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By Shengli Wu, Wei Huang, Xinliang Liu, Kaifa Zhang

The slagging behavior, the phase of primary blast furnace slag and its transformation law of structure for the single furnace burden were studied in this paper. The results showed that the formation of primary slag was controlled by CaO/SiO2, Al2O3 content, MgO content, reducibility, iron content and porosity of the furnace burden. Fayalite (2FeO•SiO2) was easily formed from acid ferrous furnace burden while kirschsteinite (2(Fe,Ca)O•SiO2) was produced from alkaline ferrous furnace burden

Jan 1, 2015

By Gui-fang ZHANG, Zhe SHI, Lei GAO

Secondary V-recycling slag, an industrial waste containing high gallium is being dumped continuously, which causes the loss of gallium. Thus, the alkali fusion process was employed to recover gallium from this slag. The effects factors on extraction of gallium such as roasting temperature, roasting time, alkali fusion agent concentration and CaO concentration were investigated in the paper. The experimental results indicated that excessive roasting temperature and roasting time is unfavorable to the recovery rate of gallium. The appropriate roasting temperature and duration are 1000 and 2 hours, respectively; The appropriate proportioning of Na2CO3: NaOH is 2:1 when the concentration of alkali fusion agent weighs 0.4 times the mass of the slag; In order to remove SiO2 from the leaching liquor, CaO should be used as an additive in the roasting process. The appropriate concentration of CaO should weigh 0.2 times the mass of the slag. Employing these optimal alkali fusion conditions in the roasting process, gallium recovery is above 90%

Jan 1, 2015

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng

The recycling of waste tires has been a big environmental problem. About 280 million waste tires are produced annually in the United States and more than 2 billion tires are stockpiled, which cause fire hazards and health issues. Tire rubbers are insoluble elastic high polymer materials. They are not biodegradable and may take hundreds of years to decompose in the natural environment. Microwave irradiation can be a thermal processing method for the decomposition of tire rubbers. In this study, the microwave absorption properties of waste tire at various temperatures are characterized to determine the conditions favorable for the microwave heating of waste tires.

Jan 1, 2015

By Xinlei Jia, Wenming Guo, Yanling Zhang

A large amount of stainless steel dust rich in Fe, Cr, and Ni has been being generated in China. Smelting treatment is accepted as a practical method for the recovery/reutilization of these second resources, during which Fe, Cr, and Ni is reduced into one metal phase and then separated from the residue slag. Based on the typical compositions of stainless steel dust, the residual slag can be termed as CaO-SiO2-MgO-Al2O3 system. In this paper, the activity coefficients of Cr in Fe-Cr-Ni-C (-Si/Al) melt and the properties of CaO-SiO2-MgO-Al2O3- 1%CrO system thermodynamically approached. Then, in laboratory experiments, the recovery ratios of Cr and its distribution behaviors between Fe-Cr-Ni-C melt and CaO-SiO2-MgO-Al2O3 slag system were examined.

Jan 1, 2015

By Sadegh Safarzadeh, Anne-Marie Suriano, Stanley Howard

The electrodeposition of metal ions from aqueous electrolyte solutions has been a well-known process for the last half century. With numerous industrial applications such as electroplating, electrowinning and electrorefining, the kinetics of electrochemical reactions involved in the process has been extensively researched. Arrhenius-type rate equations, the Butler-Volmer equation, and the empirical Tafel equation are among the most important models to explain the rate of electrochemical reactions. The study of the kinetics of metal deposition is critical to understanding the underlying mechanisms through which a certain morphology of metal deposit is formed on the cathode. The purpose of this paper is to elucidate the influence of experimental parameters such as pH and additives on the rate and the reaction mechanism determining the rate limiting step of the electrodeposition reactions.

Jan 1, 2015

By Chao Zhang, Jian Guo, Chaoquan Yao, Leige Xia, Xinyu Li, Jianliang Zhang

In this research, analytical reagents were used for the sintering experiments. And the sinters were using X-ray diffraction, scanning electron microscope and mineralogical microscope analysis to study the effect mechanism of manganese on the silico-ferrite of calcium and aluminum (SFCA) bonding phase formation during the sintering process. The results indicated that the increasing content of manganese would greatly reduce the content of SFCA, and promote the formation of calcium aluminum silicate and the amount of pores and cracks. The existence of manganese inhibited the silicon form into the SFCA and a great deal of Fe2O3 was participated in the crystal transition to Fe3O4. When the ratio of the added manganese was less than 3% in the mixing, the calcium ferrite was in substantially interleaving corrosion with hematite and magnetite. Both the porosity and silicate glass phase content were low simultaneously, which contributed to the sintering production.

Jan 1, 2015

By Bhagyadhar Bhoi, Chitta Ranjan Mishra, Pravas Ranjan Behera

Red mud of Indian origin contains around 55% plus of Fe2O3 and is considered as a hazardous waste for the alumina industry. For production of one tone of alumina employing the Bayer’s Process, around two tones of red mud is generated from three tones of Bauxite. Conventional process of steel making is not devoid of environmental pollution. In the present investigation, efforts have been made to produce steel from red mud by adopting reduction roasting, magnetic separation and hydrogen plasma smelting route. Magnetic fraction, containing enriched iron oxide and minimal content of alumina, is produced following the first two stages which is then subjected to hydrogen plasma smelting process for production of steel. This novel concept follows a green path way for production of steel free from pollution and is termed as green steel. Further, the only by-product that is produced in the process, is water, which is eco-friendly and recyclable.

Jan 1, 2015

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

By Harry Thompson

In using explosives to blast stumps from the ground in order to prepare it for farming, it is comparatively easy to place the charge under a stump having a semitaproot or a lateral system of rooting by boring or digging a hole in the earth to a point under the center of resistance and deep enough to give the desired effect.1

Jan 1, 2015

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015

By P. Schumacher, M. Fein

"INTRODUCTION Newmont’s Twin Creeks operation, part of its Nevada operations, produces gold from two large open pit mines. Mined ore is processed at one of three on-site facilities: a refractory mill with two autoclaves, an oxide mill and heap leaching facilities. Twin Creeks also processes various off-site sourced concentrates and ore including high grade underground ore from the Turquoise Ridge joint venture with Barrick Gold Corporation. This paper discusses Twin Creeks’ strategic mine planning process which is part of an in-depth continuous improvement program called “Full Potential.” The process involves cost analysis, phase design validations, life-of-mine production scheduling optimization, mill blending strategy and stockpile management. Through this Full Potential strategic planning, Twin Creeks is creating significant value by increasing near term free cash flow and life of mine net present value (“NPV”) and achieving cost reductions. TWIN CREEKS OPERATION Twin Creeks is one of the major gold producers in Newmont’s Nevada operations (see Figure 1, 2 and 3). Located approximately 15 miles north of Golconda, Twin Creeks produced approximately 28 % of the Nevada operation’s 2013 gold production of 1.8 million ounces (Newmont 2014). The production included Turquoise Ridge sourced gold ore from the joint venture (75% Barrick Gold Corporation, 25% Newmont).At Twin Creeks, there are two large open pits, named Mega Pit and Vista Pit (see Figure 4, 5 and 6). There are 3 to 5 phases in Mega Pit and 2 to 5 phases in Vista Pit depending on the gold price assumption. There is also an underground exploration project at the bottom of the Vista Pit. Twin Creeks produces gold from a variety of ore types requiring different processing techniques depending on economic and metallurgical characteristics. To ensure the best use of processing assets, engineering and processing groups at Twin Creeks utilize a Mixed Integer Linear Programming (“MILP”) model to guide the flow of mine sequences and material routing to various process facilities (Kawahata, Schumacher and Hufford 2013)."

Jan 1, 2015

By R. V. Ramani, K. V. Raj, S. Bandopadhyay

The air flow problems in openpit mines are complex. Computational fluid dynamics (CFD) models can provide detailed information regarding air flow pattern, velocity distribution, temperature, and pollutant concentration in an enclosed domain of an openpit mine. A range of turbulent models can be selected with varying complexity and accuracy. Pollutant transport models, however, differ in their assumptions and structure as well as in the algorithms they use. As a result, predictions vary from model to model. This paper presents a study of pollutant transport in an actual openpit mine under a stable boundary layer. The objective was to test two turbulence models using similar geometry and the same input conditions and model constants. Measured data were used to compare the results of the two CFD models, namely, the kappa-epsilon (к-є) model and the Large Eddy Simulation model. Despite the complex synoptic situations, different meteorological input data and fast-changing conditions, the simulation results from both the models were in good agreement regarding the dispersion of pollutants.

Jan 1, 2015

By B. T. Lusk, Q. Q. Huang, R. Q. Honaker, K. A. Perry

Rock dust is applied in underground coal mines to prevent the propagation of coal dust explosions. It is applied either dry or wet. Both methods have advantages and disadvantages, but the formation of caked rock dust particles is cited as a significant concern for wet applications. We conducted a study to evaluate the effect of modifying the rock dust particle surfaces to repel water and each other by the addition of oleic acid and sodium oleate. At a sodium oleate dosage of 1 kg/t, a contact angle of 112o was measured, indicating strong surface hydrophobicity and thus the ability to repel water. Fourier transform infrared spectroscopy (FTIR) studies indicated a chemisorption mechanism, which is necessary for long-term stability of the surface modification. The dispersibility of the modified rock dust samples was elevated by the application of both oleic acid and sodium oleate, thereby indicating a significant reduction or elimination of the detrimental effect of caking. Tests in an explosion chamber showed an 82.8 percent reduction in the dust explosion potential relative to untreated rock test applied by the wet technique.

Jan 1, 2015

By R. Gray, B. Hebblewhite

Experience from Australia had identified what is referred to as nonconventional surface subsidence behavior. This occurs under irregular surface topography, resulting in valley closure, valley floor uplift or “upsidence,” and far-field horizontal movements, occurring even beyond conventional “angle of draw” limits. This paper discusses such behavior recently observed in Pennsylvania and focuses on the 2005 case of Duke Lake Dam in Ryerson Station State Park. In July 2005, there was a significant increase in water leakage through a number of growing cracks in the dam, leading to the dam being breached to avoid an uncontrolled failure. An underground longwall mine was located approximately 900 ft to the north, mining at depths of 330 to 720 ft. Investigations, including a subsequent ground movement monitoring program, found a range of evidence in the vicinity suggesting that valley closure and farfield horizontal movements may have occurred, resulting from the adjacent mining. Besides discussing the phenomenon of nonconventional subsidence behavior and the Ryerson State Park case study, this paper includes an assessment of the mining, geology and subsidence impacts and suggested ground behavioral mechanisms.

Jan 1, 2015

By K. D. Luxbacher, E. C. Jong

Perfluoromethylcyclohexane (PMCH), a member of the perfluorocarbon tracer group of compounds, has been shown to be a viable supplement to the widely used tracer gas sulfur hexafluoride (SF6). This viability stems from the fact that PMCH can be used concurrently with SF6 while maintaining adequate chromatographic separation and comparable sensitivity during analysis. However, the release of PMCH in an underground mine ventilation system is challenging due to its physical characteristics. While SF6 exists as a gas at room temperature and pressure and can be accurately released by a variety of means, PMCH exists as a volatile liquid at room temperature and pressure, preventing it from being deployed in a similar manner. One method to release PMCH is to use a permeation plug passive release vessel (PPRV), which allows for the controlled release of the gas. This paper presents the results of a study evaluating various preparation techniques, plug thicknesses and plug materials of an aluminumvessel PMCH release source, so that a source appropriate for the mine scale may be developed.

Jan 1, 2015

By G. Bylapudi, A. Bhagwat, K. Mondal, A. J. S. (Sam) Spearing

Minimizing the effects of corrosion improves the long-term performance of the rock anchors and ground control systems in underground mines, which is fundamental for safe operation over the design period. The primary objective of this study is to explain the problems due to stress corrosion cracking (SCC), strain-induced corrosion cracking (SICC) and other forms of corrosion, and why the mining industry’s ground control professionals should take this into serious consideration. It is important to clearly determine the kind of SCC mechanisms that causes roof bolt failures in order to suggest the necessary action plan to mitigate or eliminate the possibility of the cause. Pertinent literature and studies around the globe on this complicated subject are reviewed. The secondary objective is to encourage the use of corrosion-resistant ground control products in the underground mining industry in areas of high corrosion potential. Characteristics of SCC on high strength steel are also reviewed. The literature and preliminary studies to date indicate that research work is necessary in United States.

Jan 1, 2015

By Gregg Davidson, Lonnie Jacobs, Brett Zernich, Alan Howard, Robert Pintabona

All Rights Reserved. Printed in the United States of America. Information contained in this work has been obtained by SME, Inc. from sources believed to be reliable. However, neither SME nor its authors guarantee the accuracy or completeness of any information published herein, and neither SME nor its authors shall be responsible for any errors, omissions, or damages arising out of use of this information. This work is published with the understanding that SME and its authors are supplying information but are not attempting to render engineering or other professional services. If such services are required, the assistance of an appropriate professional should be sought. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher. Any statement or views presented here are those of the authors and are not necessarily those of SME. The mention of trade names for commercial products does not imply the approval or endorsement of SME.

Dec 1, 2014

By J Balzary, A Mohais

Dynamic market and operating conditions, coupled with an environment in which multiple objectives and trade-offs are common, pose major challenges for planners and schedulers working in any mining entity. Many mining companies recognise the need to shift from a siloed mining-focused push model to an integrated value chain, demand-driven approach, but there are still fundamental barriers in business process and the supporting technology preventing a consideration of end-to-end optimality.This paper presents some elements of experiences working with companies to adopt such advanced approaches. In addition to algorithmic elements, an approach to phased and gradual deployment of progressively more sophisticated optimisation models is described. From a practical software adoption perspective, it is believed that this last concern is also of primary importance. Next generation approaches to the optimisation of complex bulk commodity demand chains, namely iron ore and coal are presented, with case studies in the world’s largest integrated operations in Western Australia and Queensland from the raw material mined through to market. Utilising accurate simulation models supported by metaheuristic optimisation techniques, a range of ways to engineer a dynamic decision support framework that can adapt and change with the inevitable changes in commodity markets is explored. Objectives such as total revenue, margin, cost, NPV, throughput, asset utilisation, contractual penalties and bonuses, and energy consumption can be managed simultaneously across the mine, plant, logistics network, port operation, shipping and sales domains.CITATION:Balzary, J and Mohais, A, 2014. Consideration for multiobjective metaheuristic optimisation of large iron ore and coal supply chains, from resource to market, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 213–222 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By A Melkumyan, K Silversides

The banded iron formation-hosted iron ore deposits located in the Hamersley Ranges of Western Australia contain marker shales that are used to distinguish lithology for geological and orebody mapping. These marker shales produce distinctive signatures in the natural gamma downhole logs, which are conventionally manually interpreted. This paper proposes an alternative method of automatically identifying these shales using dynamic time warping (DTW). A Gaussian processes (GPs)-based method for automatic identification is also considered. Both methods are tested on a deposit that contains the Marra Mamba sequence of the Hamersley Province.Both methods were trained to predict the location of the desired shales, and the resulting outputs were compared with a manual interpretation of the results to determine the accuracy. The GP method can identify signatures with an accuracy between 87.0 per cent and 92.0 per cent, which increases to 92.9 per cent and 95.7 per cent where the GP is certain. The DTW method has an accuracy between 90.0 per cent and 91.6 per cent, which increases to 94.0 per cent and 95.4 per cent where the DTW is certain.The GP method has several advantages, including a more automated library building process, a probabilistic output and a shorter run time. However, the DTW method was capable of accepting more distortion in the signature and therefore identified more signatures. This is important in a deposit where the signals are frequently distorted by events such as hydration and folding. Both methods provide a viable alternative to the current manual detection, but their differences make them applicable to different cases.CITATION:Silversides, K and Melkumyan, A, 2014. Comparison between Gaussian processes and dynamic time warping for classification of marker shales in iron ore deposits, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 177–184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By C Fricke, R Wood, P Velletri

"In a climate characterised by an ever increasing focus on cost reduction and maximising the utilisation of existing assets and infrastructure, understanding the uncertainty associated with alternative investment and operational choices becomes paramount to minimising the risk of making an ineffective decision. To assist in this process, TSG Consulting has developed an analytic framework to capture the underlying complexity of a mineral supply chain, and then quantify the impact of the uncertainty associated with the key drivers of business productivity. The technical basis of this approach follows three distinct steps: analyse the current system and identify the major factors that drive value build detailed models that can measure the response of the system to potential changes in the factors identified quantify the sensitivity of financial and capacity forecasts to these factors.Each of the above steps draws on a different area from the field of applied analytics, namely: data analytics dynamic modelling and designed experimentation meta-modelling and optimisation.Following the three-step approach described above ensures a rigorous modelling and analysis process is executed to support strategic mine planning decisions. The approach is equally applicable to the analysis of fully integrated system supply chains (pit-to-port), the evaluation of incremental capital investments to targeted areas of a supply chain, or when considering revisions to the operating philosophy of a system in the short term. The basis of each of the three analytic steps is explored in detail in this paper. The result is the definition of a structured mechanism for a business to actively manage risk and drive productivity as a component of the strategic mine planning process.CITATION:Fricke, C, Velletri, P and Wood, R, 2014. Enhancing risk management in strategic mine planning through uncertainty analysis, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 275–280 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014