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By Andrea Koschinsky

Ferromanganese crusts have traditionally been considered a potential ore for Co, whereas ferromanganese nodules have typically been considered a potential ore for Ni and Cu. However, both nodules and crusts sequester high concentrations of many metals (Table 1) from sediment pore waters and seawater, many of which are essential for high-tech applications. The resource potential of these rare and valuable metals is poorly known and they are the subject of considerable current research. The need for adequate and dependable supplies of these metals is essential for the development of new technologies. The rare-earth elements have recently received much attention in the scientific and popular press because of their use in so many high-tech applications and because more than 95% of the production comes from China (e.g., Service 2010); consequently, there is concern about the possibility of a significant decrease or even curtailment in exports from China. The lack of a primary source and the inadequate supply of Te have prohibited the development of a Cd-Te photovoltaic solar-cell industry (Hein et al. 2010). Inadequate supplies of many of the elements listed in Table 1 are limiting the development of key high-tech industries, forcing the use of alternative metals that [ ] may result in less efficiency or less favorable properties for a product. The rare-earth elements, Te, and other elements listed in Table 1 occur in high abundances in marine hydrogenetic and diagenetic ferromanganese deposits. Here, we look at the mechanisms by which these rare and valuable metals are incorporated into different genetic types of marine ferromanganese deposits.

Jan 1, 2010

By T. G. Davies

The paper presents design equations for singly laterally loaded piles embedded in sand. These equations were obtained from a comprehensive nonlinear analysis of free and fixed head piles subjected to horizontal loads. The sand is modelled as an elastic-perfectly plastic material whose strength and stiffness are proportional to depth below ground level. The soil's response is described by means of a boundary element representation of the continuum while the pile itself is created as an elastic beam. Equations for the latter are derived directly from the Bernoulli-Euler theory and are coupled with those describing the non-linear soil response. The effects of bearing failure along the front, face of the pile, shear failure along its sides and tension failure at the back face are accounted for in the analysis. Simple equations are presented to describe both the elastic and inelastic responses. The only sol parameters required to use these equations are the angle of internal friction of the sand and a parameter characterizing the rate of increase of the sand's modulus with depth. The latter can be taken as equivalent to the modulus of subgrade reaction. The results of this analysis show that soil yielding is very significant at working load levels, resulting in substantial increase in bending moments and lateral deflection.

Jan 1, 2010

Gold cyanide equilibrium adsorption isotherms in the loading range typical of operating carbon-in-pulp/carbon-in-leach plants have been established and the effect of various cations and the presence of copper cyanide species quantified. It was found that the equilibrium loading of gold was enhanced by the presence of sodium or calcium, with calcium having an order of magnitude stronger effect. The presence of copper has an adverse effect on the equilibrium loading of gold. A unified model was developed to predict the effect of sodium and calcium concentrations in solution and the competitive carbon adsorption of copper on the equilibrium loading of gold on carbon. A satisfactory agreement between the measured gold equilibrium loadings and the model results was obtained over a wide range of solution conditions.

Jan 1, 2010

By Christoph Muller, Geoffrey Liggins, Mohan Hensman

Modern commercial blasting is as much a technical process as it is a business one. As with most processes both aspects of blasting are driven by and generate new data. The time-critical nature of commercial blasting in mining and construction projects, dictate the timely exchange of information so as not to impede production or commerce. Up-to-date information about the blast to be undertaken can help suppliers: meet customers’ expectations to address challenging ground conditions; react to a market where quickly changing orders occur regularly; and address as-drilled blast patterns as opposed to baseline plans. “Real-time” data exchange into and out of the blasting process supports the whole-of-mine data management that the industry is migrating to.

Jan 1, 2010

By R. C. Reed, L. T. Wu, H. C. Harada, K. Kawagish, R. T. Wu

Oxidation of pure metals is a chemical reaction in which the metal loses one or more electrons, such that the atom of the metal changes from the neutral state to a positively charge ion and reacts with oxygen to form an oxide of the metal. The oxide can form as a protective and adherent scale that slows down further oxidation, or may spall off repeatedly, exposing fresh metal surface to react with oxygen. In multi-component alloy systems such as typical high temperature NiCrAlY bond coats, more than one oxidation mechanism may take place at once and thus, complicates the study of oxidation. To better understand the competition between formations of oxides of different compositions, a thermodynamic assessment is carried out to study the oxidation mechanism of a Ni-27Cr-9Al (at %) ternary alloy. Based on the assessment, it is demonstrated that the layering of different oxides can be determined, with the most stable oxide (alumina) existing directly above the metal-oxide interface and the least stable oxide (nickel oxide) locating on the outer most layer. A comparison between the calculated results and previously published experimental observations shows excellent agreement.

Jan 1, 2010

By Benjamin Cebrian

Metallurgical testing at Cobre Las Cruces prior to production at the mill was done with overburden gossan. Some of that test gossan was a very fine material, wet by the water conditions at the bottom of the pit. When processed and stored wet at the fines material 3000 tonne (3307 tons) silo, this material cemented in a very unusual manner.

Jan 1, 2010

By James Cornwell, John A. Elton

"Thermionic induced reactions and radiation resonance catalysis of aluminum and aluminum oxide materials exposed to microwaves and triboemissions will be described and explained from both a fundamental and practical level. Magnetron operation at distinct operating conditions that generates both plasmon and triboemissive radiation will be explained and the resulting tribochemical and radiation resonance catalytic reactions between aluminum, aluminum oxide, water and graphite will be delineated. The generation of hydrogen from these materials using triboemissive radiation and microwaves will be described, and the application of this methodology for hydrogen based technologies will be discussed.IntroductionProtective Systems Directed Energy RadiationProtective Systems, Inc, has developed a new radiation device called the EMR (Electromagnetic Resonator) that has unique characteristics that separates it from traditional microwave and rf radiation devices. The radiation from the EMR device is generated using a modified electronresonance magnetron with proprietary filters and operating characteristics.Electronic Device Shutoff. When electronic devices such as cell phones, computers, and other IC based electronics are placed within the EMR radiation, these devices become non-functional as long as the EMR beam is active. Upon removal of the EMR radiation the devices either become operational again or become operational after a cold start. The devices are not damaged by the irradiation.Faraday Cage Interaction Effect. When any of the above electronic devices are placed in a Faraday cage and activated within the Faraday cage without EMR radiation, they operate normally. However, these devices will still be rendered inoperative when an EMR beam generated outside the Faraday cage is directed at the electronic."

Jan 1, 2010

By Matthew Graham, Tapan Goswami, Geoff Brent

In dragline coal mining operations, throw blasting is used for the controlled placement of overburden to maximise coal exposure rates or to minimise overburden removal costs. This may necessitate sacrificing thin coal seams, generally less than one metre in thickness, which are often present in proximity to the main coal seam. This represents not only a significant loss of potential revenue and profit but also a waste of a valuable energy resource.

Jan 1, 2010

By Ali Kahriman, Olivio Angelini, Ibrahim Sefer, Burak Ekmen, Koray Arpak, Ertugrul Kaya, Yucel Karakus, Abdullah Sak, Aziz Ozdemir

In recent years, in order to bring solution to traffic intensity arising from transportation problems and facilitate public transportation in the modern world in paralel to urbanization and to the increase in population, it’s well known that, the construction of Access tunnels is inevitable. The driving of the tunnels is a subject of special interest in the technique of rock blasting. The essential factors in terms of tunnel driving and safety in tunnel blasting that is applied in metropolitan areas, an in depth knowledge of ground vibrations and the ways of reducing them to safer levels.

Jan 1, 2010

By R. T. Swinderman

This paper discusses how many of the common practices in conveyor specification and design are out of date compared to the current expectations of users for safe, serviceable, reliable, and fugitive material-free conveyance of bulk solids. Ten of the most common mistakes made in the specification and design stages related to user expectations are reviewed along with the cost vs. price implications of those decisions. A general specification and design hierarchy that designers can use to improve conveyor design is included.

Jan 1, 2010

By R. Rodgers

The Pinto Valley concentrator of BHP Copper Inc. restarted its sulfide mining operations in September 2007 to produce copper and molybdenum concentrates. During the plant production ramp up, the copper/molybdenum circuit quickly reached the copper grade and recovery targets, but the production and quality of the molybdenum concentrate continued to be a challenge. Even though several improvements in the molybdenum circuit were completed, the final molybdenum concentrate did not meet contractual specifications. After reviewing several options to improve grade and reduce contaminants, the installation of three flotation columns were chosen. The column design and construction were done using in-house craftsmen and engineers. Ten days after commissioning, the columns successfully reached a steady operation and began producing molybdenum concentrate to the required specifications, that is, high molybdenum tenors and low copper and iron content. The Pinto Valley operations, are comprised of the Pinto Valley concentrator, the Pinto Valley dump leaching and a solvent extraction/electrowinning (SX/EW) plant. The concentrator operated from 1972 to 1998 when mining and milling operations were curtailed for economic reasons. The SX/EW plant continued operations for copper cathode production. After a cessation of mining operations of almost 10 years, Pinto Valley operations began a restart project in January 2007, to bring the mine and the concentrator back into production. Copper concentrate production started in October 2007 after refurbishing and upgrading the facilities with a new DCS system and filter plant. The daily targets of the concentrator were to treat 56.7 kt (62,500 st) of ore, produce 762 t (840 st) of copper concentrate containing 27.5 percent copper at recoveries of 86 percent and produce 2.2 t (2.5 st) of molybdenum concentrate containing more than 80 percent MoS2.

Jan 1, 2010

By D. Seo, P. Au, S. Yandt, N. Tsuno, A. Sato

Nickel-base single-crystal superalloys are used for gas turbine airfoil applications due to their excellent high temperature properties. A good understanding of the mechanical response of these alloys under different temperature and loading conditions is essential for modeling their behavior. In this study, the low cycle fatigue behavior of CMSX 2 oriented with the loading axis along [001] was investigated under zero-compression strain-controlled loading at 1100°C. The experiments were performed with or without a two-minute dwell (hold) in compression. The microstructure before and after testing was analyzed to understand the deformation characteristics including the effect of dwell.

Jan 1, 2010

By Samantha Smith

Nautilus Minerals (Nautilus) is following the lead of the petroleum industry as it strives to tap vast offshore resources. Planning is well underway for the Solwara 1 Project in the Bismarck Sea, Papua New Guinea (PNG) to recover high-grade seafloor massive sulphide deposits in 1600 m water depth. The deposit contains an average copper grade >10 times higher than a typical land-based porphyry copper mine. The high grades combined with a relatively small amount of overburden ensure the Solwara 1 Project will have a significantly smaller physical footprint than its land-based counterparts. Offshore minerals production also has the advantage of minimal social disturbance. Nautilus is dedicated to setting a high environmental and social responsibility standard. Nautilus recognises the importance of transparent and inclusive stakeholder engagement and has taken a proactive approach to involve as many key stakeholders as possible. One of the first steps in the permitting process in PNG is the preparation of the Environmental Inception Report, which describes the project, its envisaged impacts and the proposed studies for the Environmental Impact Assessment (EIA). Local (PNG-based) and international environmental scientists, anthropologists, NGOs and other experts were involved in the definition of studies conducted for the Solwara 1 EIA and a team of world-leading experts was involved with carrying out the studies, culminating in the preparation of the Environmental Impact Statement (EIS). To ensure transparency, collaborating researchers are free to publish their findings. Following its submission, the EIS was made available for public review and public hearings were held at several locations. The EIS has also undergone a rigorous independent review by PNG government-engaged consultants. Outside the permitting process, Nautilus works alongside government officials to carry out ongoing community consultations. Information dissemination and feedback acquisition has also occurred through the Nautilus website and attendance at a number of international conferences, workshops, and meetings. This paper will outline the leading edge approach Nautilus has taken in completing the environmental impact statement for the world?s first deep seafloor copper-gold mine. In addition, this paper will review the permitting process and the government and stakeholder engagement undertaken as part of Nautilus? desire to ?do it right? in this exciting new industry.

Jan 1, 2010

By Tristan Worsey

This work was performed during the summer of 2008 during the junior year of a BS in Mining Engineering. It was observed that the mine was having a problem with back break during the blasting of development drifts. The unwanted back break was causing the mine extra costs in ventilation, ore dilution, ground support, back fill, explosives and man-hours. The blasting practices were observed for four weeks and the problems and their solutions were defined. In this paper the reasons and causes of the problem are explained with the proposed solutions to eliminate back break.

Jan 1, 2010

By Wei Luo

Nickeliferous laterites were characterized by particle size analysis, X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDX), Fourier transform infrared (FTIR) spectroscopy and thermal analysis. Results showed that the laterites consist mainly of nickel-substituted lizardite with cobble-like morphology and traces amounts of magnetite and phlogopite. As fluoride ions can react with silicon in the lizardite crystal structure and form metal-fluoride complexes, as well as increase the equilibrium constant of the lizardite dissolution in acid solution dramatically, the addition of minor fluoride salts (0.2wt.% NaF) gave a markedly enhanced metal extraction rate (Ni 81.7% and Co 52.3%) under the experi-mental conditions of particle size d50= 25 µm, 10% (v/v) H2SO4, reaction time 2 h, reaction temperature 90°C, liquid-to-solid ratio 3 mL g-1 and stirring at 500 rpm compared with H2SO4 alone (Ni 69.6% and Co 30.8%).

Jan 1, 2010

By Thomas M. Barczak

This US. Bureau of Mines report examines the roof and floor contact pressure provided by the interaction of a shield with the surrounding strata. Controlled forces were applied to an 800-ton two-leg shield in the Bureau's mine roof simulator; the distribution of forces acting on the canopy and base of the shield were measured with 24 hydraulic pressure cells. Several influential factors that affect the load distribution were investigated: (1) the magnitude of loading (leg pressure); (2) the profile of the canopy, principally the upward-sloping tip; (3) the base-lifting device; (4) horizontal load acting on the shield; and (5) compliancy of the immediate roof and floor. It was concluded that the shield does not develop full canopy or base contact without deformation of the strata. Maximum contact pressures are developed at the rear of the canopy and on the toes of the base. Less than 10 pct of the available shield capacity is developed at the canopy tip despite the design intention to ensure tip contact. Horizontal loading reduced the toe pressure acting on the base by as much as 75 pct. The base-lifting device exaggerated the inherently high toe loading, increasing the contact pressure by more than 200 pct.

Jan 1, 2010

By Braden T. Lusk, Shannon P. Lusk, Kyle A. Perry

A high explosives shock tube has been constructed and developed to test blast resistant windows with pressure versus time waveforms similar to waveforms generated by arena testing. Calibration of the high explosives shock tube, or Large Arena Test Simulator (LATS), included numerous tests performed by detonating varying charge weights at different distances from three piezoelectric pressure sensors located at one end of the shock tube (where the test subject would be installed). The maximum reflected pressure and positive phase impulse were calculated for each waveform generated in the tests. Pressure versus distance and impulse versus distance graphs were generated. Results have been graphed in order to predict charge weights and distances that correlate to the desired pressure and impulse at the end of the tube for future tests. This is a valuable tool when testing expensive, job specific components so the loading requirements are met on the first attempt.

Jan 1, 2010

Refractory gold concentrates often contain sub-microscopic gold that is encapsulated within the crystal matrix of iron sulphide minerals such as pyrite, pyrrhotite and arsenopyrite. To recover the gold, the host mineral must generally be broken down chemically, by oxidative processes such as roasting, pressure oxidation or bacterial leaching, which expose the gold for subsequent recovery by leaching in cyanide solution. The focus of attention in these pre-treatment processes is usually the oxidation of the sulphides to elemental sulphur, sulphur dioxide gas or sulphate ions. Less attention is paid to the deportment of iron and the changes in its oxidation state, although this can have a profound effect on gold and silver liberation, as well as down stream operating costs. Iron sulphide minerals break down completely during pressure oxidation, and dissolve in the sulphuric acid solution that is generated from oxidation of the sulphides. This liberates the tiny gold particles that were originally trapped in the sulphide crystals, and gold recovery during subsequent cyanidation is usually very high (>95%). Iron goes into solution in the oxidation process, initially as ferrous sulphate, but this is rapidly oxidized to ferric sulphate, which then hydrolyzes and re-precipitates. The form of the precipitate varies depending on the operating conditions in the autoclave and the presence of certain metal cations. When the acidity in the autoclave is quite low (<20 g/L H2SO4) and the temperature is high (>200OC) the formation of hematite is favoured. When the acidity is high (>20 g/L H2SO4) and the temperature is relatively low (160 to 200OC), the formation of basic iron sulphate is favoured. If the ore or the leach solution contain significant levels of certain cations (such as Na+, K+, NH4+, Ag+ or Pb2+) and the acidity is high (>20 g/L H2SO4), jarosite compounds are favoured. Hematite is the desired iron product in the autoclave discharge, for both metallurgical and environmental reasons, but it is difficult to operate an autoclave under the conditions required for effective liberation of gold without converting some of the iron to basic iron sulphate and/or jarosite. These compounds fall into a category of iron compounds known generically as iron hydroxy sulphates, all of which can cause significant processing and environmental problems in the downstream gold process. This paper deals specifically with basic iron sulphate; the conditions under which it is formed in an autoclave, the problems that are caused by its presence in the feed to a cyanidation plant, and possible remedial strategies that can be adopted, both in the autoclave and downstream.

Jan 1, 2010

By A. Taylor, E. Thorn Corthay, J. Farrell, L. A. Westfall, S. Borchardt

Mining and metallurgical industries need to minimize their greenhouse gas (GHG) emissions; Hatch specializes in conducting mining and metallurgical energy management assessments and optimizing productivity. Projects executed have demonstrated that there is a wealth of energy management, waste reduction, and process efficiency improvements that require no or low capital investment. Typical energy cost savings are on the order of 5% to 12%, with similar reductions in GHG emissions. Hatch generates Marginal Abatement Cost Curves to optimize the implementation pathway, maximizing carbon abatement and minimizing cost. The findings of a practical case study from Cameco are presented.

Jan 1, 2010

By S. Koppalkar

ABSTRACT: The development and evolution of the gravity recoverable gold (GRG) test procedure at McGill University is reviewed in this paper. Since the late 1980s, the research group led by the late Professor André Robert Laplante at McGill University has undertaken fundamental studies and applied research of the Knelson concentrator to develop a sustainable method of estimating GRG. Historically, a concept of “free gold” was used, and it was de?ned as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, the practical use of amalgamation has declined. Around 1994, a methodology using a 3-in Knelson concentrator to measure gravity recoverable gold was established at McGill University. As a result of more than 10 years of improvement and optimization, this technique has become a standard method of evaluating GRG for gold ores, gold plant streams and platinum group metals. By 2006, about 200 GRG tests were carried out at McGill University on ores from all over the world. Recently, a modi?ed version of the GRG test (a simpli?ed test) was developed to provide a quick and rough estimate of the GRG in a sample; this simpli?ed test has the advantage of reduced mass, processing time and cost. To recognize and honour the contributions made by the late Professor Laplante towards the establishment of a standard test procedure for assessing gravity recovery potential, the authors propose that the GRG test be named after Laplante.

Jan 1, 2010