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By H. Huang, R. N. Gow

"The reactivity of an enargite mineral electrode was investigated spectroelectrochemically under conditions typically found in alkaline sulfide leach solutions, with pH 11-13 and Na2S additions of 50 and 250 gL-1. A bulk enargite electrode was cycled between 0 and -1,000 mV for each set of solution conditions. Raman spectroscopy was used to determine and compare surface formations against species in mass-balanced EH-pH diagrams generated using STABCAL. Previously, it was determined that arsenic could be selectively leached under alkaline conditions at an average solution potential of -300mV, across the pH range 11-13. Operating under such conditions allowed for the selective leaching of arsenic with elemental sulfur formation. From several of the voltammograms obtained during this current testing, the formation of elemental sulfur appeared at increasingly reducing conditions with increasing sulfide concentration. At high concentrations, copper started to dissolve, possibly as a bisulfide complex, reducing the selectivity of the leach, unlike previous studies. However, the presence of the higher sulfide concentration is also anticipated to prevent passivation by consuming any surface formation of elemental sulfur. This study provides insight into the operating parameters of alkaline sulfide leaching in regards to the selectivity of arsenic leaching, as well as guidance for control of reagents and solution potential and, of course, the need for water treatment afterwards.IntroductionEnvironmental limitations on the pyrometallurgical processing of arsenic-bearing concentrates have forced operations to consider other solutions. Attempts to hydrometallurgically process enargite (Cu3AsS4) fall into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under basic conditions. The authors believe that the selective leaching of arsenic is more amenable because it produces a solid copper phase, preferably chalcocite (Cu2S) or covellite (CuS) that could then be processed using conventional methods already in place in the copper and gold industries. Potential leaching methods include alkaline sulfide leaching (Achimovicovica et al., 1999; Anderson and Twidwell, 2008a,b; Tongamp et al., 2009 and 2010), hypochlorite leaching (Vinals et al., 2003; Curreli et al., 2005; Mihaljovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and acid leaching (Gow et al., 2014b) with or without fine grinding to mechanically activate the enargite surface and increase normally slow leach reaction kinetics (Achimovicova et al., 1999; Balaz et al., 2000; Balaz and Achimovicova, 2006). In this study, the reactivity of enargite under alkaline sulfide leach conditions was examined."

Jan 1, 2015

By Thang V. Nguyen, Lisheng Shao, Gary E. Taylor

"The Community Memorial Hospital of Ventura, California, proposed to build a new state-of-the-art Cancer Treatment Center with radiation shielding walls and roof. The loose silty soils at the site had the potential to liquefy during an earthquake, which would result in significant settlement under the heavy footing loads. Treatment options included various deep foundation alternatives, as well as several ground improvement methods. The choice of wet soil mixing minimized the disturbance to the adjacent hospital during construction and potential settlement. Wet soil mixing allowed the structure to be supported on a raft foundation, meeting the stringent building total and differential settlement criteria. The authors also performed unit cell 3-D finite element analyses to evaluate the behavior of the wet soil mixing system in seismic loading conditions. This paper highlights the ground improvement design, construction, QA/QC, and the research related to evaluating the effectiveness of soil mixing for liquefaction mitigation.INTRODUCTIONThe Ventura Community Memorial Hospital proposed the construction of a new Cancer Treatment Center to replace the existing structure, which was built in 1901. The hospital complex is located in a wellestablished residential neighborhood. The soil conditions at the site of the proposed structure required ground modification to support the very heavy radiation treatment section of the building and limit settlement. Originally, 90-foot-long precast piles were considered for foundation support. Based on supplemental Cone Penetration Tests (CPTs) performed, the deepest CPT did not encounter competent pile bearing strata at a depth exceeding 30.5 m (100 ft). This could result in failure of the piles under long-term conditions, especially if hydro-consolidation occurs. The more realistic pile penetration depth would have been 36.6 to 45.7 m (120 to 150 ft). In addition, the excessive noise in association with pile driving would have been unacceptable to the community, patients, and staff of the hospital, so an alternative ground improvement solution was required.The specialty geotechnical contractor recommended wet soil mixing, an economical solution of creating a soil-cement product known as soilcrete that would significantly reduce the construction related noise and provide a more complete deep foundation for the structure.SOIL CONDITIONS AND SETTLEMENT CONCERNSThe subsurface soils were interbedded (Fig. 1) consisting of loose to medium dense silty sands, and soft to medium stiff silty clays to a depth of 30.5 m (100 ft). Groundwater was encountered at depths of 9.1 m (30 ft) and historical high groundwater was at 8.5 m (28 ft) below the ground surface."

Jan 1, 2015

By A. E. M. Warner, P. J. Mackey

"In 1988, two of the present authors Warner and Vahed [1] were amongst several co-authors on a seminal paper reviewing nickel pyrometallurgical operations of the era. Given that significant changes in the nickel industry have occurred since that time, including the overall political landscape, technology, the overall world energy picture, the countries sourcing nickel and finally the nickel market itself, the present authors considered it timely to provide a 2015 update. In 1988, total world nickel production from sulphide and laterite sources, including production in the former "Centrally Planned Economies"- was about 0.86 million tonnes/a, while in 2014 total world nickel production reached an all-time high of almost 2 million tonnes/a - some 230% higher. On the other hand, while in 1988, about 94% of world nickel was produced pyrometallurgically and of the order of 33% via laterites, today, about 88% of nickel is by pyrometallurgy, with some 41% from laterites, thus showing that more nickel is now sourced from laterites, a trend which is expected to continue.During the period under review, new processing technologies were developed and introduced, along with substantial improvements in both the technologies employed and the scale of operations. Significant productivity gains have been achieved in sulphide pyrometallurgy in part through more efficient mineral processing, particularly in pyrrhotite rejection, and the use of ever larger-scale process equipment. This made it possible to treat lower grade and more complex ores. The significant game-changer from a production perspective was the introduction in the early 2000s of nickel pig iron (NPI) in China via modified iron blast furnace smelting, an old technology long ago cast aside by other nickel producing countries. With the exception of the emergence of this new NPI capacity in China, in the laterite industry modernization and expansion of existing operations has been employed to gain productivity, to cut costs and/or offset the effect of declining ore grades. The NPI technology development has become a game changer in the traditional global supply and demand relationship, opening up a new frontier to supply nickel to low grade utility steel producers. One other key nickel development was the Indonesian ban on nickel ore exports effective in January 2014, thus effectively curtailing NPI production at existing Chinese plants, but on the other hand, potentially prompting new smelting facilities in Indonesia. This paper reviews and updates major pyrometallurgical sulphide and laterite operations worldwide, including changes in nickel extractive metallurgy. It also provides a brief review of new developments in pyrometallurgical operations, with special focus on the NPI process and presents an outlook of the potential future direction of the industry."

Jan 1, 2015

By M. Jiang, X. Fan, W. X. Chen, Z. K. Guo, H. H. Zou

"Some improvements are carried out for elasto-plastic model by taking the shear dilation effects and relaxation effects of deep rocks into accounted. The high pressure equations of states with Mie-Grüneisen form are also introduced to describe the relation of pressure-volumetric strain. Numerical simulations of free field responses for deep underground explosions are conducted by using the user subroutines which compiled by means of the secondary development functions of LS-DYNA9703D codes. It is indicated that the dynamic responses of free field are well simulated based on this improved elasto-plastic model, and the analytical results are in good agreement with the data of U.S. Hardhat nuclear test.INTRODUCTIONDynamic behaviors of deep rocks for underground explosions are obviously different from that of shallow underground explosions and have aroused great attentions of international experts who work for rock engineering. The dynamic models of deep rocks could be roughly divided into classic elasto-plastic model and fracture damage model according to different theoretical foundation. M. E.Kipp and D. E.Grady et al. are the outstanding representatives who engaged in the researches of fracture damage mechanics. Researches of dynamic problems for geomaterials were carried out by C.C.Grigorian and the conclusion that incompressible elasto-plastic medium model could not be used to solve the problems of closed underground explosion was derived, and therefore C.C.Grigorian model was proposed. In this model, C.C.Grigorian assumed that the average hydrostatic pressures and the densities of medium had one to one relationship, and the path of loading or unloading is different from each other. For shear deformations, analytical solutions of the problems were derived according to the model which was slightly different from Prandtl-Reuss model, the constitutive equations were closed by Mises-Schleiher constitutive model. However, the analysis showed that there were two inadequacies in C.C.Grigorian model. Firstly, the shear dilation effects of fractured medium after wave front could not be considered. Secondly, the relaxation characteristics of the rocks in fractured region were not taken into account."

Jan 1, 2015

By M. Gagné, F. E. Goodwin

The mining industry represents a significant investment in infrastructure of which steel plays a key role. Many structures in a mine are made of steel including shaft structures (buntons, station steelwork and headgear); stope structures (roof supports, pipe hangers); haulageway structures (ore transfer stations, electrical stubbies); and surface structures (plant buildings, tank supports, pipe gantries, conveyor belts, stacks, stockpile structures, stairways and railings). Maintenance of structural components can often be difficult because of the environment, including those where corrosive fumes persist, or limited access, such as in shafts where access is limited, or to short maintenance shifts or where limited working space is available. Thus a cost-efficient, long-lasting and maintenance-free protection system for steel should be specified. Galvanizing provides the required high-quality, long-term corrosion protection to steel. Galvanizing provides protection in two ways, first as a physical barrier to corrosion and secondly by means of cathodic or sacrificial protection that is unique to zinc. The dual nature of corrosion protection provided by galvanizing significantly extends the service life of steel even in the most challenging environments. The unique corrosion protection properties provided by galvanized steel will be highlighted with global mining application case studies.

Jan 1, 2015

By Darin Cotton, Tim Burgess, Tim Martin

"As the leading US supplier of roof control drills, J. H. Fletcher and Company® has encountered an extensive set of roof strata challenges and has overcome various drilling issues by varying machine parameters and working with customers and tool manufacturers to develop solutions. Every mine wants to drill and install roof bolts as fast as possible with maximum safety at the lowest possible installation cost for their conditions. In most circumstances, the intuitive method of higher speeds and pressures can actually have a detrimental effect on the roof drill safety and performance.This paper will outline recent tests carried out at several different coal mines in the Eastern United States. The tests focused on optimizing the drilling parameters of feed pressure, feed rate, rotation speed, and drill torque.The drill feed, rotation speed, and rotation torque, as well as the type of bit selected, have a definite impact on the performance of the roof drill including drilling speed, safety, and tool life. The drilling process can be improved while also improving operator safety and reducing bolt installation costs by maintaining the appropriate roof drill settings for the specific strata conditions.The advantages of improving the drilling process includes increased bit life, increased drill steel life, reduced hanging drill steels, reduced clogging of the vacuum system, decreased whipping drill steel potential, reduced noise generation, and increased cutting size which reduces fine dust generation and dust collection system servicing.INTRODUCTIONIn recent times, the economic pressures that coal producers are facing have created an increased emphasis on controlling operating costs. Several coal operators have pointed out their dissatisfaction with low bit life, and there is a renewed interest in improving tool life and machine performance as part of an overall cost control strategy. Operators are looking for ways to reduce tooling cost, maintenance costs, and drill downtime without decreasing drill performance. This renewed interest in reducing operating costs, along with the ongoing desire to improve safety, created a perfect environment to take a fresh look at the existing fleet of machines to see what could be accomplished. The goal was to take a practical approach to reviewing machine parameters to determine what changes could be made. The emphasis was on changes that would be feasible to roll out to an entire fleet of machines in a short period of time with minimal capital expenditure. The thought process was that significant improvements could be made by simply tuning up the machine parameters to provide a more efficient and safer bolting process."

Jan 1, 2015

By A. David Miller, Douglas M. Barber

"The Rocky Mountain Arsenal was used by the military to produce chemical warfare agents and incendiary munitions for use during World War II and later by private companies for the production of industrial and agricultural chemicals. After an investigation performed in accordance with CERCLA confirmed significant levels of contamination due to the common industrial and waste disposal practices of the era and the discovery of over 300 species of wildlife inhabiting the land the Rocky Mountain Arsenal became a wildlife refuge and contamination cleanup efforts began. Three lime basins originally used to treat wastewater from the chemical production were decided to be contained in place, requiring a seepage barrier installed around the perimeter of the site to further prevent groundwater/contaminant migration. This case study will discuss the successful installation of a soil-bentonite cutoff wall around the area using deep soil mixing. Highlights of this case study will also include a discussion of the challenges faced due to construction activities performed with Level B Hazmat PPE requirements as well as added challenges brought on by the Winter season, after the project was delayed due to a positive air monitor detection for the chemical weapon Lewisite during construction of the work pad.INTRODUCTIONThe Rocky Mountain Arsenal (RMA), located just outside of Denver, Colorado, was established by the United States Army in 1942 to produce chemical warfare agents and incendiary munitions for use during World War II. Following the war, and as weapons production decreased, portions of the site were leased to private companies for the production of industrial and agricultural chemicals. The principal lessee, Shell Oil Company, manufactured mostly pesticides at RMA facilities from the early 1950s to the early 1980s.In 1984 an investigation began in accordance with the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and confirmed significant levels of contamination due, in large part, to the common industrial and waste disposal practices of the era. It was also discovered that over 300 species of wildlife inhabited the land in the absence of regular human activity, including a group of bald eagles, leading to the passing of the Rocky Mountain Arsenal National Wildlife Refuge Act in 1992."

Jan 1, 2015

By Panagiotis (Takis) Katsabanis, Lyall Workman, Jack Eloranta

The reduction of metallic ores to concentrate consumes a great deal of electrical energy. In the past two decades, a number of case studies have demonstrated a beneficial relationship between powder factor and grindability. However, changes in mill performance cannot be attributed to changes in feed size alone. Blasting energy and the distribution of that energy appears to affect subsequent comminution beyond crushing. This experience has prompted researchers to attempt to duplicate and quantify the mechanisms involved. To date, published reports indicate a measure of success. However, the blast engineer and the mill engineer still lack the tools and basic understanding necessary for full drill to mill optimization.

Jan 1, 2015

By Bob Drew, Goran Vukovic, Bojan Zivanovic, Klaus Gamweger

Reaction bath temperature is a major factor in processing liquid metals and in many applications where a balance between process duration and temperature has to be found to run a procedure efficiently. Also extremes of temperature can decrease the output of a process if too cold or even make it impossible, conversely overheating can be detrimental to both the product and furnace integrity. With the help of the new online temperature measurement system very accurate monitoring of the process is possible in contrast to the current routine practice where the temperature is measured periodically with dip thermocouples. The system works with a digital, fiber optic pyrometer, which is embedded in a refractory housing. Installation in the lining is possible below liquid level as nitrogen is blown to keep the system open and to ensure continuous sight from the optical head of the pyrometer to the molten metal through the tuyere. This permanent temperature measurement gives optimal process control with the potential of taking appropriate actions at an early stage enabling proactive process control. Therefore energy savings and even process endpoint detections can be realized.

Jan 1, 2015

By Q. Li, X. -L. Lei

Accompanying global energy shortage and high energy prices, shale gas has been the focus of exploration and it has attracted great attention from both academia and industry. The combination of horizontal drilling and hydraulic fracturing enables the extraction of huge quantities of shale gas from impermeable shale formations. During the process of hydraulic fracturing, great amounts of water, sand and chemicals must be injected into the shale formation at a high pressure, which may trigger seismicity. Such events could occur due to the presence of faults or the reactivation of these potential faults. Shale is the main component of source rock in the Sichuan Basin, China, and has the greatest contribution to the natural gas of the basin. In order to investigate the fracturing mechanism of shale in the Sichuan Basin, China, a series of rock fracture tests under triaxial compression were carried out in the laboratory in order to investigate the hydraulic fracturing behavior in relation to the seismicity. Based on the high multichannel waveform recording system, the detailed spatio-temporal distribution of acoustic emission due to micro-cracking was used to examine the deformation and fracture behavior of shale. In addition, the effects of confining pressure on the deformation and fracture in shale under triaxial compression by acoustic emission monitoring and X-ray computed tomography were discussed in the paper. The experimental results indicate that the shale samples demonstrate brittle fracture behavior. The confining pressure has a great effect on the complexity of the fracture planes and the spatial distribution of acoustic emissions, but few contributions to the location of the major hydraulic fracturing plane. The foliation of shale plays a dominant role in the rupture process and the geometry of the major hydraulic fracturing plane. The high confining pressure increases the strength and restrains the deformation of shale during compression process. These results shed some light on the understanding of onset of hydraulic fracture initiation not only for shale gas exploration and production, but also for CO2 geological storage and underground energy storage.

Jan 1, 2015

By Arthur Barnes, Mika Muinonen, M. J. Lavigne

"The carbothermic reduction of chromite ore to produce high carbon ferrochromium is among the most energy intensive metal extraction processes performed, due not only to the highly endothermic nature of the reduction reactions but also the very high operating temperatures required for the smelting operation to separate the chrome-containing alloy from the discard slag.KWG Resources and XPS have collaborated over the last 3 years in developing a patented (Winter) processing alternative to the traditional smelting operation in which all processing takes place in the solid state at temperatures many hundreds of degrees lower than those required for liquid processing. Amongst the attractions of the process are much lower capital costs, as well as reduced operating costs, particularly of energy.A techno-economic study on the new process identifies a reduction in overall energy consumption of 70% against conventional processing and approximately 40% lower than the current best practice. By utilising more natural gas than coal based energy sources, the KWG process is able to show an overall 50% reduction in greenhouse gas emissions compared with the most energy efficient current practice. The impact of the new process on future processing is therefore regarded as highly significant, with global energy reductions equivalent to the effect of completely eliminating energy demand from a country the size of Italy.The study concluded that the potential for this process to completely revolutionise the global ferrochrome industry should not be underestimated. Its impact reaches far beyond exploitation of a regional natural resource."

Jan 1, 2015

By Russell J. Denny

"A 25m deep cut-off wall is required for environmental remediation of a Former Chlor-Alkali Plant. Extensive trials were conducted to verify the effectiveness of the mixes proposed, with the requirements of the cut-off wall to include limiting criteria for hydraulic permeability, vapour permeability and strength, over a 100 year design life. A limited number of field CSM trial panels were installed on a nearby site with similar stratigraphy, and a variety of mixes and mixing methodologies were used, together with the extraction of deep wet grabbed samples from the panels, which were tested for strength, hydraulic permeability and gas permeability. Test results obtained from these trials revealed a trend which allowed the construction methodology to be decided. Further to this, the mix design needed to be resolved, together with sensitivity analysis on the variations in the mix which might occur during construction, as a result of normal unavoidable variations in construction technique. Laboratory sampling would be used at lesser expense, to resolve the final mix design and analyse the sensitivity of the possible mix variations. An initial series of laboratory mixed samples were prepared using soil samples and groundwater obtained from the site, and testing carried out. However the test results in this initial series of laboratory tests could not match the results which had been achieved in the field trials. Closer scrutiny and investigation and rounds of sampling and testing, then revealed laboratory techniques for mixing and sampling which provided a logical way to match the actual field test results. CSM Construction is due to commence soon and will provide more extensive results which can be compared back to the laboratory trials. This project provides a valuable opportunity to resolve methods of laboratory sampling so that they compare well with results from in-situ deep mixing.INTRODUCTIONThe former chlor-alkali plant at Botany, NSW, which operated from 1945 until 2002, used mercury cell technology and brine solution to manufacture chlorine, caustic soda, hydrochloric acid, sodium hypochlorite and ferric chloride. Mercury contamination is present in the permeable alluvial soil profile beneath the site. The mercury is present in the form of elemental and inorganic mercury, together with dissolved methyl mercury in the groundwater and soil profile beneath the site and also down-gradient of the site, to depths of up to 25m. Residual clay and sandstone bedrock at approximately 25m depth are relatively impermeable and limit the contamination plume. A cap and contain approach has been recommended by consultants Golder Associates, and this involved a subsurface containment wall, or cutoff wall, to restrict groundwater ingress and egress, and lateral subsurface vapour migration. The cut-off wall is situated on the perimeter of the site, with a total length of 430m and passing through alluvial Botany Sands, with a nominal key into the underlying residual clay or sand stone at 20 to 25m depth. An HDPE liner insert was proposed for the upper 7m of wall above the water table, to further limit gas permeability."

Jan 1, 2015

By Jesse Puller, Ken W. Mills, Owen Salisbury

"An underground coal mine located in New South Wales has a target coal seam located 160-180 m deep directly below a 16-20 m thick conglomerate unit that has been associated with significant periodic weighting events on the longwall face. As part of the investigations to better understand the causes of periodic weighting at the mine, inclinometers capable of measuring horizontal shear movements through the full section of the overburden strata were installed ahead of mining at two locations approximately 1 km apart above the centre of two longwall panels. These inclinometers were monitored as the longwall approached each site. This paper presents the details of the installation, the results of the inclinometer monitoring at both sites, and the insights that these measurements provide for overburden behaviour about longwall panels.Horizontal shear movements were observed to develop on shear horizons that correlate closely across the two sites suggesting a mechanism that is consistent across a large area of the mine. Shear movements were observed to develop on a single horizon near the top of the conglomerate strata that was mobilised almost immediately after initial formation of the longwall goaf at a distance of 425 m ahead of the longwall face. The direction of horizontal movement was consistent with the relief of the major principal horizontal stress. As the longwall face approached each inclinometer, other horizons within the upper part of the overburden strata begin to shear with the upper strata moving toward the approaching goaf more than the lower strata. Within the last 30 m of longwall approach, tilting of the strata associated with the increase in vertical subsidence toward the extracted goaf caused a change in the style of deformation with tilting and reverse shear offsets.INTRODUCTIONLongwall mining is recognised from subsidence monitoring, surface extensometer measurements, and various other observations to cause significant disturbance to the overburden strata directly above the extracted goaf of each longwall panel. Disturbance to the overburden strata beyond the limits of each longwall panel is not so well understood. Subsidence monitoring indicates that horizontal movements beyond the edges of the extracted longwall panel are generally greater in magnitude than vertical subsidence and horizontal movements may extend up to several kilometres from the edge of the panel in some circumstances (Reid 1998, Reid 2001, Hebblewhite et al 2000, Mills 2001, Mills 2014). The mechanics of how these movements are accommodated within the overburden strata is only poorly understood and there are few direct measurements."

Jan 1, 2015

By Paikowsky, Samuel G.

"Due to the way drilled deep foundations are being constructed, their structural integrity and geotechnical capacity are highly variable. Drop weight systems are increasingly being used to dynamically test the capacity and integrity of drilled deep foundations. Conventional pile driving hammers are often either inadequate or not economical to test these foundations and drop weight systems have therefore been developed to allow for dynamic testing.The advantages of the tests include high mobility, short testing time, low cost relative to static load tests (allowing multiple tests at a single site), and integrity/construction quality evaluation concurrent with capacity determination. The dynamic testing method for drilled deep foundations encounter several difficulties including: the need for a pre-testing analysis for matching pile, soil and testing system, adequate mass and drop height to reflect the mobilized capacity without structural damage, test interpretations for irregularly shaped and/or non-uniform piles, need for reliable dynamic measurements depending on the impact and the distance between the impact and the measuring point, and limited knowledge about the accuracy of the predictions.The principles of the tests are presented using simplified models and demonstrated via a case history. Drop weight systems are reviewed. Dynamic measurement principles are explained and the construction and testing quality effects are outlined and demonstrated via numerical modeling and case histories. A comparison of dynamic and static tests is presented via a database, case histories and finally a short review of relevant codes is provided.1 IntroductionTraditional static axial load test is performed by a slow application of a force produced against independent reaction, imitating structural loading. It is the most reliable method to determine the pile’s performance as commonly required under typical service conditions. The major limitations of this testing are: (i) high cost associated with set-up, test duration, interpretation and construction delays, and (ii) inability to obtain information about the pile-soil interaction along the pile without additional testing means (e.g. tell tales, strain gauges, etc.). These limitations are acute when high capacity foundations are involved."

Jan 1, 2015

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By J. Pancher

"Stainless steel castings are used in abundance in the mineral processing industry. In rotary kiln-based processes, these castings are typically exposed to high loads, corrosive elements, mechanical abrasion and cyclical temperature exposure. In the processing of iron ore pellets, it is typical to use a traveling grate preheater or a straight grate furnace to heat the pellets. Both machines have a conveyor that is mainly comprised of high temperature stainless steel castings. It is these castings which are the focus of this study. The expected life of these castings can be quite short, their cost quite high and the effort to replace them very labor intensive. The goal of this study was to gain a better understanding of the failure modes of these castings. With that basic understanding, modifications to the alloy content could be made to achieve a new operational paradigm. That paradigm could be a cheaper casting, a longer lasting casting or a casting tailored to special operating conditions (for example, highly corrosive gases or sudden temperature shocks). Over the past 4 years, Metso Minerals has sought to achieve a better understanding of the failure modes through modeling, laboratory testing and sampling of used castings from various end-users. In addition, we have tested new alloys in a laboratory setting and also in the field to see how they would perform compared to the existing ""standard casting"". Our testing has revealed interesting data concerning the impact toughness, sigma phase content and formation, chloride attack and other performance attributes of various grades of stainless steel when exposed to cyclical temperatures. Interesting results were also obtained concerning the addition of rare earth elements (Niobium, Boron, etc), nitrogen and manganese to a typical ASTM A297 grade of stainless steel. To date, a few hundred test castings have been installed in iron ore pellet plants worldwide. Many of these test castings have already experienced a year or more of operation with good results.INTRODUCTION Cast stainless steels (ASTM A297 and similar) are a main constituent used in the construction of iron ore pelletizing equipment. A typical straight grate pelletizing machine would contain upwards of 160,000lbs of ASTM A297 Grade HH castings. With a typical casting lasting only two to four years, and a casting costing around $35USD, it is easy to see that the castings are a main contributor to the overall cost of producing the pellets. Grade HH and HI (see chemical composition listed below) became the “go to” materials in the 1960’s and very few changes have been made to this day (the exception being plants that switched to flux pellet production in the 1980’s)."

Jan 1, 2015

By Wei Yin, Yu Wu, Xiexing Miao

"For engineering problems of “three under” coal (coal trapped under buildings, waters-bodies and railways) exploitation, environment protection and gangue separation from raw coal underground exist in Tangshan Coal Colliery. By analyzing concrete technical problems, a technical approach of closed cycle “coal mining-gangue washing-backfilling-coal mining”, i.e. integration of coal mining, gangue separation and solid backfilling, is put forward with key technologies including gangue transportation with great depth, gangue separation from raw coal underground and integration of coal mining and backfilling. Based on the specific geological conditions of Tangshan Coal Colliery, 591m vertical feeding transportation system with great depth is designed; meanwhile, for efficient gangue transportation, ancillary wear-resisting pipe size and buffer equipment are optimized. Underground gangue separation system is created to be joined with the existing production system and backfilling system; besides, as per separation characteristics of coal and gangue, buddle jig is adopted for gangue roughing of raw coal underground. By cooperation of backfilling hydraulic support and other key equipment, the designed stope backfilling system completely realizes integration of coal mining and backfilling. Engineering practice shows that, through the research and implementation of the above key technologies, integration of coal exploitation, gangue separation and solid backfilling is successfully implemented in Tangshan Coal Colliery; moreover, it completely solves the three major engineering problems and realizes waste disposal, underground washing and separation, and ground surface subsidence control.INTRODUCTIONSo far, “three under” coal (coal trapped under buildings, watersbodies and railways) and key state-owned coal resources trapped under villages in China have reached 13.7 billion t and 5.22 billion t, respectively. With the development of coal enterprises, China currently has more than 1,600 gangue dumps (Miao et al., 2010a) with accumulated stack amount of 4.5 billion t, occupying a land area of 150,000 km2; moreover, surface subsidence caused by mining activities has damaged the environments of industry, agriculture, transportation and living, while new environmental pollution sources formed by coal related industries also result in damage to ecological environment (Huang et al., 2011a). On the one hand, due to large scale coal mining, some coal collieries suffering from resource exhaustion are faced with survival problems; on the other hand, coal mining has caused and been faced with increasingly prominent environmental problems, such as “three under” coal exploitation, waste disposal and ground surface subsidence control (Miao et al., 2010b; Zhang et al., 2009)."

Jan 1, 2015

By J. -M. Bosgiraud, G. Armand, S. Dewonck, L. Richard-Panot

"The Meuse/Haute-Marne Underground Research Laboratory (URL) is located on the eastern boundary of the Paris Basin. The URL started to be built in 2000 (shaft sinking operations) in the framework of ANDRA’s (French national radioactive waste management agency) research program aimed at determining the feasibility of a reversible deep geological disposal of high-level and intermediate-level long-lived radioactive waste (HLW, IL-LLW). Its underground drifts are used to study the Callovo- Oxfordian claystone layer between 420 m and 550 m in depth.The ongoing research program (started in 2006) following the “Technology Readiness Level” (TRL) Scale is more dedicated to technologies improvement and demonstration issue of the different disposal components, even if characterization and monitoring studies are still ongoing.In rock mechanics, at the main level of the URL (located at 490 m), construction and evolution of disposal cells of different size are studied for HLW and IL-LLW packages. A step by step approach, started in 2006, is carried out based on comparison of HM behavior of parallel drifts excavated/supported by different construction methods. These various configurations give insight of the influence of construction method on the EDZ extent and evolution and on the progressive loading of the support, which are key issues to design the Cigéo disposal drifts and excavations.The concept of disposal cells studied for HLW consists in horizontal steel lined micro-tunnels 80 m long and 70 cm in diameter. Several campaigns of tests have been carried out since 2009 in order to demonstrate the feasibility of excavating such micro-tunnels and study their behavior under different conditions (with and without back filling the annular gap between the rock and the casing, watertight or not casing). A full scale demonstrator representative of the benchmark concept has also been excavated, to study its behaviour under thermal loading with heat produced by electrical heaters."

Jan 1, 2015

By S. Bastola, Y. P. Chugh

"This research determines shear strength and stiffness properties of bedding planes and joints in the roof strata rocks within 7.5 to 9 m (25-30 ft.) overlying the Illinois #6 coal seam (within the pressure arch zone). A shear test loading device was designed into a 1.334 kN (150 t) Forney Compression Loading Machine to perform direct shear tests in accordance with ASTM D5607-08 “Standard Test Method for Performing Laboratory Direct Shear Strength Tests of Rock Specimens under Constant Normal Force”. The data were used to determine peak and residual friction angles and the dilation angle. A total of 49 bedding plane samples were tested, out of which 46 (36 intact and 10 relatively weak and loose) samples passed QA/QC procedures in accordance to ASTM D5607. Samples from eight (8) different bedding planes- shale/limestone (SL), shale/sandstone (SSs), shale/bone (SB), laminated sandstone (LS), shale/shale (SS), bone/bone (BB), bone/limestone (BL), and limestone/limestone (LL) were tested. The number of samples tested for each bedding plane were: SL- 11, SSs- 8, SB- 5, BB- 4, LS- 6, SS- 9, BL- 1, and LL- 2. Peak and residual shear strength values at 2.75 MPa normal stress range 1.06 – 6.26 MPa and 0.82 MPa to 0.82 – 4.14 MPa, respectively. The average normal and shear stiffness values are about 11.98 GPa/m and 3.11 GPa/m. Dilation angles are low (<10?) and negative in some cases. Angle of sliding friction values range from 9? to 42?. Joint Roughness Coefficient (JRC) values were less than 10.INTRODUCTIONRock mass may be defined as the total in situ rock medium containing bedding planes, faults, joints, folds and other structural features. Therefore, it is discontinuous and may have heterogeneous and anisotropic engineering properties. Upon creation of an excavation in a rock mass, bedding planes and joints are the most likely points of failure initiation. The failure typically occurs either in tensile or shear mode. Upon failure initiation stresses are transferred to the neighboring rock mass and the failure progresses until stability is achieved through equilibrium of stresses and strength. An example of this mechanism is development of the pressure arch. This study determined the shear strength and stiffness properties in shear and compression of bedding planes and joints in the immediate roof strata rocks within 7.5-9 m ( 25-30 ft.) overlying the Illinois No. 6 coal seam (within the pressure arch zone). Since such data are currently not available for Illinois Coal Basin mines, researchers and engineers have been using estimated values for design purposes. The immediate roof lithology in the proposed mining area consists of shale 0.62 m; Bone 0.09 m (0.3 ft.); Limestone, 0.10 m (0.33 ft.); Shale 2.37 m (7.9 ft.); and sandstone 0.55 m (1.83 ft.). The bedding plane samples were provided by a mine in south-eastern Illinois operating at a depth of about 180 m (600 ft.)."

Jan 1, 2015