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By D. Dolinar, T. P. Mucho

Horizontal stresses are caused by global plate-tectonic forces. During 1995 alone they were largely responsible for the closing of two longwall mines in the United States. This paper presents six case histories from Pennsylvania, West Virginia, Kentucky and Alabama. In each case, a mine encountered roof falls or difficult ground conditions at the headgate caused by horizontal-stress concentrations. The problems are detailed, and the control measures adopted are described. In most cases, nearby longwall panels without stress concentrations were trouble free. The paper also discusses detailed measurements that were made at two adjacent Pennsylvania longwalls. One headgate was oriented to avoid a horizontal-stress concentration, and the other was not. Eliminating the stress concentration dramatically reduced roof support loads and roof deformation. The paper concludes that proper panel orientation and sequence is the key to maintaining headgate ground control. The optimum orientation is not parallel to the maximum horizontal stress, as previously thought, but rather it is 20° in the stress shadow of the gob. Other stress-control techniques, including artificial support, are briefly discussed.

By R. V. Lundquist

Past reports by the Bureau of Mines have described the extraction of alumina from numerous aluminum silicate materials by the lime-soda sinter process. The results from pilot-plant investigations of six materials, with alumina-to-silica mole ratios from 0.3 to 8.7, indicated a relationship between the alumina-silica ratios and the processing characteristics of the sinter. A series of laboratory tests was conducted to define this relationship. Sinter and leach tests determined that an alumina-to-silica mole ratio of 0.90 or greater resulted in the best alumina and soda recoveries while leaving the leach slurries practically free from any tendency toward gelation. The widely different chemical and mineralogic properties of the various aluminous materials used in compounding the mixes had no perceptible effect on the leaching characteristics of the sinter. The blending of low-cost, high-alumina materials with aluminum silicate materials to give an alumina-to-silica mole ratio of 0.90 or greater would improve alumina and soda extraction and minimize operating problems in the lime-soda sinter process.

Jan 1, 1970

By Van E. Shaw

Bastnaesite is a natural rare-earth fluorcarbonate of the cerium group that affords an abundant and high-grade source of the lighter rare-earth elements. A simple and efficient method has been developed by the Bureau of Mines for extracting rare-earth compounds from this mineral. Digesting of a flotation concentrate with sulfuric acid converts the rare-earth compounds from fluorcarbonates to sulfates. Action of the acid releases gaseous com-pounds of fluorine and silicon, leaving the sulfated material free of these elements; carbon dioxide from carbonate decomposition is eliminated at the same time. Calcining the sulfated material at 1,200° F. renders the gangue constituents insoluble, whereas the rare-earth sulfates are left in water-soluble form. Leaching with water yields a solution of pure rare-earth sulfates. Bastnaesite could become prominent as a source of cerium-group rare-earth elements. It is rich in the light rare-earth elements and comparatively easy to process; reserves of the mineral are extensive enough to supply a greatly expanded market for many years.

Jan 1, 1959

By Frederick H. Raab

The electromagnetic retransmission system is a new, automated method of locating trapped mine workers. This technique overcomes many 1 imitations inherent in electromagnetic direction finding by reducing the effects of the conducting ground to an acceptable maximum, by finding position accurately in the presence of antenna tilt, and by eliminating the need for the receiver to be located directly above the subsurface transmitter. Three transportable three-axis magnetic-dipole transmitters on the surface create a system of electronic grids in which the phases of the downlink Signals convey position information. The subsurface retransmitter modulates the uplink carrier of the existing beacon transmitter with the received downlink signal; the coal-pillar loop antenna is used for both receiving and transmitting. The uplink receiver uses a three-axis antenna and extensive digital signal processing. A small computer integrates data, estimates position, and controls system operation through VHF-FM communications. Both coal-mine and deep-mine operation are possible by selecting appropriate transmitting power and signal frequencies. This report shows such systems to be both feasible and practical.

Jan 1, 1980

By R. S. Dean

[During t!~c past f isc.~l y~:-.r the Xetzllvz-gicd 3ivi oion has made im- portant contribution-, don,- tlie lines rlictnteil by the Bureau policy of con- servation of domestic rnker~l rcsoul-ces throui;h use. During t!~c past f isc.~l y~:-.r the Xetzllvz-gicd 3ivi oion has made im- portant contribution-, don,- tlie lines rlictnteil by the Bureau policy of con- servation of domestic rnker~l rcsoul-ces throui;h use.]

Jan 1, 1940

By R. S. Dean

[During the past fiscal year the Metallurgical Division has made important contributions along the lines dictated by the Bureau policy of conservation of domestic mineral resources through Its investigations include determining of fundamental data of metallurgically important materials improvement of standard ore-treatment method to eliminate waste and improve the grade or recovery of the products; and development o new metallurgical processes.]

Jan 1, 1940

By Paul T. Allsman, William H. King

This paper describes the mineral deposits and discusses mining and milling methods and related operating conditions in an important gold , silver , lead , and zinc producing area in Ouray , San Juan , and San Miguel Counties , Colo . , embracing 250 square miles . The area is extremely rigged , ranging in altitude from 8,000 to 14,000 feet . White men first penetrated the area in 1860 , when a group known as "Baker's party " reached the Animas River at the present site of Silverton . Difficulty with the Ute Indians and severe winter conditions forced the group to leave and discouraged prospecting until 1870 when a second party reached the area and succeeded in producing 27 tons of ore yielding $ 150 a ton in gold . In 1874 , a treaty with the Indians opened the way for settlement , and mining was established . The total production of recovered gold , silver , copper , lead , and zinc from 1873 to 1947 in the three counties is valued at $347,057,047 . The greatest amount of the total production of metals has come from quartz veins in a series of volcanic flows and tuffs covering the area and comprising a blanket 4,000 to 6,000 feet thick . The igneous rocks were laid down upon an old , erosion surface and are underlain by Paleozoic and Mesozoic sedimentary rocks and pre - Cambrian metamorphic rocks . The entire series has been intruded in late Tertiary time by volcanic dikes and larger intrusive masses . Because of the great differences in relief generally , mining is con-" ducted through long adits to a depth of nearly 3,000 feet below surface in places . Walls of the veins generally stand well , and shrinkage stoping is the most common method of mining . As virtually all of the ore is sulfide below the zone of oxidation , flotation is the common method of milling . Generally , where gold is important , provision is made for its removal by jigs . Bulk concentration of the sulfides is practiced at smaller mills , but the larger operations make a selective lead and zinc concentrate or a lead , zinc , and copper . concentrate . ·

Mar 1, 1950

By B. J. Moore

This Bureau of Mines publication contains analyses and related source data for 276 natural gas samples from 23 States. All samples except four were collected during calendar year 1984. Those four samples were collected earlier, but releases granting permission to publish were not received until 1984. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by the mass spectrometer and chromatograph. The results of these investigations are published annually to make the information available to the petroleum industry and the general public. Twenty-eight publications have presented the results of 13,957 gas analyses made prior to 1984. The first three bulletins (1-3)2 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960; these bulletins have been supplemented annually by information circulars (4-17, 19-24, 26-28) containing 8,453 analyses of samples collected since 1960.

Jan 1, 1985

By L. E. Cardwell

This Bureau of Mines publication contains routine analyses and related source data for 495 natural gas samples from 21 States and three foreign countries. Of this total, 376 samples were collected during calendar year 1968. The remaining 119 analyses are of samples collected during previous years, but releases granting permission to publish the results Here not received until 1968. All samples were collected as a part of a continuous survey of the free world for occurrences of helium in natural gas. This survey has been conducted in the United States by the Bureau of Mines since 1917 and in late 1965 was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus which are described in Bureau of Mines Bulletins 4863 and 576.4 Ten previous publications have presented results of 8,165 gas analyses made by the Bureau of Hines Helium Activity prior to 1968. The first three, Bulletins 486, 576,6 and 617,7 contain analyses and related source data on

Jan 1, 1970

By D. S. Kingery

Investigations over several years have disclosed that the principal manners of occurrence of shuttle-car injuries are in order: 1. Victims in contact with roof or crossbars. 2. Victims in contact with ribs or timber legs. 3. Victims falling from, or jerked from, shuttle cars. 4. Victims in contact with overhanging brows or protruding pine for pin timbers, or water lines. 5. Contact with persons or collisions with parked equipment. 6. Victims injured by roof falls or falling timbers caused by knocking out roof supports with shuttle cars. 7. Victims injured by runaway shuttle cars. 8. Victims injured while loading or unloading timbers or other materials from shuttle cars. These recurring types of shuttle-car accidents reflect the physical conditions of the working sections, certain safety deficiencies in shuttle-car maintenance and design, and unsafe practices by operators.

Jan 1, 1952

By J. E. Murphy

The Bureau of Mines developed a hydrometallurgical method for recovering mercury metal from mercury sulfide concentrates. Sulfide flotation concentrate from the McDermitt Mine was leached in a cupric chloride solution at 80° C. The redox potential of the solution was maintained at 850 mV during leaching by chlorine sparging. Mercury extractions exceeded 99 pct in 3 h of leaching. After leaching, the pH of the solu-tion was increased from 1 to 4.5 to precipitate copper as atacamite. The pregnant solution typically containing 100 giL Hg was sent to elec-trolysis to produce high-purity mercury metal and chlorine for recycle. In a 200-A electrolytic cell operated for 24 h, current efficiency was 99 pct and the energy requirement was 0.9 kW·h/lb of mercury produced. Mercury removal from the waste stream was also investigated. Iron or zinc cementation, sulfide precipitation with H2S, and activated carbon adsorption all decreased the mercury concentration from 10 giL to 0.01 mglL, which is less than the Environmental Protection Agency limit on wastewater of 0.02 mg/L.

Jan 1, 1987

By P. M. Sullivan

Galvanizers' sal skimmings have been treated by two methods of leaching in attempts to produce preflux solutions suitable for use in galvanizing operations. Both water-leaching and acid-leaching procedures are effective, except in severely exhausted skimmings when water-leaching becomes impractical. A preliminary analysis of the skimmings is not required. Solutions in the recommended concentration range can be produced conveniently by control of pH, specific gravity, and chlorine content. A technician would require only a short period of training to be able to perform the operations described.

Jan 1, 1958

By David N. Montgomery

The characteristics of a closed cavity acoustic coupler were measured. Various configurations were investigated to determine their feasibility for use in a portable audio dosimeter calibrator.

Jan 1, 1976

By A. L. Engel

As a part of the program of the Rare and. Precious Metals Experiment Station, Reno, Nev., in connection with investigations of treatment methods for precious and precious-base metal ores, to further conservation and recovery of precious and base metals, tests Were made on samples from the Buzzard Mine, located in the vicinity of Placerville, Calif. These samples represented ore exposed during previous development work, in tunnels and a shaft on the property, including highly oxidized material from the surface zone and sulfide ores from depths of 150 to 300 feet. The surface samples contained little base metal and only enough gold 80 that economic exploitation of them would depend on development of a large tonnage of ore, low-cost mining methods, and satisfactory treatment methods. The sulfide samples were valuable enough to warrant further exploration and development and, if present in suitable tonnage, the installation of a treatment plant for recovery of both precious and base metals. The oxidized surface-zone samples carried 0.11 to 0.14 ounce gold per ton. Standard amalgamation and flotation tests of these samples gave low recoveries. Standard cyanidation tests indicated high consumption of lime and cyanide and gold extraction of 79.4 and 82.7 percent. Water-leaching the ore after crushing to minus 10-mesh improved cyanidation considerably. Ex-tractions of 82.7 to 85.8 percent were obtainec1 with lime consumption of 6 to 7 pounds per ton of ore and cyanide consumptions of 1 to 4 pounds. Grinding the samples to minus 200-mesh followed by water-leaching and cyanidation gave improved extractions of 91-92 percent of the gold, but with slightly increased consumptions of lime and cyanide.

Jan 1, 1949

By J. A. Ruppert

The Bureau of Mines investigated methods of refining iron-contaminated zinc to marketable quality and developed a laboratory-scale process in which aluminum, added as a refining agent, reacted with the iron, forming solid Fe2Al which floated to the surface of the melt. Solids were separated by both filtration and centrifugation, using a unique type of "dipping" centrifuge devised during the work. Typical zinc recovery was 95 percent, and iron content of the metal was lowered from 0.37 to 0.02 percent.

Jan 1, 1967

By P. C. Good

To meet a growing need for thorium metal of high purity and amenability to fabrication, the Bureau of Mines devised a method for preparing thorium metal by the reduction of thorium tetrachloride. Thorium tetrachloride was prepared by chlorinating calcined thorium oxalate with carbon tetrachloride. The crude thorium tetrachloride, containing oxygen-bearing compounds, was purified by a double vacuum distillation at 800 to 900° C., and thorium metal was made in the form of a dense sponge by the reaction of metallic sodium or magnesium with thorium tetrachloride at 800° C. Vacuum arc melting was used to consolidate the sponge metal to ingot form for evaluation of its physical and chemical properties.

Jan 1, 1960

By Lawrence G. Houk

Lithium is the lightest of all metals, but as it deteriorates rapidly in air it has no structural applications. Alloys of lithium that will float upon water can be made with other light metals, but these ultralight alloys are not useful in aircraft production or elsewhere at present. Alone or alloyed with alkaline earth meals, lithium acts as reining agent on molten metals, and as a minor constituent with other metals it imparts characteristic properties to the allay. Lithium compounds have somewhat wider application in commerce than either the metal or the alloys. They are used in the glass, ceramic, chemical, and air-conditioning industries and less extensively in the optical, pharmaceutical, electrical, and textile industries. The United States is the leading producer anti consumer of lithium ores and compounds and apparently has the largest known ore reserves. The value of lithium ores and primary chemical byproducts produced is relatively small, yet the lithium chemical industry yields products worth hundreds of thousands of dollars each year, owing partly to the high degree of purity demanded by the trade for most finished products and to the low combining weight of lithium. Fortunately, the low-grade ores can now be concentrated economically, and this fact, together with our extensive reserves, assures adequate supplies to meet any reasonable increase in demand. Lithium is listed as essential by both the American and British war agencies, and its military importance may be greatly enhanced.

Jan 1, 1942

By E. C. Perkins

The purpose of the research described in this report was to develop techniques for using ilmenite from domestic deposits for the production of titanium tetrachloride. The research was done by the Federal Bureau of Mines in cooperation with the General Services Administration under contract DMP-116, Utilization of Domestic Ilmenite. Bench-scale continuous chlorination of an Idaho ilmenite containing 27.9 percent titanium and 35.6 percent iron yielded a crude titanium tetrachloride suitable for purification and for the production of titanium metal and pigment. A summary of the results of 380 hours of operation showed that 82.4 percent of the titanium was chlorinated, with 92.5 percent utilization of chlorine. The construction- of a. quartz tube chlorinator 4-inches in diameter and 24 inches long is described with the necessary details of operation.

Jan 1, 1961

By J. E. Matta

The Bureau of Mines made laboratory absorption measurements on oil shale samples, which showed that the amount of methane absorbed is proportional to pressure and oil yield, and can be much larger than would be predicted based solely on porosity. Oil shale cores collected in the field were also measured for their gas content using the Bureau of Mines direct method. Cores taken from deep locations and far from outcrops yielded more gas than cores from shallower locations or at outcrops, when taking into account variations in oil yield, and all data indicate that oil shale mines that are both deep and far from an out-crop will emit low levels of methane gas.

Jan 1, 1977

By E. C. Perkins, R. S. Lang, D. M. Taylor, H. Dolezal

The amenability of titaniferous slags and domestic mineral concentrates to chlorination was determined in a 6 - inch diameter fluidized bed chlorinator . Ilmenites from Valley County , Idaho ; Aiken , S.C ,; Trail Ridge , Fla .; and MacIntyre , N.Y .; and a titaniferous magnetite from Iron Mountain , Wyo . , were used in preparing the slags . The domestic minerals tested were an ilmenite concentrate from Valley County , Idaho , and a rutile concentrate from Magnet Cove , Ark . A high - grade Australian rutile was used as a standard for comparison . The impurity content of the slags and minerals tested , which was the most critical factor affecting their performance , was dependent on the geographical source of the material . All of the materials tested were amenable to chlorination in a fluidized bed although some required special operating conditions . Titanium extractions and chlorine utilization were over 90 percent for most of the slags and the Australian rutile . The Valley County , Idaho , ilmenite performed well in the reactor despite its 34 percent iron content .

Jan 1, 1963