt is a tendon which can be a rod or a cable inserted into a borehole drilled in rock masses or soils. Traditionally, the material of rock bolts was steel. However, engineering practices showed that the steel rock bolts can be easily corroded by the moist environment in underground mines. Next, Fiber Reinforced Polymer (FRP) was used to manufacture rock bolts, which are termed as FRP rock bolts. Experimental results proved that the FRP rock bolts can effectively reinforce the surrounding rock masses without being corroded (Wang et al., 2018)."

Jan 1, 2019

"Yara Siilinjärvi in Finland is the Western Europe's only apatite mine. Annually it produces one million tons of apatite concentrate, which creates 10 million tons of tailings. At the beginning of 2017, Yara replaced their conventional TSF with a new tailings treatment plant, which increased the solids content of the slurry from 45–48% to 66–68%, making it possible to deposit as a paste. This extended the life-span of the current TSF from 2020 to 2035. This paper presents the storyline of the Yara paste plant project. The project began with laboratory testing and then progressed to pilot-scale thickening and beaching trials. After successful pilot trials, the final process design was implemented. Process automation played a key role in the project. An advanced control system is needed to maintain process stability and the desired operation point in various operational circumstances. Since commissioning the paste plant has been running consistently with an underflow solids content of 66-68%, with average beach slope angles of 3.5 degrees in the tailings disposal area. Robust thickener operation also leads to the trouble-free high-density pumping and high availability of the plan. During first year of operation the plant’s availability has been very good, over 97%, and currently, the plant is operated remotely from the main concentrator plant.INTRODUCTION The Yara Siilinjärvi Plant is owned by Yara International, a Norwegian fertiliser company. Yara Siilinjärvi is Western Europe's only apatite mine, and it primarily produces apatite concentrate for its Siilinjärvi phosphoric acid plant. A portion of the concentrate is also dried and shipped to other Yara fertiliser plants. The site annually produces one million tons of apatite concentrate, which creates approximately 10 million tons of tailings. Extending the lifespan of the 1150-hectare tailings storage facility has been studied in Siilinjärvi for a long time. The aim has been to use the same tailings area footprint, without any new land purchases or major dam increases. An important part of the process has been to study the possibilities for using new technologies, especially thickened tailings technology (Ruhanen, 2014)."

Jan 1, 2019

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By Jerry C. Tien, Yingjiazi Cao

"Coal spontaneous combustion (SponCom) is a natural phenomenon in underground operations, which can either happen naturally or be triggered by human activities. For underground operations, espe-cially in coal, SponCom can happen frequently as a result of air leakage, although its incubation period may vary depends on types of coal and surrounding environment, resulting in uncertainty in control. In China, most of the underground coal operations now use longwall mining method because of its superior safety, high productivity and efficiency. With an increased popularity, there is also an increasing necessity to study spontaneous combustion, its occurrence and management. There have been many theoretical analysis and experimental studies over the past half century hoping to understand the occurrence of coal combustion and its control measures to better understand the occurrence and to design controlling measures to limit the dam-age it causes. In this paper, research on coal spontaneous combustion fundamentals from these three aspects will be reviewed, gaps highlighted and possible directions for future studies. INTRODUCTION The history of anthropic development is the history of human's energy utilization progress. From the first usage of fire, people have been continuingly seeking energy resources on earth. Coal, as an abundant, economic and convenient source of fuel quickly became indispensable and made significant contribution to economic growth worldwide. With technology and societal development, people are becoming more and more coal-dependent, but at the same time, problems of fossil fuel combustion came into sight. In global coal mining industry, spontaneous combustion has now presented one of the most challenging safety issues, it is also believed that it has contributed significantly toward the climate change. It is essential that more effort be invested to examine the cause of SponCom and its control measures. Coal SponCom is a complex process, with both physical and chemical inter-actions among various interrelated factors such as local airflow distribution, ventilation pressure, methane emissions (if any), and physical surroundings underground. With the advent of powerful computers, simulation techniques and af-fordable modelling packages in recent years, significant advances have been made in understanding sponta-neous combustion. But because of the complex nature of combustion and varying underground conditions, there are still areas that need further examining. This paper will focus on illustrating the current research of coal spontaneous combustion and addressing research gaps and future study areas."

Jan 1, 2019

By U. Caliskan, S. Miskovic

Gravity separation is a technique that depends on the difference in density of minerals for their separation. Although this method is one of the oldest separation techniques, it is still preferred in the industry because of its low capital and operating cost while it is environmental-friendly. In this paper, we present a new numerical methodology that can be used to investigate dynamics of dense slurry flows in gravity separation systems. A simple channel with a set of riffles is selected as a test platform in order to observe the effect of the riffle shape on segregation profile of particles with different densities. It is believed that the riffle shape would affect the slurry flow and possibly cause one class of particles to segregate within the riffle zone. The turbulence, as a disturbance effect within the riffle zone, causes heavy particles to displace the light, that is, the heavy particles will be trapped in riffles, while the lighter particles are carried by water to the end of the channel, which is an example to uninterrupted suspension. MP-PIC model in OpenFOAM is used to study the effect of riffle shape and slurry percentage of solids in this simple gravity separator on particle segregation profile of four discrete mineral density classes, which are Quartz/Clay (SG 2.6), Pyrite (SG 4.2), Chalcopyrite (SG 5.1), and Gold (SG 19.32). Gold particles are found to be readily captured and retained in the riffles because of their high density, while particles with the intermediate densities are more influenced by the flow. The developed model framework has been proven robust and capable of providing physical results even for the flows with a very high percentage of solids, characteristic for mineral processing operations. INTRODUCTION Gravity-based ore concentration techniques make use of differences in density of minerals within an ore to enable separation of valuables from the gangue. As some of the oldest techniques used for ore beneficiation, they are known to offer a range of benefits such as low specific energy consumption and low capital and operating costs (Burt, 1999; Falconer, 2003; Holland-Batt, 1998), however, they suffer from low selectivity, poor separation efficiency, and low capacity. Gravity separation techniques are common practices in the mining industry and are employed widely for the precious mineral concentration, iron ore recovery and coal preparation (Kroll-Rabotin, Bourgeois, & Climent, 2013; Laplante & Spiller, 2002; Williams, 1997). For example, gravity separation systems are highly applicable for precious metal enrichment operations by being included in primary grinding circuits, shaking table tailing separation, pre-concentration of leach feed and flotation concentrate enrichment for both flash and conventional flotation purposes (Burt, 1999; Falconer, 2003; Holland-Batt, 1998; Laplante & Spiller, 2002; McAlister, 1992). Gravity separation can be employed in the copper processing circuits by being integrated into the pre-flotation circuit to capture the gravity recoverable gold (GRG) and any free copper aiming to enhance the gold and copper recovery of the plant. When native copper and GRGs are present in the deposit, this integration not only facilitates plant overall performance via removal of the valuables early in the circuit, but it also reduces downstream operational expenditures due to less retention time of coarser copper particles in the system.

Jan 1, 2019

By J. A. Scott, K. Moreau, H. Shang

"Trials of automated technology at underground mine sites around the world have reported increased production and the potential for lower energy consumption. Autonomous mining eliminates a range of delays related to operator downtime and travel to the workface and facilitates continuous operation in conditions that are unsafe for workers. Automation also introduces complexities and safety hazards arising from equipment–personnel interactions; automated processes must be isolated from other stope-cycle–related activities such as production drilling, development, loading, and backfilling, poten¬tially requiring changes to the mine design to maintain an efficient and safe operation. This paper reviews and discusses the implementation of automated equipment in deep underground mining operations and the challenges and advantages associated with the technology. ¦ KEYWORDS Automated equipment, Emissions reduction, Energy, Productivity, Sustainability, Technology, Underground mines RÉSUMÉ Des essais de technologies automatisées dans des sites miniers souterrains aux quatre coins du monde ont indiqué une production accrue et la possibilité de réduire la consommation d’énergie. L’exploitation minière autonome élimine tout un éventail de retards liés aux temps d’immobilisation des opérateurs et aux déplacements vers le front de taille, et facilite l’exploitation continue dans des conditions qui s’avèrent peu sécurisées pour les travailleurs. L’automatisation introduit également des complexités et des risques pour la sécurité, qui surviennent en raison des interactions entre l’équipement et le personnel. On recommande d’isoler les procédés automatisés des autres activités liées au cycle des chantiers telles que le forage de production, le développement, le chargement et le remblai, ce qui pourrait entraîner des changements au niveau de la conception de la mine afin de préserver rendement et sécurité dans l’exploitation. Cet article examine et aborde la mise en oeuvre de l’équipement automatisé dans des exploitations minières souterraines profondes, ainsi que les enjeux et les avantages associés à cette technologie. ¦ MOTS CLÉS durabilité, énergie, équipement automatisé, mines souterraines, productivité, réduction des émissions, technologieINTRODUCTION As the mining industry continues to exhaust easily accessible orebodies, the need for efficient, deep (typically below 2,500 m) mine operations increases (Atlas Copco, 2013a); however, the mining process can become economically infeasible at great depths because operation costs drastically increase. This has resulted in investigations into automating mining operations as the industry strives for improved productivity (Schunnesson, Gustafson, & Kumar, 2009) and ways to remove personnel from hazardous work areas."

Jan 1, 2019

By T. E. Wakefield

"Final Galloway (stage) designs for vertical drill and blast shaft sinking projects evolve from complex thought patterns which integrate operational processes, systems and methods of communication, power supply, drilling, blasting, ventilating, mucking, supporting, surveying, dewatering, sealing, concrete lining and shaft furnishing. Attention to ergonomic design detail at the shaftsman / structure interface is at the heart of safe and successful multi-deck working platforms. For economy the end product must have a low mass to reduce suspension rope end loads to be able to use smaller suspension hoists and have lighter headframe structures, be robust to withstand concussion damage, be easily constructible on site, be maintainable in the shaft barrel, and comply with safety and legislated standards. This paper’s ambition is to describe a systematic design framework and sequenced thought process that delivers a product that is engineered with excellence, illustrated by making use of two designs that evolved during recent Galloway projects, one destined for a large diameter man/material shaft, the other for a ventilation shaft. The stage engineering iterative process starts with mapping permanent and sinking hoisting layouts, followed by laying out horizontal deck plans, mostly constrained by the permanent shaft purpose and configuration, whilst maximizing openings to enable muck to be removed rapidly for the best sinking cycles. Concurrently the designer needs to understand the chosen sinking methodologies in conjunction with crewing to determine the number of decks and fix their spacing. Insufficient access to move and line up formwork, set reinforcing rods and pour concrete in the confined spaces of the stage is an inherent major risk to be mitigated. An iterative and integrative process follows for the primary configuration which delves into increasing design detail, accommodating all other methodology influences, resulting in 3D layouts for further risk assessment, review and fine tuning by seasoned shaftsmen. INTRODUCTION Documented colliery shaft sinking practice from the late 1800’s makes reference to purpose built walling (bricked lining) cribs with floors suspended in sinking shafts, thereby allowing shaft lining to proceed concurrently with the excavation. Improvements were made by Sir William Galloway who introduced two decks supported at the corners by angle irons. The sinking stage, or Galloway, has developed substantially over time to be the in-barrel heart of the sinking operation, with overwhelming complexity for those who have to design one for the first time."

Jan 1, 2019

By C. Villaseca, F. Penna, R. Villarroel

Acid mist is the undesired result of copper electro-winning (EW) process, generating a contaminated and hazardous environment in the working areas, as well as promoting high corrosion conditions for structures and equipment in the EW tank-house due to the buoyancy of sulfuric acid in aerosol form. Likewise, organic entrainments that occasionally occur in this process contaminate the cathodes, as well as increasing the risk of fire. LateralVex® and LateralFlow® are technologies that effectively and efficiently solve these problems, without affecting the usual activities of the operators, thus presenting a significant distinction with respect to other technologies that seek to solve these problems. Minera Antucoya, an AMSA group company, which produces 80,000 tons of electrolytic Cu per year, decided to install both technologies for its EW tank-house, LateralVex® in commercial cells and LateralFlow® in scavenger cells to keep both the acid mist and the organic entrainments under control. This paper presents the effects of applying these technologies in Minera Antucoya’s electro-winning plant, the challenges addressed, the difficulties encountered, the problems and opportunities that their implementation involved, as well as the surprising results obtained at the time of measuring the acid mist— less than one hundred’s part of the Allowed Weighted Limit—in samples taken with the plant operating at maximum current capacity. Additionally, the paper includes some of the improvements identified during the period, more than 3 years, in which these technologies have been in operation in Minera Antucoya. INTRODUCTION Electrowinning is the most used electro-chemical process in the hydrometallurgical industry for the recovery of highly pure metallic copper as its final product, which is formed in previous stages in an aqueous medium that goes through a selective process using organic solvents to separate impurities and concentrate the metal in a sulfuric acid solution. In the last stage, this solution goes through a process in which high- density current at a low voltage is applied, so that the metal in the solution will deposit in solid state on a plate, usually a stainless-steel plate. This last process involves the generation of other sub-products due to the electro-chemical dissociation of the electrolyte’s components, or to the addition of chemical additives, or due to specific physical conditions or lack of controls during the operation.

Jan 1, 2019

By Lassi Klemettinen, Ari Jokilaakso, Dmitry Sukhomlinov, Pekka Taskinen

The solubilities and distributions of molybdenum and iridium in iron silicate slag and copper-iron mattes were studied using an equilibration-quenching technique and subsequent direct phase composition analyses by EPMA (Electron Probe X-ray Microanalysis) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry). The equilibrations were carried out on a wide matte grade interval, ranging from 55 wt-% Cu to 75 wt-% Cu, in pSO2 = 0.1 atm at 1300°C. The results in equilibrium with a solid iridium-molybdenum alloy indicated an iridium solubility of 150–500 ppmw in the sulphide matte, depending on the matte grade, and a molybdenum solubility of 100–600 ppmw. Iridium was distributing predominantly in the sulphide matte with the distribution coefficient of 10+3 - +4 but molybdenum deported predominantly in the slag with Lm/s(Mo) = 0.02–0.1. The effects of alumina and lime additions in the smelting slag were also examined. INTRODUCTION Iridium is a highly siderophile element (HSE), which means that it is incompatible with the sulphide forming elements and possesses a small solubility in mattes, such as copper- and nickel-iron sulphide melts. Molybdenum behaves only modestly in that way (Walker & Li, 2008; Righter et al., 2017). They both are known to be trace elements accompanying copper and nickel sulphide ores. No solubility data, however, are available for them in copper-rich sulphide mattes. Geochemical data on the behaviour of Ir and Mo deal mostly with low-iron silicate systems, e.g. basaltic melts, and high-sulphur sulphide solutions and mattes (Ertel et al., 2008; Fonseca et al., 2007). They also indicate that Ir and Mo dissolve in silicate melts primarily as oxides and not as electrically neutral metal species. Most geological data of iridium focus on high-sulphur systems of the monosulphide composition and typically Fe-Ni mattes where copper is a trace element (Fleet et al., 1996; Sattari et al., 2002). Direct solubility measurements for mattes and iron-lean silicates have also been made using pure Ir or an Ir alloy as the saturation phase (Borisov & Palme, 2000; O’Neill & Eggins, 2002; Makovicky & Karup-Møller, 1999; Ertel et al., 2008; Mungall & Brenan, 2014). A recent summary about the solubilities of HSE’s in iron- and sulphur free silicates is available in Laurenz (2012). The thermodynamics of molybdenum partitioning between oxides and Fe-S-O melts was studied by Mengason et al. (2011). Their results indicate strong accumulation in the iron-rich sulphide in reducing conditions (pO2 = 10-9.6 atm in Ni-NiO equilibrium at 1050°C). Molybdenum dissolves in iron-lean silicate melts as MoO3 species in oxygen pressures above the Fe-FeO equilibrium and as MoO2 in more reducing conditions (Farges et al., 2006; Righter et al., 2017).

Jan 1, 2019

By J. Keough

During industrial electrowinning of copper, uneven growth can impact current efficiency, cause short-circuits in the cell and negatively impact the final quality of the metal product. Copper electrodeposits can be made smoother by incorporating a host of additives in the electrolyte but uneven copper growth may still occur due to variations in electrolyte composition throughout the cell-house. To quantify roughness, 3D images of the surface may be combined with scaling analysis to gain further insight into the deposit structure. Moreover, scaling analysis may offer a method to predict long-term deposit structure using short-term copper deposits. In this paper, the application of Atomic Force Microscopy (AFM) and scaling analysis are used to monitor copper growth and extract surface roughness characteristics. The cathode was a 304 stainless steel disc that was polished to a mirror finish. Copper was deposited onto this surface over a range of 10, 20 and 30 minutes from an acidic sulfate solution (40 g/L Cu) at 40oC from an electrolyte that contained or was free of guar. AFM images were acquired to obtain 3D topographical information on the samples and scaling analysis was performed to extract the root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. INTRODUCTION During the process of copper electrowinning, the dissolved metal ions are reduced and thereby deposited onto a cathode substrate which is later recovered by stripping the metal from the cathode surface. Although this process is widely used in the industry, the conditions of the deposition procedure may cause the growth of the metal product to be uneven which can not only impact the current efficiency and final copper product quality but may also lead to plant interruptions through short-circuits if the anode and cathode make contact. To create more uniform copper deposits, a host of additives may be included in the electrolyte which may act as brighteners, leveling agents and inhibitors which may include guar gum, glue, thiourea or polysaccharides or polyacrylamides and their industrial use has changed over time (Moats, Luyima, & Cui, 2015). As such, the electrolyte composition is often complex and subtle variations in the solution matrix throughout the cell-house may impact the surface morphology of the final copper product. In an effort to quantify the roughness of copper samples, image analysis is often applied and may include Scanning Electron Microscopy (SEM) or Atomic Force Microscopy characterization. While both are appropriate, AFM offers 3-dimensional information which may be used to both qualitatively and quantitatively characterize the surface characteristics.

Jan 1, 2019

By M. Visnjic

Open Pit Mine Production scheduling under commodity price uncertainty suffers from an exponentially increasing problem size as simulations and real options flexibility are used to generate and evaluate multiple production schedules. Robustness evaluation techniques attempt to evaluate a production schedule that is generated on a single set of economic parameters against several varying prices and sources of uncertainty. This approach is invalid as the corresponding optimal LOM mine plan will change for each set of evaluation parameters. Using commodity market futures and treasury bonds as production schedule economic input parameters provides fully price and time-value-of-money risked scheduling parameters that maintain a deterministic problem size. This paper will provide comparative analysis of project NPV’s coming from traditional price uncertainty evaluation based on a single fixed LOM mine plan using varying prices versus evaluation based on varying LOM plans that are both generated and evaluated using varying prices. When cross evaluating constant price mine plans against simulations, the upside potential and downside risk of a project are significantly misrepresented. INTRODUCTION The life of mine (LOM) production scheduling problem seeks to answer the question of from where and when to extract a given block within the ultimate pit limit as well as where and when to process it. Solving this problem takes into account the constraints of extracting any particular block while seeking to maximize the net present value (NPV) of the mineral asset as a whole. A direct driver of the value of a block, and there for the entire asset, is the market price of the commodity in question. Complications arise when an optimal production schedule is attempted to be solved under price uncertainty. Many solution methodologies have been proposed in an attempt to optimize under this criterion, yet there are three salient aspects that are overlooked during this process. They are: • Generating a single production schedule and evaluating it against many simulated price paths. • Failing to understand the mechanism describing particular commodity price behavior • Inappropriate risk adjustment In an effort to address these aspects of production scheduling under commodity price uncertainty, we propose a methodology to define the economic parameters as input that is applicable to most if not all production scheduling approaches. This methodology will not only simplify the production scheduling process in terms of establishing block value but utilizes the risk adjustment of real options valuation to avoid the arbitrary blanket risk adjustment of traditional discounted cash flow valuation. Our findings conclude that attempting to optimize around individual price paths is futile and using a market risk adjusted single price forecast provides a justified economic basis for production scheduling while maintaining the same problem size as a deterministic production scheduling problem.

Jan 1, 2019

By P. Latostenmaa, O. Forsén, M. Lundström, J. Aromaa

The history of electrolytic copper production in Finland is closely connected with the industrialization of Finland and events of the Second World War. Production of cathode copper by electrowinning from the processing of Outokumpu ore started in 1913 based on the Hybinette nickel process, however due to the poor performance of this process, the plant was closed in 1929. Outokumpu commenced copper smelting at Imatra in eastern Finland in 1936 producing blister copper for refining outside the country. Due to the threating military situation, a new electrolytic copper refinery was built in 1941 at Pori in western Finland to refine the anodes. This was the first electrolytic copper refinery in Finland. It was built with 108 cells having a capacity of 12,000 tonnes/y. In addition, the smelter was relocated to nearby Harjavalta in 1944–1945. To fulfill the war reparations included in the peace treaty with the Soviet Union, a doubling of the smelter capacity was realised, with the Pori refinery capacity increasing to 20,000 tonnes/y in 1946 by adding additional cells. The cornerstone of Finnish metallurgical technology — Outokumpu flash smelting — was invented with the new technology commissioned at Harjavalta in 1949 replacing the electric furnace and providing a further increase in copper output with subsequent enlargement of the refinery. By 1963, the plant consisted of 380 cells with a capacity of 48,000 tonnes/y of cathode copper. The Pori electrolytic copper refinery has operated continuously since 1941. Commencing in 2004 the Pori refinery has been part of the Boliden group of Sweden. The most recent plant upgrade was in 2007 with the installation of permanent cathode technology. In 2017, the production of the Pori refinery was 133,000 tonnes of copper cathode, 2,300 tonnes of nickel sulphate, along with 66 tonnes of silver and 4.6 tonnes of gold. This paper describes these outstanding achievements. INTRODUCTION In 1809 the Kingdom of Sweden was defeated by the Russian Empire in the Finnish War, and Finland was annexed by the Russian Empire as the autonomous Grand Duchy of Finland. Finland’s commercial and industrial interests were developed to serve the Empire’s needs. Finland had raw materials, but at the start of the 20th century Finnish industry was based on the use of wood as raw material and agricultural products. The mining industry was only a few percent of the country’s industrial production.

Jan 1, 2019

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019

By F. L. Pirkle, W. C. Bagby

The International Mineral Valuation (IMVAL) Committee, founded in 2012, develops strategies for conducting mineral valuations. These strategies have been developed into a mineral asset valuation template called the International Mineral Property Valuation Standards Template and is part of IMVAL's work to establish consistent international standards for mineral property valuation and reporting. This template is a living document that is updated from time to time and is based on three core values or pillars (Fundamental Principles): Competence, Materiality, and Transparency. Objectivity, Independence, and Reasonableness may be applied as required by national codes or standards. The Template harmonizes international standards for valuation of mineral assets as real property and represents a consensus of current good practices. It is not a stand-alone reporting code and does not supersede existing national reporting standards. The Template deals with mineral-property valuation as distinct from mineral-project evaluation. INTRODUCTION In his 1989 book, “The New Realities”, Peter F. Drucker, Clark Professor of Social Science at Claremont Graduate School, California, stated: “Information is data endowed with relevance and purpose. Converting data into information thus requires knowledge. And knowledge, by definition, is specialized.” (p. 209) The discipline of mineral valuation is knowledge-based and requires a mineral valuer to collect, analyze, and interpret data that are material to a mineral valuation assignment. In so doing, the valuer turns the data into information (data come first, followed by information as determined by the mineral valuer) for use by the client (from whom the valuer obtained the mineral valuation assignment) and other intended users. The valuer uses his or her experience and education (each valuer’s knowledge base) supported by a foundation built upon competency, materiality, and transparency, the three pillars of mineral valuation (“minerals valuation”, “mineral-property valuation”). The International Mineral Valuation Standards Template (“IMVAL Template”, IMVAL”, “Template”), third edition dated May 2018, defines mineral valuation as: “The estimation of the Value of a Mineral Property in money or monetary equivalent. The word ‘valuation’ can be used to refer to the estimated value (the Valuation conclusion) or to refer to the preparation of the estimated Value (the act of valuing).” (p. 14) Furthermore, the IMVAL Template clearly separates valuation from evaluation: “The Template deals with Valuation, which is distinct from Evaluation. The distinction inherent in these defined terms is that Valuation addresses the estimation of value of a Mineral Property, whereas Evaluation addresses the broader assessment of a Mineral Property for an investment decision.” (p. 2)

Jan 1, 2019

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019

By Ian Bell

This paper investigates fragmentation in an aggregate quarry using the fragmentation-energy fan concept. Six blasts were monitored, located one behind the other in the same quarry area. The rock structure was blocky, the water level and the usage of explosives were variable within and between the blasts. The powder factor above grade was between 0.28 and 0.44 kg/m3 (0.47 and 0.74 lb/yd3). Fragmentation of the plant feed was measured using an online digital image analysis system and three belt scales. The oversize material that was not directly fed to the plant after the blast corresponds to 3‒9.3 % of the total. Data from image analysis was used to build the size distribution in the coarse range (fragments above 120 mm), and the passing fractions at 120 and 25 mm (4.72 and 0.98 in) obtained from belt scales data were used in the range 120‒25 mm (4.72 ‒ 0.98 in) . The non-dimensional percentile sizes between 10 and 90 % for each blast are described through power functions of the powder factor above grade; the model coefficients are statistically significant. From them, using the principles of the fragmentation-energy fan and the Swebrec distribution properties, the fragmentation can be expressed in terms of the powder factor by means of five parameters: the fan focus coordinates and the three parameters of a function of the exponents vs. the percentage passing. The model shows a good capability to describe fragmentation.

Jan 1, 2019

By A. M. Martinez, L. Melis, R. C. Peláez, L. G. Garcia

Orovalle Minerals S. L. operates a copper/gold mine in the Asturias region of northern Spain, with the operation dating back to December 1997. The feed to the El Valle mill, consisting of oxide/sulphide (skarn) mineralization, is highly variable, even on a shift by shift basis and presents challenges to the mill operating staff on a daily basis. The mineralogical characteristics of the ore are quite complex with copper present as native copper and sulphides as well as copper minerals with deleterious elements. Gold is present as native gold and electrum. The mill circuit includes SAG/ball mill grinding, gravity recovery of native copper and gold, flotation of copper concentrate, carbon-in-leach gold recovery and SO2/air cyanide destruction. The paper will provide a description of the different unit operations and present operating data of the mill operation.

Jan 1, 2019

By N. A. Beier, N. Slingerland

"Oil sands tailings impoundments rank among the largest (spatially) in the world, covering a total of approximately 220 km2 of northern Alberta, Canada. A preliminary geomorphic design for an oil sands tailings storage facility (TSF) landform was completed with the goal of eventual closure and delicensing in mind. This paper outlines methods identified during the design process that streamline closure when implemented early in the mine planning and TSF design stages. With most oil sands TSFs currently in active operation (and some still in the planning stages), geotechnical engineers and mine planners have the opportunity to make operational and design decisions, such as those outlined herein, that are likely to improve the geotechnical and environmental performance of the landform post closure. ¦ KEYWORDS Alberta, Athabasca oil sands (AOS), Landform design, Reclamation, Sand dam, Tailings storage facility (TSF) RÉSUMÉ Les bassins d’accumulation des résidus issus des sables bitumineux font partie des plus grands (en termes d’espace) au monde, et couvrent au total environ 220 km2 dans le nord de l’Alberta, au Canada. Une conception géomorphologique préliminaire a été réalisée pour le modelé d’une installa¬tion de stockage des résidus (ISR) issus des sables bitumineux en gardant à l’esprit la fermeture et le retrait de permis à terme. Cet article présente les méthodes identifiées pendant le processus de conception qui simplifient la fermeture lorsqu’elles sont mises en oeuvre dès les premières étapes de planification de la mine et de conception de l’ISR. La plupart des ISR issus des sables bitumineux se trouvent dans des exploitations actives (dont certaines en sont encore aux étapes de planification), aussi les ingénieurs géo¬techniques et les planificateurs miniers ont la possibilité de prendre des décisions en termes d’exploita¬tion et de conception, telles que celles présentées ici, qui pourraient améliorer la performance géotechnique et environnementale de la phase suivant la fermeture du modelé. ¦ MOTS CLÉS Alberta, assainissement, barrage de sable, conception du modelé, installation de stockage des résidus (ISR), sables bitumineux de l’Athabasca (SBA)INTRODUCTION The Athabasca oil sands (AOS) underlie 140,200 km2 of land in northeastern Alberta, Canada. Oil sands located within 100 m of the original surface account for 4,800 km2 of the total area and are considered to be economically mineable (Figure 1; ERCB, 2009). Bitumen, the thick, tar-like substance contained in the AOS, is extracted through open-pit mining and in-situ methods. During mining, the overburden is first removed as waste and the sandy, bitumi¬nous ore (“oil sand”) is transported to processing facilities via conveyor belts and 400 t trucks. Warm and hot water, as well as process aides such as caustic soda, are mixed with the oil sand, creating a slurry from which bitumen is mobilized and extracted. The resulting slurry waste product is called “tailings” and contains mineral solids, process water, and small proportions of unrecovered bitumen (Masliyah, Zhou, Xu, Czarnecki, & Hamza, 2004; Sobkowicz & Morgenstern, 2009)."

Jan 1, 2019

By T. Lux, M. Hanel, Degel, A. Filzwieser, R., H. Joubert

It is the increasing demand for an economic and cost saving operation mode that requires effective cooling in order to achieve low refractory wear and good furnace lifetime, which is making cooling technology an important aspect of furnace operation. In addition, the requirements for safety are getting more and more into focus. However, the use of water—today’s standard cooling medium—has major drawbacks as it can cause problems both during furnace start up and operation, namely hydration problems, corrosion, and explosion. Not to forget the severe risks for the operators as well as economical damage in case of a malfunctioning water cooling system. With this new and patented cooling technology ILTEC and the ionic liquid IL-B2001 as the cooling medium, it is possible to realise a water-free cooling solution and therefore the door is wide open to rethink existing and conventional cooling solutions. Furthermore, there is also the chance to recover heat from the process in a more efficient way. However, since the technology is novel and unique there are a lot of concerns and doubts regarding safety for plant operators and employees. The paper is intended to cover both: highlighting the enormous potential of the technology but also to eliminate concerns mainly caused by rumour and unawareness. INTRODUCTION All of us are aware of the risks when water is used as a coolant and placed in the vicinity of the liquid metal phase. Unsuitable design solutions or wrong operation modes of the furnaces or failures of refractories can cause a direct contact of water with liquid metal. The consequences can lead to equipment failures, vessel destruction but even worse to injuries and even fatalities. Over the past decades, countless incidences were reported. Fatal accidents caused by water coming into contact with liquid metal happen every year (Oterdoom, 2014; Filzwieser, Konetschnik, Filzwieser, Wallnerm & Preiss, 2014). With the novel ionic liquid cooling technology virtually all negative effects of a water cooled system regarding safety are eliminated and even additional benefits can be provided (Voermann, Ham, Merry, Veenstra, & Hutchinson, 1999;Verscheure, Kyllo, Filzwieser, Blanpain & Wollants 2006; Wallner, Filzwieser & Kleicker 2006). The fact that no explosion occurs when IL-B2001 gets in contact with molten metal results in a revolutionary solution for the metallurgical industry in terms of safety—new safety standards can be achieved.

Jan 1, 2019