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By G. A. Van Wielingen

"The conditioning of natural gas to meet contract pipeline specifications involves in the majority of cases in Western Canada, the appropriation of substantial capital expenditures for treating and processing installations. It is therefore of vital importance to the owners and producers of natural gas to arrive at an appreciation of the economics pertaining to the production and surface handling of their gas reserves at the earliest possible stage of field development. The treating and processing of natural gas often results in considerable changes in composition and related physical characteristics between the wellhead and the point of delivery of the saleable gas. This paper presents a general outline of engineering calculations which can be applied in the pre-determination of the effects that surface handling of gas will have on the composition and physical characteristics of sale-able gas. Emphasis has been placed on the calculation of hydrocarbon dew-points, heating values and shrinkages prevailing at the various stages in the surface handling of natural gas. It is believed that advance information indicating the approximate ranges of these physical properties will facilitate process selection and will provide a basis for the estimation of capital and operating costs of process installations."

Jan 1, 1960

By S. Torizuka, I. Mizushima. Kawasakitohri, A. Ohmori, K. Nagai

Strain (work)-hardening in tensile tests were examined for low carbon steels with various ferrite grain sizes ranged from 0.4µm to 16µm. The steels had microstructures composed of ferrite grains and dispersed cementite particles. They were fabricated through warm caliber rolling with an accumulative area reduction of 93%. Strain-hardening rate at a given strain increased with an increase in volume fraction of cementite particles. The balance of yield strength and uniform elongation for ultrafine-grained structures could be improved by the dispersion of cementite particles. Effects of the cementite dispersion and the ferrite grain size on the strain-hardening rate can be roughly explained by the work-hardening model with GN-dislocation density. Strain-hardening design using dispersed cementites was proved to be effective in controlling ductility of the ultrafine-grained steels.

Jan 1, 2004

By D. F. Sherwin

"THE AREA which is described in this paper (Fig. 1) includes the continental margin of eastern Canada extending from the Gulf of Maine to the north edge of the Grand Banks, which, including the continental shelf, slope and rise, comprises an area of about 600,000 square miles. The paper is intended to give a background of the geological setting of this region in the context of its ultimate potential for oil and gas reserves in close proximity to the Nova Scotia energy market.HISTORY OF EXPLORATIONThe history of geological exploration of this area really began in 1878, when U.S. fishing boats brought back samples of rock recovered in trawls from their expeditions to the long-famous fishing banks off Canada's East Coast. Tertiary and Cretaceous fossils recovered from these samples indicated that the eastern Canadian continental shelf was actually the submerged northern extension of the Atlantic Coastal Plain."

Jan 1, 1972

By F. P. Morawski, J. E. Schelske, J. R. Geddes, B. R. Eberts, D. M. Wilson, J. D. Jeffries

"The Griffith Mine is located 200 miles northeast of Winnipeg and is 30 miles south of Red Lake, Ontario. Owned by The Steel Company of Canada Limited and managed by Pickands Mather & Co., it has an annual rated capacity of 1.5 million tons of high-grade iron ore pellets with an analysis of 66.3 per cent iron and 4.5 per cent silica.Development of the mine and construction of the plant got underway in January of 1966 and operations began in February of 1968. The orebodies outcrop on the shore of Bruce lake and run under the lake. The ore in its crude form is a metasedimentary low-grade magnetite and occurs in a highly folded banded formation. The average iron analysis of the crude is 29 per cent and the over-all weight recovery is 32 per cent.In order to mine the portion of the orebody under the lake, the soft varved clay on the lake bottom was hydraulically dredged and a dyke constructed of rock, with till used to provide an impervious seal on the lake side of the dyke, prior to dewatering.Mining is carried out by conventional open-pit tech-niques. Ore dressing is achieved by combining one crushing stage and a two-stage grinding system, with beneficiation by magnetic separation, hydroseparation and flotation. Agglomerating is done with conventional balling drums and pelletizing is carried out in shaft furnaces.Of interest and discussed in detail are the 32-foot autogenous cascade mills ."

Jan 1, 1970

By E. W. Shaw

The past year (1950) has been a big one for the oil industry in Canada, with new records being set in almost every phase of exploration and development activity. New highs were reached in acreage holdings, in geophysical activity, in wildcat drilling, and in field development and production. The only item that did not show a substantial increase over recent years was the amount of reserves added by new discoveries. This was not due to a decrease in the number of new discoveries, however, hut rather to the fact that most of the discoveries were made during the later months in the year and could not be fully evaluated by the year end. The foregoing remarks pertain mainly to activity in Western Canada. In Eastern Canada, operations continued on a modest scale. with exploration drilling down slightly from the previous year but with development drilling and production at about the same level. Returning to Western Canada, it is observed that the general exploration play was one of expansion and intensification. The issuing of new petroleum and natural gas regulations by the province of British Columbia precipitated a moderate entry of companies into the northeastern part of the Province.

Jan 1, 1951

By C. M. Diaz, S. W. Marcuson

In the late 19th century, the discovery of rich nickel-copper sulfide ore bodies in Sudbury and the need for tonnage quantities of the metal to be used in nickel steel armor provided the foundation for establishing the Canadian nickel industry. For almost 50 years, International Nickel was the key player. In 1930, Falconbridge Nickel entered the field. These two companies remain the key Canadian nickel producers. This paper discusses the factors that have influenced the evolution of nickel smelting processes. The initial Sudbury ore smelting and nickel copper separation technologies were imported from abroad. It was only in 1937 that International Nickel established a process research laboratory in Copper Cliff The explosive post WW II industrial development created a strong demand for a broader variety of nickel products. For both International Nickel and Falconbridge, R&D became an essential business tool to succeed in the new market scenery. In the last few decades, new technologies were developed and commercialized to respond to the raising cost of energy, society pressing environmental concerns, the advent of nickel laterites as an important source of new metal, the incorporation of new nickel producers to the market, and, therefore, the need to increase productivity. Canada thus became an important exporter of technology. In this paper, the authors review this history with the objective of highlighting the forces that have triggered the most important changes in Canadian nickel smelting.

Jan 1, 2005

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By W. Leblanc, J. C. Marsh, D. Kettle, J. Tompkins, G. Hartley

"The Lingan Mine is the newest of the four operating collieries of the Cape Breton Development Corporation and is located on the east coast of Cape Breton Island. Development of slopes began in 1969 using four Dosco Roadheaders. Production commenced in October 1972, when a partial extraction section utilizing a continuous miner, loader and shuttle car was installed. A second Joy unit is scheduled to begin production early in 1973. This paper describes the production and development operations, the ventilation system and the equipment in use at the mine."

Jan 1, 1973

By Scott Honan, Tassos Grammatikopoulos, Mike Johnson, Kelton Smith, Niels Verbaan, Ernesto Bourricaudy, Eric Larochelle, Rick Sixberry

"NioCorp is developing the niobium/scandium/titanium Elk Creek carbonatite resource deposit. The carbonatite phase contains significant niobium (0.71% Nb2O5), titanium (2.68% TiO2) and scandium (72 g/t) and is composed predominantly of calcite, dolomite and ankerite. Niobium is mostly (80%) contained in the pyrochlore and the balance in various Fe-Nb-Ti oxides, which also host most of the titanium. Scandium is distributed homogeneously throughout the ore mineral assemblage. The process flowsheet recovers separate niobium, titanium and scandium products. Scandium is extracted from whole ore hydrochloric acid leach solutions through solvent extraction, and is further refined through a re-leach and precipitation process. Scandium leach residues are treated with sulphuric acid to recover separate niobium and titanium precipitates. Both hydrochloric acid and sulphuric acid reagents are recycled within the flowsheet. This paper will discuss key bench and pilot test results (focusing on the scandium flowsheet) and will present a conceptual flowsheet developed by the project team for NioCorp at SGS Minerals.INTRODUCTION NioCorp is developing North America's only niobium/scandium/titanium project. The Elk Creek project is located near Elk Creek, Nebraska, and is the highest grade niobium project in North America and the largest prospective producer of scandium in the world. These elements are unique and valuable superalloy materials that are strategic and critical to many industries and national defense technologies. The project includes the Elk Creek Carbonatite (the Carbonatite) that intruded older Precambrian granitic and low to medium grade metamorphic basement rocks. Both the carbonatite and Precambrian rocks are interpreted to be unconformably overlain by approximately 200 meters (m) of Paleozoic marine sedimentary rocks of Pennsylvanian age. As a result of this thick cover, there is no surface outcrop within the Project area of the carbonatite, which was identified and targeted through magnetic surveys and confirmed through subsequent drilling. The available magnetic data indicate dominant northeast, west-northwest striking lineaments, and secondary northwest and north oriented features that mimic the position of regional faults parallel and/or perpendicular to the Nemaha Uplift."

Jan 1, 2017

By C. Rocha R.

Petioles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world's foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Petioles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process, particularly the operation of the jarosite circuit and its effective removal of impurities such as arsenic, antimony, indium, selenium and tellurium, is reviewed.

Jan 1, 2006

By Alyson Morley

The mining sector in Canada is facing significant challenges to develop a competent workforce, including increased technical and logistical operational demands, and the imperative to promote local content. There is an increasingly unpredictable labour pool which can be aging, or have skill shortages, or non-aligned skills. As globalisation continues, companies also require efficiencies during operation across various locations. AMEC has met these challenges in the global oil and gas sector by developing our Capability Development and Competence Assurance (CDCA) program. CDCA is applicable across all process industries, including mining. CDCA supports simultaneous consistency and flexibility by defining competence at task level, with corresponding best practice blended training programs, and evaluation criteria and processes. CDCA then defines role profiles mapped to local task definition. When combined with web-based technology, this granularity allows us to manage high volume workforces, while retaining individual learning plans and progression, aiding job satisfaction, and employee retention.

May 1, 2007

By J. A. Brothers, M. R. Foran

"AbstractThis paper reviews the progress made in the manufacture of hydraulic cement from iron blast-furnace slag by simply grinding the granulated material with other constituents. The influence of the chemical and mineralogical composition of the slag, the conditions of granulation, the manner of drying, and the fineness of grinding, on the hydraulic properties of the cement, is discussed. The effect of additions of lime, portland cement, and anhydrite, alone and in combination, on the physical and cementing qualities of the mortar and concrete made from Sydney blast furnace slag, is shown in tables of data and is reviewed in some de- tail. The work at the Nova Scotia Technical College has shown that a cement equivalent in every respect to portland cement can be made from basic blast furnace slag- by the us2 of certain quantities of portland cement as an activator.IntroductionBlast furnace slag is a potentially valuable material for the manufacture of hydraulic cement. It is a by-product of the manufacture of iron in the blast furnace, and is formed by the combination of the silica and alumina .of the iron ore with the limestone flux. The metallurgist terms a slag .acid or •basic according as the percentage of lime is less or greater than the percentage of silica plus alumina. The basic slags have the •more pronounced hydraulic properties."

Jan 1, 1950

By Thomas Mütze, Frank van der Meer, Gunnar Kretschmar

"The air classification of moist bulk materials is addressed in the literature insufficiently. Therefore a feasibility study investigated the influence of feed moisture on the separation efficiency expecting a reduction with higher moisture content in the feed. Two iron ore samples were characterized in terms of the nature of bonding of moisture as well as its effect on the agglomerate strength. The classification tests themselves were conducted with two dynamic laboratory air classifiers at cut sizes from 45 to 110 µm and a moisture of the feed material between 0 to 10 wt.-%. The quality of classification was assessed by split factor, cut size, separation efficiency, moisture of both products, as well as the yield of the fines as product fraction in a corresponding processing plant. An initial approach was found for a technological implementation: A sufficient drying of a moist feed can be realized simultaneously to the pneumatic transport inside the classifiers. In the present case the drying effect and dispersion intensity was sufficient to provide good separation results up to 3 wt.-% feed moisture. An additional drying step was necessary beyond 3 wt.-%.INTRODUCTIONSpecific information about the influence of moisture in air classifiers is very rare. Mostly only dry products are processed and/or drying prior to classification is recommended. Apart from the specific influence of the feed moisture a lot of literature can be found regarding air classification itself. Altogether air classification can be divided into several sub-process (Leschonski, 1977):- dosage of the feed material,- dispersing the solid feed material into a gas stream,- feeding the dispersed material into the classification zone by pneumatic conveying,- separation of coarse and fine particles, and- separation of fine particles from gas.For wet feed particles also drying plays an important role. Interesting for the present investigation are the humidity of the feed and its influence on the single sub-processes."

Jan 1, 2016

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is con-?ned by tectonic shear zones between marble and metapelites, extending laterally into the marble astabular, pod or lenticular oreshoots (up to 50 m x 20 m x 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical pro?les across mineralized zones con?rm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the in-situ supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly in?uenced by seasonal ?uctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent ?ooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2~10-3.8 to 10-1.4) and oxygenated (fO2~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sul?des and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+was transportedinto karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Abstract-Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is confined by tectonic shear zones between marble and metapelites, extending laterally into the marble as tabular, pod or lenticular oreshoots (up to 50 m ?? 20 m ?? 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical profiles across mineralized zones confirm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the insitu supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly influenced by seasonal fluctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent flooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2 ~10-3.8 to 10-1.4) and oxygenated (fO2 ~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sulfides and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+ was transported into karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2 in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2 increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By S Grönstrand, C. Perez, A. B. Yañez, F. Coddou, P. Morales, H. Elgueta

"The TankCell® 300 forced air flotation cell designed and built by Outotec, with active volume of over 300 m3, was installed at Codelco’s Chuquicamata concentrator in September 2008. After that, a program was conducted, where the new cell was tested against the plant’s existing flotation cells of type TankCell® 160, with an active volume of over 160 cubic meters.Testing program was exhaustive and detailed. Grade-recovery curves for each setup were reported, along with recoveries by particle size. Secondly, operational characteristics like air feed and froth height setpoints, and power consumption are compared side-by-side. As the third topic, gas dispersion characterization included velocity mapping, holdup, bubble size and bubble surface area flux operating range. The fourth area of interest was the retention time distribution (RTD) of the 300 and 160 m3 cells in comparison. A detailed campaign using radioactive tracer tests was conducted to clarify this.All of the investigations mentioned above are reported in separate papers for more detail. The aim of this paper is to collect the key findings, and present them in real terms, always referring to operability and metallurgy of the cells. It is destined for people designing new plants and to those improving and expanding existing ones. The most frequently heard question is: will the new large cells operate at same efficiency as the smaller ones. In short, the answer is: NO. They operate at improved efficiency!INTRODUCTIONIn the last two decades of minerals processing, there have been three dominant trends of development in the flotation technology: equipment scale-up, cell characterization and circuit modeling. Equipment scale-up has been rapid in the past two decades. In the year 1990, the largest flotation cell in use was 50 cubic meters of size. This year, 300 cubic meters is the largest installed cell. Characterization of flotation equipment and circuits is a very popular subject nowadays and has helped many operations to improve their recoveries through better control strategies, for example by using optimized air feed and level control profiles (Gorain, 2005), (Doucet, Gomez, Finch, 2006), or through better maintenance (Coleman, Urtubia, Alexander, 2006). Characterization work is closely linked to circuit modeling. The aim is to produce sufficient amount of data to allow reliable model building. These models are then used to design new circuits and to improve existing ones. So in summary, these three lines of development have slightly different aims – from capital and operational cost to performance optimization. Ultimately, they converge in the same end result – maximizing the profitability of the operation. Following chapters will summarize the extensive test work and scientific studies at Codelco Chuquicamata. The aim was to compare a TankCell® 300 cell, with nominal volume of 300 m3, against two TankCell® 160 machines, with 160 m3 volume in each. The work should yield answers to questions: does the larger cell produce similar results – is the scale-up successful?"

Jan 1, 2010

By S. Vongpaisal, T. R. Yu

"A set of new blast damage criteria has been developed, with special reference to blasthole mining operations, for assessing damage by incorporating the vibration level, rock properties, site characteristics and the effects of ground support systems. The main objective of this work was to provide a database with reasonable accuracy for use in optimizing blast design, numerical analysis and ground control expert system module development.The new damage criteria allow one to estimate the degree of damage to rock structures in terms of a dimensionless parameter defined as Blast Damage Index (BDI). This allows for the description of blast damage in a unified form, and facilitates the development of codes for numerical modelling to express the degree of blast damage universally. A number of field investigations from several stope production and slot opening blasts at a large underground base metal mine were carried out to verify the developed index. The results show a good correlation between the observed damage and the type of damage predicted from the BDI values.Practical measures are also provided for minimizing blast damage in large underground blasthole mining operations"

Jan 1, 1996

By A. Brown

"The first printed report on Canada's coal resources was published in Paris in 1672(1. Written by Nicholas Denys, then Governor for France of Isle Royale (Cape Breton Island), the report dealt exclusively with the coal of the Atlantic region because little or nothing was known about the interior of North America. Clearly, also, he wrote about a resource of which much was known among the military and early settlers of that day. This early knowledge is not surprising because the presence of coal is clearly displayed in the coastal cliffs of Cape Breton as it was also, at a later date, to the first arrivals on Vancouver Island.An example of early use was that of the French garrison at Fort Louisburg in the first half of the 1700s. Still earlier, in 1643, Governor Winthrop of New England reported the receipt of a small ship load of coal from New Brunswick (2). Despite this early knowledge there was no significant development of coal mines until the 1800s. This had to await the ending of wars between the French and British factions and the growth of population. Basically, also, its development awaited the beginning of the Industrial Age. Organized coal mining began in Canada in 1825 with the formation of the General Mining Association. This British firm was the creation of a group of London jewellers which had been granted royal rights, by the British crown, to all minerals in Acadia (substantially the present Maritime Provinces). The Association took over a number of existing small mines and opened up larger operations in the Sydney coal field. Subsequently, it expanded to the mainland Nova Scotia fields at Stellarton and Springhill. The Association continued in existence as the major coal producer in Canada until 1899 when it sold its properties to the Nova Scotia Steel and Coal Company, Limited (3). This Montreal-based firm managed the coal mines as a major Canadian producer of coal until 1968 when financial problems led to the expropriation of the mines by the Government of Canada. The federal government established the Cape Breton Development Corporation to operate the larger mines on Cape Breton Island. This Crown corporation continues to be a .major producer of coal in Canada."

Jan 1, 1985

By Sarah Bélair, Denis Beltrami, Valérie Weigel

"Mabounié is a polymetallic deposit in Gabon containing niobium (1.2%), tantalum (0.03%), rare earth elements (REE) (1.4%) and uranium (0.03%) that are mostly carried by Pyrochlore minerals. Classical route for niobium recovery is a pyrometallurgical process that consists in pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF.ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore. After solubilisation of the valuable elements, niobium / tantalum are precipitated as a concentrate (12% w/w Nb and 0.3% w/w Ta) while REE (2.7 g L-1) and uranium (90 mg L-1) remain in solution. Nearly 90% of REE are recovered from the solution by conventional REE double salt precipitation [NaREE(SO4)2.xH2O) method but some REE still remain in solution as this method does not allow to quantitatively recover medium (Sm, Eu, Gd, Tb, Dy) and heavy (Ho, Er, Tm, Yb, Lu, Y) rare earth elements. From the different process routes studied (solvent extraction, precipitation, ionic exchange etc.), an innovative method has been developed and patented to recover REE residual concentration in solution. This is based on an aluminum removal step followed by precipitation of REE as REE phosphate concentrate (REEPO4) by phosphate addition into solution. The phosphate concentrate is then purified according to the conventional monazite treatment, i.e. caustic conversion and REE solubilisation in acidic media."

Jan 1, 2016