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By Alexander Malahoff

The summit of L_ihi submarine volcano changed dramatically after seismic activity beneath L_ihi during the month of August 1996. Bathymetric re-surveys of the L_ihi edifice using SeaBeam, Simrad and deep-towed Reson-Focus multibeam systems showed the presence of new north-south striking fissures, normal faults and a new pit crater located at the site of a former 300-meter high volcanic cone. Comparisons between the pre-1996 SeaBeam data and the new bathymetry show a net loss of about 100 million cubic meters of rock volume on the summit. This loss is localized at a new pit crater -- the 300-meter deep by 1,300-meter wide Pele's Pit. Submersible observations with Pisces V show the northern edge of Pele's Pit to be bounded by a normal fault located north of the site of the former Pele's Vents cone that has disappeared into the new pit crater. A new hydrothermal field, the Ikaika Vents, extending from a water depth of 1,311 meters to 1,287 meters has formed at the northeastern edge of the floor of Pele's Pit. Submersible observations of these new Ikaika Vents during September 1996 showed vigorous venting at the site with extensive white-colored bacterial mats hanging off the rock face above the vents. Follow-up mapping and sampling of the vent sites during August 1997 showed vent temperatures of up to 198°C, dense populations of vent shrimps around the vents and a centimeters-thick veneer of fine-grained polymetallic sulfide mineralization along the rock walls above individual vents. The mineralogy of the sulfides shows a barite, chalcopyrite, sphalerite, and pyrite composition.

Jan 1, 1998

By Tetsuo Yamazaki

Metal market prices rose drastically in 2006, and most broke historical records as shown in Figs. 1-4. This increase has been basically driven by economic growth in Asian countries, especially China. The growth trend is expected to continue for several years. Then, India will follow the same growth trend. Their metal demands keep the price levels high for 20 years or more. One more additional important factor on the metal market prices is hedge funds come into the market. Japan imports all metals for domestic use from overseas. The amounts imported were 1.27 million tons in copper, 0.32 million tons in lead, 0.59 million tons in zinc, 0.20 million tons in nickel, and 1.18 million tons in manganese, respectively in 2006 (Source: http://www.jogmec.go.jp/j_resourse/index.html#03). Though mainly we import the concentrates and our domestic customer smelters take the part of metallurgical leaching, the payment necessary for purchasing the concentrates is estimated about US$ 10 billions in 2006. The payments in 2005 and in 2003 were about a half and a quarter of the 2006, respectively. Japan must have effective counter measures to reduce the future payments.

Sep 24, 2006

By Yves Fouquet

Results of the two main drilling operations on hydrothermal fields demonstrate that the two dimensional submersible operations need to be followed by drilling expeditions to study the third dimension of hydrothermal systems and understand hydrothermal and ore forming processes. Two types of environments were drilled recently in basaltic environment on slow spreading ridge, and on a sedimented ridge. Similar work has still to be done and targets to be discussed in other environments such as back-arc basins for felsic rocks environments and slow spreading ridges for ultramafic rock environments.

Jan 1, 2011

By V. V. Ivanov, A. I. Khanchuk, E. V. Mikhailik, M. G. Blokhin, P. E. Mikhailik

At present, marine ferromanganese crusts of seamounts are of great interest as a source of high-tech metals. The metals most enriched in these deposits are essential for a wide variety of green-tech, emerging-tech, and energy applications (Hein et al., 2013). There is a grate number data on the content of major and minor metals (thousands analyses). However, information on the content of such elements as platinum, gold and silver in the world literature is limited. The concentrations (N – number of analyses) of platinum, gold and silver in the Pacific are 418 ppb (N = 105), 35 ppb (N = 72), 1.02 ppm (N = 26), respectively, and in the North Pacific Prime Zone - 477 ppb (N = 66), 55 ppb (N = 13), 0.1 ppm (N = 4); in the Atlantic Ocean is 567 ppb (N = 2), 6 ppb (N = 2), 0.20 ppm (N = 18), in the Indian Ocean, 211 ppb (N = 6), 21 ppb (N = 2), 0.37 ppm (N = 9) respectively; (Hein et al., 2013). The northern part of the Pacific is poorly studied in this question. The samples of ferromanganese deposits (FMD) was recovered from the Govorov Guyot (Magellan seamounts), MZh-33 Guyot (Marshall Islands), as well as the Detroit Guyot (Imperor Ridge) and Yomei Guyot (Fe-Mn placer Holes 431 and 431A DSDP, Imperor Ridge).

Jan 1, 2018

By John Parianos

2013 has seen good progress for Nautilus Minerals and our projects due to the determination of our people and the continued support from shareholders and stakeholders. Our focus remains Solwara 1 in Papua New Guinea for which the build continues on the seafloor production tools, subsea slurry pump and riser and lifting system.

Sep 14, 2011

By Gale L. Hubred

Kennecott?s Ledgemont Laboratory developed the Cuprion Process to recover metal values from manganese nodules in the early 1970s. A reducing leach of monovalent cuprous ion attacks the manganese oxide matrix, converting the manganese dioxide to manganese carbonate and releasing the copper, nickel, cobalt, and zinc as ammine complexes. Cuprous ion is generated by contacting leach liquor with carbon monoxide. Copper, and nickel, are recovered by solvent extraction and electrowinning. Cobalt is precipitated as cobalt sulfide and recovered as cobalt powder. Manganese, molybdenum, and zinc can be recovered optionally but have not been included in this process. Kennecott authors have described aspects of the process, but the Cuprion process has not been revealed except in patents. Tables are included for capital and operating costs and revenue. Even though economic recovery of nodules is not anticipated in the foreseeable future, some of the process steps may have application in other places. The Ledgemont Laboratory was a unique operation we think worth documenting. The report is based upon work done up until the mid 1970s. The report represents the work of the entire Kennecott nodule team. It is this author?s intention to save this result and credit the work of that nodule team. The paper is dedicated to the memory of Dr. Herbert Barner, a key member of the team who died in 2003.

Jan 1, 2005

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamajim, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamaji, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By K. T. Damodaran

The Chavara and Manavalakurichi placer deposits have been known since a long time for their rich reserves of heavy minerals like ilmenite, rutile, monazite etc. While detailed work has been conducted on the mineralogy and texture of the bulk placer sediments, reports on the detailed investigations on individual minerals are relatively scanty. Though, limited work pertaining to the chemistry of ilmenite has been carried out by Nair et al (1995) and Ramakrishnan et al (1997), a comprehensive study of the weathering patterns of ilmenite along the longitudinal and vertical profiles has not been, so far, undertaken. Data on the microscopic analysis of ilmenite from the southwest placers, too, is sketchy. The present work deals with the variation of the weathering undergone by ilmenite in the southwest placer deposits based on chemical and mineralogical analyses.

Jan 1, 2002

By S. Rajendran

The area of the Exclusive Economic Zone (EEZ) of India is about 2.014 million km2 and the resource evaluation of placer deposits is one of the objectives of Government of India. Placers are detrital metallic minerals found on beaches and in the near shore areas. Quantitatively more important are placer deposits of light heavy minerals such as zircon, ilmenite and rutile. Rivers and other drainage channels are the main carriers of the placers which contain heavy minerals like magnetite, ilmenite, garnet, zircon, monazite, rutile etc. The present beach as well as part of the shelf was land during Pleistocene as a result of the world wide lowering of the sea levels. The coast line shifted a number of times. Hence, the heavy mineral placers on the beaches are expected to extend to offshore areas chiefly with Pleistocene lowered sea level strands. India has extensive deposits of heavy mineral placers along the beaches. Placer deposits of heavy minerals occur in discontinuous patches on the beaches along many parts of the east and west coasts. Along the central west coast of India (12??N - 19? N lat.) the placer containing 14 - 17% ilmenite form an estimated reserve of 4 million tons. On the Ratnagiri coast of Maharashtra, the proportion of heavy mineral varies between 54 and 70% in the bulk samples, consisting mainly of 14 - 39% magnetite and 16 - 30% ilmenite. The National Institute of Oceanography (NIO) surveys show that the sediments off the central west coast consist largely of silty sand, sand silt and clay. The core samples show that a reddish brown clay overlay olive gray clay which in turn overlay heavy mineral rich sands. The heavy mineral concentration ranges upto 90% and has mainly ilmenite and magnetite with minor quantities of apatite, rutile, zircon, kyanite etc. Siddiquie et al. reported 42 - 75% TiO2 in the ilmenite.

Jan 1, 1998

By Stephen J. Juras

The Myra Falls deposits comprise a complexly metal-zoned polymetallic volcanogenic massive sulfide district located 90 km from Campbell River in central Vancouver Island, British Columbia, Canada. The massive sulfide deposits are hosted by subaqueously-deposited rocks of the Devonian age Myra Formation of the Sicker Group volcanic assemblage. The deposits comprise many individual massive sulfide lenses grouped into several major zones within two main felsic volcanic stratigraphic intervals - the upper Lynx-Myra-Price Horizon and the lower H-W Horizon. The largest of these zones, the H-W and Battle, occur within the H-W Horizon. The first claims in the area of what is now Boliden-Westmin?s Myra Falls Operations were staked in 1917. Early prospecting resulted in the discovery of three massive sulfide showings which eventually became the Lynx, Myra and Price mines. Sporadic exploration was carried out until 1961 when Western Mines Ltd. (now Boliden-Westmin Ltd.) acquired the claims. Subsequent ore definition outlined 1.9 million tonnes of ore (approximately 5 years of mine life) in the Lynx deposit, and mining began in 1966. Pre-mining geological reserves (to January 1, 1997) comprised 6.7 million tonnes grading 3.3 g/t Au, 130.6 g/t Ag, 2.0 % Cu, 1.4 % Pb and 10.2 % Zn for the Lynx-Myra-Price deposits, 17.1 million tonnes grading 2.3 g/t Au, 32.7 g/t Ag, 2.3 % Cu, 0.3 % Pb and 4.2 % Zn for the H-W deposits and 4.2 million tonnes grading 1.1 g/t Au, 27.0 g/t Ag, 2.2 % Cu, 0.5 % Pb and 12.0 % Zn for the Battle deposits. Property-wide production to January, 1996 has been 15.7 million tonnes grading 2.1 g/t Au, 58.7 g/t Ag, 1.9 % Cu, and 5.2 % Zn.

Jan 1, 1998

By Jan Stenlokk

The Norwegian Petroleum Directorate, which is the Government agency for the management of offshore geo-resources including seabed minerals, is about to finish this year’s marine data acquisition cruise in the Norwegian Sea. We would very much like to present the preliminary results of that cruise, including the discovery of a new black smoker and surrounding sulphide deposits.

Jan 1, 2018

By G. Rehder

The release of methane as free gas from the seafloor into the water-column well within the hydrate stability field is a natural process observed today in various ocean settings, such as the Cascadia margin, the Black Sea, the Guayamas Basin, and the Gulf of Mexico. The subsequent dissolution of gas bubbles into the water-column determines the vertical distribution of aqueous methane in the water-column and the upwards methane flux. Understanding this process not only is essential to describing the impact of natural deep-sea gas seepage, but also to assessing the hazard potential from blowouts and offshore exploitation activities, which are steadily expanding to greater ocean depths. Furthermore, the fate of methane from seeps contributes to scenarios of global change in the past and future involving the large scale destabilization of gas hydrates on a. We recently reported on the extended lifetime of methane bubbles within the hydrate stability field due to the formation of a hydrate skin (Rehder et al., 2002), based on in situ measurements of methane and argon bubble dissolution in the depth range 400 to 800 m. More recently, these observations were extended to depths from 900 to 1500 m. Single bubbles were injected from the ROV Ventana into an attached, back-illuminated, flow-through imaging box. The ascent of individual bubbles within the imaging box was recorded with Ventana?s HDTV camera system by piloting the 3-ton ROV upward, at the bubble rise velocity, for up to 400 m of vertical transit. Observed rise velocities were approximately 30cm/sec for all depths. Post-dive analysis of the HDTV video allowed detailed measurements of the bubble shrinking rates. The results of the earlier and new experiments lead to the following conclusions: (A) Methane bubbles released below the hydrate stability field showed markedly enhanced lifetimes, attributed to hydrate skin formation. The change in radius with time, dr/dt, varied from -7.5 micrometer/s above the hydrate stability field to about -1 micrometer/s at the deepest release depth. (B) Bubble lifetime within the hydrate stability field increased with distance in P-T space from the hydrate phase boundary. (C) Before hydrate skin nucleation, dr/dt for CH4 bubbles was comparable to dr/dt above the hydrate stability field. Although variable, the onset time for the hydrate skin effect to occur generally decreased with distance from the hydrate phase boundary (super-pressurization and super-cooling with respect to hydrate formation). (D) Even before the onset of the hydrate skin effect, a slight decrease of dr/dt with increasing depth was observed.

Jan 1, 2005

By Derek V. Ellis

This article is a summary, with documentation and references, of recent global developments in identifying environmental issues affecting the marine mining industry. It is recognised that marine mining for various products occurs at various depths from shallow water (e.g. aggregate and diamond mining) potentially to great depths (e.g. metalliferous muds, and manganese crusts and nodules). Nevertheless there are environmental issues in common, even though the options for resolutions will vary greatly. The point of this review is to identify the issues, so that where site-specific resolutions are considered, it is possible to draw on experience with the issues elsewhere. Related mining issues, e.g. tailings effluent quality, orebody geochemistry, are mentioned where relevant but are not detailed in this article, although obviously they are a part of there solutions to the environmental issues. The environmental issues and their resolutions are important - on the basis of the ethic of not creating more impact than is inevitable, and the long-term financial and social costs at a mine-site of not getting the resolutions right.

Jan 1, 2000

By Mark D. Hannington

Drilling of the active Trans-Atlantic Geotraverse (TAG) deposit during ODP Leg 158 indicated that the size of the mound-stockwork complex is approximately 3.9 million tonnes, including 2.7 million tonnes of massive and semi-massive sulfide (ca. 2% Cu) at the seafloor and 1.2 million tonnes of mineralized breccias (ca. 1% Cu) in a subseafloor stockwork. Quartz-pyrite veining in the stockwork zone extends from about 40 meters below seafloor (mbsf) to a depth of 95 mbsf. Siliceous wallrock breccias in the lower part of the stockwork grade abruptly into chloritized basalt breccias at the margins of the mineralized zone, and massive sulfides at the flanks of the deposit onlap relatively unaltered, partially hematized basalts. The pipe-like dimensions of the stockwork zone do not exceed the diameter of the sulfide mound. Comparisons with samples collected during earlier dive series confirm that the vent complexes at the surface of the mound are not representative of the bulk composition of the deposit. Dramatic vertical zonation of metals within the mound suggests that a long history of hydrothermal reworking has effectively stripped the constituents that are soluble at lower temperatures from the massive sulfides and concentrated them at the top of the deposit through a process of zone refining.

Jan 1, 1998

By J. Bruce Gemmell

ODP Leg 158 drilled seventeen holes into the active TAG hydrothermal mound and underlying stockwork, 26°N, Mid-Atlantic Ridge. Drilling in five different areas, including a high-temperature black smoker complex and a lower-temperature white smoker vent field, revealed the multi-stage depositional history and character of sub-seafloor mineralization and alteration. The upper portion of the mound consist of massive pyrite and pyrite breccias which are underlain by pyrite-anhydrite breccias and then by quartz-pyrite breccias. Quartz-pyrite breccias grade down into silicified wallrock breccias. Chloritised basalt breccias occur at depths greater than 100 m. Several stages of quartz-pyrite±chalcopyrite veins occur in the stockwork zone and lower portions of the mound, whereas anhydrite±pyrite±chalcopyrite veins occur within the upper parts of the mound. Recovery of unaltered basalt near the edges of the mound has constrained the extent of the stockwork zone to a pipe-like feature 80 meters in diameter. A detailed sulfur isotope investigation of sulfides and sulfates within mound and the underlying stockwork zone has revealed the overall range of sulfide d34S analyses to be 0.35% to 10.27%. Anhydrite has a tight range of d34S values 20.55% to 21.56%. There are distinct differences in d34S values between the different textural types of pyrite (massive sulfide, breccia clasts, disseminations associated with alteration, and veins). The massive sulfide and breccia clasts have a similar distribution of d34S values (6%-8%), however the d34S values of the disseminated pyrite associated with the alteration are distinctly heavier (8%-10%). Vein sulfides have the lightest d34S values (5%-7%). Sulphur-isotope values at TAG are, in general, the heaviest reported for unsedimented mid-ocean ridge deposits.

Jan 1, 1998

By T. Yamazaki, T. Goto, R. Arai, N. Nakatani

The importance of cobalt-rich manganese crusts on the Pacific seamounts for possible future rare metal sources has been recognized these 30 years. The thin layer-type coverage and the micro-topographic undulation of basement affect not only the excavation efficiency but also the economy of mining venture. Because of these distribution characteristics, no economic feasibility has been recognized through the past economic analyses. On the basis of a recent geological study about seamount rocks, a possibility of by-product substrate recovery for phosphorous supply with cobalt-rich manganese crust mining has been highlighted. In the mining model, the substrate rocks are utilized as phosphates for agricultural and chemical usages. Under some preliminary technical and economic assumptions, the possibility of cobalt-rich manganese crust mining venture is examined. The results show a better economy of the venture including the substrate rock usage for phosphorous supply. Introduction Cobalt-rich Manganese Crusts and the Economic Feasibility Cobalt-rich manganese crusts on the Pacific seamounts received attention as potential sources for strategic metals such as Co, Ni, Cu, and Mn, due to their vast distribution and higher cobalt concentration than manganese nodules (Cronan, 1980; Halbach, 1982; Manheim, 1986). In the earlier stage, the geological distribution characteristics were reported (Cronan, 1984; Clark et al., 1984; Misawa et al., 1987; Pichocki and Hoffert, 1987) and a systematic feasibility of the mining was studied (Hawaii DPED, 1987).

Jan 1, 2018

By Dwight D. Trueblood

The Benthic Impact Experiment (BIE) is designed to address the effects of sediment redeposition prior to the commencement of commercial mining. The experiment is being conducted in collaboration with Russian scientists from the Yuzhmorgeologiya Association aboard the R/V YUZHMORGEOLOGIYA. Sediment resuspension and subsequent redeposition during manganese-nodule mining is predicted to be one of the primary impacts on benthic communities living on the abyssal seafloor. The redeposition thicknesses that will cause significant faunal mortality in the deep sea are unknown. Sediment redeposition could adversely affect abyssal benthic communities through entombment, or through starvation caused by food dilution and obstructed feeding. This spring NOAA conducted the main portion of the BIE experiment, blanketing the experimental area with varying thicknesses of sediment using the Deep Sea Sediment Resuspension System (DSSRS). The DSSRS was conceived by NOAA scientists, designed and built by Williamson and Associates, and is the critical piece of equipment used to generate the controlled sediment redeposition environment on the 4800-m deep abyssal plane. The DSSRS consists of an 1800-kg sled, 4.8 m long, 2.4 m wide, and 2.2 m high. The sled was towed and powered using an 8,000-m, 26-mm single conductor cable having a 3,000 VAC capacity. As the sled was towed across the bottom, mud was ingested through two rear-facing, 45-cm wide intakes using two 7.6-horsepower pumps, and discharged 10 to 20 m above the bottom through two 20-cm diameter riser hoses. Each pump was instrumented with optical backscatter sensors providing real-time information about the discharge concentration.

Jan 1, 1992

By Jonguk Kim

Submarine hydrothermal activity and mineralization related to island arc volcanism along the Tonga arc were explored during two research cruises in October 2009 (KODOS 09H) and February 2010 (KODOS 10H), respectively. In KODOS 09H cruise, geophysical survey, including multi-beam bathymetry, marine seismic and magnetic investigations, was performed on 10 volcanoes to find out possible structural discontinuity that can act as fluid pathway for formation of hydrothermal deposits at submarine caldera system. The result provided acoustic and seismic image maps and magnetic anomaly maps of targeted volcanoes. Then, detailed seafloor observation and sampling as well as deep tow side scan sonar survey were performed in KODOS 10H cruise on 5 volcanoes which are selected as targeted areas from the previous cruise. Among 5 targeted volcanoes, TA26 shows most extensive hydrothermal activity. Hydrothermal vents and alteration zone were observed on western caldera and summit of eastern cone of the TA26. Although only weak hydrothermal alteration was observed on eastern cone, mineralized fragments of chimney and mound were sampled from western wall of central caldera on TA25 volcano. On TA12 volcano, strong hydrothermal plume and alteration zone was detected during video tows operated between SW scoria cone and small ridge. However, only small amount of hydrothermal altered rocks were collected from TA12. Although hydrothermal activity and mineralization might be formed, supported by plume detection and result of geophysical survey, only weak alteration zones were observed on other two volcanoes (TA19 and TA22). The exploration area generally show shallow depth up to several tens of meters on summit where subsurface boiling of hydrothermal fluid might occur due to low hydraulic pressure, which can affect on styles of hydrothermal venting and mineralization process observed on Tonga submarine arc volcanoes.

Jan 1, 2010

By Raymond A. Binns

The Eastern Manus Basin (EMB) contains three major active hydrothermal zones and a number of smaller occurrences of hydrothermal deposits, and can be considered as a regional-scale modern analogue for volcanic-hosted mineral fields on land. Unlike the central Manus Basin, a back-arc spreading zone with some MORB-like basalt-hosted massive sulfide deposits, the EMB is a pull-apart rift zone between two transform faults, where a basement of Eocene-Oligocene arc crust is being thinned by extension, with rapid sedimentation on the tilted fault blocks. Present-day submarine igneous activity in the EMB, with which hydrothermal activity is associated, has arc geochemical affinities and is related to subduction of the Solomon Sea Plate at the New Britain Trench. Overall, hydrothermal deposits in EMB are found with lavas ranging from picritic basalt to rhyodacite in composition, although the two major occurrences of massive sulfide are hosted by the more siliceous dacite and rhyodacite variants. Some volcanic edifices are central eruptions, mostly of porphyritic lavas or domes, while others are elongate ridges formed by fissure eruption in which the typically aphyric lavas were very fluid. Evidence for shallow-level fractional crystallisation controls of lava chemistry implies presence of subjacent differentiated intrusions or former magma chambers. Seismic tremor at one site during the nearby 1994 Rabaul eruption suggests magma movement in the chamber.

Jan 1, 1998