Search Documents

By Shadia J. Ikhmayies

CdSxTe1-x and CdS1-yTey solid solutions are usually formed in the interfacial region in the CdS/CdT thin film solar cells during the deposition of the CdTe layer and/or the processing steps of the device. It is well known that CdCl2 heat treatment encourages the formation of the CdSxTe1-x alloy which improves the solar cell performance. In this work, indium doped CdS1- yTey thin films are produced by first producing CdS:In thin films by the spray pyrolysis (SP) technique on glass substrates, then annealing the films in nitrogen atmosphere in the presence of elemental tellurium. The films are characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and transmittance measurements. The transmittance is used to deduce the optical parameters such as; the extinction coefficient, refractive index, besides to the real and imaginary parts of the dielectric constant. The dispersion parameters such as Eo (single-oscillator energy) and Ed (dispersive energy) of the deposited films are also estimated and discussed.

Jan 1, 2015

By Ma Lijuan, Zhang Yubing, Wang Bo, Sun Huilan

The effect of lime ratio on phase composition and alumina leaching property of MgO-contained calcium aluminate clinker were investigated by analytical reagent, the XRD analysis of its mechanism was discussed. The results showed that: when the sintering temperature was 1350 ℃, C/A was 1.4, A/S was 1.3 and the content of MgO was 4%, the increase of the C/A promoted the formation of C12A7 and restrained the formation of Q-phase. The alumina-leaching ratio of the clinker (A/S was 1.3) was increased from 74.33% to 91.34% when the content of CaO was 5.21%.

Jan 1, 2015

By Mingmei Zhu, Lang Hu, Yu Wang, Hongpo Wang, Congjing Zhang

Magnetic field has a great effect on the crystallization behavior of mold flux and properties of the flux film between mold and strand, on which the surface quality of strand was deeply depended in continuous casting process. Therefore, studying the change law of the crystallization properties of mold flux in magnetic field is of great significant. In the present work, based on intensity of the applied magnetic field with the range from 0mT to 60mT, the crystallization ratio, crystal size and mineralogical phases of the flux film were discussed. The results show that crystallization ratio increases with the increasing magnetic field intensity, and the crystal size becomes bigger at the same time. The magnetic field promotes the crystallization ratio and growth speed of the crystallized grains of mold flux. However, magnetic field doesn’t change types of the mineralogical phases.

Jan 1, 2015

By Hongbo Zhao, Jun Wang, Wenqing Qin, Guanzhou Qiu, Xueduan Liu

Bio-hydrometallurgy technology was applied for the extraction of copper from the raw ores of Chambishi Mine in Zambia. A copper extraction of 93.29% was obtained for small scale column bioleaching within 63 days, while a copper extraction of 89.05% was achieved for large scale column bioleaching in 90 days, thus confirming the amenability of the raw ores for effective extraction via bioleaching. The bacteria were cultured in a 6-stage enlarge cultivation. The bacterial cultures with cell concentration of more than 1×108 cells/mL were added into a spray pond of sulfuric acid to be applied in the dump leaching, and a copper extraction of about 50% was achieved within 2 months. The production report revealed that the copper extraction increased by approximate 20%, and the acid consumption was reduced to around 35% as a consequence of adding the bacteria. The industrial demonstration of the bio-hydrometallurgy technique is now well established in Zambia, and further applications of bio-hydrometallurgy in both Zambia and Congo are currently in progress.

Jan 1, 2015

By Alana Pereira Ramos, Walman Benicio de Castro

Amorphization and martensitic transformation (Ms) characteristics of Ti–Ni-Cu alloy ribbons prepared by melt spinning were investigated by means of differential scanning calorimetry and X-ray diffraction. In these experiments particular attention has been paid to change the wheel linear velocity from 21 to 63 m/s. Then the cooling rates of ribbons were controlled. The effect of this cooling rate and alloy composition on martensitic transformation behavior is discussed.

Jan 1, 2015

By Yuan Lu, Yiming Rong, Richard D. Sisson Jr

With the development of quench technology, there is a trend of using gas quench to replace liquid quench for less distortion and residual stress. The fundamental difference between the liquid and gas quench is the heat transfer coefficient, not only the values but also the shape of the curve as a function of temperature. The equivalent heat transfer coefficient for the liquid and gas quench is analyzed by simulations and experiments. Even it may result in the same hardness in the liquid and gas quench, the steel microstructure may be different because of the different cooling processes, and therefore other steel properties, such as toughness, may be different. The cooling process, microstructures and properties such as hardness and toughness should be examined when designing the liquid or gas quench processes.

Jan 1, 2015

By Jing Zhan, Gui Li, Wei-feng Li, Li-Hua Jiang, Chuan-fu Zhang, Jian-yang Hwang

Thermodynamics analysis for processing the charge with lead concentrate and lead sulfate-containing materials in bottom blowing smelting furnace was conducted. The results show that the technology of large-scale processing PbSO4- containing materials with PbS concentrate in bottom blowing furnace under the condition of using high-iron slag type, batch heat supplement, high temperature and rich oxygen is thermodynamically feasible. The exploration test and industrial experiment confirm the results. When S content in mixed ore is 16~17% with coke foam content of about 5%, the lead paste amount can be increased up to 40%.

Jan 1, 2015

By G. Plenge, M. Brittan

"Plant design parameters for gold extraction, leach residence time and cyanide consumption are generally determined from standard bench-scale bottle roll or agitation leach tests. The application of laboratory data to process design has essentially evolved from the testing of oxide or low cyanide-consuming ores. Such scale-up factors may not be appropriate for ores that deplete cyanide and oxygen since this interferes with gold extraction kinetics. High cyanide-consuming ores also exacerbate the differences between the conditions applicable to small batch tests and large continuous operations. Testing a reactive high-sulfide South American ore deposit necessitated the re-evaluation of conventional bench-scale cyanidation procedures. Pulp density can be a major factor affecting the results for plant design purposes and should be treated as a test work variable. As with high clay-bearing ore, where pulp viscosity can hinder mass transfer, minimizing the influence of test equipment on gold extraction kinetics may require low pulp densities. This introduces interpretative complexity since cyanide consumption changes as a function of pulp density. Activated carbon also consumes cyanide, so its effect has to be accounted for in the case of carbon-in-leach (CIL) or carbon-in-pulp (CIP) plant flowsheets. Since cyanide is an expensive reagent, often a major component of plant operating costs, it is important that the scale-up of cyanide consumption from laboratory to plant be representative. The traditional method of reporting cyanide consumption in bench-scale testing is questioned since it takes credit for residual free cyanide in leach tails. The projected plant consumption may be better estimated by using the total cyanide addition in a laboratory test. We propose a test work protocol that categorizes the cyanide consumption into its components but requires more extensive testing to generate design data. The ultimate validation of scale-up factors used by project engineers requires rigorous bench-scale versus commercial plant comparative data. Such data are not readily available.IntroductionMajor factors in the design of a gold processing plant are gold recovery, leach residence time and cyanide consumption. These parameters are important determinants of project revenue and costs and, thereby, potentially of project financial viability. Estimates of the associated design criteria for a commercial plant are normally generated from laboratory cyanidation, carbon-in-leach (CIL) or carbon-in-pulp (CIP) tests using standard procedures (Angove, 2005). The key question is whether the standard laboratory test work procedures developed historically for low reagent consuming ores are appropriate for ores that are highcyanide and oxygen consumers.The present paper examines test procedural factors that can influence the test work results and, therefore, their interpretation for design scale-up purposes. The study refers in particular to a high cyanide-consuming sulfide ore. The ore was being tested to develop scoping level engineering design criteria for a proposed project in South America."

Jan 1, 2015

By L. Magne, M. Maldonado, R. Varela

Real-time optimization of flotation circuits demands for accurate and reliable measurements to support the decision making process. The collection zone gas holdup is an important variable in this context as integrates the effect of machine and chemical factors on the bubble size and velocity distributions. It has been demonstrated that gas holdup not only correlates with bubble surface area flux, which defines the particle collection rate and recovery in the collection zone, but also with water overflow, a variable which has been related to the froth zone recovery. Therefore, on-line gas holdup measurements provide a reliable alternative to judge efforts leading to the optimization of flotation cells and columns. Estimation of gas holdup in flotation from electrical conductivity measurements has been proposed and extensively used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the conductivity of the liquid medium and of the mineral pulp with and without air bubbles included. These measurements require a conductivity cell which covers a representative volume of the flotation cell, and creates a homogeneous electric field throughout this volume that ideally is not affected by the conductivity of the medium. The development of such a cell in the limiting space and geometry of a laboratory flotation cell has been problematic, but a multi-electrode arrangement offers a promising alternative. Electrodes were installed in the flotation cell of a Denver unit; the results of preliminary testing are discussed with a focus on its performance in the measurement of two- and three-phase dispersion conductivity.

Jan 1, 2015

By Sumit Kumar Biswas, Moyukh De, Sibapriya Mukherjee

"The piles often are also subjected to lateral (horizontal) forces and moments. In fact, there are some structures where the primary function of piles is to transfer lateral loads to the ground. Proper analysis of laterally loaded piles is very important to the geotechnical and civil engineering profession.In the present investigation an experimental study has been carried out with free head short model cast iron hollow piles of outer diameter of 24 mm and L/d ratios of 8, 10, and 15. The experimental results have been supplemented by numerical techniques using PLAXIS-3D Foundation version 2.1 software. The results have been found to agree reasonably well with the experimental results. Further finite difference approach has been adoptedto reduce the computational time and to calculate the coefficient of modulus of subgrade reaction (?h) from the load- deflection data obtained from PLAXIS output at different pile depths. The parametric study has been extended for the non-dimensional form defined as flexibility ratio (F.R.),where ?h, L, Ep and Ip are the coefficient of modulus of sub-grade reaction, the embeddedlength of model pile, elastic modulus of pile material and the moment of inertia of model pile about the central axis respectively).The variation of coefficient of horizontal modulus of sub-grade reaction (?h) has been studied with respect to the following parameters for homogeneous soil system: relative density andL/d ratio. It has been found that the logarithm of flexibility ratio increases with increase inrelative density and increase inL/d Ratio. The values of ?h obtained by the proposed method have been, found to be close to the numerical results.As output of this research, graphs have been generated in respect of different parametric variations to gain an insight into behavior of piles under lateral load for short piles."

Jan 1, 2015

By Mark Spence, Tom Lardner, Matthew Janes

"IntroductionThe design-build method streamlines project delivery through a single contract between the Contract manager and the design-build team. The design-build method places emphasis on collaborative project management between design and construction disciplines to minimize project schedule, reduce costs, encourage balance risk amongst the design-build team. Since 1985, the percentage of nonresidential design and construction projects has increased from 5% to 45%.1A project carried out in Edmonton, Alberta, Canada will be used as an example to illustrate the challenges of the design-build project delivery method and the merits of establishing a GBR. The project involved a complex slope stabilization as part of an extensive freeway widening. At the project location the roadway was being widened within the base of a historic stream valley into a steep slope with a history of a previous slope failure. The slope was to be steepened through the installation of a series of 14 interlocking arc structures constructed half way up the slope. Access and schedule proved critical to the successful completion of the project.Geotechnique and Site HistoryThe geotechnical investigation undertaken for the site included six boreholes drilled at the crest of the slope to depths ranging from 14.5 m to 30.2 m. Laboratory testing of the soil samples included direct shear tests, Atterberg limits and grain size analysis. The geotechnical report also referenced a previous geotechnical investigation that was carried out in response to a failure of the slope in 1971."

Jan 1, 2015

By Sumantra Sengupta

"Northeast Frontier Railway (NF Railway) intends to connect Imphal, the capital of Manipur (bordering Myanmar) with Assam by railway link. They have planned a 125km long railway line that passes through steep rolling hills of Patkai region, eastern trail of Himalaya, and as a result large number of tunnels and bridges need to be designed. While the high mountains are penetrated by tunnel, the deep gorges between the mountain ridges are connected by tall bridges. The tallest of such bridges connects a gorge at about 140m above its bed level with an overall length about 700m at rail level. In all, five such bridges with tall piers are now under construction. With extensive study on possible alternate arrangement of the bridges considering the effect of high seismicity of the area, moderately to highly weathered siltstone/ sandstone as ground bed material, slope of the hills etc it was decided that bridge will be founded on 1.5m diameter bored cast in situ piles with length varying from 20m to 30m depending on the location. The substructures are RCC hollow pier and superstructures are steel open web through type girder of 103.5m span. Considering absence of any major construction work in the vicinity, it was decided that prior to design work, Site-specific spectrum study will be carried out and design will be carried out considering the varying stiffness of the tall piers, each of different height. Interesting results were obtained regarding behavior of piles under lateral loads generated by high seismic conditions. The paper discusses in detail the design of Pile foundations and the effect of bed material along the steep slope on which the piles are being constructed.INTRODUCTIONIndian Railway has undertaken the construction work of connecting the North-Eastern states of India through railway line. The major stretches of the area passes through hilly terrain and as a result the line passes through tunnels and bridges in succession. The tall mountains are being penetrated with tunnels and immediate after deep gorges are crossed with high level bridges. The entire area is under high seismically active zone. The bed material below the ground level of the sloped hill is 4 to 10 meter of mixed soil of sand, gravel, pebbles etc underlain by moderately to highly weathered sandstone, siltstone at the higher level and moderately weathered sandstone, siltstone at lower level. Considering all the aspects like constructability, maintainability, geological and geotechnical aspect, seismicity, stability, safety, functional aspect and cost it was finally decided that the bridges will be simply supported structure with open web through type steel superstructure of maximum span 103.5m and hollow cylindrical discretely varying RCC substructure with 1.5m diameter group of piles as foundation. The paper discusses on the design aspect of the pile foundation in the rocky strata in the hill slope. The codes and standards that have been followed for design are IRS (Indian Railway Standard), IS (Indian Standard), IRC (Indian Road Congress), AREMA (American Railway Engineering and Maintenance-of-way Association), UIC (International Union of Railway) provisions."

Jan 1, 2015

By Jogeshwar P. Singh, Mohamed Ashour

The Soil-Foundation-Structure-Interaction (SFSI) problem involves Kinematic Soil- Foundation Interaction occurring during large (cyclic and permanent) ground deformations as well as Inertial Foundation-Structure Interaction occurring during shaking all of which take place while the soil and possibly structural properties degrade with time. The design of the deep foundations for liquefaction induced lateral spread loads include estimation of passive pressure applied by the liquefied material as well as the amount of anticipated displacement. Coupled analyses for SFSI problems that account for liquefaction induced lateral spread and their interaction with the deep foundation system can be performed using sophisticated numerical modeling techniques based on finite element and/or finite difference methods using computer programs such as FLAC or OPENSEES. Such complete SFSI analyses are very tedious and expensive and not feasible for most projects. In 2011, California Department of Transportation (Caltrans) released guidelines for foundation loading and deformation due to liquefaction induced lateral spreading. This simpler prescriptive approach combines empirical and analytical methods through decoupled analyses using computer programs such as LPILE and SLOPE-W together with liquefaction induced lateral spread estimates based on published empirical equations. Pile group effects and pile caps are accounted for using a concept of super-pile. In this paper, we discuss the solution of the same lateral spreading related SFSI problem using computer program CGI-DFSAP (CGI-Deep Foundation System Analysis Program) based on the strain wedge theory that can account for liquefaction, lateral spreading, pile groups, pile caps and nonlinear behavior of piles in a more coupled manner to analyze the foundation system under the lateral spread loadings. CGI-DFSAP can be used to analyze piles in sloping ground conditions as well as piles beneath the abutments near a free-face slope. We have included Strain Wedge Model (SWM) solutions using CGI-DFSAP of several field and laboratory case studies of lateral spreading related to pile foundations. Finally, we have also included the SWM solution of one of the Caltrans (2011) example problems.

Jan 1, 2015

By Sergio Sanchez-Segado, Yuan Zhang, Animesh Jha, Ahmad Fahmi Ruzaidi

Niobium and tantalum are considered critical materials because the increasing demand in the energy sector which is reliant on limited abundance of these two metals in minerals. Traditionally, niobium and tantalum mineralsare digested using hydrofluoric acid at moderate temperatures, producing oxy-fluorides which are separated by solvent extraction, involving the use ofhazardous chemicals. The increasing environmental pressures are forcing the industry to search for alternative low carbon processing methods. In this paper alkali roasting based separation and beneficiation, which is not well understood in the literature, is proposed, for which the kinetics and thermodynamic equilibria for the formation of sodium tantalate and niobate with sodium hydroxide are analyzedat the temperature range of 400ºC to 700ºC. The apparent activation energy of formation,changes from 31.0±0.8 to 22.3±1.2 kJ mol-1 and from 23.8±1.2 to110.2±12.8 kJ mol-1, for tantalate and niobate, respectively. The reaction mechanism is examined on the basis of the analysis of reaction products using X-ray powder diffraction (XRPD) and X-ray fluorescence (XRF).

Jan 1, 2015

By Yonghua Li, Fanling Meng, Weitao Zheng, Xiaodong Wang

The NiTi thin films were deposited onto copper substrates by magnetron sputtering. Tensile tests were carried out on CSS-44100 electron universal test-machine. X-ray diffraction profile Fourier analysis method has been used to study the mechanical properties of deformation NiTi thin films. The surface micrographs of the NiTi thin film were obtained using scanning electron microscopy (SEM). It has been found that the dislocation density and the deformation storage energy density increased with elongation increased. Microhardness was calculated from the dislocation data. The results showed that the microhardness values were not in a good agreement between calculated values and measured values. The oxide layer on the surface of NiTi thin film affects the measured values of microhardness. The Vickers hardness measured values are larger than the calculated values. The experimental results showed that a series of parallel cracks grew in a concerted fashion across the thin film and the cracks were equally spaced.

Jan 1, 2015

By Jiang Diao, Xuan Liu, Tao Zhang, Bing Xie

In the present study, the oxidation process of vanadium and chromium bearing hot metal was investigated by using CaO-FetO-SiO2 slags at 1653K in MoSi2 furnace. The results indicated that both the vanadium distribution LV and chromium distribution LCr were of the orders of 2.2~2.4 with the basicity range of 1.32~1.78 and FeO weight percent range of 28%~45%. Both LV and LCr decreased with increasing basicity and decreasing FeO weight percent. The phosphorus distribution LP was of the order of 1.34~1.56. However, LP increased with increasing basicity and decreasing FeO weight percent. The oxidation ratio values of V and Cr in hot metal were above 84% and the values of P were nearly 50%. In other words, it means the addition of CaO in vanadium slag provided a certain ability of dephosphorization along with keeping high oxidation ratios of V and Cr.

Jan 1, 2015

By James C. Sever

The mode of operation of dolomite kilns at a magnesium reduction plant using the Magnatherm process was designed to minimize operation cost and maximize kiln refractory life. Analysis of downstream operation issues shows the quality metric for dolime changed from loss on ignition to specific surface area. This produced a complete change in kiln operation; the net results being major plant productivity increases decrease in operating cost, and increases in both kiln operating costs and reline frequency.

Jan 1, 2015

By Hector Carreon

During fretting, high points or asperities of the mating surfaces adhere to each other and small particles are pulled out, leaving minute, shallow pits and powdery debris. Sometimes these surface conditions are neglected, but they are important in some application such as the aerospace industry. In this research work, non-contacting and contacting thermoelectric power techniques are performed in fretted 7075-T6 and Ti-6Al-4V samples. It has been found that the contacting and non-contacting thermoelectric power measurements are associated directly with the subtle material variations such as work hardening and residual stresses due to plastic deformation produced in the fretting zone but surface topography. Therefore, both techniques could be used for a global characterization of the most relevant fretting induced effects. Potential of these techniques to monitor subsurface changes in other severe surface plastic deformation processes are clearly envisaged.

Jan 1, 2015

By Ruirui Wei, Yanhui Liu, Fangqing Yin, Meilong Hu

In China, Basic Oxygen Furnace (BOF) slag is traditionally used as an aggregate for civil engineering, for road engineering and fertilizer. In order to make full use of BOF slag, the experiments of BOF slag with high temperature roasting has been carried out and the phase transformation is studied. The BOF slag from Chongqing Iron & Steel is roasted in the electric muffle furnace at three different temperature. The influences of the high temperature roasting on change the phase composition of BOF slag was characterized by XRD. The results revealed that SFCA was produced at the high temperature in air atmosphere and melting temperature of slag was lowered. Therefore, if the BOF slag which treated by roasting was utilized in the sintering process, it is advantageous to improve the sintering strength and the formation of the liquid phase and reduce fuel consumption in the sintering production process.

Jan 1, 2015

By Niels Verbaan, Ralph Fitch, Charlotte Forstner, David Dreisinger

A process has been developed to extract gold, silver, indium, gallium, lead, copper, zinc, and other metals from a large resource using an oxidizing acid chloride heap leaching technology. The ore is crushed and/or ground to improve reactivity and then contacted with a solution containing NaCl-HCl-NaOCl. The value metals are leached into solution as chloro-complexes. The leachate is treated in a series of separation and recovery processes to produce separate saleable or disposable products. The paper will provide a summary of process development and application to a silver-indium ore from Bolivia. The possible application of the process to other ore types will be presented for discussion.

Jan 1, 2015