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In the course of an investigation of the influence of bismuth on copper carried out some years ago, (1) the author found that phosphorus exerted a beneficial effect on bismuth-copper alloys of low bismuth and oxygen content by neutralizing the embrittling effect of the bismuth. In the intervening years, a further examination of bismuth-phosphorus-copper alloys has been canied out and the influence of other elements and combinations of elements on copper containing bismuth has been studied.The results recorded in the present paper are part of this investigation.MATERIALSAll the alloys were made from high-grade copper (KS.A. wire-bar) of the following composition: copper 99·95%, oxygen 0,040'%, iron 0·0015%, sulphur less than 0-001%, bismuth less than (j>'OOl%, other elements each less than O· 0010/<-. The bar was hot rolled and cold drawn to strip which was cut into short lengths and cleaned in nitric acid ready for melting.A piece of this 'strip was drawn to wire 0·08 in. diam., annealed at 5000 C, and measured for electrical conductivity as a check on purity. The result was 101·5% of the I.E'.C. standard.In making the alloys, phosphorus was added as 14% phosphor-copper, bismuth as 17% bismuth-copper, and the other constituents either as copper alloys or as elements of a high degree of purity.PREPARATIQN OF STRIPSThe charges were melted in plumbago crucibles (Morgan salamander brand) in an oil-fired furnace, Le;, in the manner commonly adopted in industrial practice. The copper was first melted under charcoal, well stirred with a chaned stick, and the necessary alloying elements added and stirred in with the stick. The weight of a charge varied according to requirements but generally was about 4 lb. The charges were poured into slightly tapered brass moulds heated to about 1000 C and dressed with a mixture of mineral oil and tallow. They were not only poured under charcoal through the burning mould dressing but also- through a ring of flame produced by burning kerosene on asbestos cord wrapped round the top of the mould. Experiments carried out with plain copper proved that by this means oxygen could be excluded from the stream of metal. The billets were 7·5 in. long x O·83 in. diam. x 1·3 lb. weight.The billets were cropped about 1 in. from the top, cleaned in nitric acid, and measured for density by the usual method of weighing in air and -in water. As these measurements were required only as a check on casting, technique a high degree of accuracy was not essential (accuracy = -+ 0·2%).

Jan 1, 1942

The primary object of this paper is to describe the present metallurgical practice of the Emperor Combined Mill, wherein ores from the adjoining and Associated Mining Companies, Emperor Gold Mining Company Ltd., Loloma (Fiji) Gold Mines, N.L., and Dolphin Mines, Ltd., are treated for the recovery of gold and silver.The mining field is located in the foothills, five miles from the sea, on the northern side of Viti Levu, the largest and most important island of the Fiji group.The orebodies occur in basalt and associated ash beds overlain by andesite, tuffs and sediments. The basalt is a dark greenish-black rock and in much of the ore mined is weathered with alteration of the olivine to serpentine and iron oxides, of the augite to chlorite and of the minute included crystals of iron ore to other iron oxides. Into the basalt intrudes a considerable number of andesite dykes, and the lodes occur as veins in these dykes, as "flatmakes" along fissures or, ash beds extending horizontally from the dykes and at the contact of the basalt and the andesite dices.The Emperor orebody is the largest and most important, and consists essentially of massive, shattered, well altered and mineralized basalt.Little or no free gold occurs in the ore at present being milled, the most important host minerals for gold being the tellurides sylvanite and hessite, next in importance being the sulphides, pyrite, marcasite and arsenopyrite. Chalcopyrite is present in quantities large enough to be troublesome in the subsequent concentrate treatment section, while sphalerite, tetrahedrite, bornite, galena and native tellurium are present in small quantities.Unimportant occurrences of native copper have been observed in both Dolphin and Emperor orebodies.

Jan 1, 1953

Among the various methods of thick-seam mining already well-tried in practice longwall caving with extraction of a single slice, as thick as possible, abandoning the top and/or the bottom coal, seems to be the most suitable one for the Australian coal mining industry. The production units of the future should be equipped with heavy double-drum shearer-loaders, wide armoured conveyors, (with one or two central chains) and shield support. Material of this type has been developed for seams up to 6 m thick. Output figures of more than 6,000 tROM/d from a single face can be looked upon as a quite realistic expectation. The problems of co-ordinating such large production units with the whole layout of the mine are discussed. The factors to be taken into account in the planning work and for preven- tion of mine fires caused by spon- taneous combustion are dealt with. For economic reasons the highest possible utilization factor of the very expensive equipment must be aimed at. Furthermore, the seams or parts of seams to be extracted should be carefully selected.

Jan 1, 1976

By K Knorr

Desktop X-ray powder diffraction using a D2 PHASER equipped with fast linear detector was performed on several iron ore and mill scale samples. Data were analysed using cluster analysis and Rietveld quantitative phase analysis. The quantitative mineralogy of both materials could be established. Thus the input is provided for understanding the energy consumption and the CO2 emission during iron production. Furthermore, tabletop XRD allows to distinguish iron ore from mill scales and to quantify their mixtures.

Jul 11, 2011

The recent trend of installing flotation cells with volumes as large as 200 m3 in concentrators is driven mainly by economic considerations such as lower capital, operating and maintenance costs. Despite the economic advantages, the metallurgical benefits from these large cells have not yet been fully realised by the industry. This is mainly due to the lack of understanding of cell operation, viz cell mixing and hydrodynamics, gas dispersion and froth transportation behaviour in large cells. There is still no rational basis for selecting optimum cell operating conditions and down-the-bank operating profiles. The relationship between cell operating conditions and metallurgy is not well established. This has resulted in poor utilisation of cell capacity in many operations. The present trend of installation of fewer cells in a bank requires each cell to be operated very efficiently. Optimisation of cell operation provides an opportunity for significant metallurgical improvements in a flotation circuit with minimal capital expenditure. Extensive work on optimising of cell performance has been carried out at various Teck Cominco operations in Canada, Peru and USA. Three different levels were involved in this work. The first level was aimed at identification of cell operating conditions for optimum mixing and hydrodynamics, gas dispersion, entrainment and froth flow behaviour in individual cells. The objective of the second level was to identify the optimum bank operating profile for cells down the bank in a circuit. The third level then focused on controlling these cell operating conditions and bank operating profiles for tighter control of concentrate grade and recovery for optimum bank metallurgy. This paper presents some of the major findings at all three levels and demonstrates the importance of each level in optimising the performance of flotation banks installed with large cells.

Jan 1, 2005

By P Townsend, F Russell

Palabora Mining Company operates an integrated open pit mine, concentrator, smelter and refinery complex located in the Northern Province of South Africa. The Palabora open pit went into production in 1966, mining 30 000 t/d to produce some 62 000 tpa of copper. With continuous modification and improvement, a mining rate of 82 000 t/d, producing up to 135 000 tpa of refined copper, has been achieved. While these improvements have also enabled the mine life to be nearly doubled, the open pit will reach the end of its economic life by 2003. The Palabora orebody is vertical and the reserve extends to a depth of 1800 m over an area of 700 m by 200 m. Studies to assess the economics of mining the orebody by underground means began in the mid-1980s. These studies indicated that block caving is the lowest cost underground mining method that would generate a suitable return. In March 1996, a decision was made to develop a 30 000 t/d block cave mine that will extend the life of the Palabora Mining Company by a further 20 years. In terms of the relatively high rock strength and the resultant coarse fragmentation that is expected at the drawpoint, the Palabora cave can be considered rather unique when compared to other block cave operations. This paper describes the project in broad terms and details the mining method, particularly with respect to the cavability of the orebody and the design features to deal with the coarse fragmentation. The project commenced in July 1996 and final development of the undercut and drawbells is scheduled for completion in November 2003. This paper describes the status of the project and planning as of April 2000.

Jan 1, 2000

By D Kent, J Kirkpatrick

The mining industry has long wanted a single communication back bone to cover the majority of their requirements underground. The convergence of communication technologies in the office/surface environment has been identified by the mining industry as a means to achieve their long-standing goal. In particular use of Internet Protocol (IP) systems are seen as proving a basis for a mineÆs communication infrastructure. This paper presents the development philosophy and work undertaken by Inco Limited in Canada, as well as the implications of this on suppliers to enable the technology to be mine worthy and readily available.

Jan 1, 2005

By Hall C. E, Chrisholm J. M

Resource calculations for shear hosted deposits of any type are difficult regardless of which calculation technique is used. One of the main problems is the determination of the geometry of the mineralisation. Once this has been elucidated then the appropriate resource calculation methodology can be employed with a search distance and orientation that is relevant.

Jan 1, 1993

By Griffiths J. B

From its mining lease at the northern end of Cohens Reef at Walhalla in the North Gippsland Mountains, the Long Tunnel Extended Gold Mining Company produced 13,695 kg of gold, which at 1980 prices represents a value significantly in excess of $200 million. In the period 1885 to 1908 the mine was one of Australia's principal reef gold producers, being top Victorian producer in six of these twenty-four years. Prior and subsequent occupants of the lease produced an additional 160 kg of gold. The Extended and the other mines on Cohens Reef whilst contributing importantly to the financial resource of Victoria, were the sole important support for the substantial town of Walhalla that had grown up around them. When the mines closed, Walhalla gradually reduced from a bustling developed town to the present attractive mountain village so favoured by tuurriSts. To allow the visitor to obtain a better ;ri.icrstanding of Walhalla's mining past, important parts of the Long Tunnel Extended Gold Mine workings and site are being

Jan 1, 1981

By C Gypton

This paper gives some insights into what to look for when reviewing feasibility studies. The review by a third party is an important element of the risk management process and may be the last remaining opportunity to uncover errors, or identify and reduce project risks on paper before they are converted to financial disappointments, steel and concrete monuments to process failures or cost overruns. The mining industry has had a spotty record in the area of estimating initial capital costs and operational performance, even though the standard of feasibility studies is generally acknowledged to have improved in the last decades. Third party reviews rarely have the luxury of enough time and unlimited funds, so where should the reviewers focus their efforts to be most effective? Assuming that the project already apparently meets investment criteria, the authors suggest where and how to look among fundamental project parameters for signs that serious flaws exist that have the potential to become project killers. We also give advice on how to review cost estimates without becoming lost in the details. The paper is supported with numerous actual examples.

Jan 1, 2003

Leichhardt Colliery is developed for underground mining of coal seams at depths exceeding 280 m. Investigations of the area were conducted in phases, each designed to delineate seam characteristics more accurately and to indicate with increasing precision the nature of local geological features and the ranges of those coal properties susceptible to variation. The investigational campaign is described phase by phase summarizing evaluation of the area at the conclusion of each phase. Predictions of geological conditions likely to influence engineering planning are contrasted with actual conditions observed during trial mining.

Jan 1, 1974

Cable bolts have been used extensively in the development of the footwall of the Mt Whaleback Mine as a part of the ground improvement program since 1986. High tensile seven wire stress relieved steel strand similar to that used in pre-stressed concrete and grouted in place with sulphate resistant cement have been employed for rock-mass reinforcement.Most of the footwall is developed in Mt McRae Shale which contains a 20 m thick pyritic shale layer 14 m below the ore/waste contact. Due to extensive folding of the footwall rocks, the pyritic shale layer regularly occurs on, or close to the pit slope. Rain water run-off seeping through pyritic shale becomes acidic to the extent where its pH value can be as low as 1.5.

Jan 1, 1992

By Nagai K, Moriyama K

Toyo smelter has been making s veral efforts to reduce and diversify energy for dealing successfully with such :n:;rgy problems as the first and second oil crises. ::,specially it is one of th:; most important subjects to substitute oil by alternative: energy source, because oil is expensive and unstable with respect to its supply. t _'hercfore i was decided to propel tnC ezhstitution of coal *jr oil. in the first place, the supple- mental fuel oil in the reaction shaft was replaced by oil to coal in 1981, and then th, fuel substitution of pulverized coal was achieved in the steam superheater in 1984. 3y these fuel substitutions about 7u,' of the total fuel energy at 2oyo smelter has been replaced by coal. in this paper the fuel substitu- tions at loyo smelter are described in detail.

Jan 1, 1987

By T J. Scanlon

Heavy minerals recovered from recently discovered deposits in the Murray Basin are proving to be somewhat more difficult to process into saleable ilmenite products than ilmenites from existing operations. This is due to the nature of the gangue minerals present, the impurities in the valuable minerals and the size distribution of the mineral assemblages. Ilmenite product quality, in particular, can be adversely affected by any of these factors. Over the past two years the authors have been involved in assessing the potential to manufacture ilmenite products from a variety of mineral sand deposits in the Murray Basin. The steps undertaken to define the potential products and develop suitable flowsheets have evolved in parallel to the exploration efforts, in cooperation with companies undertaking exploration in the Murray Basin. A combination of an understanding of detailed mineralogy, application of magnetic fractionation and modification of magnetic susceptibility of the ilmenites has in all cases, been successful in improving ilmenite product quality. The targeting of particular ilmenites to specific downstream processes for TiO2 pigment manufacture is the most challenging aspect of this development.

Jan 1, 2001

By Tsuchiya N, Takada Y, Okabe K

Alkalis in the blast furnace are removed mainly by the slag, Alkali removal by the slag was studied as a rate process of alkali vapor- ization from the slag flowing through the dropping zone in the blast furnace. The vapor-, ization rate of I:20 from CaO-Si02-A1203 IZ20 slag was- measured under various experimental conditions. An empirical formula for the vaporization rate was obtained as a function of slag basicity, temperature and surface area per unit mass of slag. A simulation model of IC20 vaporization in the dropping zone was evaluated using the rate equation when the true velocity and surface area of the slag was de- termined from a flow dynamic model of counter- current gas-liquid flow through packed beds. The influence of the dynamic conditions of flow, as well as the slag basicity and temperature, on alkali removal by the slag was estimated.

Jan 1, 1980

By J Rapkoch, M Cerna

As long as the tendency of Chilean copper ores continues to feature high levels of impurities, the smelters will tend to produce high-impurity mattes. The most notable impurities include As, Sb, Pb and Zn. Producing high-quality copper with such materials is a major challenge to metallurgical engineers and operators. More investigations into process optimisations and/or alternatives are needed, using both theoretical knowledge and operational skill. Converting of matte in Chile depends on the matte grade using established technologies. Mattes up to 66 per cent Cu, such as those from Outokumpu Flash furnaces, are converted in two stages, while typical Teniente Converter mattes, ranging from 70 - 74 per cent Cu are converted in one blow, directly to copper. In this paper thermodynamic data are used to evaluate possible variations in the use of traditional technologies applied to smelt copper concentrates with high impurity levels. The results of this analysis help to predict the impurity distributions between matte-slag-gas during the slag blow, and between copper-slag-gas during the copper blow. For converting high-impurity white metal, the effectiveness of volatilisation in the slag blow is analysed. In the copper blow, the type and the amount of flux (SiO2, CaO and others) are altered with the aim of optimising impurity distribution to the slag and gas.

Jan 1, 2005

By Allnutt S. L, Carswell J. T, Mutton A. J

The Dugald River Zn-Pb-Ag deposit occurs within the complexly deformed and metamorphosed sediments of the Middle Proterozoic Cloncurry Terrane, Eastern Succession, Mount Isa Inlier. The sedimentary sequence comprises a thick package of variably carbonatic argillitic and siliciclastic sediments of the Corella Formation, Lady Clayre Dolomite and Knapdale Quartzite. A slate and calc-argillite unit locally referred to as the Dugald River Slates is the host to the economically significant deposit. The deformational history of the Dugald River area involved three phases of ductile deformation. The present geometry of the Dugald River Main Lode is recognised as a strike extensive steep westerly dipping tabular sheet, within which a steep north westerly plunging zone of pronounced thickening is evident. This zone is interpreted to have formed during folding via remobilisation of the sulphides into a shoot-like body, the geometry of which was controlled by stretching associated with the folding. Further modification of the shoot and sulphide re-distribution has resulted from late phase transgressive shears. The sulphide mineralisation is characterised by three distinctive sulphide types, laminated, banded and breccia, the distribution of which define two broad zones. The northern zone is a narrow I - 5 m thick stratabound unit comprising finely laminated and banded sulphide mineralisation within a well bedded fine grained argillite sequence. This is part of the Lady Clayre Dolomite sequence and is a predeformational precursor form of mineralisation. The southern zone comprises the thickest development of mineralisation (up to 30 m) characterised by slate-sulphide breccias and veins derived from complex polyphase remobilisation of the sulphide mineralisation. It is this zone which forms a stratabound locally transgressive body within the high strain Dugald River Slates and which contains the main body of economic mineralisation. Sulphide mineralogy comprises sphalerite, pyrite, pyrrhotite, galena and traces of chalcopyrite, pyrargyrite, tetrahedrite, marcasite and arsenopyrite. The present resource for the Dugald River deposit stands at 38 Mt grading 13.0 per cent Zn, 2.1 per cent Pb and 42 g/t AS. The Dugald River Zn-Pb-Ag deposit is regarded as an example of a syndiagenetic stratabound sulphide accumulation which, as the result of polyphase deformation and upper greenschist to middle amphibolite facies metamorphism, has undergone extensive remobilisation and Rccrystallisation.

Jan 1, 1993

Caving is the lowest cost underground mining method, provided that drawpoint spacing, drawpoint size and ore handling facilities are designed to suit the caved material and that the drawpoint horizon can be maintained for the draw life. In the near future several open pit mines that produce in excess of 50 000 tons per day will have to examine the feasibility of converting to low cost, large scale underground operations. Several other large scale, low grade underground operations will experience major changes in their mining environments as large dropdowns are implemented. These changes demand a more realistic approach to mine planning than has occurred in the past, where existing operations have been projected to increased depths with little consideration of the change in mining environment that will occur. As economics force the consideration of underground mining of large, competent orebodies by low cost methods, the role of cave mining will have to be defined. In the past caving has generally been considered for rock masses that cave and fragment readily. The ability to define cavability and fragmentation, the availability of large, robust LHDs, a better understanding of draw control requirements, improved drilling equipment for secondary blasting and reliable cost data have shown that competent orebodies with coarse fragmentation can be exploited by cave mining at a much lower cost than with drill and blast Methods.

Jan 1, 1995

By O&apos, Malley G. B

The properties of bearing metals are of considerable interest to mine engineers, since continuous running of mine and mill machinery is of vital importance. Of the several available types of bearing metal, the low melting point lead or tin base alloys are most generally used in mining plant because of the ease of replacement and the possibility of remelting scrap metal from old bearings. The most valuable property of these "white metals," however, is the plasticity which gives a self-aligning character to the bearings, enablingthem to adjust themselves to inequalities which may exist at the time of fitting, or which may develop during running. The object of the present paper is to explain in general terms the physical structures of white bearing metals, and to point out that constitution rather than composition determines the physical properties of these alloys. The same, indeed, is true of most engineering alloys. In steels, for example, a change in the structure may affect the properties to a far greater extent than a change of chemical composition.Structural changes in steels are produced chiefly by heat treatment. In the case of bearing metals no good purpose is served by heat treatment; the microstructure is determined by the conditions of casting, and striking differences in constitution (and therefore in properties) are encountered in an...

Jan 1, 1932

By Gao K, Wu C, Xia J, Burdett M

X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques have been adopted in this study, to investigate the structure of carbonaceous materials such as graphite, brown coal char as well as coke, in order to explain their dissolution performance during ironmaking. These materials have been selected for study since they are commonly used recarburizers in the metallurgical industry. It was concluded that the crystal structure in a carbonaceous material can have a significant influence on its dissolution into iron melts. The material with the highest degree of ordering, which is graphite, showed the best dissolution performance. In contrast, the material with the lowest degree of ordering, which is brown coal char, showed the worst dissolution performance.

Jan 1, 1996