Search Documents

By Yasuhiro Konishi, Yoshiyuki Noda

"This paper describes a new processing of rare-earth oxide precursor, in which rare-earth carbonate powders are precipitated directly from emulsions of rare-earth loaded carboxylate solutions, using CO2 gas and water. This synthetic route of rare earth carbonate is a combined process of the stripping and precipitation stages in a conventional solvent extraction. Using this technique, lanthanum carbonate and yttrium carbonate were prepared at temperatures of 10 to 80°C and CO2 pressures of 0.1 to 3.0 MPa for 120 min. The rates of carbonate precipitation in a batch autoclave were sensitive to processing parameters such as CO2 pressure, temperature, and organic-phase composition. The particle size distributions of the carbonate powders were markedly dependent on temperature and C02 pressure.IntroductionSolvent extraction is the most appropriate commercial technology for separation and purification of rare earths. In typical commercial processes, the rare earths are stripped from loaded solvent extractants using aqueous solutions of mineral acid. After adjusting the pH of the aqueous strip solution, the rare earths are precipitated as insoluble powders of oxalates or carbonates, from which oxides can be produced by calcination. Such conventional processing can be simplified when the stripping and precipitation stages are combined by emulsifying rare-earth loaded solvent extractant with aqueous oxalic acid solution. It is likely that the single-stage precipitation stripping results in a marked decline in the consumed amounts of precipitating and neutralizing agents, thereby saving on both running and capital costs.Yoon and Doyle1) first demonstrated that oxalate powders of lanthanum and yttrium are directly precipitated from rare-earth loaded carboxylic acid solvent extractant when contacted with aqueous oxalic acid solution at ambient temperature and atmospheric pressure. Yttrium oxalate pow4ers were also prepared by precipitation stripping of di-(2 ethylhexyl) phosphoric acid. (D2EHPA) extractant using oxalic acid-hydrochloric acid solutions. 2) Moreover, neodymium oxalates were directly precipitated from organic solutions of tertiary aliphatic monocarboxylic acid and 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester using aqueous oxalic acid solutions, and powder characteristics of the resulting oxalates were compared with those of powders by the conventional solvent extraction routes. 3 • 4) Recently, attention has been directed towards the influence of processing parameters on the particle size distributions of yttrium oxalate precipitates. 5)"

Jan 1, 2000

By James Green

It has often been said that the best contracts written are by people who are suspicious of each other. The Spanish philosopher, Ortega y Gasset, said: "Every contract is an Act of Distrust." The arena for dispute settlement outside of the courts is increasing day by day - contracts, especially construction and civil engineering contracts, are written containing arbitration clauses for settling disputes - the very drafting of standard forms of contract, do in some instances by their very construction, create an ambiguity as to intent and provide a breeding ground for dispute. I come from a land far across the sea - the most southern land before the South Pole. Being a young country, 150 years old, we are still progressing - being far removed from the trouble free zones of the world and nuclear free we enjoy a lifestyle second to none.

Jan 1, 1987

By Dominic T. Jordan, Quinn G. Reynolds, Christopher J. Hockaday, Ian J. Barker

A direct-current (DC) plasma arc furnace is a type of electric furnace used for metallurgical operations. The successful operation of DC furnaces depends to a large extent on gaining a fundamental understanding of the arc phenomenon itself, and ensuring its presence in the furnace at all times. A method for detection of the presence of the arc in a DC circuit is presented, along with discussion of why this may be of value for certain modes of furnace operation such as brush-arc. The theoretical development of the method is presented along with supporting experimental work conducted on large-scale pilot-plant facilities.

Jan 1, 2014

By H. M. FRENCH

ARC welding can be defined as a process whereby two A pieces of metal are brought together, heated to a molten state by the heat of an electric arc, and fused into one piece. There are several kinds of arc welding: the metallic arc, the carbon arc, the atomic hydrogen arc and the shielded arc methods. A short description of each, together with its major applications, will serve to distinguish between them. Metallic arc welding involves an arc drawn between a metal electrode and the material to be welded, called the work or the "parent metal." It may be further subdivided into hand and automatic welding, depending on whether the electrode is fed to the arc by hand or by motor drive. This form of arc welding can be applied to most welding operations. Exceptions to its use consist of applications where very thin metals are to be welded; where it is desired to join the work with- out adding metal; or where extreme ductility may be required:

Jan 1, 1930

By Wolfgang Linden

One of the most important factors in successful electric steelmaking is the continuous observation of the process and the reaction to it. Traditional electric arc furnace control uses mainly direct controls which are based on the electric power input. Not considering the furnace conditions will necessarily lead to suboptimal operation in terms of energy consumption and productivity not fully utilized.The ARCCESS FEOS (Furnace Energy Optimization System) includes the simultaneous control of the transformer tap, impedance operating point, reactor tap, burner and carbon injection, and DRI charging control. FEOS has proven in practical operation benefits of high melting yields, no interruptions through switch offs in borderline temperature area, rapid reaction, reproducible and efficient electrical energy input and short power-on times.

Jul 30, 2018

By Andreas G. Mueller

Gold-silver and copper-gold deposits with high-temperature wallrock alteration of Ca-Mg-Fe-Al silicates occur in ca. 3.0 Ga old greenstone belts of the Yilgarn Block, Western Australia. The deposits are hosted by amphibolite-facies komatiites, basalts and BIF, controlled by ductile shear zones and located within the contact-metamorphic aureoles of composite granodiorite-granite batholiths. Disseminated sulfides and free gold form foliation-parallel ore zones in a gangue of anhydrous silicates (garnet, clinopyroxene, olivine), hydrous silicates (amphibole, biotite) and calcite. The deposits may be classified on the basis of their dominant economic metals as: 1(1) Gold skarns with substantial silver as by-product, represented by the Marvel Loch mine (production: 2,200,000 t at 3.5 g/t Au), and characterized by the mineral association pyrrhotite, loellingite, arsenopyrite, galena, gold and magnetite. (2) Gold skarns with low silver contents, represented by the Nevoria mine (production:1,850,000 t at 3.4 g/t Au), and characterized by the mineral association pyrrhotite, chalcopyrite, arsenopyrite, gold, Bi-tellurides and magnetite. (3) Copper-gold skarns, represented by the Elverdton mine (production: 850,000 t at .7 5 Cu, 0.81 g/t Au), and characterized by the mineral association magnetite, chalcopyrite, pyrrhotite, pyrite, gold and Ag-Bi tellurides.

Jan 1, 1990

By R. W. Hodder

"Archean lode gold deposits of both vein and chemical sedimentary types typically have major enrichments of certain rare elements, including Au, Ag, As, Sb, B, W, Se, Te and Bi, coupled with low or negative enrichments of the more abundant and mobile base metals, Cu, Pb and Zn. On the other hand, in massive base metal sulphide deposits Au, Ag, Cu, Zn and in some instances Pb are all enriched by a factor of 200 to 2000 t:'Jf'1pared to background and there is no large separation of gold relative to the base metals.The fluids from which gold was precipitated in veins were at temperatures of 320 to 480°C, at lithostatic pressure, had significant C02, and Na """" K; whereas the fluids which generated base metal deposits were at 250-300°C, at hydrostatic pressure, had C02 < < H20 and Na > > K.Many lode gold deposits are characterized by K, C02 and Si additions to their enveloping rocks, whereas base metal deposits typically have a fixation of Fe, Mg, Si and S in footwall rocks. Lode gold deposits may also have a relatively large halo of low-temperature oxidative, sadie spilitization in enclosing volcanic rocks, where seawater has later streamed into cooling stocks or flows that have initially acted to focus gold mineralizing fluids along thermal contraction fractures. The submarine environment is one hydrologically appropriate for the mixing of two initially independent hydrothermal systems, and the blending of their separate characteristics. Hence, lode gold and base metal massive sulphide deposits appear to be products of two distinctly different crustal and hydrological regimes. The former involves a high-temperature, high-pressure discharge of fluids which probably were generated during dehydration accompanying burial and progressive accumulation of volcanic-sedimentary sequences, with an additional influence of marine water in the near-sea-floor environment. The latter represents thermally driven convection of ocean water at lower temperatures and under hydrostatic conditions.Auriferous fluid systems with only minor base metal content could plausibly be generated during dehydration accompanying burial and metamorphism, when the water-to-rock ratio is low and halogen availability is limited by crustal abundance (- 60 ppm Cl). These two factors may constrain the uptake of the abundant base metals into fluids, but the solubility of rare elements is not constrained by limited fluid; and preferential uptake of Au along with other rare elements may be promoted if such elements compete more successfully for the limited halogens than the base metals, and/or have an alternative complexing agent such as CO or C()j-."

Jan 1, 1982

By A. J. Hynes, Lutes. G. G., Ravenelle. J. -F.

"The Anomaly A area of the Clarence Stream gold deposits in southwestern New Brunswick contains mineralized structures that bear geometrical relationships to regional folding events. The four mineralized zones of Anomaly A (AD, MW, 93, and Murphy) are hosted by turbiditic graywacke, quartzose wacke, siltstone, and argillite sequences of the Kendall Mountain Formation. A regional scale structural analysis reflects at least four deformational events, three of which appear to control the folded geometry of Anomaly A (D2, D3, and D4). F2 and F3 folds are coaxial and are refolded into a dome and basin geometry by F4 folds. The mineralized zones are subparallel to axial surfaces of F2 folds. Structural analysis of a mineralized zone exposed at surface indicates that gold mineralization is hosted by a quartz-vein system that comprises veins generated during both D2 and D3. Threedimensional representations of Anomaly A created using drill-core data and ®GoCAD suggest that the quartz-vein system was emplaced in fault structures during D2 as well as within brecciated dilation zones during D3. Three of the four zones that make up Anomaly A have F2 hinge surfaces that can be linked through a geometry compatible with the style of F3 and F4 folds. The apparent continuity of these three zones indicates the potential for kilometer-scale mineralized structures at Anomaly A. Le secteur de l’Anomalie A du gisement aurifère Clarence Stream contient des zones minéralisées qui montrent des relations géométriques avec les épisodes de déformation régionale. Les quatre zones minéralisées de l’Anomalie A (AD, MW, 93, Murphy) sont comprises dans une séquence turbiditique composée de grauwacke, de wacke quartzitique, de siltstone, et d’argilite appartenant à la Formation de Kendall Mountain. Des quatre épisodes de déformation étudiés par l’entremise de cartographie structurale, trois semblent contrôler la géométrie de l’Anomalie A (D2, D3, et D4). Les plis P2 et P3 sont coaxiaux et sont replissés en dômes et bassins par les plis P4. Les zones minéralisées sont subparallèles aux plans axiaux des plis P2. Une analyse structurale effectuée sur une zone minéralisée exposée à la surface indique que la minéralisation aurifère est localisée dans un système de veines de quartz qui contient des veines générées durant D2 et D3. Des représentations en trois-dimensions créées avec le programme informatique ®GoCAD à partir de données de forages suggèrent que le système de veines est localisé dans des zones de failles D2 ainsi que dans des zones de dilatation associées avec D3. Trois des quatre zones qui forment l’Anomalie A possèdent des plans axiaux P2 qui peuvent être liés par l’entremise d’une géométrie qui respecte le style des plis P3 et P4. La continuité apparente de ces trois zones indique qu’une structure minéralisée pourrait s’étendre sur plusieurs kilomètres dans le secteur de l’Anomalie A."

Jan 1, 2008

By Jeff Starchuck, Harald Kullmann

"In 2005, an inspection showed that the Deception Bay Wharf in the Canadian Arctic was at the end of its service life. Although Deception Bay is closed with landfast ice up to 5 ft thick, shipping operations continue year-round, with additional voyages in the summer open-water season to supplement mine supplies. The rehabilitation scheme that allowed minimal interruptions to shipping involved concrete caissons cast on barges and an ingenious placing system.WorleyParsons Westmar of Vancouver, B.C., performed the inspection under contract to the owner, Xstrata Nickel, Montreal, Quebec. The wharf, on the coast of the Nunavik region of Quebec, was originally constructed in 1971 for an asbestos mine, and is now used to support Xstrata’s Raglan nickel mine, importing fuel for p o w e r g e n e r a t i o n a n d general mine supplies, and exporting nickel concentrate to smelters in the south. Emergency repairs were essential to allow operations to continue at the site, while the parties considered permanent rehabilitation options and secured funding. The repairs were done in the openwater seasons, and included reinforcing the failed interlocks above water level with steel patch plates and injection grouting of the cell fill below the port crane in 2005. In 2006, workers installed a circumferential belting system below water level.Westmar held critical planning sessions with the mine operation personnel to find ways to stretch the limits of the mine supplies and nickel storage facilities. In the end, the parties agreed to shut down construction activities four times during the ice-free season to allow access to the dock site.Westmar developed a plan that allowed mine operations to continue during construction, and Xstrata approved the plan and budget in September 2006, for execution in 2007. Rapid construction was essential. To accommodate the short construction season and maintain minimum levels of service for the mine, the work was radically different from conventional Arctic deep-sea port construction. Like the original Deception Bay Wharf, construction practice was to use steel sheet pile circular cells with the consequential heavy support services for the labour force. Construction duration was typically two seasons. The plan for Deception Bay was executable in one season based on a concrete caisson structure. Only a modest amount of schedule float was needed."

Jan 1, 2009

By Donald E. Wakefeld

"The pace at which mining will occur in Northern regions and Arctic lands will depend on the answers to a number of questions. Who are the local aboriginal participants? What land uses are they pursuing? What are their objectives? What is their understanding of the process of mining development? This paper will focus on the last question, communicating the process of mineral development to local aboriginal communities.IntroductionIn the environmental impact hearings for the BHP-DiaMet diamond mine, the smaller Dene Treaty 8 Nation argued for the settlement of its Land Claims as a pre-condition to development. However, the larger Dene Treaty 11 Nation were prepared to permit the mine to proceed on the basis that their people would receive benefits during the construction and operation of the mine.Wherever mining is the significant basis for tax revenues and economic development expectations may be encouraged beyond the realities of the situation. Izok Lake has been known for several decades as a significant mineral deposit but because of its size and the transportation costs involved, it is now a “frozen” ore body. The extent of its mineralization at current metal prices will not support the mining and processing costs without substantial government support for infrastructure and roads. At the opposite side of Canada, Voisey’s Bay clearly satisfies all technical criteria but, nonetheless, two Inuit groups, the Innu, and Métis, have all made LandClaims relating to the mine area.Contrasting the mineral deposits at Voisey’s Bay and Izok Lake emphasizes that the timing of production is dependent on factors such as the grade and amount of reserves, their market price, location and availability of government support. Nonetheless, it is this author’s thesis that given an economic orebody the next most important factor is good communications. It is his view that Arctic mineral development will occur quickly only where good communication has resulted in the trust and mutual respect necessary to implement the mammoth cultural changes required."

Jan 1, 1996

By Natalia Konstantinova, Kira Mizell, James R. Hein, Georgy Cherkashov, Amy Gartman, Mariah Mikesell

"Two types of metallic deposits have been found in the deep Arctic Ocean: Hydrothermal Fe, Cu, and Zn sulfide deposits form along Gakkel Ridge in the Eurasia Basin and associated ridges between Greenland and Europe; and iron and manganese oxide crusts (Fe-Mn crusts) and nodules, precipitated from seawater onto rock surfaces in the Amerasia Basin, contain many rare metals of economic interest. Fe-Mn crusts and nodules collected in the Amerasia Basin during 2008, 2009, and 2012 cruises on the USCGC icebreaker Healy are characterized by unique mineral and chemical compositions, very high Fe/Mn ratios, fast growth rates, and other unique characteristics compared to those formed elsewhere in the global ocean. These characteristics reflect temporal and spatial variations in geological, oceanographic, and climatic conditions in the Arctic Ocean and surrounding continents over the past ~15 Myr.RESULTS AND CONCLUSIONSDiscrimination diagrams show that the crusts and nodules found in the Amerasia Basin north of Alaska are hydrogenetic. However, the mineralogy is not typical for hydrogenetic Fe-Mn crusts and nodules, which usually include only amorphous Fe oxyhydroxide and ?-MnO2 (vernadite). The Arctic samples also include the Mn oxides birnessite and 10Å manganates (todorokite, buserite, asbolane), and the Fe minerals also include goethite, lepidocrocite, feroxyhyte, and ferrihydrite. This mineralogy reflects formation under lower oxygen conditions than typical for samples formed elsewhere.The Amerasia Basin crusts have a unique chemical composition compared with crusts from other areas of the global ocean. The key difference is the high Fe contents relative to Mn contents, which determines the types of trace metals hosted by the Fe-Mn oxide phases, and their concentrations. The high Fe/Mn ratios reflect the expansive continental shelves (>50% of the Arctic Ocean) and upper slopes that support redox cycling and release of Fe and other metals to bottom waters, and to the large fluvial input from North America and Siberia. Brine formation on the shelves and currents promote the distribution of the metals throughout the Amerasia Basin, including the deep basins."

Jan 1, 2017

By I. M. Ritchie

Cyanide owes its great success as a lixivant for gold to the great strength of the Au-CN bond. A replacement for cyanide must similarly be a strong complexant for gold (I) or gold (III). The various alternatives are briefly considered and it is concluded that only thiosulfate has a reasonable chance of replacing cyanide as a relatively non-toxic lixivant at the present time. However, there are considerable technical problems to be overcome before thiosulfate can be considered to be a realistic alternative to cyanide. Firstly, the leaching of gold using aerated ammoniacal thiosulfate with copper as a catalyst is a complex process which needs to be understood and controlled carefully in order to achieve maximum recoveries with minimum reagent losses. Secondly, there needs to be an option similar to the CIP process for recovering and concentrating the dissolved gold thiosulfate complex from pulps produced in the processing of low grade gold ores. The prospects for overcoming these technical&apos; challenges are evaluated and discussed.

Jan 1, 1998

By Hugo E. Camargo, Amanda S. Azman, Brian Kim

Repeated noise exposure and occupational hearing loss are common health problems across industries and especially within the mining industry. Large mechanized processes, blasting, grinding, drilling, and work that is often in close quarters put many miners at an increased risk of noise overexposure. In stone, sand, and gravel mining, noise is generated from a variety of sources, depending on the type of ore being mined as well as the final consumer product provided by that mine. Depending on the source of noise generation, different strategies to reduce and avoid that noise should be implemented. The National Institute for Occupational Safety and Health (NIOSH) has evaluated the noise profile at three operational surface stone, sand, and gravel mines. A-weighted sound level meter data as well as phase array beamforming data were collected throughout the mines in areas with high noise exposure or high personnel foot or vehicle traffic. Sound level meter data collected on a grid pattern was used to develop sound profiles of the working areas. These sound contour maps as well as phase array beamforming plots were provided to the mines as well as guidance to modify work areas or personnel traffic to reduce noise exposure.

Jan 6, 2022

By M. Schwartz

Mining in Argentina is diverse in terms of the number of minerals extracted from the country, but also in terms of the varied approaches and attitudes of mining investors and their trust in the country's individual provinces. Laws are discussed, investment attractiveness and taxation.

Jun 1, 2015

Arizona Bureau of Mines and College of Mines and Engineering, University of Arizona, Tucson, Ariz. Lists of the maps and bulletins available will be sent upon request to G M Butler, Director, Arizona Bureau of Mines, Tucson, Ariz Bulletin 119, A resume of the geology of Arizona, by N. H Darton, is sold for $1, postpaid Fourteen other bulletins, any five of which may be had free of charge (additional numbers may be purchased for 10 cents each) are available as follows - 106, A geological reconnaissance of the Tucson and Amole Mountains, by Olaf P Jenkins and Eldred D Wilson, 114, Fluorspar, by M A Allen and G M Butler, 120, Gold and copper deposits near Payson, Arizona, by Carl Lausen and Eldred D Wilson, 122, Quicksilver resources of Arizona, by Carl Lausen and E D. Gardner, 123, Geology and ore deposits of the Courtland?Gleeson region, Arizona, by Eldred D Wilson; 125, The mineral industries of Arizona, by J B Tenney, 126, Asbestos deposits of

Jan 1, 1933

By Charles T. Steuart

The Arkansas Novaculite of Devonian and Mississippian age is the most distinctive formation in the central Ouachita Mountains of Arkansas from the standpoint of both topography and lithology. The formation typically forms precipitous, narrow ridges (hogbacks) which reflect the steepness of dip and the resistance and thickness of the rock units. The Arkansas Novaculite varies from less than 200 feet thick in the north to locally over 800 feet thick in the south and outcrops over an east-west distance of 360 km (200 miles) in the Ouachita Mountains of Arkansas and Oklahoma. Most of the rocks of the formation are highly siliceous with novaculite predominating, and lesser quantities of chert, siliceous shale, conglomerate and rarely sandstone. Novaculite is commonly defined as a homogeneous mostly white rock, translucent on thin edges with a dull to waxy luster and composed almost entirely of microcrystalline quartz. The word novaculite comes from the Latin word novacula, meaning razor hone. This term was first used by Richard Kirwan in his mineralogy text of 1784. The origin of novaculite remains controversial but we believe it was a primary silica derived mostly from the alteration of submarine volcanic-rich materials, with numerous fine biogenic components and some minor clastics (derived mostly from foreland facies via turbidity currents) and deposited as an amorphous siliceous ooze in the deep Ouachita trough. It was subsequently converted to microcrystalline quartz during diagenesis by the compaction of the overlying rocks and the intense Late Paleozoic Ouachita Mountain tectonism. In the central and southern portions of the region three divisions of the formation have been defined: a Lower Division predominantly of light-colored novaculite; a Middle Division of interbedded dark chert and shale; and an Upper Division of massive often calcareous novaculite. In the northern exposures the formation is thinner and contains more black chert and shale, chert-shale conglom¬erate, sandstone and less novaculite. The massive novaculite of the Upper and Lower Divisions is a source of high purity silica (99+%). Indians were the first to use novaculite. They made their various tools and hunting implements from the weathered broken rock until they learned the quarrying techniques. The first white men in the area recognized the use of novaculite for sharpening their tools and knives: previously whetstones were obtained in small quantities from Europe. To this day whetstone is quarried mostly in areas which the Indians and possibly the Spanish previously worked. Some of the current mining practices have changed very little from those of the early quarryman. In areas where the novaculite of the Upper Division is poorly cemented, this friable tripolitic material has found applications in such uses as an abrasive, as a filler or extender in paints, plastics and other purposes. Some of the dense novaculite is suitable as a filler in fire bricks and also in plastics. Because some of it has the tendency to decrepitate when heated not all novaculite can be used for these applications. Several quarry operators are crushing novaculite for road, concrete, and other aggregate. This use was formerly rather limited due to the abrasiveness of the novaculite on crushing and screening equipment. Further potential uses of novaculite are speculative but include application of high purity silica in the production of silicon metal for solar cells, seed or "growing", and fusing quartz for electronics.

Jan 1, 1985

Arkansas Geological Survey, Rooms 443-447 State Capitol, Little Rock, Ark George C Branner, State Geologist A list of available publications will be sent upon request Publications issued by the U. S Bureau of Mines, U S Geological Survey and Oklahoma Geological Survey, pertaining to&apos; Arkansas, are also available through this Survey office. Annual Reports may be had for the following years. 1890, 3147, 1891, 81 35; 1892, $1 10 Other available publications: The slates of Arkansas, by A H. Purdue, with a bibliography of the geology of Arkansas by John C Branner (1909), $1.10, Coal mining in Arkansas, pt 1, by A A Steel (1910), 3175, An outline of the physical features of Arkansas, by George C Branner (1927), free, An outline of the metallic minerals of Arkansas, by George C Branner, free, Bulletin 3, The geology of the Arkansas Paleozoic Area, by Carey Croneis (1930), $3 20, Bulletin 4, St Peter and older Ordovician sandstones of northern Arkansas, by A W Giles (1930), $1 95, Bulletin 5, A geomagnetic survey of the bauxite region of Arkansas, by Noel H Stearn (1930), 80 cents, Information Circular 1, A barite deposit in Hot Spring County, by B Parks and George C Branner (1932), $1, Information Circular 2,

Jan 1, 1933

By R. Weber

Methane explosions in underground coal mines are a major concern across the mining industry. After the Pike River disaster, Arnot Coal became even more aware of the explosion risk. To determine whether Arnot has adequate precautions against a methane explosion, such as the one that led to the Pike River disaster, a literature survey covering the causes of the incident and what preventative measures should have been in place was conducted. Many different methane explosion prevention methods were evaluated, as well as codes of practice. Based on the findings, Arnot?s measures to prevent conditions favourable for a methane explosion were evaluated.

Jan 1, 2014

By Gavin Beer

The Chelopech Copper/Gold Mine, located in west-central Bulgaria, has been in operation since 1953 producing a low-grade copper/gold concentrate containing up to six percent arsenic by weight. The penalties and restrictions imposed on smelting this concentrate, have seen the past operators of the mine strive to find a balance between achieving acceptable metal returns from the smelters and installing novel or unproven technologies in the face of changing political and economic climates. This paper documents the colourful history of the concentrate processing alternatives that have been investigated and implemented over the 45 year life of the Chelopech Mine, culminating in the high pressure oxidation option that is now the focus of a Definitive Feasibility Study (DFS) presently being undertaken by GRD Minproc Limited. The fundamental chemistry of the preceding alternatives is outlined followed by a discussion as to why each was ultimately not employed. A detailed description of the technology proposed in the DFS is given including: pressure oxidation, arsenic fixation, SX/EW copper recovery, CIL gold recovery and AVR/SART cyanide/copper recovery processes. Keywords: Arsenic, Scorodite, HPOX, Chelopech, Dundee

Jan 1, 2005

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019