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By Malcolm T. Wane

The subject matter of this paper, "Applied Rock Mechanics?," has its genesis in a recent field trip taken by the author. A more or less standard question asked at the mines visited was "How are you using the principles of Rock Mechanics to assist you in maintaining an efficient, safe, and competitive mining operation?" The question was couched in a number of different forms, but the intent was to determine whether or not a general theory based on reason and the scientific method was applied or whether the alternatives of tradition, intuition, ?common sense', revelation, ?shotgun methods' or authoritarianism were invoked. Perhaps two responses to this query will be illustrative of the general nature of the replies. At operation XYZ an extension to the known ore body has been found. The extension is of large enough size and grade that a mining scheme using load-haul-damp techniques is envisaged. Since this represents a departure from the present mining scheme, questions have arisen regarding pillar sizes, room and entry sizes and possible support requirements. A task force has been set up to expeditiously plan for these things and write the necessary specifications and requirements. The fundamental question was posed to members of this group.

Jan 1, 1971

By H. Matsuoka, M. Kawata, K. Haga, K. Mitsuhashi, C. Tokoro, A. Shibayama, R. Kawarabuki

"The mineral surface characteristic is important for the flotation because it affects the flotation behavior of the mineral. Conventionally, in the flotation process for Cu sulphide ores, the degree of ore floatabilities varies depending on the mineral phase such as chalcopyrite, bornite, or chalcocite. Therefore, mineral surfaces are treated with activators and depressants to control the floatability of target minerals and obtain high recovery performance. There are lots of flotation reagents which have many effects on ores depending on ore characteristics and conditioning methods. For example, sodium hydrosulphide (NaHS) as activator is known to have the effect of resulfurizing and activating oxidized surface of chalcocite and bornite. On the other hand, NaHS is reported to depress chalcopyrite floatability. In this study, the evaluation of mineral surfaces was conducted to predict flotation behavior. Activation of Cu minerals (chalcocite, bornite, and chalcopyrite) by NaHS was experimented. The three Cu minerals were treated in two steps. Firstly, they were oxidized in the drying oven. Secondly, they were treated with NaHS solution. After each treatment step, each mineral was measured by contact angle apparatus then analyzed by X-ray photoelectron spectroscopy (XPS). The results of surface characteristics after oxidation and NaHS treatment were utilized to accomplish the study’s objective. INTRODUCTIONCopper sulfide minerals such as chalcocite (Cu2S), bornite (Cu5FeS4), chalcopyrite (CuFeS2) are well-known abundant copper-containing minerals. Generally, these minerals are recovered and concentrated via collector flotation. In flotation, the wettability of the mineral surface is an important factor in its recovery. When the surface is hydrophobic, the mineral has high floatability and when the surface is hydrophilic, it has low floatability. Usually, Cu sulfide minerals have high floatability. However when their surfaces are oxidized, their floatability becomes lower in flotation. In this case of surface oxidation occurrence, activators are added before flotation to modify the surface property of the Cu sulfide minerals so that they can be floated at a certain flotation condition. Sodium hydrosulfide, NaHS, is known as one of the activators. Zhao et al. (2018) reported that NaHS is often used as sulfurizer for oxidized sulfide minerals (Becker et al., 2014, Clark et al., 2000, Newell et al., 2006, 2007, Newell and Bradshaw, 2007). Although the floatability of Cu sulfide minerals was raised by adding NaHS generally, the results of this flotation study showed that the flotation behaviors of mixed chalcocite, bornite, and chalcopyrite were different. Therefore, it was considered that NaHS works differently for each mineral."

Jan 1, 2018

Over the last four years, a major collaboration between CSIRO-MIS, UCT and JKMRC has produced two significant advances in the modelling of comminution. The Universal Comminution Model (UCM) uses parametric SPH/DEM studies of comminution and separation devices to calibrate mathematical models which are suitable for industrial use. The Virtual Comminution Machine (VCM) uses the same computationally intensive techniques based on discrete element modelling (DEM) and smoothed particle hydrodynamics (SPH) to directly model any comminution device by combining a CAD file describing the machine design, sophisticated ore characterisation methods and advanced particle scale flow and breakage simulation. The UCM should be useful for process analysis and optimisation of existing equipment and circuits while the VCM should make a major contribution to the evaluation and development of new machines. Progress to date is encouraging with several processes now well described using DEM. This paper also reports on progress towards combining DEM for particles with a realistic slurry model based on SPH for different types of comminution devices. In due course, this combination should allow accurate modelling of particle transport in wet mills to be combined with DEM models.

Jan 1, 2014

By I Villalba

The need to continue the development of the Ensham mine has led to blast up to 75 m to the Eastern side of a water dam in the vicinity of Ramp 23. The water dam wall is exposed to blasting over a distance of approximately 500 m. The first decision was to determine that the existing rock pillar between the Eastern side of the water dam and the blasting operations may not be less than 75 m in order to minimise the damage that the blast could generate to the dam wall. It was also necessary to define blasting practices to minimising the blast damage to the rock properties of the dam wall and to avoid adverse effects from vibration and gases generated by the detonation on structures.For this purpose analytical designs and test blasts were conducted to assess the ground vibration attenuation within the rock pillar. From this analysis, it was concluded that the best practice to reduce the rock damage was to create a zone of fractured rock adjacent to the side of each production blast. This fractured zone would create an effective filter both for vibration and for gases generated by the blast. This zone of fractured rock was created by firing two buffer rows. In terms of pattern size and powder factor the two buffer rows were designed just to generate a fractured rock zone. To date approximately 500 m have been excavated along the eastern wall of the water dam where each production blast was preceded by a Trim blast. This practice has given good results with regard to minimising the damage generated by production blasting.

Nov 8, 2011

By R Morrison, P Walters, B Adair, V Jokovic

‘Grade Engineering<sub>®</sub> is an integrated approach to coarse rejection that matches a suite of separation technologies to ore specific characteristics and compares the net value of rejecting low value components in current feed streams to existing mine plans as part of a system-view’ (Walters, 2017). Two of these technologies are directly recoverable through screening stages: Natural Deportment and Induced Deportment. The potential for taking advantage of “Natural Deportment” by size following blasting and crushing has been demonstrated for a range of ore types. Simple and low cost screening can in some cases generate a fine product with improved grade and a lower grade oversize which can be directed to leach or to waste. Where an ore body consists of many different ore types, the traditional approach of blending to metal grade will often add to complexity of treatment, which will reduce the effect of “natural deportment” by size.CITATION: Jokovic, V, Walters, P, Adair, B and Morrison, R, 2018. Applying enhanced grade engineering to complex ore bodies, in Proceedings Complex Orebodies Conference 2018, pp 21–23 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By Q. Feng

Study has been carried out to apply fly ash as a high strength, water-resistant precast construction material through geopolymerization. Experiment results show that the working conditions such as water content, the concentration of NaOH, curing temperature and curing time, significantly affect the mechanical property of geopolymer matrix. Through optimization, an above 100 MPa compressive strength has been achieved with the geopolymerization products. Water soaking tests show that the geopolymerization product has a very high water resistance without losing noticeable compressive strength even after a one month soaking time. To elucidate the geopolymerization mechanism, microscopic techniques such as SEM/EDS and XRD are also applied to investigate the microstructure, the elemental and phase composition of geopolymerization products. The findings of the present work provide a novel method to apply fly ash as a high strength water-resistant precast construction material. INTRODUCTION Geopolymerization is a process of obtaining a polymeric structure from aluminosilicate by dissolving aluminosilicate sources in a strong alkali (NaOH) solution and condensation of free [SiO4] and [AlO4] tetrahedral units (Davidovits, 1985 and 1988; Duxson et al, 2005; Xu et al, 2000, 2002). After being cured at an elevated temperature for a specific time, the geopolymerization product shows a greatly increased compressive strength. Therefore, the product can be used as construction material such as bricks and road pavement. It provides a very promising method to apply aluminosilicate sources such as fly ash as a construction material for a sustainable development. Fly ash is a main industrial waste which needs to be carefully impounded because of its potential impact on environment. Many efforts have been tried to utilize fly ash as construction materials substituting Portland cement because of the following reasons. First, fly ash is a silica/alumina rich aluminosilicate source, which makes the specific material an ideal source for the geopolymerization process. Secondly, the particle size of fly ash is usually very small (< 50 microns) and it saves a lot of energy consumed during the production process of cement for grinding. Thirdly, fly ash is an ideal source for geopolymerization because it is reactive to alkali even at a mild temperature. In the past twenty years, many studies have been carried out on the geopolymerization of fly ash to a make construction material. However, there are some disadvantages associated with the conventional methods of treating fly ash (Palomo et al, 1999; Perera et al, 2007; Temuujin, et al, 2009; Hanjitsuwan et al, 2014). First, in most of the proposed geopolymerization methods, a salient amount of sodium silicate has to be added. It therefore makes it complex whether the achieved mechanical strength of geopolymerization products is due to a real geopolymerization process between fly ash and alkali or just largely the solidification of metal silicate in air at an elevated temperature. Secondly, the authors have noticed that when the geopolymerization product is soaked in water, the solution pH increases sharply and the products will lose its compressive strength gradually in water. Thirdly, the compressive strength of the geopolymerization product as reported is usually less than 50 MPa.

Jan 1, 2019

By S. Makni, G. Gagnon, F. Couët, C. Rochefort

"Comminution represents a significant part of mineral processing plant operating costs. Yet, autogenous (AG) or semi-autogenous grinding mills (SAG) are difficult to control because of disturbances like feed size distribution and rock hardness. AMIRA, within project GeMIII, developed a comminution index from laboratory crusher data. The index correlated with the Bond ball mill work index and with the A×b parameter. The present work extends the use of crusher data as a grindability indicator to real-time industrial applications. The aim is to improve comminution operation using online hardness estimation. Because the operational work index is proportional to the ore work index, rock hardness variations can be estimated from the feed and product size distributions, the throughput, and the power draw of a crusher. Real-time estimation of rock hardness can help understand the dynamic behavior of AG and SAG mills. Multivariate time series were analyzed to understand the impact of hardness on a SAG operation. Results showed that the estimated hardness influences the SAG operation and its throughput. Moreover, non-linear dimension reduction was used to ease the process visualisation and search for potential control strategies. In the future, online hardness measurements should also impact the understanding of comminution circuits and improve their operation.INTRODUCTIONThe variability in hardness, and the feed size distribution, are two of the main disturbances affecting comminution circuits (Sbarbaro & del Vilar, 2010). Size distribution can be measured by imagebased granulometry systems such as WipFrag (Maerz, Palangio, & Franklin, 1996), or by 3D vision systems when the fines are difficult to discriminate by 2D segmentation (Faucher, Makni, Gagnon, Lavoie, & Roberge, 2015).There are few examples of online hardness measurements. One example was the work of Casali et al. (2001) who developed a hardness indicator. The ore grindability soft sensor used the fraction of each lithological class in the ore, as determined by image analysis, to predict the work index of the material. The model was developed using a moving window with a width of 12 months and trends were shown over many years with one data point per month."

Jan 1, 2016

By J. E. De Waele, J. J. Lee, M. J. Mulheron, Luke R. Deamer

There is increasing demand for geotechnical contractors to commit to carbon reduction, net zero or science based targets. A lot of focus has therefore been placed on using low carbon materials and low emission rigs. However, whilst these are ways to help reduce carbon, there is a need to look beyond just substituting materials and fuels to meet net zero. Using the IEMA carbon hierarchy, there is a need to first look at eliminating and reducing emissions, before considering substitute materials. For example, in geotechnical designs, this may mean considering using ground improvement or reducing the number of piles, before considering using low carbon cements. Equally, for remaining emissions, this hierarchy means considering carbon negative products to offset emissions, such as ground source heat pumps. This hierarchy can also be applied throughout geotechnical contractor organisations. For example, considering video conferencing for meetings, before considering public transport or using an electric vehicle. This article explores the carbon hierarchy and how it can be applied to all areas of a geotechnical contractor’s business. Only through embedding this hierarchy across the business can geotechnical contractors achieve the step change required to meet net zero.

May 1, 2022

By Charles Tkaczuk

In order to remain competitive the mining industry must keep up with changes in technology. Many innovative technologies from the mining perspective are commonplace in other industries. A ?Global? review of technologies will often reveal existing technologies that can be innovatively applied in the mining industry. Industries, which are rife with proven solutions include, medicine, biotechnology, security, manufacturing, telecommunications, etc. This paper addresses the communications aspect of mining where greater productivity, lower costs and the ability to quickly react to mining related events is obtained through an increase in remote monitoring and operating control. A review of the communications systems in place globally reveals technologies that, with minimal modification, can be immediately applied to the mining environment. We discuss the concept, advantages and implementation of existing communications technology from an industry that is not usually associated with the mining industry. This technology will form the basis of a solid platform on which can be built a state-of-the-art process monitoring, control, and communication system. This lays the groundwork for providing one solution to the underground mining industry?s most difficult problem, establishing a reliable, maintainable and cost-effective underground bi-directional wired/wireless data, video and analog communications system. We need look no further than our own doorsteps to find such a solution. The cable that you see coming from the simple green or brown box on the boulevard into your home contains hundreds of television broadcast channels, FM radio channels and data channels. And if you have a set-top box, you are in control of it all. The Cable Television Broadcast Distribution System suppliers of today are at the leading edge of converging all the different methods of communications onto a common carrier, coaxial cable or fibre optic cable. There is no fundamental difference between providing a reliable communications network to a city/neighbourhood/home/personal computer than there is to a mining operation/underground level/equipment or person. The principle is the same. Only the application is different. Realizing this, we can capitalize on the efforts of other industrial sectors, to solve our communications problem. Where else can you find a solution to a problem that is mature, having been developed with the input of thousands of engineers, and having hundreds of millions of dollars spent on research and development, manufacturing, distribution, global presence and engineering support?

May 1, 2003

By J. Fisher, M. Barish

Over the past several years, Somerset International has successfully installed over 20 patented Sub325® Fine Coal Recovery Systems in the United States, Australia, Canada and Russia. These installations recover between 5 TPH and 40 TPH for the host sites. In addition to the increased revenue from the direct recovery of a recirculating load (Screen Bowl “Insurance”, Direct Recovery vs. Indirect Recovery via Recycle, CPSA 2020), host sites have seen benefits ranging from improved operation of refuse equipment to a reduction in the solids content of the refuse streams. As Somerset has improved ultra-fine coal recovery through the introduction of Sub325® Effluent Flotation and, most recently, the Sub325® Effluent Settler™, the amount of coal that has been recovered from these systems has increased by up to as much as 25%. Many host sites have taken a sense of ownership in the Somerset system and consider it to be a critical circuit in the overall optimal performance of the plant. In the past year, Somerset has taken the initiative to expand upon the capabilities of the Sub325® Fine Coal Recovery System, primarily the Sub325® Solid Bowl Centrifuge, to include Refuse Tailings Dewatering to allow for co-mingled refuse disposal. As slurry ponds and boreholes are becoming difficult to impossible to permit and operate, there is a need for a reliable, low-maintenance, continuous operation that can produce a handleable refuse cake. Refuse tailings disposal applications are by no means limited to coal plants and impoundments. Somerset has successfully tested at iron ore and phosphate locations throughout the world and have begun commercial installations. The ability to dewater -325 mesh material, whether it be coal, coal refuse, iron ore tailings, or something else, is a vital piece of processing capability for the continued production of mining operations across the globe. This paper highlights the success that Somerset has had in the coal industry worldwide as well as the initial successes with phosphate, iron ore, and copper tailings (patent pending).

Mar 2, 2022

By Y Lanwin

The Australian mining industry, a cornerstone of the nation’s economy, is on a journey towards greater equity and inclusion. Th paper introduces a comprehensive exploration of how universal design principles, stemming from architectural roots, have evolved through automation and digital technology into the more encompassing frameworks of inclusive design and equitable design. The paper proposes a practical framework for those involved in work, facilities and equipment design in the mining industry to identify and assess for equity and inclusion. Universal Design emerged in the 1960s with a primary focus on architecture, aiming to create spaces accessible to people of all abilities. Its foundational principles sought to ensure equitable use, flexibility, simplicity, perceptibility, tolerance for error, low physical effort and optimal spatial considerations. Over time, these principles evolved and expanded beyond physical spaces, finding applications in various fields, including technology, education and transportation. In response to advancements in technology and a growing understanding of the multifaceted nature of diversity, Universal Design evolved into Inclusive Design. Inclusive Design goes further than mere accessibility, considering a broader spectrum of users with varying cognitive, sensory, cultural and socio-economic backgrounds. It emphasises user centred design, customisation options, diverse user research and continuous iteration. Equitable Design emerged as a framework that addresses not only the diversity of needs but also systemic disparities. It emphasises fairness, justice and the elimination of structural inequities. Equitable Design encompasses accessibility and affordability, representation and diversity, ethical considerations and community engagement. This paper will explore the applications of these design principles through a series of case studies including village and on-site facilities, remote operations and office based work design and technology design. By applying these frameworks in a mining context, the paper proposes that mining companies and suppliers can improve diversity, equity and inclusion leading to safer, more engaged and productive workplaces.

Apr 16, 2024

By Alejandro Berrios, Matheus DaSilva, Erick Siqueira

Vazante mine is an underground polymetallic mine that produces zinc, lead, and silver, which belongs to Nexa Resources in Minas Gerais, Brazil. The mine, a sublevel stope underground mine, mainly applies two subvariants: VRM – Vertical Retreat Mining and Open Stope. In a specific place of the mine, the geology allowed the design of a production stope with larger dimensions than the standard stopes, commonly called Super Stope. At this place, the plan was to apply both sublevel variants simultaneously. This mining block comprises rings in two different levels, with access by two ore drives on each level; the dimensions would be approximately 50 meters high, 50 meters long, and 35 meters wide. Opening the Free Face to mine the whole Stope was a challenge due to operational issues, such as hazard risks from loading over void space, exposure to uncontained places, and the impossibility of implementing the optimal blast sequence. Wireless blasting initiators have gained popularity recently due to their convenience, safety, and efficiency. This initiation system was applied to preload all the rings required to open the Free Face, ensuring a safe and optimal blast sequence. Wireless initiation prevented hazard risks, enhanced the blast sequence to guarantee the required void space, and optimized the equipment's operational cycle. The blast crew carried out the activity without exposure to the risk of loading over void space. The wireless detonators also avoided after-blast activities, which were required to provide secure access to the blast crew, optimizing the operational cycle.

Jan 21, 2025

By S. Angioletti

This paper addresses strategic investment decisions when they are nested in a project development format where each project is implemented in phases and each phase is approved to move on to the next phase only if certain technical and economic requirements are met. This configuration is sometimes referred to as a ?Project Portfolio?. Mining companies maintain project portfolios in their exploration investment plan. This study proposes a procedure to best manage an exploration project portfolio including technical and economic uncertainties. The procedure may support decision makers in a simple and intuitive way, while maintaining the rigor and precision required by the rather large amount of financial resources typically called for by mining projects. The procedure was tested in a real case study of a gold mining company and its exploration projects portfolio. The procedure uses the following approaches: i) investment valuation methods under technical and market uncertainties based on Option Pricing Model, Real Option Theory and Option Space; ii) portfolio management and Stage Gate®1 method; iii) Monte Carlo simulation.

Jan 1, 2010

By J. J. Davis, C. A. J. Fletcher, M. Li, T. Jancar

This paper summarises the experimental approach to spiral modelling at the Julius Kruttschnitt Mineral Research Centre, University of Queensland, involving the use of plastic density tracers to determine partitioning performance on three models of coal spiral. This work has led to phenomenological models of the three spiral profiles most widely used in the Australian coal industry. The results from a parallel computational fluid dynamics approach to spiral modelling currently underway at the University of New South Wales are also presented. The computational simulation has been successfully applied to generic spiral geometries and is capable of predicting the fluid phase three dimensional flow fields and corresponding free surface profiles for moderate Reynolds&apos; number and Froude numbers. Simulation predictions are compared with experimental results from a Mineral Deposits LD9 coal spiral.

Jan 1, 1995

By M. Araos

Non-ideal explosives can be characterised by different methods like velocity of detonation measurement, double pipe tests, underwater tests, aquarium tests, etc., to name a few. Both aquarium and velocity of detonation tests were selected to characterise a non-ideal explosive that is based on hydrogen peroxide, fuel, and void sensitisation. The detonation process in an aquarium of this sensitised explosive was captured at 80,000 frames per second using a high-speed camera. The explosive product was detonated using 51mm (2inches) diameter acrylic pipe charges. The product was detonated at different densities in an aquarium (cube box containing water). An aquarium provides a homogenous confinement for the detonation of explosives and more importantly, allows observing the shock wave as it changes the refraction index of water. The analysis of the video footage allowed the calculation of the velocity of detonation, pressure, gas rate release, and how the shock wave's shape in water changes with densities. It is suggested that the calculation of the rate of gas release could be related to the bubble data obtained from underwater tests.

Jan 1, 2024

By Ann E. Visser

Aqueous Biphasic Systems (ABS) form upon the admixture of certain water-soluble polymers or polymers and salts above critical concentrations, and thus represent liquid/liquid extraction systems whose nature is entirely aqueous. We are currently investigating the utility of ABS (and its solid phase analogs) as "green" alternatives to the use of volatile organic diluents in separations of metal ions. Chaotropic (water-destructuring) metal ions with small negative AGhyd (e.g., Tc04) tend to partition quantitatively to the PEG-rich phase of an ABS, but even hydrated metal cations can be partitioned to the PEG-rich phase if a suitable extractant (e.g., halide, dye, crown ether, etc.) is used to produce a more chaotropic ion-complex.

Jan 1, 1999

By D. J. Chaiko

Certain radionuclide ions (e.g., TcO4) exhibit unusually strong Affinities toward the polymer-rich phase in aqueous biphase systems generated by combinations of salt solutions with polymers such as poly(ethylene glycol) (PEG) and poly(propylene glycol) (PPG). Thus, aqueous. polymer ,phases could potentially be used to selectively extract these ions during pretreatment of radioactive tank wastes at Hanford. To help develop a fundamental understanding of the interactions between various ions and polymers in aqueous solution, interaction enthalpies between sodium -perrhenate and a random copolymer of PEG and PPG (UCON-50) were measured by microcalorimetric titration. An entropy compensation effect was observed in this system in which changes in enthalpic interactions were balanced by entropy changes such that the interaction free energy remained constant and approximately equal to zero.

Jan 1, 1999

By James A. Voigt

"The efficient separation of metal species from aqueous streams by precipitation techniques requires a fundamental understanding of the various processes that occur during precipitation. These processes include particle nucleation, particle growth by solute deposition, agglomerate formation, and agglomerate break-up. The application of the population balance approach has been used to develop a kinetic model that accounts for these competing kinetic processes. The usefulness of the model is illustrated through its application to the precipitation of yttrium hydroxynitrate, YHN. The kinetic parameters calculated from the model equations and system specific solution chemistry are used to describe several aspects of the effect of pH on the precipitation of the YHN. Implications with respect to the simultaneous precipitation of more than one cation type are also discussed through use of example systems. The effects of solution chemistry, precipitator design, and solvent choice are considered.IntroductionThe application of precipitation technologies to the separation of metals from solution is widely used. Regardless of its application, be it in such diverse areas as the preparation of metal oxide powders for use in commercial products or as a unit operation in the removal of trace metals during wastewater clean up, the fundamental processes involved are the same. These processes include: nucleation from solution, either homogeneous or heterogeneous; growth from solution with chemical reaction either in solution or at the precipitate/solution interface; growth by particle agglomeration; and particle break-up by collisional or shear forces. The effectiveness of the operation and the properties of the precipitate formed, or ""quality"" of the product, are determined by the competing kinetics of the different processes. The kinetics of the processes, in tum, are determined by system-specific solution chemistries and the conditions used to carry out the precipitation operation. For example, generally, when system conditions are such that the supersaturation driving force for precipitation is very high, growth species normally do not have the time to organize themselves with a high degree of crystallographic order and the precipitate is amorphous. In this case nucleation rates are invariably extremely high and the primary mechanism for growth is the agglomeration of nuclei. Conversely, when the supersaturation levels for the same system are reduced, the kinetics of the nucleation and growth processes also are greatly reduced, and a crystalline precipitate can be formed, since the growth species have time to order on particle surfaces."

Jan 1, 1996

By James A. Voigt

The efficient separation of metal species from aqueous streams by precipitation techniques requires &apos;a fundamental understanding of the various processes that occur during precipitation. These processes include particle nucleation, particle growth by solute deposition, agglomerate formation, and agglomerate break-up. The application of the population balance approach has been used to develop a kinetic model that accounts for these competing kinetic processes. The usefulness of the model is illustrated through its application to the precipitation of yttrium hydroxynitrate, YHN. The kinetic parameters calculated from the model equations and system-specific solution chemistry are used to describe several aspects of the effect of pH on the precipitation of the YHN. Implications with respect to the simultaneous precipitation of more than one cation type are also discussed through use of example systems: The effects of solution chemistry, precipitator design, and solvent choice are considered.

Jan 1, 1996

By G. Van Weert

Refractory gold ores and auriferous concentrates containing silver tend to form refractory silver jarosites during pressure oxidation. Earlier work with pure Ag2S has shown that the addition of iodine species to the autoclave feed yields cyanide soluble iodargyrite (Agl) instead. Near complete silver extractions from the autoclave product were obtained at a I-/Ag+ ratio of 5 or more. This paper reports on the pressure oxidation and cyanide leaching of two industrial refractory (arseno) pyritic silver-bearing concentrates: 1. from Peru (sulphosalts) and 2. from the USA (pyrite, with acanthite occlusions). While using a I-/Ag+ mol ratio of only 1 in the feed, it has been possible to obtain 98 and 97% Ag extraction from the two autoclave products by cyanide leaching, respectively. This compares to 11 and 54% Ag extraction from the as-received concentrates and 4 and 15% Ag extraction, respectively, after pressure oxidation without KI present. The results of the testwork are discussed in terms of concentrate mineralogy and pressure oxidation conditions.

Jan 1, 1994