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By Horace Freeman

"IN THE writer's opinion, the most important industrial re-search problems in Canada concern development of technology for the treatment and commercial utilization of the recent discoveries of v.ast quantities of easily concentrated iron ores in both eastern and western Canada. They exist in both magnetite and hematite forms. The subject is doubly important because of the lack of metallurgical coking coal in Canada. Methods for utilizing our lower grade eastern and western coals for reduction purposes must be developed. We are fortunate in our supplies of oil and gas, which can supply the heat requirements for processing or for thermal electric plants, which are now competitive with hydro-electric plants in the industrial areas. These are among the reasons which have prompted the writer to continue the development of the co-current rotary kiln direct-reduction process outlined •in his report to this Institute at the 1956 Annual Meeting ( 1) in the face of the scepticism which has surrounded the numerous costly failures in 'sponge' or 'direct' iron production. The work involved in bringing the concentrating ores of Canada to the metallic state involves, firstly, concentration of the ores; secondly, preparing the concentrates for reduction; thirdly, reduction of the 'reconstructed' ore; and finally the steel making process. These briefly will be dealt with in order, giving emphasis to the most important of these steps, the reduction process which is the main subject of this paper."

Jan 1, 1959

By John F. Kearney

Labrador Iron Mines (?LIM?) Schefferville Projects consist of 20 major DSO deposits lying along a 120 km strike length in both the provinces of Newfoundland and Labrador and in Quebec. The town of Schefferville, Quebec lies close to the middle of this 120 km strike. LIM?s various properties comprise twenty different iron ore deposits which were part of the original Iron Ore Company of Canada (?IOC?) direct shipping Schefferville operations conducted from 1954 to 1982 and formed part of the 250 million tons of historical reserves and resources previously identified by IOC. LIM intends to develop all these resources in five separate stages. The first four stages will see the various deposits treated in three beneficiation plants, to be built adjacent to several of the deposits that comprise the Central, South Central and North Central Zones. The final stage is not yet planned but will likely involve a fourth plant. A Feasibility Study has not been completed on any of these Projects. LIM plans the development and mining of the various deposits in separate Stages. It should be noted that only the James and Redmond deposits have been permitted. All other deposits require environmental assessment and permitting. Only the James and Redmond deposits have been subject to detailed mine design. The Houston deposit has had preliminary mine design carried out. All other deposits will require detailed mine design when further geological data is collected and compiled. Detailed metallurgical testwork has been carried out on blue ore from James, Houston, Redmond and Knob deposits and to a more limited extent on yellow and red ores from these deposits. Only limited review work has been carried out on the high-silica blue ores. All of this work will be needed to be complete to confirm the final process routes. Additionally some metallurgical work will be required to be conducted on each of the other deposits to characterize their metallurgical response and to confirm expected recovery levels. Detailed mine design and metallurgical testwork has been carried out on those deposits that will form the basis of production for the initial years but further exploration, testwork and design is required for all the remaining resources. The first plant at Silver Yards and mine construction at James are now complete and initial production is expected in the spring of 2011. Metallurgical testing of the first stage deposits has established that the ore can be successfully upgraded to marketable standards. Based on the current testwork, a program of plant enhancement on the Silver Yards plant is now planned with the objective to increase both the plant throughput and recovery. Production of direct shipping lump ore and sinter fines is forecast at around 1.5 million tonnes in 2011 and, based on current and historical resources, growing to approximately 5 million tonnes in 2015 and thereafter. Production from the first four stages is expected to continue at about this rate through to about 2028.

May 1, 2011

By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016

By A. E. Lehmberg

"IT IS KNOWN that some ores of sulphide type, such as pyrite, chalcopyrite, and bornite have an electrical conductivity comparable to that of metals, and accordingly much higher than the conductivity of any unmineralized rock. This physical property has long been used for the detection of orebodies of this kind by means of electrical measurements made at the surface of the ground.The present paper will deal with a new electromagnetic instrument for the investigation of subsurface conductors, which has been recently introduced into field practice and has already led to successful results in Canada.The principle of the instrument will be described. How it operates, and how the observations made can be interpreted will be explained. Field examples will •be shown to illustrate its application.Description of Instrument and of Operating TechniqueThe equipment (1) includes a low-frequency alternating current generator. The a.c. is supplied to a transmitter coil and generates a primary field which induces eddy currents in the ground, the intensity of which is proportional to the ground conductivity."

Jan 1, 1952

By Frédéric Flament, Luc Lachance

"The important task of metallurgical accounting that used to be done manually is being more and more automated. Currently available solutions can generate accounting reports without human intervention or almost. However, the practical conditions for fully delivering the promised benefits of those solutions are sometimes overlooked either by end-users or by integrators. The mere fact of filling reports with values satisfying several constraints such as mass conservation constraints does not, by itself, ensure a high quality metallurgical balance. Since managers make decisions based on these reports, it is logical that the metallurgical balance performance be monitored and retrofits be made if necessary. Such retrofits may involve modifications to the measurement strategy or the reduction of the spatial resolution of the material balance model. This requires an estimability and redundancy analysis (ERA) tool to assess the feasibility of the modified model. Since determining by hand the estimability and redundancy of a set of non measured and measured variables is not trivial, even for a medium-sized mineral processing plant, a dedicated ERA tool brings valuable assistance to the metallurgist in charge. The present paper aims first at explaining how a state of the art metallurgical balance is a key enabler for the adoption of a smart process plants paradigm (SPPP) in mineral processing. Then, the fundamentals behind the building of an ERA algorithm are introduced and illustrated by two examples. Finally, the role of an ERA tool in achieving state of the art metallurgical accounting and how it contributes to delivering additional value are discussed.INTRODUCTIONThe Smart Process Plants Paradigm (SPPP)Mineral processors have seen an increase lately in external pressures toward operating performance improvements. Indeed, the globalization of the mining business is a key driver to becoming more productive, more responsive to market changes, to improving corporate governance and reporting standards. Furthermore, mineral processors are also expected by their neighbouring communities to continuously improve their sustainability score. These current pressures differ somewhat from the past ones in leading to a larger than ever number of conflicting constraints that plant managers must concurrently satisfy while maximizing plant profitability. It is in turn not surprising that this context requires actions involving more real-time collaborative actions between more people in more places than ever before."

Jan 1, 2011

By Nathaniel Schaefer, Christopher Newman, Zach Agioutantis

"As mining reserves continue to be developed in deeper and more complex geological and geometric conditions, there has been an increased demand for underground mine designs to better reflect site-specific conditions, measurements, and observations with respect to ground control safety and stability. Current ground control design software are limited to a given device and data files generated can only contain a single design. However, with the growth of cloud computing and increases in internet access, even underground where permissible, web-based software applications allow for in-the-field calculations, as well as collaborations, from multiple users. webGroundControl (webGC) utilizes a multiple-tier architecture, building upon existing NIOSH ground control design software, more specifically ARBS, ALPS, and ARMPS. By providing operators the ability to access ground control design programs from any device, given an internet connection, webGC allows for on demand calculations to ensure underground pillar and roof stabilities with respect to current site-specific parameters, geometries, and geology. Through the development of new features, which aid in design analyses, as well as project collaborations, webGC provides the modern engineer with a more versatile ground control design tool for the improvement of underground health and safety. With the completion of the ARBS, ALPS, and ARMPS modules, this paper introduces potential users within the mining industry to the navigation and operation of the webGC application, as well as its ability to facilitate collaborations between operational personnel and planning engineers. The purpose of this paper is to raise interest in the web-based application before its official launch in Summer 2018."

Jan 1, 2017

By D. Marcotte, R. V. Dutaut

In most exploration or mining grade data-sets, the presence of outliers or extreme values represents a significant challenge to mineral resource estimators. The most common practice is to cap the extreme values at a predefined level. A new capping approach is presented that uses QA/QC coarse duplicate data correlation to predict the real data coefficient of variation (i.e., error-free CV). The cap grade is determined such that the capped data has a CV equal to the predicted CV. The robustness of the approach with regard to original core assay length decisions, departure from lognormality, and capping before or after compositing is assessed using simulated data-sets. Real case studies of gold and nickel deposits are used to compare the proposed approach to the methods most widely used in industry. The new approach is simple and objective. It provides a cap grade that is determined automatically, based on predicted CV, and takes into account the quality of the assay procedure as determined by coarse duplicates correlation.

May 1, 2021

By H. L. Gilbert, C. Travis Anderson, W. J. Kroll

IN a previous paper,1 the use of a split graphite tube resistor as a heater element for high-temperature furnaces has been described. The principal advantages of this type of construction are: I. The quadruple resistance or voltage compared with the top-bottom clamp resistor furnace. 2. Free expansion of the resistor. 3. The ease of protection from oxidation by air. 4. The firmness by which it may be held in the compact split clamp. This construction appeared to be well adapted for the fusion of high melting metals which require fusion in a vacuum. Zirconium metal had previously been melted at the Albany Laboratory of the Bureau of Mines in a vacuum arc furnace on a water-cooled plate, using a movable tungsten top electrode.2 When larger furnace capacities were desired, this type of construction proved to have its limitations as the largest tungsten rods available were about 7/8in. in diameter. The supply of direct current of high amperage for producing the . desired arc characteristics was also not available. Considerable difficulty was also found in compensating the atmospheric pressure on the flexible tubing of the movable electrode, at the same time keeping its movement sufficiently free to enable the striking of an arc on any part of the metal briquet. Among the various materials used for the electrodes in conducting experiments in the vacuum arc furnace was graphite. It was found that zirconium fused in a graphite cup with a carbon arc was contaminated to only 0.2 pct carbon. It was therefore decided to melt zirconium directly in graphite crucibles. A high-frequency furnace was first used in the attempt to melt the zirconium in graphite crucibles. The high-frequency heating coil was placed outside a silica tube which was evacuated by means of an oil diffusion pump backed up by a mechanical pump. The graphite crucible was thoroughly degassed at 1900°C before use. Considerable difficulty was experienced in operating at such temperatures in vacuo because, as shown by Zintl,3 carbon vapor formed and reacted with silica according to the reaction: Si02 + C = SiO + CO. The silicon monoxide which is volatile at these high temperatures reacted with the zirconium, thereby contaminating it with silicon and oxygen. The presence of carbon monoxide was detected by means of a gas discharge tube placed in the vacuum system as indicated by the pale blue glow of the tube as soon as carbon vapor started to react with the hot silica. The reaction between the carbon vapor and hot silica was avoided by the use of split cylindrical molybdenum shields which were inserted between the graphite crucible

Jan 1, 1948

By Wu Aixiang, Zhou Qian, Zhou Zaibo, Liu Juanhong, Wang Hongjiang

To improve the pumping capacity and engineering efficiency of fresh thickened tailings slurry, a high charge density superplasticizer was developed to improve the rheological properties of tailings slurry. The effects of superplasticizer content, the concentration and fineness of tailings, the proportion and type of cementitious materials, temperature, and hydration time on the rheological properties of unclassified tailings slurry and backfill materials were studied. The variation characteristics of the slurry yield stress, plastic viscosity, and thixotropy with different factors were measured by a Brookfield R/S-SST plus rheometer. The experimental results of fresh thickened tailings illustrated that the higher the concentration of the slurry and the finer the tailings, the worse the rheological properties of the slurry. The results of cemented paste backfill materials indicated that the rheological parameters increased as binder content and time increased. The rheological parameters decreased as the temperature increased. The addition of a superplasticizer reduced the rheological parameters and improved the rheological behavior of the fresh thickened tailings and cemented paste backfill materials, which was beneficial to the slurry’s pipeline transportation. This paper can provide technical guidance for slurry transportation in the backfill system and provide a reference for designing the superplasticizer used in tailings.

Jan 5, 2022

By Cesar Carrasco, Heath Arvidson, Mark Forster

Block models built to represent the geology and rock characteristics of mineral deposits represent huge complex data sets, which form the basis of strategic and business planning, and public reporting of Mineral Resources and Mineral Reserves. Recent advances in cloud computing and database technology developed for the Internet of Things offer a different way of working with these critical data sets. Enabling a cloud based, open data structure with high performance data analytics capability presents a compelling improvement in governance and a democratization of ore body knowledge that can lead to automation use cases that support the digitalization of mining.

Jun 25, 2023

By Alfred E. Schwaneke

A new high-temperature soft soldering system has been developed by the Bureau of Mines for use on copper, copper alloys, and low-carbon steel; the method is applicable to automobile radiators and home appliances. The system uses a unique sacrificial metal coating method to promote spontaneous wetting and spreading of zinc and zinc alloy solder: on metallic substrates. The 10-5 to 10-6 cm thick, electroplated or sputtered, sacrificial nickel coating is absorbed by the molten filler alloy during soldering and produces a direct solder-substrate metallic bond. Preliminary measurements on butt joints with copper members give tensile strengths up to 22,000 psi at room temperature using 95 Zn-5 Al alloy as solder. Spontaneous wetting, spreading, and capillary penetration are extremely rapid and produce joints as easily as 50-50 tin-lead solders. Recrystallization or annealing of the wrought copper joint members is negligible at the soldering temperatures of 450° to 490° C and lower. A list of fluxes and solder alloys is included in the report.

Jan 1, 1970

By J. M. Demarthe

MINEMET RECHERCHE (IMETAL Group, formerly Le Nickel-Penarroya-Mokta) has studied on a laboratory scale and patented a new process to recover metal values -copper- from sulphide ores and concentrates. It combines a cupric leaching, solvent extraction and copper sulphate electrowinning according to the main following steps - A direct and selective leaching of copper sulphide ores or concentrates at atmospheric pressure with cupric chloride to form cuprous and ferrous chlorides and elemental sulphur. Pyrite remains in the sulphur residue. - The leach solution is separated into two parts -In the first one, air is injected to precipitate iron as goethite. The oxidation step can be easily realized at atmospheric pressure by maintaining an excess of cuprous and-ferrous chlorides in the liquor. Copper is extracted from the second part as cupric ion by an LIX reagent. Direct injection or air in the mixing chamber maintains good extraction conditions, so that only one mixer settler is required. - Iron, in the form of ferrous ion, is not coextracted. - Copper is stripped from the organic phase, transferred into a sulfuric phase and sent to sulphate electrowinning cells, which are now conventional in copper metallurgy. - Only electricity and air are required. After a feasibility study, the next step will be to develop it on a pilot and commercial scale.

Jan 1, 1976

By Alireza Javadi Nooshabadi, Kota Hanumantha Rao

Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by sulphide minerals during grinding was examined. It was found that pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite ((Zn, Fe) S), and galena (PbS) generated H2O2 in pulp liquid during wet grinding and also when the freshly ground solids are placed in water immediately after dry grinding. Pyrite produced more H2O2 than other minerals and the order of H2O2 production by the minerals was found to be pyrite > chalcopyrite > sphalerite > galena. The pH of the water influenced the extent of hydrogen peroxide formation with greater amounts of H2O2 produced at highly acidic pH. Furthermore, the effect of mixed sulphide minerals, i.e., pyrite-chalcopyrite, pyrite-galena, chalcopyrite-galena and sphalerite-pyrite, sphalerite-chalcopyrite and sphalerite-galena on the formation of H2O2 showed increasing H2O2 formation with increasing pyrite fraction. There is clear correlation of the amount of H2O2 production with the rest potential of the sulphide minerals; the greater the rest potential of a mineral the greater the formation of H2O2. This study highlights the necessity of revisiting the electrochemical and/or galvanic interactions between sulphide minerals, and interaction mechanisms between pyrite and other sulphide minerals in terms of their flotation behavior in the context of inevitable H2O2 existence in the pulp liquid.

Jan 1, 2014

By Behram H. Wadia, Robert S. Lehto

A new metallurgical treatment for capturing as much of the values as possible from zinc refinery feed has been devised by personnel in Cerro de Pasco's Peruvian operation at La Oroya. Results from a pilot test illustrate that 50 metric tons of throughput can be maintained whereby substantially all the silver and copper report in the sponge iron while zinc and lead with indium and cadmium volatilize in the fume. This new technique named the Zileret (zinc leach residue treatment) process complements the electrolytic system used in the refinery so that all values in a zinc concentrate are economically recovered. In the system, dried zinc leach residue is pelletized with soluble zinc sulfate which already exists in the leach residue and a finely divided reducing agent such as anthracite coal. Upon heat addition, the loose anthracite in the charge maintains a reducing atmosphere while the free space above the charge has an oxidizing nature. When the charge reaches the reaction zone at about 1100°C, metals such as zinc, lead, cadmium and indium volatilize from the pellets, are oxidized in the upper kiln atmosphere, and are then carried in suspension as an oxide fume to the cooler and baghouse. The copper and silver content in their reduced forms, along with the iron, discharge from the kiln as a calcined product which is then cooled to below 130°C before being exposed to the air.

Jan 9, 1969

By H. R. Green

The design of slurry launders has usually been based on strictly empirical concepts. An examination of the most common procedures reveals that they do not account for many of the variables that are recognized as Significant for slurry transport. These may include flow rate, volume concentration of solids, solids specific gravity, solids size distribution particle shape, launder geometry, and roughness of the wetted surface. It was decided to develop a design procedure, which would accomplish two things: First: Take into consideration most of the known significant variables and systematize the procedure to assure consistent results. Second: Provide a rational basis for examining and utilizing operating data to refine and improve the system. To accomplish this, it was necessary to develop a basic design concept. This concept has been developed through a complex development history, and yet still appears workable and technically sound. That concept may be outlined as follows: First: The solids transport velocity is the fundamental basis for slurry launder design. Second: The stream configuration, hence the launder size, is integrated with the solids transport velocity so that the actual stream velocity exceeds the solids transport velocity. Third: The launder slope is that which will achieve the required actual stream velocity. It was originally planned to utilize a series of charts and nomographs for the design procedure. A nomograph, based on data given in Taggart's Handbook of Mineral Dressing (1), was developed to determine the solids transport velocity. The velocity thus determined was used with Manning charts to determine the launder slope .and configuration as though the fluid were water. It was planned to utilize a "slope adjustment factor" to increase the slope to compensate for the apparent viscosity of the slurry. All attempts to develop a suitable correction factor failed. This failure was principally due to the complex relationship of viscosity to the required slope. It was then decided to revise the entire approach. Specifically, the present procedure is based on the Darcy-Weisbach flow equation, which is rationally preferable to the Manning equation. The Camp (2) equation is used for the solids transport velocity. The necessity of reference to the Moody curves for the Darcy friction factor is avoided by using the Colebrook and White (3) equation. The resulting mathematics require iterative solutions for several of the unknowns.

Jan 1, 1978

The Kalgoorlie Golden Mile is proposed as an Archaean volcanogenic-type deposit, modified and redistributed along later-developed structures. Rich pyritctelluride and Green Leader gold mineralization is associated with the end phase of basic volcanism and, in a general sense, is confined to a broad interface zone between the products of marine basic volcanism and later acid volcanism. There is virtualIy no ore associated with the main body of acid volcanics.Green Leader is the local name of a type of ore that occurs at some igneous rock contacts in association with graphitic sediments and layered acidic tuffs. It is characteristicalIy green, of various shades, and commonly yields very high gold assays, the reasons for which are not apparent in hand specimen.Carbonates, carbonaceous shales, tuffites, rich gold ores, and acid and intermediate dykes, alI indicating a common heritage, are features common to the main ore hosts, viz. the Paringa Basalt (Calc Schist) and theGolden Mile Dolerite ("Quartz Dolerite Greenstone").Several probably related fracture systems have reconstituted most, but not all, of the original deposits into a large number of steep tabular lodes.Includes two sets of discussions and comments from later Proceedings volumes.

Jan 1, 1974

Current models for the origin of banded iron-formation (BIF) derived in situ iron ore deposits assume that the typical chert and iron oxide banded BIF is the primary rock from which enriched iron ore deposits arise by the selective leaching of quartz and the residual accumulation of the iron oxides. Weathering extends to the base of all the hematite deposits of the Hamersley Province, which lie within the saprolitic weathering zone, as shown by the preservation of the primary textures, and are overlain by a hydrated goethite zone representing the solum. Since groundwater typically contains dissolved silica, derived from the hydrolysis of silicate minerals, greatly in excess of the saturation solubility of quartz, it is incapable of removing quartz from below the watertable, and quartz is preserved in all saprolites derived from quartz bearing rocks. Quartz may be dissolved in the solum due to the influx of meteoric water having little or no dissolved silica, but soil-forming processes that dissolve quartz likewise alter the oxides by hydration and transposition with consequent destruction of primary textures, and there is no suggestion of soil-forming processes having produced the deposits, which typically extend to considerable depths below the water-table. A characteristic feature of the typical hematite orebodies is the unaltered nature of the iron oxides in the ore compared to those in the adjacent cherty BIF. Although the solubility of ferric iron at >10 ppb is much less than quartz, any process capable of dissolving the huge volume of quartz must also affect the iron oxides, but evidence of this is completely lacking in most ore deposits. Hydrothermal alteration at Koolyanobbing in the Southern Cross Province affects both cherty BIF and ore, and clearly shows equal mobilisation and recrystallisation of hematite within quartz/hematite veins and in the surrounding cherty BIF, which shows no evidence for the selective leaching of quartz. Similarly, any metamorphic process capable of removing all quartz from BIF would leave characteristic evidence in the remaining oxides. However, a hydrothermal process may account for at least portions of certain ore deposits, in which the chert bands have been replaced by carbonates at comparatively low temperatures, to produce a quartz-free magnetite/ carbonate rock that is readily upgraded to high-grade ore by supergene dissolution of the carbonates. This process is interpreted to have formed high grade ore at Mt Gibson, Koolyanobbing æAÆ Deposit and Mt Tom Price North Deposit. In addition to carbonate replaced cherty BIF at Mt Gibson in the Murchison Province, there are extensive sequences of magnetite BIF without chert bands, and this chert-free facies of BIF is interpreted as the precursor to the majority of in situ hematite ore deposits, through oxidation and weathering of magnetite and iron silicate and carbonate minerals. The world-class martite/microplaty-hematite deposits of the Hamersley Province are a special case of BIF-derived iron ore deposits that were initiated during the Proterozoic era. Evidence from overlying Wyloo Group conglomeratic horizons containing clasts of Hamersley Group BIF indicates that microplaty-hematite formed within the clasts before deposition, and that Proterozoic subaerial oxidation and weathering of uplifted Hamersley Group formations produced the microplaty-hematite in both chert-free and cherty BIF.

Jan 1, 2002

By Sridhar Seetharuman

Sulfur and oxygen dissolved in nickel and cupronickel melts can be removed as gaseous oxides of sulfur by a vacuum treatment. Presented in this paper is a new matched thermochemical diagram that permits direct evaluation of the equilibrium partial pressure of SO, as a function of temperature over an alloy of specified composition. The matched thermochemical diagram consists of a central plot which shows the integral Gibbs' energy of mixing for the binary system S-O2, at different temperatures. The central plot is flanked on either side by terminal plots of the chemical potentials of oxygen and sulfur, as functions of temperature, for different alloy compositions. By projecting the chemical potentials of oxygen and sulfur from the terminal plots on to the central diagram, the equilibrium pressure of SO2,can be directly read on the nomograms on the central plot at different temperatures. The matched thermochemical diaerams are - useful in assuring the efficiency of vacuum refining.

Jan 1, 1993

By Ekkehart Mertins, Hans-Dieter Wasmuth

During the last years many new concepts have been presented for magnetic separation of feebly magnetic minerals by using the new high-duty permanent magnetic material especially in Open Gradient Magnet Systems (OGMS). In this respect KHD Humboldt Wedag AG developed an improved version of a drum-type magnetic separator called PERMOS® with a special magnetic field configuration for the NdFeB permanent magnets, which gives a magnetic field strength of at least 0.7 Tesla and a wide working zone outside the drum. The magnet system within the PERMOS® unit is no longer made of relatively large magnet blocks of alternating radial magnetisation; the system is now made up of a multitude of small NdFeB bars with a specially oriented magnetisation. This PERMOS® Open Gradient Magnetic Separator can be used for dry magnetic separations in "top-feed" and 'free-fall" feed configuration as well as in the conventional wet "drum-type" feed mode. It allows high throughput rates of up to 40 metric tons of solids per hour and meter of drum length without any clogging problems, even when strongly magnetic com-pounds are present in the feed material. The important design features and the actual machine characteristics of the improved PERMOS® units for dry and wet magnetic separation are described and typical examples for their commercial application for industrial minerals and for martitic iron ores are presented.

Jan 1, 1995

By C. H. Herty Jr, C. H.

FEW subjects have attracted the attention of metallurgists more than oxygen in steel. From the days of Mushet and Ledebui interest in this subject has been increasing, and as additional knowledge has become available, the problem has naturally grown more complex. Instead of using the simple term "oxygen" we now distinguish between iron oxide, silicates of various kinds, oxysulfides, oxygen as gas and oxygen in solid solution in steel. There are five general methods for determining oxides in steel: hydrogen reduction; vacuum fusion; various wet-extraction methods, including electrolytic methods; methods depending on volatilization of the iron away from the oxides; and metallographic methods. For oxygen in solid steel each of these methods has both advantages and disadvantages. The hydrogen-reduction method is of no use on steels above about 0.20 per cent. carbon; 1 furthermore, it gives only FeO and possibly some MnO. The vacuum-fusion method2 is expensive and gives total oxygen, with the exception of some A1203, and does not differentiate between the various oxides in which the oxygen exists. Most of the wet-extraction methods3 give only the more insoluble oxides SiO2 and A1203, though the iodine method gives MnO to an uncertain degree (information that may be more misleading then no information

Jan 1, 1957