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By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto

"The theoretical technique of computational modeling and the experimental determination of the enthalpy of adsorption of a ligand molecule onto a mineral surface deliver the same output parameters and, therefore, complement each other in investigating the affinity of different ligand types for mineral surfaces.This study ran parallel experimental tests and computational calculations to determine the enthalpy of adsorption of a series of increasing chain length xanthates onto a pyrite surface. The outcomes showed that, while the absolute energy values were different, the trends were similar. Both computational and experimental approaches showed that the extent of the interaction of the xanthate molecule increases with increasing carbon chain length. The computational values were larger than the experimental values, which could be explained, in part, by the addition of water to the computational system, which resulted in a decrease in the heat of adsorption on the (100) surface, compared to the adsorption of the collector in a vacuum. The computational method showed that, in the case of the pyrite (100) surface, the most exothermic reaction was obtained when the two xanthate sulfur atoms bridged two pyrite 5-coordinated iron atoms. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted for each of the C2, C3, C4 and C5 chain length xanthates.The experimentally determined exothermic increase in heat of adsorption for the addition of each CH2 group was found to be -8.17 kJ/mol. The contribution of the thiol head group was -34.9 kJ/mol. Previous studies on self-assembled monolayers have shown that these values are compatible with lateral interactions between CH2 groups and the exclusion of water. This study provides a rigorous experimental and computational approach which is intended to afford confidence in modelled data for the screening of new ligands for flotation processes.INTRODUCTIONComputational modelling is a fast and cost-effective method of screening collector molecules for the efficacy of their adsorption onto mineral surfaces. However, it is desirable to measure the computational outputs against experimental outputs to check for congruency. Computational modelling and experimental microcalorimetry both deliver the same output parameter: the energy of adsorption of the molecule onto the solid surface. These techniques are therefore ideally suited to complement one another in investigating the affinity of the interaction between collector molecules and mineral surfaces."

Jan 1, 2018

By G. Y. Liu

The structure-activity relationships for four thionocarbamate collectors are discussed in this pa-per. These collector classes are alkyl alkyl thionocarbamates, allyl alkyl thionocarbamates, acyl al-kyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates. The main emphasis will be to highlight the differences between collectors and their affinities for copper and iron sulfide minerals on the basis of data on electronic-structure properties obtained by vacuum and solution density functional calculations, flotation experiments and analysis measurements. The mechanism of interaction of these collectors with sulfide minerals is also discussed with perturbation theory. The theoretical study results indicate that acyl alkyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates have best performance in these agents as flotation collectors with improved collecting power for copper sulfide minerals and excellent selectivity against iron sulfide minerals, which are consistent with the experimental data reported in the literature.

Jan 1, 2014

By J. Sachweh

The last few years have shown a significant increase in the demands for fine products, which means everything under 10µm. There are more and more applications requesting extremely fine ground powders leading to the development of several milling machines which are better adapted to the new products. Cost saving machinery is important for the worldwide competition. Especially the energy consumption is extremely important for any fine ground product. A worthwhile field for mechanical engineering companies is the dry milling machinery as there are not as many solutions available compared with wet milling applications. In many cases wet mil-ling is the only solution to reach the requested quality, but there are also a lot of applications which can be performed in a dry way on the premise that the right mill and classifier are available. Dry milling permits to save energy and allows to influence the particle size distribution more easily, as a classifier can be used in that case. This will significantly reduce production costs and can enable the production of new products with better properties. The Tower Mill is well-known already in the field of wet grinding. Recent research work and end user reports have shown clearly that this mill has a lot of advantages compared to a ball mill. Up to now this advantage is limited to wet grinding as only few mills have been used for dry grinding. There is no doubt about the efficiency of dry grinding, but new and improved feeding and discharg-ing systems have to be developed in order to enable the full range of its advantages. Especially the high production capacities are a challenge for mill and classifier designers. The Tower Mill with its special grinding mechanism allows to cope with very high feed rates, because machines with more than 1 MW are available. Improved grinding efficiency will decrease the circulation load through the classifier and also lead to smaller classifier sizes. Together with im-proved mills the classifier can work more efficiently because the feed material is finer. Results of a test center plant production will be shown together with a comparison between stan-dard machinery and the MaxxMill®. Preferential applications for each mill will be explained.

Jan 1, 2014

By V. Panayotov, M. Panayotova

"The combined use of semiconductor properties and specific flotation characteristics of minerals under different conditions with external influences ensures a possibility for process control and management. This work presents the relations between the volumetric and surface characteristics of minerals and the minerals' flotation ability (flotability), as well as the possibility for the flotability purposeful change. Results from proprietary laboratory and industrial research are presented showing how controlled impacts on minerals and flotation pulp improve flotation technology. Such an approach reveals prospects for the creation of new technologies for the minerals' beneficiation.INTRODUCTIONThe decrease of the useful components content in the ores, the increasingly complex nature of the raw materials, the increasing energy consumption per the unit of production, and the need to solve the problems related to the environment pollution require solutions different than the existing classical ones. One of the ways to find such solutions is the detailed consideration of the fundamental properties of minerals and, in particular, of minerals having semiconductor properties. The studies of Plaksin et al. (1968), Chanturia and Shafeev (1977), Chanturia and Vigdergauz (2008), Carta et al. (1973), Hoberg and Shneider (1975), Rao et al. (1992) have given an idea of the energy state of the minerals, their flotation ability, and the ways in which this ability can be changed in one or the other direction. The main line in these works is the study and use of the relationship between bulk and flotation properties of minerals. To improve the efficiency of the process, it is also necessary to consider the relationship between the surface properties of the minerals, especially minerals-semiconductors, and their flotation ability.THEORETICAL BACKGROUND IN BRIEFA quantitative estimation of energy changes in a solid phase in the process of flotation may be made by taking in account the changes in the Fermi level. Its position in the forbidden band is an indicator about the direction and the intensity of electron exchange between solid and liquid phases. The Fermi level energy EF enables the estimation of flotability, intensity of needed external impact before flotation, as well as efficiency of the process going on. Quantitative estimation of these processes can be made by means of the flotability coefficient Kf."

Jan 1, 2018

By V. A. Luganov

Methods of treatment of pyrite concentrates differ, depending on the content of pyrite and non-ferrous metals: oxidation roasting, sulphatization roasting, smelting, direct hydrometallurgical treatment and so on. Existing technologies do not provide for high recovery of metals, expenses associated with existing technologies are high, and environmental issues, associated with the existing technologies need serious attention. We have developed universal technology of the activating-dissociating autogenous roasting of pyrite concentrates using air based, or air, enriched with oxygen, blow. The basic process is taking place in accordance with the following reaction: (1-x)FeS2 + (1-2x)O2 = Fe1-xS + (1-2x)SO2 +Q The products of this reaction are pyrrhotinized cinder and roasting gases, rich in SO2 (up to 18 % in case of air blow) and poor in SO3, that contain up to 1 % of elemental sulphur. Cinder contains different forms of pyrrhotite. These forms of pyrrhotite differ by its content (from Fe0.843S to Fe0.945S), thermodynamic, magnetic (from 4.10-1 to 3.6 SI units), flotation properties (with pyrite dissociation the ?-potential of the product is moving towards more electrically positive charge, from 0.95 for pyrite to 0.2 for dissociation products) and other properties that depend on the conditions of roasting. The combination of pyrrhotizing roasting with different methods of cinder treatment allows to increase the level of sulphatization of non-ferrous metals during the roasting; reduce the amount of blow used during the processing; reduce dust losses to the gas phase; reduce the capacity of gas cleaning system and increase resistance to corrosion of the gas-treatment system, used for the production of sulfuric acid from pyrites. This combination of treatments also allows to use magnetic separation and flotation for separation of ferrous and non-ferrous metal compounds during cinder treatment; perform de-arsenation of arsenic containing concentrates and by-products. Pyrrhotinized cinder may be treated by oxidizing and non-oxidizing hydrometallurgical methods. Keywords: Pyrite, polymetallic ores, sulphidization roasting, pyrrhotite, magnetic separation, arsenic sulphide

Sep 1, 2012

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

By S. Saha

Minerals in coals cause operational problems in various coal utilization technology as well as act as diluents towards its heat value. Indian coals contain higher percentage of mineral matter compared to foreign coals due to its formation through drift origin. Efficient utilization of high ash coal in environment friendly manner is the driving force for the development of clean coal technology. Coal gasification offers practical means meeting stringent environment controlled parameters for producing power, chemicals, liquid fuels and clean energy on a single platform. It is well accepted that gasification technology has sufficient potential for sustainable development of clean coal technology. Gasification reactivity depends on the coal properties and operational parameters as well as minerals present in coal. Minerals not only create operational problems but on the other side also catalyze the gasification and combustion reaction. Therefore to understand the effect of minerals on the gasification reactivity, present paper proposes to study the variation of gasification reactivity with various gravity cuts such as, 1.4-1.5; 1.6-1.7; and 1.8-1.9 of a selected coal. Gasification reactivity has been studied by thermo gravimetric analyzer (TGA) using CO2 as gasifying agent. Surface properties such as, true density, apparent density, porosity, surface area of different gravity cut samples have also been measured to find out the effect of gravity separation on gasification reactivity. Keywords: gasification, reactivity, mineral matter, gravity separation

Sep 1, 2012

By M. Eraydin

Dewatering fine particles (e.g., flotation concentrates) is inefficient, energy intensive and often requires large capital and operating costs. To address these issues, a series of advanced dewatering technologies have been developed at Virginia Tech. These include novel dewatering aids and a hyperbaric centrifuge. Typically, the moistures obtained using these methods are 30% to 50% lower than those obtained using conventional methods, as demonstrated in laboratory and pilot-scale test programs. With another novel dewatering technology that has been tested in bench-scale tests, the moistures can be reduced to levels once believed to be attainable only through the use of thermal dryers. In this communication, test results obtained with these advanced dewatering technologies are presented and compared.

Jan 1, 2014

By Jaeheon Lee, Jae-Chun Lee, Doyun Shin, Minseuk Kim, Hyunsik Park

"The appropriate treatment of cyanide waste water is becoming an emerging issue because of the toxic residue and large quantity produced from gold processing plants. In the present article, we designed and operated a continuous biological cyanide treatment system using domestic sewage sludge and various microorganisms including a cyanide-producing and degrading bacterium, Chromobacterium violaceum. The synthetic wastewater containing 50 mg/L of cyanide was pumped continuously into the reactor at a flow rate of 500 mL/d for 21 days. When 50 mg/L of cyanide was fed, the cyanide concentration in the effluent of the reactor inoculated with activated sludge (S-50) decreased by 7.5 mg/L in the effluent. The other reactors did not show significant cyanide degradation and the reactor inoculated with C. violaceum showed increased cyanide concentration in the effluent. The microbial community in the reactors was analyzed by 16S rRNA-gene based pyrosequencing technique to investigate microbial response to cyanide addition and operation time. The microbial community analysis shows that the phylum Proteobacteria was detected in the reactors showing significant cyanide degradation (S-50), while Firmicutes and Bacteroidetes was dominant in the other reactors with very low cyanide degradation. Proteobacteria could not compete when the other phyla Firmicutes or Bacteroidetes were inoculated. This study shows the feasibility of the biological cyanide treatment system for gold processing plants and contributes new fundamental knowledge about the microbial community in the biological cyanide treatment system. INTRODUCTION Cyanidation has been widely used to recover gold from ores or secondary resources since first proposed by MacArthur and Forrest in 1888 (MacArthur et al., 1888) and it is used in many states of the USA, including Nevada, Arizona, California, Colorado, and Idaho (Laitos, 2012). Cyanide compounds are highly toxic and create serious problems for wildlife and water management (Solomonson, 1981; Donato et al., 2007). Furthermore, because many countries have imposed strict standards for cyanide discharge (USEPA, 1985), it is essential to develop a cost-effective and environmentally friendly technology for treating cyanide-containing wastewater."

Jan 1, 2018

Most of the Indian coking coals are medium coking and of very high ash content. Beneficiation of these coals is a must for their utilisation in coke making. During washing while the ash content of the coal is reduced, the same is expected to affect the reactive-inert ratio and the proportion of various petrographic constituents in the clean coal. This will affect the coking behaviour, including the expansion characteristics, of such coal. An increase in expansion behaviour of coal increases the wall pressure and may damage the battery wall. Therefore, close monitoring of coking properties along with drop in ash is necessary for smooth use of the coal in coke ovens. An effort is, therefore, essential to understand the impact of washing on its coking properties. The studies were carried out with captive coals of Tata Steel, India. Three medium coking coal samples namely, VII A, VI A and XI SEB seam coals of West Bokaro Colliery were used for the study. The coal samples after washing to different ash levels were subjected to the following analysis: proximate, crucible swelling number (CSN), LT GK test, dilatometer and plastometer tests and petrography. The experimental data were then analysed to assess the relationship of various coking properties of the coal with its ash content. The studies clearly show that there is a strong impact of beneficiation of the coal on its coking behaviour. The impacts are more at lower level of ash in the clean coal. In general, the coking properties increase with a decrease in ash. This is primarily due to an enrichment of vitrinte materials in the clean coal and an increase in the reactive-inert ratio in the coals. However, the most important impact of the lowering ash is on the increase in the swelling nature of the coal. The coals with lower ash become highly expanding in nature. This may be very critical from operations of coke ovens point of view, especially stamp charged coke ovens. Necessary precaution should be taken in selecting the other coal blend constituents when these coals are beneficiated to a very low level of ash content.

Jan 1, 2014

By T. Damyanov

Spherical grinding media (balls) are the most widely used media for comminution of ores by grinding. A modelling simulation study of the behavior of two grinding media in the grinding process was conducted to determine the possible advantages of the new shape milling bodies called tetraballpebs. Tetraballpebs are in the shape of tetrahedrons with spherical convex walls. A three dimensional CAD model of the mill drum with a diameter of 1200 mm was used. A continuous operating mode was simulated in terms of the 3D contact elements of the model (milling bodies and mill drum). Simulation tests were carried out in a typical grinding mode and at a typical rotational speed of the drum mill (75 per cent of the critical speed in cataracting mode). Studies carried out with both grinding media include equal number of milling bodies with the same weight and volume. Having thus ensured a uniform mass of the grinding media and same number of milling bodies, and constant other conditions and process parameters, conclusions can be drawn about the influence of the shape of the milling bodies on the grinding process. A kinematic analysis of the system using CAE (computer-aided engineering) model parameterization was conducted. The controlled parameters are: ? Power draw; ? Kinetic energy of each milling body; ? Motion of milling bodies inside the drum Keywords: grinding, grinding simulation, balls, tetraballpebs, DEM, CAD-CAE

Sep 1, 2012

By Aziza A. Yousef, Suzan S. Ibrahim, Mahmoud A. Arafa, Mohamed A. Abdel Khalek

In view of the shortage of soft water all over the Middle East countries, seawater may be used to replace the fresh water in flotation beneficiation. The flotation process required about 7 m3 of fresh water/ ton ore. This article aimed to study the effect of seawater cations and anions on the flotation process of four important mineral commodities. The adsorption of collector, zeta-potential, zero point of charge and floatability of pure minerals were studied. The individual effects of different cations and anions that are predominant in seawater, within their more or less actual concentrations were studied on individual mineral and on groups of them. The troublesome Ca2+ and Mg2+ ions, in the anionic circuit could be controlled by soda ash addition to the pulp before the anionic collector. The addition of sodium silicate improved the floatation selectivity of mineral mixtures and natural ore. At the optimum conditions the calcareous phosphate ore yielded a concentrate recovery of 83% with a grade of 34% P2O5, with 0.61%MgO, which from an ore assaying (25.3% P2O5 and 9.4% MgO).

Jan 1, 2003

By P. N. Mohan Das, K. Harikrishna Bhat

"The major ilmenite reserves are located in India at Chavara (CH), Manavalakurichi ( MK) and Chatrapur, Orissa (OR). India stands first in terms of ilmenite reserves, which are estimated to be 278 million tonnes out of which, 142 million tonnes are processable. Mineralo-chemical analysis shows that Chavara ilmenite is the most weathered one with about 60% TiO2 while Chatrapur is the least weathered with about 50% TiO2. Co-existence of ilmenite with pseudorutile, rutile and haematite is observed in substantially varying amounts in the three deposits. It is observed that the tropical weathering rather than the source rock difference has apparently played an important role in imparting major compositional and structural dissimilarities among ilmenites in different places.In processing of ilmenite through the Becher process, aeration rusting of pre-reduced ilmenite is found to be the rate limiting step thus, affecting the productivity of the process. Investigations have proved that the addition of some organic compounds such as glyoxal, sucrose etc., to the system accelerates the reaction to such an extent that the rusting time has been reduced to less than half.A new route of processing ilmenite for synthetic rutile has also been developed in which, ilmenite is carbothermally reduced and then processed through plasma route. The slag thus obtained is processed further to get high-grade synthetic rutile, metallic iron and high purity iron oxide. The process has been scaled up in a continuous moving bed plasma reactor. It is technologically and economically more viable where, all the iron values are recovered as salable byproducts. This paper describes the salient features of the technologies developed for the beneficiation of ilmenite to synthetic rutile."

Jan 1, 2003

By Leopoldo Gutierrez

Eight oil sand ores with the bitumen content ranging between 3.6 and 15 wt.% and the fines content (-44 micrometers size fraction) between 9 and 69 vol.% were subjected to the standard alkali extraction test used to measure the degree of oxidation of metallurgical coals. The results showed that there is a strong correlation between the absorbance of extracted solutions at a wavelength of 520 nm and the ratio of the fines content to the bitumen content. The latter factor is directly relevant to assessing the extractability of bitumen from oil sand ores. Bitumen extraction tests showed that the bitumen recovery decreased from 90 % to 30 % when the absorbance at 520 nm increased from 0.23 to 0.64. A comparison of the UV/visible spectra of solutions obtained from the alkali extraction tests with solutions of Aldrich Humic Acids suggest that low bitumen/high fines oil sand ores release substantial amounts of organic matter very similar, if not identical, to humic acids. In contrast, high-bitumen and low-fines ores do not release as much of the organic matter, and UV spectra of these leached substances are quite different from those of humic acids. Overall, the results show that chemical composition of bitumen in the tested ores varies greatly with ore type and oxidation, and that the alkali extraction test is a promising technique to quickly assess the extractability of bitumen from a given ore type.

Sep 1, 2012

By Ralph J. Holmes, Victor Sharp, Steven J. Spencer, Kevin J. Davey, Jonathan J. Campbell, Peter L. Phillips, David G. Barker

"Improved measurement tools for monitoring and control of AG/SAG mill performance have a high level of interest in industry. Historically, acoustic emission monitoring has been widely used on SAG/AG/ball mills and hydrocyclones to provide new information on the conditions inside these devices affecting their performance. The current work was focused on a new technique using surface vibration monitoring of a number of pilot-scale and production-scale AG/SAG mills to yield insights into the events occurring in the mills. The development of relationships between signal analysis outputs and mill operating conditions can be used for soft-sensor measurement of mill process variables. The technique used an array of accelerometers mounted on the mill lifter bolts linked to a fast data acquisition system which monitored the surface waves generated during operation. Details of the system are presented. Mill operating variables were adjusted systematically to provide a wide range of operating conditions for surface vibration signal collection. The experimental approach is discussed.The signals acquired during the experiments were analysed using a range of techniques. The results show that strong relationships exist between measured vibration power (both total power and within certain frequency bands) and mill load level/power and mill speed. A new method for extraction of power spectral density and band power information on features of interest in a mill rotation cycle is also presented.These results show that single sensor analysis information from the surface vibration system can be used as soft sensor inputs for monitoring process variables such as mill load that until now, have not been reliably measured. System outputs also show considerable promise in the area of condition monitoring. An example of the signal analysis output is presented showing elevated vibration levels in an area with higher resultant wear. Eventually, it is considered that outputs from this system for process variable and wear condition monitoring will be key new inputs to an online AG/SAG mill monitoring and control system."

Jan 1, 2003

The ultimate goal of a mineral processing plant is to recover as much of the target mineral(s) as possible from the ore being treated to achieve the best economics. Selection of the mineral processing techniques is the most important step in achieving this goal. However, due to the complexity of the ore, the recoveries of valuable minerals may be not satisfactory even when the mineral processing technique(s) are well chosen. In other words, minerals of interest can be lost to the tailings for mineralogical reasons. For example, gold is mainly extracted from the ore by gravity, flotation, cyanidation, or a combination of these processes, and high recovery (>90%) can be achieved when gold occurs as coarse grains. However, when a refractory ore is being processed, gold extraction will be challenged by mineralogical factors, which often cause gold losses to various tailings. Mineralogical factors affecting gold recovery mainly include grain size, shape, surface coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of slow-dissolving gold minerals and the refractory nature of submicroscopic gold. Among these factors, locking in sulphide, silicate and other minerals as fine-grained gold inclusions and/or as invisible submicroscopic gold is by far the most common factor leading to poor gold recovery encountered in gold ore processing. Processing of PGE ores faces the same challenges as gold. Small grain size and locking of PGM in sulphide and non-sulphide minerals often cause PGM losses. When silver ore contains significant amounts of pyrargyrite, proustite and stephanite, silver recovery by cyanidation can be very low because of the slow dissolving kinetics of these minerals. In the processing of base metal ores, high content of pyrite, intergrowth of chalcopyrite with sphalerite and presence of clay miner-als may cause problems in recovering Cu-, Pb- and Zn- bearing minerals. Process mineralogy helps address all issues and problems related to mineral processing with predicting and trouble-shooting being two major objectives. It provides useful information on process selection, flowsheet development, recovery improvement and reagent consumption optimization. The information acquired from a process mineralogical study can be used as a guide for a metallurgical testwork program for process design or optimization.

Jan 1, 2014

By Brian Hart, Liuyin Xia, Staman Dimov

The recovery of rare earth elements (REE) is fast becoming of significant interest globally. Modern research and development programs (outside China) towards the optimization of REE mineral recovery by flotation have been lacking. Due to the mineralogical nature of many hosting deposits, the separation and recovery flotation flowsheets can be very complex. As part of a research project, a selected suite of hydroxamic acid collectors (Naphthoyl, Cyclohexyl, Benzoyl, Octyl, Terta-butyl benzoyl, Salicylic) were tested in order to examine their potential for recovery and selectivity. Micro flotation tests were conducted on a feed sample, recovery and grade of the products were used to evaluate their relative flotation efficiency and selectivity and these results (flotation with the hydroxamate collectors) were compared to a phosphoric acid/sulphonate collector mix(shorten as "mixed"). In the testing, the flotation response with the hydroxamate collectors was significantly better than the "mixed" collectors on freshly ground (no slimes removed) samples. Furthermore the tests revealed that for most of the hydroxamate reagents tested, their dosage requirements to achieve recoveries at the same levels was less than that for the "mixed" reagents. Product assays show that recovery of both La and Ce is significantly better for using the salicylic hydroxamate and that Nb, Y and Zr recovery are favored by using octyl hydroxamate. These results indicate mineral flotation selectivity could be achieved by using selective hydroxamtes. Spectral fingerprinting by TOF-SIMS surface analysis has allowed for the identification of reagent species. TOF-SIMS surface analyses of grains analysis confirmed that REE bearing grains reporting to the concentrates are doing so in response to collector attachment whereas grains reporting to the tails are doing so in response to a lack of collector. The TOF-SIMS surface data bas been used to examine the factors promoting flotation stream partitioning.

Jan 1, 2014

By G. Deschênes

In the last 4 years, the high price of silver attracted more interest for improving its extraction. Metallic silver and silver minerals require a high concentration of cyanide and show slow leaching rates and poor extraction. This investigation determined the effects of dissolved oxygen, lead nitrate and a pretreatment on silver leaching from slurry containing quartz mixed with metallic silver and high purity acanthite. Stephanite, pyrargyrite and polybasite were also used in the study. The silver minerals were characterized by chemical assay, X-ray diffraction analysis (XRD), image analysis (MP-SEM-IPS) and electron microprobe analysis (EMPA). Increased dissolved oxygen of the slurry produced the fastest silver leaching kinetics. The leaching of silver from high purity acanthite was determined under various conditions and compared to a new process called ?CANMET Enhanced Leaching Process (CELP). For a slurry containing acanthite, a 23% improvement (from 76% to 99%) in silver extraction was obtained with the CELP. In presence of pyrargyrite and polybasite, silver extraction increased from 75% to 90% and 86% to 99% respectively using the CELP. No improvement was obtained for the slurry with stephanite (99% extraction in 72 hours). However, the sliver leaching rate was much faster with the CELP. XPS analysis of individual silver mineral particles showed that CELP leached surfaces were considerably more oxidized relative to the conventional cyanidation leached surfaces. Leaching of two gold/silver ores indicated that the efficiency of the CELP increased with the refractoriness of the sample. Gold extractions were comparable for the two technologies while silver extraction improved up to 5% (70g/t) for the CELP. The final leach solutions contained lower concentrations of copper, which consequently reduces the effluent treatment costs.

Jan 1, 2014

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and. crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study. Examination of the elemental composition of the minerals, ion-molecular components of the liquid phase in suspensions, surface properties of sulfides and different flotation reagents sorption forms was performed using the methods of X-ray phase and spectral analysis, potentiometry, UV and IR spectrometry, computer image analysis, and computer simulation techniques. The role of isomorphous impurities in the formation of hydrophobic sulfhydric collector layers on mineral surfaces in complex ore processing has been elucidated. The parameters characterizing the variability of the Fe:S ratio in pyrite of different origin have been determined based on non-stoichiometry characteristics of natural gold-bearing sulfide crystals. An ingenious method of formatting and linear approximation of experimental data was used to find out the quantitative relationships between the impurity content, electrophysical characteristics, non-stoichiometry and floatability of pyrite from a number of different deposits. The effect of the impurity species present in sulfides on the characteristic pH value marking the floatability peaks as such and their trend of shift towards higher alkalinity has been revealed. A theoretical substantiation has been given to prognostic assessment criteria for processing characteristics of gold-bearing sulfide minerals with varying composition. New flotation reagents and advanced reagent systems which help to increase the contrast of processing characteristics for different gold-bearing sulfides, resulting in improved selectivity, have been developed. The mechanism of selective flotation of precious metal-bearing Fe and As sulfides achieved by using short-chain dithiocarbamates and a mixture of cyclic trithiocarbonate with oxyalkylsulfides has been analyzed.

Jan 1, 2003

By Leon Lorenzen, Victor E. Ross, Anton W. Kleingeld

Key to successful innovation, whether at organization, industry or national level, is the alignment and utilization of resources in the most appropriate and efficient way. Innovation needs to be directed strategically, and it needs to be auditable in a systematic and integrated fashion. In the light of these considerations, this paper describes the construction and use of a topographical map of the innovation landscape. The purpose of the map is to provide a holistic view of the key factors that enable innovation (the so-called ’landmarks’), how well they are aligned to support a particular type/nature of innovation in the organization, and to identify possible gaps. The significance (importance) and height (performance) of the landmarks in supporting and enabling innovation within the organization is determined by means of a selfappraisal audit. The topography of the landscape derived thus is subsequently interpreted in terms of the organization’s particular innovation strategy and environmental context. The application of the Innovation Landscape Methodology is illustrated in a number of organizations within the Mining and Minerals Industry of South Africa. Important observations and conclusions regarding the strategic alignment of enabler strengths within these organizations are made.

Jan 1, 2003