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By V. I. Lakshmanan

"Historically flowsheets are developed for efficient separation of metals for economic recovery. With increasing emphasis on reduction, reuse and recycle (3Rs) efficient methods are sought to recover values from a variety of feeds where cost of collection, transportation, local consumer behaviour and regulatory guidelines dictate the development of economically viable flowsheets. Innovative understanding of potential market applications can provide means to develop value added end products. The paper with examples will discuss the use of innovative-separation technologies to obtain value added end use materials from secondary sources.IntroductionFlowsheets are developed for the efficient separation of materials of value for economic recovery. However with increasing societal pressures and regulatory initiatives for stricter environmental guidelines, there is strong need to provide focus to recover materials efficiently and economically in an environmentally accepted manner. North American industries are increasingly caught between demands for high technology value added products and responsibility for environment. An aspect that is receiving increasing attention is Design for Environment'. This incorporates a system wide approach for product design and incorporates environmentally preferable features such as recyclability, disassembly, maintainability, reusability and use of safe materials as part of a product's design objectives.The present paper with case histories will address innovative flowsheet development to convert wastes into recyclables value added products or for minimising generation of waste materials. Case HistoriesProcess for Separating Fibres from Composite Materials 1In the automotive industry, sheet molded compound (SMC) is used to produce panels, bumpers and the like. During the manufacture and at the end of life, considerable waste materials are generated which are potentially recyclable. Fibre reinforced plastics where fibre substrate impregnated with thermosetting resin, find applications in several manufacturing processes and are potentially recyclable at the end of life."

Jan 1, 1996

By James C. Sever

Two green field magnesium reduction plants are under consideration using dolomite as the raw material. The Calix calciner was independently selected for both plants. The unique design of this calciner is detailed and the advantages defined for the specific application. The low carbon foot print of this unit combined with the ability to capture food grade carbon dioxide makes this an environmentally proactive approach to carboniferous ore calcination.

Jan 1, 2015

By Roger Agnew

Sulphide ores mined by Inco Limited in the Sudbury District contain small quantities of cobalt. During beneficiation, cobalt distribution to various streams is similar to nickel. After smelting, nickel is selectively extracted by carbonyl refining and the cobalt remains in the carbonylation residue. This residue is processed in a specialized hydrometallurgical plant to produce precious metal residues, copper cathodes, and a nickel- cobalt carbonate intermediate product. The nickel-cobalt is shipped to Port Colborne where the cobalt is separated as cobaltic hydroxide and refined to metallic cobalt. This paper deals specifically with the recently constructed Electro Cobalt Refinery. The cobaltic hydroxide is dissolved and residual zinc, copper and nickel are removed by ion exchange and organics by a carbon column. The purified cobalt solution is fed to the electrowinning circuit where cobalt rounds are produced on stainless steel mandrels. In the design and construction of the refinery, special attention was directed to materials of construction both for the process equipment and the physical plant, operating control and flexibility, and the quality of the working environment. The end result is an efficient and clean operation which yields a product of excellent quality.

Jan 1, 1988

By K. S. Kumar

FLS miljø, Inc. markets, designs and supplies particulate collection devices for dusts, fumes, and mists; In this paper, the application of both wet and dry electrostatic precipitators (ESPs) in smelting, and roasting plants is discussed.

Jan 1, 1998

By W. Zhao

Several years ago, Reddy and Blander presented upriori model for calculating the sulfide capacity of binary silicate melts. It is modified now to apply to CaO-AlO 1.5 melts at different temperatures and compositions. Our predictions are in very good agreement with the available experimental data. From a comparison of binary calcium aluminate and calcium silicate systems, higher sulfide capacities are obtained in aluminate systems. The sulfur can be removed from hot metal more effectively by adding aluminate melts.

Jan 1, 1995

By A. V. Tarasov, V. M. Paretsky

"The design is based on the thermal processing of the wastes in· the intensively bubbled melt in the Vanyukov furnace at the relatively high temperatures (1350- 1450 °C), In this case: -the secondary wastes are not formed; - the especially toxic substances at the outlet from the furnace are absent. The technology was tested on a large scale (on semicommersial bases). Technical and economical basis show profitability of recovery complex for processing of hard garbage waste (HGW) using this technology: the period of capital, investments refunding for the, recovery, complex construction with process annual capacity of 240 thousands tons of wastes is 1,5-2,5 years,"

Jan 1, 2000

By Roger N. Kust

Removal of heavy metals from industrial process streams is becoming increasingly important for _the recovery and reuse of values in process tails. Technology has been available for several years which removes heavy metals, from dilute (0.1-3.0 g/L) streams, as hydroxide or hydrated oxide sludges, allowing discharge of washed cakes with up to 60% solids. This paper reports on improvements to this technology which now allows treatment of streams with metal concentrations in excess of 60 g/L while eliminating the need for thickeners. Streams containing copper, iron, aluminum, chromium, nickel, zinc, cobalt and lead have been successfully treated.

Jan 1, 1992

By Keith M. Axler

This report addresses issues specific to the generation of hydrogen fluoride via reaction of calcium fluoride with sulfuric acid. This process has been established on a commercial scale and is under consideration for treatment of calcium fluoride residues from uranium processing. Magnesium fluoride slags are also available as a product of uranium processing. The technique of using sulfuric acid for the production of hydrogen fluoride from magnesium fluoride is also under consideration as a residue processing scheme. In the current study, thermodynamic modeling was used to investigate these chemical processing systems. The results presented herein reveal information relevant to the selection of processing temperatures and conditions. Details include predicted effects in system composition based on operating temperatures for both the calcium fluoride and the magnesium fluoride systems.

Jan 1, 1996

By R. G. Reddy

The oxidation kinetics of A13Ti intermetallics have been studied at the temperature range of 850°C to 100O0C in pure dry oxygen. The oxygen diffusion rates were investigated using TGA method. Parabolic rate constants were calculated. The oxidation scales were analyzed using SEM, EDS and X-ray diffraction. A continuous A120, scales with a little TiO2(rutile) were formed on the intermetallic surface. The A13Ti intermetallic exhibited excellent oxidation resistance among the Ti-Al base intermetallics.

Jan 1, 1997

By C. E. Dodson

Conventionally hydrometallurgical recovery processes from sulphide concentrates include roasting, leaching, precipitation, impurity removal and zinc electrowinning. The use of the novel (yet commercially proven in other mineral and metallurgical industries) TORBED process reactor for the flash roasting of sulphides will be proposed. The potential advantages in its application will be discussed including very fine particle processing capability, lower cost smaller roasters, waste minimization, improved leaching efficiency and overall process simplification.

Jan 1, 1999

By H. Forrest

Lead smelting at Cookson Industrial Materials was formerly carried out using a combination of Blast and Reverberatory Furnaces. In the late 70' s these furnaces were replaced by two 20 tonne capacity Rotary Furnaces. This furnace type has proved to be more flexible in the range of feedstock that can be processed, including lead drosses, battery plate and even whole batteries. High rates of production have been achieved whilst attaining a good level of environmental control. The majority of the sulphur in the feedstock can be fixed by use of appropriate fluxes.

Jan 1, 1990

By Balasivanadha Prabhu, Prasad P. Shanmugasundaram, Narayani Narasimhan

"The grain refinement and mechanical properties of 6061 aluminium alloy produced by equal channel angular pressing (ECAP) have been analyzed in this present study. A innovative triple shear ECAP die was developed for the processing.It was observed that the grain refinement takes place for greater number of passes. It was also found that reducing the process temperature gives fine grain and high microhardness and hence improved propertiesIntroductionTechnological changes in manufacturing industries have depended heavily on development in materials processing and process technologies. Modem industries need high performance materials for severe service conditions. Hence, it is necessary to improve required material properties to achieve better performance and greater service life. As mechanical properties of the materials strong! y depend on grain size ( d) - Hall-Petch relationship [ 1-4], the ultrafine grained (UFG) materials offer superior mechanical properties based on the above relation.Synthesising massive nanocrystalline materials presents a challenge to basic research as well as to application-related processing efforts. Production of ultrafine gram microstructures in metals and alloys having different crystal structures but always an initially coarse microstructure using severe plastic deformation can significantly enhance the physical and mechanical properties of materials. Severe Plastic Deformation (SPD) is an efficient method to induce ultra fine grained structure in materials by deforming it to large strains. Traditional techniques for introducing deformation of higher strains, such as forging, extrusion, drawing or rolling do have the inevitable limitation on required equipments of exerting enough load or pressure to cause uniform nanometer level grain refinement."

Jan 1, 2011

By Katsukiyo Marukawa, Mashamichi Sano, Shigeta Hara

"Various subject of studies are discussed to develop ·innovative refining processes in the 21st century for cost reduction, production of high quality steel and environmental conservation. The future refining reactor should have abilities of highly efficient mixing and separation of different phases. It is stressed ·that applications of electromagnetic and ultrasound energies, and control of flow fields rate required to create the highly efficient mixing I separation reactor.IntroductionIn recent years, it seems that the research and development in the field of steelmaking has shifted its emphasis to the solidification I ingot-making process in which continuous casting plays the leading role. From a long-range point of view, however, the need for continual development of the refining process will probably increase but is very unlikely to decrease. In order to meet such demands, it is required that problems and issues of the present process should be clearly grasped and that there must be rapid progress in process elements, such as highly efficient mixing and separation of different phases.Applications of electromagnetic and ultrasound energies and flow field control will become important options for resolving the above-mentioned problems. By efficiently and skillfully incorporating these new technologies into high-efficiency mixing/separation reactors, the innovative refining process will be established in the early 21st century."

Jan 1, 2000

By Xiao Songwen

Based on the anion coordination polyhedron growth unit theory, the polymorph transformation mechanism of antimony white (Sb2O3) in hydro-process was investigated. The new findings had been verified in the commercial-scale test and it was shown that adding a small amount of tartrate ions was economical and effective for polymorph transformation of antimony white in hydro-process.

Jan 1, 2003

By R. G. Hilton

This paper deals with application of Super Detox? stabilization technology to the treatment of electric arc furnace dust (US-EPA listed hazardous waste KO61 ). The process has been used on approximately 170,000 tons of electric arc furnace dust. In addition to the nearly four years of commercial experience at Sterling, Illinois, the process is now being permitted for application at two other locations. The process was originally developed by the Bethlehem Steel Corporation and then further improved by Conversion Systems, Inc. (Bethlehem Steel's Licensee). The treatment process offers many unique bases for its selection, including: A) Low cost compared to the treatment alternatives; B) Lowest available TCLP leachate levels for any process treating K061. Many other processes leave some residue that represents a disposal requirement, although often not addressed; C) Produces minimized final waste disposed, including the fact that the total volume of dust generated and less than the volume occupied by the residue slag from HTMR; and, D) Opportunities for the beneficial utilization of part or all of the waste stream through the development of chemical and physical characteristics. Each of these aspects will be specifically discussed in the paper, including that status of the operations now under permit.

Jan 1, 1994

By E. Gutierrez-Miravete

Hot pressing processes are widely used to shape metallic, ceramic, and glass components. The process is an essential step in manufacturing ceramic fibre-glass matrix composites. The paper describes the use of computer simulation by the particle method, to the analysis of the deformation and flow of glass during hot pressing. The hot glass is represented by an assembly of interacting particles which deform in response to the applied pressure. The results, which should be regarded as complementary to continuum-based studies, provide useful insight about the hot pressing process.

Jan 1, 1990

By A. V. Tarasov, A. D. Besser

A processing flowsheet has been developed for treating substandard lead-containing polymetallic bulk concentrates and intermediate flotation products containing precious metals, which comprises oxidizing roasting in a calcination kiln and electrothermic smelting generating low volumes of off-gas. The proposed flowsheet also incorporates a dust collection system and sulfur dioxide recovery from off-gas. It is proposed to implement this process by using a reaction smelting technique. For this purpose, the charge to be fed to the smelting furnace after its calcination in a drum-type rotary kiln must have a ratio of sulfide sulfur to sulfate sulfur of at least 1 :2. Electric smelting makes it possible to produce lead bullion that also collects the precious metals contained in the feed, as well as copper-lead matte and slag containing zinc. The recovery of lead into lead bullion and into matte is approximately 83% and 14%, respectively (thus the overall recovery is 97%); the total recovery of gold and silver into lead bullion and matte is 98%; th\lt of copper into matte is 89%; the recovery of zinc into slag is 96%; and that of sulfur into sulfuric acid or gypsum is 90%. After the recovery of zinc from slag, the latter can be utilized in the construction industry.

Jan 1, 2000

By Norbert Steiner

For the desulfurization of weak SO2 gas streams, Degussa developed a process using dilute H2SO4 solution containing H2O, instead of conventional gas scrubbing with all solid absorbent medium (limestone, MgO). The process is based on fast reaction of H2O, with SO2 yielding H2SO4 up to 70% strength, depending on off-gas temperature. Compared to the conventional systems with typically < 95% efficiency, independent on the raw gas SO2 concentration, residual SO2 concentrations of less than 20 mg/Nm3 can be easily achieved, corresponding to nearly 100% removal. These features render the H2O, process a very attractive, low capital cost technology to retrofit existing conventional desulfurization plants.

Jan 1, 1996

By Billy W. Osborne

The use or primary dross as a source for aluminum ion in the manufacture of aluminum sulfate offers opportunities for an inexpensive raw material. The aluminum sulfate industry in the US is a mature market with numerous small plants operating close to major users. The majority of manufacturers use either bauxite or aluminum oxide trihydrate as a source for the alum¬inum ion.. However, using process technology developed and patented by IWC, the oxides are removed from primary dross for use in manufacturing aluminum sulfate prior to metal recovery. This process offers the benefit of reducing costs for metal recovery. This paper discusses some of the methodology used in this process.

Jan 1, 1995

By D. J. Wang

Based on the thermodynamic arid kinectic aspects, the vaccum distillation processes for the separation and recovery of metals from wastes are analyzed. As to the separation criteria, The separation coefficient and equilibrium composition relation between vapor phase and liquid phase are the bases of recovery of metals by vacuum distillation, The vaporization rates and condensation mechanisms are also discussed. Some experimental results which deal with metals-containing wastes are described and the performances of a new kind of horizontal vacuum furnace are introduced, which demonstrate that , vacuum distillation may be a prospective technique for circulation and regeneration of some non-ferrous metals from industrial wastes.

Jan 1, 1996