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By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By J. U. MacEwan

THE basis on which the modern metallurgical industry is operated is the endeavour to attain maximum return in purchasing power for the least expenditure of energy. This has always been the general objective of the industry, as of all industries. In recent years, however, it has received a new emphasis. Today, as never before, increased attention is being directed to the detailed study of plant operations and the application of scientific knowledge and of business principles in order to achieve the maximum efficiency. This new emphasis is the result in large part of the new problems and conditions with which the industry has been confronted, chief among which are the following: (l) Development of new ore-bodies and the treatment of complex ores. (2) Necessity of achieving a greater degree of purity in some of the metals in order to meet the newly discovered demands for some of the industrial metals. (3) Discovery of new markets for many of the metals, either in pure form or in the form of alloys. ( 4) Change in values, absolute or relative, of some of the important metals. (5) Increasing scale of investment in expensive plant and equipment, which makes imperative most efficient utilization if total unit costs are to be kept to a minimum. (6) Increasing scale of operations in some important branches of the industry, which also makes essential maximum efficiency in organization, administration, and operation. The success with which the metallurgical industry has met the problems created by these changing conditions has been due primarily to the following factors: (1) Results of research and experimental work carried on by universities, government laboratories, and many private corporations in the industry itself. (2) Closet study of every detail of plant operation, both from the technological and from the economic point of view, with the object of increasing plant efficiency. (3) Interchange of information and experience amongst the operating companies. It is only by the concerted efforts of numerous investigators and experimenters that the underlying fundamentals of plant operations can be learned. The exchange of results permits their easy assembly and correlation with maximum benefit to the whole industry. Unnecessary duplication of research and experimental work is avoided and the industry as a whole is able to reap the fruits of this work with the maximum of-speed and efficiency. (4) Advances made in recent years in so-called 'scientific management' in industry as a whole and the application of the principles learned to the metallurgical industry. A review of the modern trends in extractive non-ferrous metallurgical processes illustrates the afore-mentioned new conditions and problems, and gives some idea of the methods by which they have been and are being surmounted.

Jan 1, 1937

By Jack G. Hazan

The Critical Path Method is the modern scientific answer for solving the planning and scheduling problems inherent in today's complex projects. With this method, nothing is left to chance. All resources are controlled and kept to the minimum. The various phases are properly planned and strategically determined. Optimum conditions are evaluated for the most economical and fastest way to complete a definite project. The method must be fully understood and implemented with positive data and continuous feedback to obtain the best results. This paper covers the various aspects of the Critical Path Method and mentions some of its applications in the mining and metallurgical fields. T 0 progress to a higher state of human welfare necessarily involves sacrifices. The greatest sacrifice is to relinquish social freedom in favour of economic freedom. In the old days, for example, a cobbler was free to work at whatever time of the day he chose; today, he can't. He is now forced to adapt himself to environment and to work at stand-

Jan 1, 1965

"The Crescent, DM, and Pothook zones are copper-gold porphyry deposits which formed in association with alkalic intrusions of the early Jurassic Iron Mask batholith. The characteristics of the Crescent and DM deposits are nearly identical. Both formed along the contact between the Cherry Creek monzodiorite and Pothook diorite phases of the batholith. Permeable intrusion breccias along the contact concentrated the flow of hydrothermal fluids. Early, pre-ore alteration is represented by pervasive, sulphide-barren potassium metasomatism. The precipitation of copper-gold ore occurred during subsequent fracture-controlled potassic alteration, and is most strongly developed in chlorite-sulphide veins and their alteration envelopes. A central zone of potassic alteration is surrounded by a propylitic, pyritic halo in both deposits. The DM zone is unique among alkalic porphyry deposits in its high abundance of quartz-sulphide veins.The Pothook deposit formed at the westernmost contact of the Iron Mask batholith with enclosing Nicola Group volcanic rocks. Pervasive potassium metasomatism, similar in style to that at Crescent and DM, is associated with intrusion of the Cherry Creek monzonite. Pervasive and fracture-controlled albitic alteration is associated with intrusion of the Sugarloaf diorite and introduced minor copper-gold mineralization. Most of the copper-gold mineralization was introduced during formation of veins and breccia matrices dominated by magnetite/hematite and sulphide. Late-stage chlorite veining may have remobilized or introduced additional gold mineralization.Copper and gold assays in the Crescent deposit are well-correlated and have a nearly constant Cu:Au ratio, suggesting that the metals coprecipitated during a single hydrothermal event. In the Pothook deposit, copper and gold do not correlate closely, lack spatial correspondence, and suggest that transport and/or deposition of the two metals were not identically controlled and that they may have been introduced at different times by separate hydrothermal events."

Jan 1, 1995

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By T. P. Weldum, W. Conger

"These studies address the relationship between mill media sizing and its grinding efficiency. Starting with the results from a review of the literature, the issues of initial media sizing for a new ball milling circuit, and then optimal media sizing for an existing milling operation, were studied. The Functional Performance parameters “Mill Grinding Efficiency” and cumulative “Mill Grinding Rates” from both plant and test-scale equipment were used, and provide valuable new insight into this topic. A plant media sizing diagnostic tool is presented, as are newly developed testing equipment and evaluation methods, and recent case studies.REVIEW OF MEDIA SIZING LITERATURE For a plant metallurgist to answer the question “How can I maximize plant profit by manipulating this grinding circuit variable?” she must know what effect the variable has on grinding circuit efficiency. Despite the significant cost of grinding media and its potential effect on production capacity, the ‘best’ media sizing remains ill-defined for any given ball mill circuit in the industry today. The underlying reasons for this will be discussed. But the importance of this issue drove Metcom and its industrial partners to take on the challenge of how to engineer the ball charge for an existing grinding circuit. In the absence of any proven method, the first step was a review of the literature. Sponsored by Cleveland-Cliffs, Inc., a broad review of the literature was undertaken, producing “The Effect of Media Sizing on Ball Milling Efficiency” (McIvor, 1997). Among hundreds of publications that were reviewed that discuss the topics of media sizing or wear, forty-five were studied in detail. These were grouped into: plant experiences; laboratory and pilot plant investigations; media wear studies; population balance modeling studies; and general papers on ball milling which included the topic of media sizing. The reader is encouraged to refer to that review. The findings remain unchanged, although some relevant papers have been written since (e.g. Staples et al, 1997; Banasi et al, 1999; Orford et al, 2006; LaMarsh, 2015). The main findings of the review were as follows:"

Jan 1, 2018

By T. V. Simpkinson

Abstract A brief history of the electric arc furnace process of steel-making is given. The greater relative importance of this method of steel manufacture to the Canadian steel industry, as compared with its importance in the steel industry of the United States, is shown. The scope of the process is outlined and brief mention is made of the difficulty of obtaining melting stock low in alloy content. The physical chemistry of steel-making is discussed at length in simple terms, with emphasis on oxidation, de-oxidation, and the role of hydrogen. Carbide-type and silicon-type slags are described and the particular usefulness of each is outlined. The importance of various factors in the melting practice is evaluated on the basis of practical experience. Introduction Although electric furnace steels constitute only a small portion of the total weight of steel used in industrial operations, their importance is relatively much greater than is indicated by comparative tonnage figures. Tool steels, which are vital to all industry, are made almost exclusively by the basic electric arc furnace process, as are stainless steels, valve steels, and the higher alloy types of the class usually referred to as "alloy steels'. For many applications where steel other than electric furnace quality is often used, and when first cost is secondary to performance in service, the extra steel cost of electric furnace quality material is usually returned with interest by consistently longer service life. The electric furnace is pre-eminent in the quality alloy steel field because of the control that may be exercised over conditions of oxidation, de-oxidation, and temperature, the fundamental operations in steel making.

Jan 1, 1948

By W. H. MacLean, P. J. MacGeehan, A. J. Bonenfant

"The Norita deposit is an Archean volcanogenic-exhalative Fe-Zn- Cu sulphide accumulation of the distal type, consisting of six overlapping stratiform massive sulphide lenses, interbedded with exhalative cherts and thin pillow basalt flows, which formed down-topographic-slope from a mineralized hydrothermal discharge zone in the Norita rhyolite. The sulphide lenses are of two main types: channel-fill deposits such as the Main Zone and Main Zone West, composed of intricately layered pyrite-sphalerite-chert, which formed by the dynamic down-slope transport and re-deposition of sulphide exhaled from the vent zone; and stratiform lenses such as the Cu-rich A-Zone and A-Zone West, which formed even farther down-slope, in basinal depressions flanking the dome. Although rotated into a vertical position by folding, the sulphide lenses are otherwise essentially undeformed and contain a wide range of preserved primary sedimentary structures.Of prime importance in exploration has been the recognition that the formation of the distal sulphide lenses was controlled by submarine paleotopography, and that it is possible to approximate the sea-floor paleotopography using variations in the thickness and strike extent of the interbedded volcanic rocks. This has proved to be a major and successful exploration tool in the search for further sulphide mineralization in the mine, and offers prospects for use elsewhere in the district."

Jan 1, 1981

By R. G. K. Morrison

As mines grow deeper, the problem of ground control becomes one of increasing importance. The literature on the subject has grown extensively in the past few years, but is still far from conclusive. Detailed and precise observations are on record covering most phases of the problem, and control measures have progressed to the point where, in a large measure, they are effective. The success of methods to date must be attributed to the efforts which have been exerted to reduce convergence of stope walls and to the realization that a regular progression of stope faces approaching longwall has a beneficial effect. This paper attempts to explain the relationship between these two factors and the general problem of ground control. The problem at present lacks the co-ordination of the practical with the scientific outlook, but fortunately as time goes on there are indications that our scientific friends are becoming more interested and more familiar with the practical issues involved. Opinions vary widely regarding the mechanism of the problem and there are several schools of thought, two only of which will be discussed. One associates the incidence of rock-bursts with the stresses built up by a sagging hanging-wall, while the other takes the view that stresses primarily responsible for the sagging hanging-wall are also the cause of rock-bursts. The first group starts its reasoning from the convergence of the walls, probably the most conspicuous feature of deep mining, and works back to the conclusion that rock-bursts are in sorne way due to the breaking up of the sagging layers. The second group begins with the stress zone apparent around excavations at depth and follows mathematical conceptions based on certain assumptions which, in the absolute sense, are known to be inaccurate, but which are justified by the similarity between the conclusions reached and the results obtained in practice. This reasoning is followed to the point where rock-bursts result from the failure, under stress, of rock in situ, quite independent of wall convergence.

Jan 1, 1939

By W. A. Jankola

Teck Cominco Metals Ltd. operates an integrated zinc-lead smelter at Trail, British Columbia, Canada. The zinc circuit comprises three parallel operations: conventional fluid-bed roasting, direct zinc pressure leaching of concentrates and atmospheric leaching of zinc oxide fume recycled from the lead smelter. The products from these three areas are combined in the main leaching plant where they undergo iron purification. Unlike most leaching circuits, the leach process in Trail begins with an acid leach and is followed by a neutral leach. An evaluation was undertaken to determine if the process at Trail could be improved by converting to the conventional neutral leaching process with a subsequent acid leach of the residues. This paper explores the results of these tests and the implications for Trail Operations.

Jan 1, 2006

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By R. E. MacAfee

THERE have been great changes in the design, capacity, and pressure of steam generating units over the past fifty years. If we go back as far as 1890, the plants then existing were largely horizontal return tubular boilers, hand-fired, with the boilers supported on the brick sitting which was com-posed of red brick with, probably, a refractory lining one brick thick in the combustion chamber. About this time, the water tube boiler began to supplant the H.R.T. boiler and, where new plants were being constructed of any size, water tube boilers were largely installed. In those days, say from 1890 to 1905, a 250 h. p. water tube boiler was considered a large unit. These boilers were largely the straight tube type and were set with the first row of boiler tubes three to six feet above the grates. The brick setting was a combination of red brick and fire-brick. The fire-brick lining in the furnace proper was usually 9 in. thick and in the first pass 4 1/2 in., while the rest of the setting was entirely red brick. These units were largely hand-fired and were expected to produce about 100 per cent rating as a maximum. It may be well at this point to define rating, which is the evaporation of one boiler horse power per hour by each ten square feet of heating surface in the boiler. A boiler horse power is the evaporation of 34.5 pounds of steam from and at 212°F. Consequently, a boiler containing 2,000 square feet of heating surface is rated at 200 h. p. and the evaporation at 100 per cent rating is 200 X 34.5, which equals 6,900 pounds of steam per hour from and at 212°F.

Jan 1, 1939

By W. N. Hamilton

"Evaporites abound in the Western Canada sedimentary basin, recurring throughout the stratigraphic column and widely scattered over the basin region. Alberta, situated centrally over the basin, includes many of the evaporites within its borders, but only a few have the right geological conditions to form potential economic deposits of salt or gypsum. These include the Middle Devonian Elk Point Group and related evaporites, Upper Devonian Wabamun Group-Palliser Formation evaporites, and evaporites of the 'Triassic Charlie Lake and Whitehorse formations.Salt deposits underlie almost half of Alberta. The major deposits belong to the Elk Point Group, which includes thick salt units in the Lotsberg, Cold Lake and Prairie Evaporite formations. Another, younger salt deposit in the Wabamun Group has only local distribution. Elk Point salts have a maximum aggregate thickness of 430 m in east-central Alberta. The deposits deepen southwestward across the province, from minimum depths of210 m at Fort McMurray to 1820 m at Edmonton.The thickest, most extensive salt deposits are the upper Lotsberg and Prairie Evaporite salts. Both have excellent development potential. The upper Lotsberg is up to 150 m thick, consists of clear, very coarse crystalline halite with only minor impurities, and has a notable lack of non-salt strata in its succession. Analytical data for the Lotsberg Salt show extraordinary chemical purity. Prairie Evaporite Salt differs lithologically from the Lotsberg in having a significant non-salt component. The deposit is up to 200 m thick and consists of medium crystalline halite, brownish coloured and cloudy as a result of finely dispersed impurities. The main impurities-shale, anhydrite and dolomite-are most prevalent as interbeds in the salt succession, ranging from very thin laminae to beds several metres thick. Although of lesser purity, the Prairie Evaporite Salt is shallower, thicker and more extensive than the Lotsberg and the salt quality is quite acceptable for most industrial uses."

Jan 1, 1982

By Laura Prati

Gold-on-carbon catalysts resulted very active and selective in liquid phase oxidation [1, 2, 3] and during past studies we established that activity is ruled by two factors: particle dimension and gold exposure on the carbon surface [4]. These two parameters are also connected to the nature of activated carbon where the chemical nature of the surface oxygenated groups probably plays an important role [5]. Our studies, focused on the design of an active gold-on-carbon catalyst for liquid phase application, were aimed, operating a fine tuning of all the parameters involved in determining activity, to optimize gold-on-carbon preparation, keeping in mind that gold particle activity increases with decreasing particle size and increasing gold exposure. Gold sol immobilisation represents a versatile methodology in preparing gold catalysts [6]: throughout this work we used as sol stabilizing agent, the N-dodecil-N,N-dimethyl-3-amino-1-propan sulphonate (SB), that provides both sterical and electrostatic stabilisation, a condition we already demonstrated necessary to preserve particle dimension when carbon is used as the support [6]. We generated different gold sols by varying the relative amount of reagents (HAuCl4, SB, NaBH4), the type of alkali and the temperature of the gold precursor reduction. Moreover, as we had recently evidenced that there is also a carbon effect [5], we employed only one active carbon to immobilize the sols.

Oct 1, 2003

By William G. Pariseau

"This contribution describes linkage of stress concentration at the face of tabular excavations, for example, longwall coal mine panels, at a meter scale to surface subsidence at a kilometer scale. Joints are considered according to orientation and spacing at an intermediate scale. A new dual-node, dual-mesh technique based on first principles uses a multi-scale technique that allows for computing whole mine surface subsidence while also allowing for computational details of stress, strain and displacement about main entries and pillars, panel entries, and bleeder entries. The technique is implemented in a conventional continuous Galerkin finite element program that has been in use for many years.The advantage of the dual-node, dual-mesh technique is the capability to do a whole mine analysis that takes into account interaction between all sections of a mine where stress transfer over long distances is often the rule rather than the exception while at the same time allowing for details of stress concentration at working faces where caving is initiated and subsidence begins. The technique, outlined recently during ARMA 2014 (Pariseau, 2014), is applied to an underground coal mine in central Utah where mines are developed from outcrops in steep canyon walls. Meshes contain over 10 million, three-dimensional nodes; runtimes are typically overnight, as a practical matter. Results compare favorably with mine subsidence measurements made over a period of several years and show the capability of this new technique to provide useful design guidance for tabular deposits such as underground coal mines. The role of variability or uncertainty in strata properties is illustrated in element safety factor distributions about development, bleeder and main entries and pillars. Such details are new in this contribution. Energy tracking for mine-induced seismicity is also new. Results show a high correlation between number of events and failed elements and suggest a simple index to mine induced seismicity."

Jan 1, 2015

By H. J. Conolly

The area around Osisko lake, the Horne mine, and the town of Rouyn, in northwestern Quebec, presents a most interesting structural problem. The present discussion is confined to an area around Osisko lake, about six miles long and three miles wide, shown in Figure 1. The writers are particularly indebted to Mr. Thayer Lindsley, of Ventures Limited, who sponsored the investigation and gave permission to publish this paper. Mr. H. L. Roscoe and Mr. Oliver Hall, of Noranda Mines, Limited, gave every possible assistance; and the Noranda geologists, Mr. H. M. Butterfield, Dr. Peter Priee, and Dr. G. G. Suffel, contributed many data and ideas. It is a pleasure to acknowledge also the fuidance of Dr. W. F. James and Dr. B. S. Buffam and the full use made o their maps and criticism. Dr. M. E. Wilson and Dr. A. Lang, of the Geological Survey of Canada, kindly furnished data on the geology in neighbouring fields. Mr. E. Bailey assisted ably in the field, and Mr. H. F. King kindly reviewed the text. Memoir 166 of the Geological Survey of Canada, The Geology and Ore Deposits of the Roztyn-Harricanaw Region, Quebec, by Cooke, James, and Mawdsley, proved an invaluable source of information. STRATIGRAPHY The following stratigraphie sequence is based in part upon the interpretation of the structure as outlined in this paper:

Jan 1, 1936

By Graeme G. Strathdee

"IntroductionThis paper presents an overview of the industry status, describes current potash industry practices at three mills, and summarizes developments that have taken place since the previous review by Banks (1985).The commodity potash is produced in both New Brunswick and Saskatchewan from the evaporite ore sylvinite. This ore is a mixture of co-crystallized halite, NaCl, and sylvite, KCl, and a minor assortment of silica, carbonate, sulphate, and clay minerals. Carnallite, KMgCl3.6H20, is also dispersed throughout the bedded deposits and can affect the recovery of sylvite for fertilizer and industrial uses.Canada continues to be a principal source of supply of agricultural and industrial potash products. Figure 1 shows the sector performance between 1989 and 1997 in the context of the world supply and demand situation as reported by Prud'homme (1997) of Natural Resources Canada.Potash industry output is traditionally measured as the quantity of potassium nutrient and reported as tonnes ofK20. Mineralogically, the principal form of potash produced in Canada is sylvite, KCl, and 1 nutrient tonne K20 corresponds to approximately 1.64 tonnes of sylvite of agricultural grade, about 95% KCI. In 1997, the Canadian industry milling capacity was 13.4 million metric tons (Mt) ofK20 (22 Mt KCl) while the actual production was 9.0 Mt K20 (14.8 Mt KCl). Worldwide milling capacity in 1997 was 35.9 Mt K20 (58.8 Mt KCl) and global consumption was 25.3 Mt K20 (41.6 Mt KCl). Canadian producers can deliver about 35% of the global demand for potash commodities"

Jan 1, 2000

By Taisuke Sakakibara, Shinya Suzuki, Tatsuya Kato, Chiharu Tokoro, Kenichi Muto

Surface complexation using a diffuse layer model were constructed for arsenic (As(V)), zinc (Zn(II)) and silicate (Si(IV)) for aluminum hydroxide in the co-precipitation process. From experimental investigations using isotherms, zeta potential measurement and XRD analysis, it was confirmed that co-precipitation involved not only surface complexation but also surface precipitation. However, surface complexation was major mechanism for As(V), Zn(II) and Si(IV) removal under the target removal level of the Japanese effluent standard. In surface complexation modeling, exchange capacity of aluminum hydroxide was determined from specific surface area obtained from experimental measurement and site density obtained from reference. Surface complexation coefficients were determined by fitting the removal property and sorption isotherm obtained from co-precipitation experiments. These parameters were in agreement with the numerical parameters found by Karamalidis and Dzombak (2010) who reported a database of adsorption equilibrium constants for gibbsite. The surface complexation models constructed in this study were applied to neutralization process of an actual AMD treatment. Our model could successfully represent the pH edges for As(V), Zn(II) and Si(IV) in the neutralization of AMD.

Jan 1, 2015