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Teeter-bed (i.e., hindered-bed) separators are used throughout the mineral processing industry for both classification and density separation. The high capacity and sizing characteristics of these units make them ideal for feed preparation prior to coarse flotation (+0.100 mm) circuits. Teeter-bed separators are typically easy to control with two basic operating parameters including fluidization water rate and bed level. However, data show that these two parameters greatly interact with one another. Given this finding, a high-level automatic control scheme was developed and implemented on a full-scale separator. In addition, dialogue with plant operators has led to several simple changes to an already established design that improves operational and maintenance characteristics.

Jan 1, 2010

By C. Caceres

Fibre reinforced shotcrete in combination with other types of support systems is becoming the leading support method for underground excavations, especially those present in low quality rock masses. Sudden or rapid ground support failure can expose workers to safety hazards, damage to equipment and others resulting in production interruptions that will impact the cost of operation. Knowing the peak and post-peak strength characteristics of the support system over time are of major importance. Round Determinate Panel Testing of fiber reinforce shotcrete is the primary test used by the mining industry to determine strength characteristics; however, the tests are costly and significant manpower is required in a mine environment to build, store, handle and test the panels. For these reasons numerical modeling can result in an effective method to produce realistic results. This paper examines the strength characteristics Round Determinate Panel tests and its ultimate application in underground excavations, using Itasca?s three dimensional particle flow code (PFC3D).

Jan 1, 2010

By Robert C. Dyni

The use of techniques and equipment designed to pneumatically place backfill into an underground mine opening through boreholes for subsidence abatement has historically met with limited success, largely due to the inability to directly monitor the placement of the backfill in the opening. The success of a backfilling project cannot be guaranteed if it is not known whether the underground opening has been completely filled with backfill material. To overcome the inability to directly monitor backfill placement, the U.S. Bureau of Mines developed a pneumatic backfilling system that allows for direct viewing of the backfill as it is placed in an underground mine opening. This system utilizes a recently developed pneumatic nozzle coupled with an instrumentation package that allows for real-time observations and measurements of backfill placed in an underground opening through a borehole. The nozzle utilizes a high-velocity airstream to redirect backfill falling through a pipe in the borehole and directly in front of the nozzle; the airstream redirects and propels the backfill horizontally into the .mine opening at over 100 ft/s. The instrumentation package, mounted directly to the nozzle, contains a video camera, high-intensity lamps, laser-rangefinder, electronic compass, and water sensor.

Jan 1, 2010

By D. R. Tesarik

As part of its research program to investigate ways of improving resource recovery and reducing subsidence, researchers from the U.S. Bureau of Mines placed instruments in the B-North ore body of the Cannon Mine, Wenatchee, WA, to monitor cemented backfill and rock deformation during mining. The vibrating-wire gauges proved to be reliable and versatile, and approximately half of the instruments are providing data after 2 years of use. A two-dimensional, finite-element model was used to analyze the Cannon Mine's multilevel bench cut-and-fill mining method and predict rock and backfill displacements. The model accurately predicted rock displacements, but the predicted and measured displacements in cemented backfill had a correlation coefficient near zero, indicating that the model should only be used to predict rock displacements and not backfill displacements. A finite-difference model was also used to evaluate the stability of a cemented backfill pillar. Results can be used to conservatively predict backfill stresses, but on-site observation of pillar failures coupled with in situ measurements are needed to make more accurate predictions. An ongoing evaluation of the mining system has indicated that filling the primary stopes tight to the back with cemented backfill allowed these pillars to carry overburden loads soon after the cemented backfill was placed.

Jan 1, 2010

By S. L. McGill

The U.S. Bureau of Mines has determined the microwave heating rates for a suite of minerals and reagent-grade compounds. Maximum temperature achieved for the samples and the time required to reach temperature are reported. Heating rates of powdered samples are presented as a function of incident powers up to 3,000 W at 2,450 MHz. Descriptions of the microwave cavities, test cells, and a thermocouple assembly used to measure temperature in the microwave field are given. Many minerals of value heated in the microwave field, whereas host rock or gangue materials did not. In general, heating rates increased as incident power was increased. Exceptions to this were some very good (CuO, Fe304, and PbS) and very poor (CaC03 and SiO2) microwave-absorbing materials that showed negligible changes with increased power. Applications demonstrating the use of microwave energy in mineral processing that are described herewith include oxidation-reduction reactions, mineral liberation, and mercury retorting-vaporization. Microwave data on mineral heating rates will provide insight to possible chemical and mineral processing applications as well as assist in predictions of processing parameters.

Jan 1, 2010

By M. G. Vieira

This investigation addressed the possibility of producing pellet feed at a silica content of = 1.0% using a representative sample of Samarco´s mechanical flotation tailings. This sample contained 11.0% Fe and presented an F80 = 116 µm and a d50 = 63 µm. The higher silica content was verified in the coarser fractions and the higher iron content in the fraction -37 µm. Specular hematite is the most abundant mineralogical phase in the fraction -37 µm. The technological tests used one of four methods: magnetic concentration using a wet high-intensity magnetic separator, magnetic concentration using a SLon high-gradient magnetic separator, reverse flotation or direct flotation. The methods using the magnetic concentrator SLon, reverse flotation and direct flotation did not present results meeting the target of the study: iron content in the concentrate (rougher stage) greater than 34% or iron recovery greater than 80%. Cleaner stages were not achievable with the resulting concentrates. In contrast, the most successful method consisted of using wet high-intensity magnetic separators (WHIMS) as a rougher stage and reverse flotation as a cleaner stage. Using this route, it was possible to produce a pellet feed with a silica grade of 1.0% and high specular hematite content.

Jan 1, 2010

Refractory gold concentrates often contain submicroscopic gold that is encapsulated within the crystal matrix of iron sulfide minerals, such as pyrite, pyrrhotite and arsenopyrite. To recover the gold, the host mineral must generally be broken down chemically by oxidative processes, such as roasting, pressure oxidation or bacterial leaching, which expose the gold for subsequent recovery by leaching in cyanide solution. The focus of attention in these pretreatment processes is usually the oxidation of the sulfides to elemental sulfur, sulfur dioxide gas or sulfate ions. Less attention is paid to the deportment of iron and the changes in its oxidation state, although this can have a profound effect on gold and silver liberation, as well as downstream operating costs. Iron sulfide minerals break down completely during pressure oxidation, and dissolve in the sulfuric acid solution that is gener-ated from oxidation of the sulfides. This dissolution liberates the tiny gold particles that were originally trapped in the sulfide crystals, and gold recovery during subsequent cyanidation is usually very high (>95%). Iron goes into solution in the oxidation process, initially as ferrous sulfate, but this compound is rapidly oxidized to ferric sulfate, which then hydrolyzes and reprecipitates. The form of the precipitate varies depending on the operating conditions in the autoclave and the presence of certain metal cations. When the acidity in the autoclave is quite low (<20 g/L H2SO4) and the temperature is high (>200°C), the formation of hematite is favored. When the acidity is high (>20 g/L H2SO4) and the temperature is relatively low (160 to 200°C), the formation of basic iron sulfate is favored. If the ore or the leach solution contains significant levels of certain cations (such as Na+, K+, NH4+, Ag+ or Pb2+) and the acidity is high (>20 g/L H2SO4), jarosite compounds are favored. Hematite is the desired iron product in the autoclave discharge, for both metallurgical and environmental reasons, but it is difficult to operate an autoclave under the conditions required for effective liberation of gold without converting some of the iron to basic iron sulfate and/or jarosite. These compounds fall into a category of iron compounds known generically as iron hydroxy sulfates, all of which can cause significant processing and environmental problems in the downstream gold process. This paper deals specifically with basic iron sulfate: the conditions under which it is formed in an autoclave, the problems that are caused by its presence in the feed to a cyanidation plant and possible remedial strategies that can be adopted, both in the autoclave and downstream.

Jan 1, 2010

By H. K. Lin

The free-milling ore characteristics of the Fort Knox gold deposit are ideal for studying gold and silver behaviors in various processing circuits without serious interference of sulfide minerals and other refractory factors. A galvanic effect leads to faster silver dissolution than gold dissolution and, as a result, the Au/Ag solution concentration ratio increases through the leach circuit. In the CIP circuit, Au adsorption is more effective than Ag adsorption. The Au/Ag solution concentration ratio decreases from 10.0 to 1.0 as the slurry advances from CIP tank #1 to CIP tank #5, while Au/Ag ratio in the carbon increases from 3.2 to 15.3, as the carbon advances from CIP tank #5 to CIP tank #1. Silver is stripped more effectively than gold from the loaded carbon. The Au/Ag ratio in solution reaches 2.0 in the first 75,700 L of strip solution that pass through the loaded carbon; as the stripping process continues, the Au/Ag ratio in the strip solution increases. In the electrowinning circuit, the Au/Ag ratio in the spent electrowinning solution is significantly lower than that in the electrowinning feed, indicating that Au is more rapidly deposited onto the cathode than Ag.

Jan 1, 2010

By Alexander May

The U.S. Bureau of Mines investigated the application of oxidation-reduction potential (ORP) and pH measurements to environmental studies of mining and mineral processing wastes, and developed a computer program to estimate the concentrations of species of lead present in samples from a lead processing waste site. The methods and techniques for the ORP-pH measurements were investigated using known standard solutions made in the laboratory, samples from a ferric oxide waste disposal pond at a rutile production plant, and samples of well water and stream water from the lead processing waste site. ORP values were measured from 5 to 80 °C, from pH 1 to pH 12, and at various ratios of oxidant to reductant. The ORP-pH values can help identify valence values and species of ions present, including those of major, minor, and trace concentrations, and also indicate possible reactions at various pH values. The ORP measurements versus temperature yield data from which thermodynamic values can be calculated. The application and limitations of these measurements are discussed, and a brief discussion of the computational program to identify species of lead is presented.

Jan 1, 2010

By D. R. Tesarik

Displacement and stress changes in cemented backfill and ore pillars at the Buick Mine, near Boss, MO, were monitored by engineers from the U.S. Bureau of Mines and The Doe Run Co., St Louis, MO. A test area in this room-and-pillar mine was backfilled to provide support when remnant ore pillars were mined. Objectives of this research were to evaluate the effect of backfill on mine stability, observe backfill conditions during pillar removal, and calibrate a numeric model to be used to design other areas of the mine. Relative vertical displacements in the backfill were measured with embedment strain gauges and vertical extensometers. Other types of instruments used were earth pressure cells (to identify loading trends in the backfill), borehole extensometers (to measure relative displacement changes in the mine roof and support pillars), and biaxial stressmeters (to measure stress changes in several support pillars and abutments). Two-and three-dimensional numeric codes were used to model the study area. With information from these codes and the installed instruments, two failed pillars were identified and rock mass properties were estimated.

Jan 1, 2010

By Thomas L. Vandergrift

To significantly increase the stability of underground excavations while exploiting the full advantages of confined rock strength, methods must be developed to actively control the distribution of stresses near the excavation. This U.S. Bureau of Mines study examines theoretical and practical aspects of rock pres¬surization, an active stress control concept that induces compressive stress in the wall rock through repeated hydraulic fracturing with a settable fluid. Numerical analyses performed by incorporating the rock pressurization concept into a variety of boundary-element models indicate that rock pressurization has the potential to improve underground excavation stability in three ways: (1) by relocating stress concentrations away from the weak opening surface to stronger, confined wall rock; (2) by inducing additional stresses in a biaxial stress field to reduce the difference between the principal stress components near the surface of the opening; and (3) by counteracting the tensile stresses induced in the rock around internally loaded openings. Practical aspects of the rock pressurization concept were investigated through a series of hydraulic fracturing experiments. The use of sulfur as a settable fluid for hydraulic fracturing was demonstrated, although problems related to sulfur viscosity suggest that other molten materials, such as wax, may be better suited to practical field application of the rock pressurization concept.

Jan 1, 2010

By N. Kuyucak

While Acid Rock Drainage (ARD) occurs naturally, its management poses challenges especially at the decommissioned sites. Two passive systems were designed and implemented at two different decommissioned mining sites in Canada in order to treat the seepage with ARD characteristics. One seep originating from a reclaimed tailings pond was neutral mine drainage (NMD) containing circumneutral pH and dissolved metals (e.g., nickel, zinc) in elevated concentrations. The other ARD from a tailings stack showed net acid drainage characteristics with low pH and higher metal concentrations than regulated limits. Due to the different ARD characteristics occurring at each site, different types of treatment systems were designed and implemented. Both sites experience extreme winter conditions. The NMD has been treated mainly by limestone drain and aerobic systems since 1997. The acid ARD has been treated by a system consisting of an anaerobic sulfate reducing bacteria (SRB) cell, an aerobic cell and a limestone filter since 2004. As this site has no access roads, space, or power, a significant capital cost as well as sludge disposal/storage requirements would have been required to institute a chemical (active) treatment system. Both systems have been successfully treating seepage and producing a water quality year round that could comply with regulated objectives.

Jan 1, 2010

By Fred C. Turin

The U.S. Bureau of Mines conducted a human factors analysis of hazards associated with roofholting activities in underground coal mines. Emphasis was placed on hazards related to the movement of the drill-head boom or mast of a roof bolting machine. The objective was to identify hazards and recommend solutions. The data-collection effort consisted of analysis of U.S. Mine Safety and Health Ad-ministration accident data; visits to underground mines and interviews with experienced roof bolting machine operators; discussions with roof bolting machine manufacturers; interviews with workers injured while performing roof bolting tasks; and reviews of research on roof bolting safety. A set of recommendations to increase the safety of roof bolting operations was developed. In particular, the following list of recommendations was presented in ranking order: (1) use an interlock device to cut off power to controls when an operator is out of position, (2) place fixed barriers at pinch points, (3) provide appropriate control guarding, (4) reduce fast-feed speed, (5) use automatic cutoff switches at pinch points, (6) redesign control bank to conform to accepted ergonomic principles, and (7) use resin insertion tools and resin cartridge retainers.

Jan 1, 2010

By G. J. Slavens

The U.S. Bureau of Mines conducted research on preparing submicrometer titanium nitride (TiN) powder as a substitute for tungsten carbide (WC) in cutting tools and wear-resistant parts. Earlier research on a small scale was expanded to include a larger reactor. The TiN powder was produced by contacting titanium tetrachloride (TiCI4) with anhydrous ammonia (NH3) in the presence of Mg at 1,100° C. The powder was collected in an electrostatic precipitator (ESP) filled with ultra-high-purity (UHP) Ar. All collected powder was thermal vacuum distilled to remove Mg and magnesium chloride (MgCl2), leaving the purified TiN. Powder handling and purification procedures were conducted to assure low oxygen content in the powder product. Oxygen content in the distilled TiN powder product was as low as 0.40 wt pct. Nitrogen averaged near 22.0 wt pet with a high of 22.4 wt pct. The purified powder product had an average median particle diameter of 0.14 µm with a standard deviation of 0.09 µm.

Jan 1, 2010

By M. Ye. Melnikov

The report is about oceanic ferromanganese crusts ? covers of iron and manganese hydroxides developed over an opened rock of seamounts and rises. Ore bed parameters of crusts are understandable as their thickness and content of main economic components ? manganese, cobalt and nickel. All known results of research activity on ferromanganese manganese crusts point to that crust are characterized by notable variability of thicknesses and composition. It is possible to separate few levels of variability. The most evident is the first level of parameters variability, which is manifested in various regions of the Ocean, and connected first of all, with an age of submarine mountains, a host objects for a crusts. It was proved by many authors, that most powerful crusts are connected with submarine mountains of Cretaceous age. [1]. Crust thickness at the Magellan Seamounts reaches, for example 12-15 cm, sometimes exceeds 20-22 cm. Thicknesses of Hawaii Archipelago or Tuamotu crusts in 3-4 times less. Biostratigraphy studies of crustal sections at the Magellan Seamounts already show, that its main part started to form in the Late Paleocene. Four layers with well expressed features in structure and composition of a layer are separated in the section. From foot to top: Late Paleocene ? Early Eocene layer I-1, Middle-Late-Eocene layer I-2, Miocene layer II and Pliocene ? Quaternary layer III. Relics of more ancient Campanian ? Maastrichtian ore layer [2, 4] were discovered. It is evident for example, that Oligocene mountains could not be a host for two lower layers in the crust section.

Jan 1, 2010

By Shin-Kun Ryi

The world nowadays faces many challenges associated with excessive utilization of fossil, fuels, such as poor air quality and greenhouse gas emissions. Hydrogen appears to be an attractive alternative to the conventional, fossil, fuels with better energy efficiency and less environmental, impact. Pd and Pd-based alloy are the most often used membranes for hydrogen separation due to their superiority over other membranes. However, the stability of the commonly-used thin Pd-based composite membranes at high temperatures still, remains a big challenge. In this presentation, we will, report our progress on thin Pd-Ru alloy composite membrane by electroless plating high temperature applications.

Jan 1, 2010

By P. L. Sibrell

Electrorefining of Ti in nonaqueous solvents has been studied by the U.S. Bureau of mines as a method for recycling impure scrap Ti. Electrochemical behavior of Ti species was investigated using cyclic voltammetry. Research results showed that Ti metal can be dissolved in polar solvents such as dimethylformamide or dimethyl sulfoxide. However, deposition of Ti from these solvents was not successful. Several solvent systems were investigated for electrodeposition of Ti but no deposits were obtained. Reduction of Ti4+ complexes to Ti3+ proved to be straightforward, but reduction to lower oxidation states could not be confirmed. In dimethylformamide solutions, cyclic voltammetry results demonstrated the reduction of Ti to an oxidation state of less than three, but no Ti metal was identified. In dimethyl sulfoxide solutions containing LiCl, it was possible to deposit Li metal. After adding Ti salts to the solution, electrolysis quickly passivated the electrode. Deposition of Ti was also investigated in solutions of dimethoxyethane and propylene carbonate but, again, no reduction of Ti to oxidation states of less than three occurred. Therefore, the prospects for a nonaqueous electrorefining system for Ti metal do not appear promising.

Jan 1, 2010

By Rob Farnfield, Ben Williams, Bob Woolley

This paper outlines how drilling safety standards are being driven forward in the United Kingdom’s surface mining and quarrying industry with developments in equipment, procedures and competence.

Jan 1, 2010

By H. T. Ozkahraman

It is important to know the breakage mechanism in materials since this knowledge influences the results of subsequent grinding operations. There are two distinct failure mechanisms in breakage: one is tensile micro crack generation at low stresses, which leads to macroscopic failure by disintegration, and the other is formation of shear zones under heavier dynamic impact forces, which generates more fines as seen in crush zones in blasting. Tensile fracturing simply breaks the material into fragments. It is seen as the disintegration of the specimen into two or more separate fragments. This happens under the absence of lateral stresses and the material is free to expand. On the other hand, compressive-shear breakage produces finer fragments due to shear stresses. The first mechanism is observed in laboratory tensile and bending strength tests and the second mechanism is observed both in laboratory brittleness tests and in situ blasting operations under dynamic impact forces. The friability of rocks and ores can be determined by a brittleness test. A test apparatus to determine the friability value has been designed to suit limestone strength characteristics used in cement production. The friability and stored strain energy values of barite, marble, limestone and bauxite have been determined and compared with the corresponding Bond work index (Wi) and grindability index (G) of these materials. The physico-mechanical properties of the tested materials have also been determined to investigate their effect on friability and grinding. The relationships obtained between the indices were in surprisingly good agreement, with high correlations (0.99 and 0.97). The Bond work index and grindability index can therefore be estimated from the friability value, which can be determined more rapidly than the Bond test. But for certain rock types such as andesites the relationships does not hold. Key words: comminution, tensile stress, shear forces, brittleness test, strain energy.

Jan 1, 2010

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-g (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet, and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 1600 C for 1 h dissolved more than 95 pct of the PGM from virgin catalysts and more than 90 pct from used pellet catalysts. More than 85 pct of the PGM was dissolved from used monolith catalysts when a third autoclave step was added. Solid PGM concentrates containing more than 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 2500 C and used catalyst to 2750 C for 1 h. The solution after heating contained less than 0.2 ppm. total cyanide. The virgin residues passed the EPA Extraction Procedure Toxicity Test (EP Tox Test), the EPA Toxicity Characteristic Leaching Procedure (TCLP), and the California Waste Extraction Test (WET) for all elements except Ba. Adding sodium sulfate (Na2S04) to the virgin leach residues reduced the amount of Ba dissolved to an acceptable level. The used leach residues passed the EP Tox Test for all elements but failed the WET and TCLP for Pb.

Jan 1, 2010